Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides
Abstract
Tungsten oxide, WO3·nH2O, is a unique layered oxide material that offers enhanced performance in electrochromic and energy storage applications. Herein, we report the formation of a new, never previously synthesized, Na-containing layered tungsten oxide phase, Na0.20WO3·0.81H2O, using a chemical preintercalation approach. The structure and composition of this novel phase were investigated via microscopy, spectroscopy, and diffraction methods. Electrochemical cycling of Na0.20WO3·0.81H2O electrodes revealed initial discharge capacities of 37.43 mAh g-1, 480.8 mAh g-1, and 253.2 mAh g-1 in aqueous H2SO4 cells (potential window of - 0.2–0.8 V vs. Ag/AgCl), non-aqueous Li-ion cells (potential window of 0.1–4.0 V vs. Li/Li+), and non-aqueous Na-ion cells (potential window of 0.1–4.0 V vs. Na/Na+), respectively. Additionally, a reversible, pressure-induced color change from pale yellow to dark brown/black was observed for the Na0.20WO3·0.81H2O sample when it was placed under pressures of 1000 psi or higher. Our results demonstrate the viability of chemical preintercalation synthesis approach to produce new oxide phases with interesting functional properties.
- Authors:
-
[2];
[1]
- Drexel Univ., Philadelphia, PA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Science Foundation (NSF)
- OSTI Identifier:
- 1876288
- Grant/Contract Number:
- AC05-00OR22725; DMR-1609272; DMR-1752623
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Science
- Additional Journal Information:
- Journal Volume: 57; Journal Issue: 16; Journal ID: ISSN 0022-2461
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; chemical preintercalation; tungsten oxide; layered materials; confined water; energy storage
Citation Formats
Clites, Mallory, Blickley, Adam, Cullen, David A., and Pomerantseva, Ekaterina. Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides. United States: N. p., 2022.
Web. doi:10.1007/s10853-022-07190-z.
Clites, Mallory, Blickley, Adam, Cullen, David A., & Pomerantseva, Ekaterina. Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides. United States. https://doi.org/10.1007/s10853-022-07190-z
Clites, Mallory, Blickley, Adam, Cullen, David A., and Pomerantseva, Ekaterina. Tue .
"Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides". United States. https://doi.org/10.1007/s10853-022-07190-z. https://www.osti.gov/servlets/purl/1876288.
@article{osti_1876288,
title = {Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides},
author = {Clites, Mallory and Blickley, Adam and Cullen, David A. and Pomerantseva, Ekaterina},
abstractNote = {Tungsten oxide, WO3·nH2O, is a unique layered oxide material that offers enhanced performance in electrochromic and energy storage applications. Herein, we report the formation of a new, never previously synthesized, Na-containing layered tungsten oxide phase, Na0.20WO3·0.81H2O, using a chemical preintercalation approach. The structure and composition of this novel phase were investigated via microscopy, spectroscopy, and diffraction methods. Electrochemical cycling of Na0.20WO3·0.81H2O electrodes revealed initial discharge capacities of 37.43 mAh g-1, 480.8 mAh g-1, and 253.2 mAh g-1 in aqueous H2SO4 cells (potential window of - 0.2–0.8 V vs. Ag/AgCl), non-aqueous Li-ion cells (potential window of 0.1–4.0 V vs. Li/Li+), and non-aqueous Na-ion cells (potential window of 0.1–4.0 V vs. Na/Na+), respectively. Additionally, a reversible, pressure-induced color change from pale yellow to dark brown/black was observed for the Na0.20WO3·0.81H2O sample when it was placed under pressures of 1000 psi or higher. Our results demonstrate the viability of chemical preintercalation synthesis approach to produce new oxide phases with interesting functional properties.},
doi = {10.1007/s10853-022-07190-z},
journal = {Journal of Materials Science},
number = 16,
volume = 57,
place = {United States},
year = {Tue Apr 19 00:00:00 EDT 2022},
month = {Tue Apr 19 00:00:00 EDT 2022}
}
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