High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes
Abstract
All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of lithium mixed-metal chlorospinels, Li2InxSc0.666-xCl4 (0 ≤ x ≤ 0.666), with high ionic conductivity (up to 2.0 mS cm-1) owing to a highly disordered Li-ion distribution, and low electronic conductivity (4.7 × 10-10 S cm-1), which are implemented for high-performance ASSBs. Owing to the excellent interfacial stability of the SE against uncoated high-voltage cathode materials, ASSBs utilizing LiCoO2 or LiNi0.85Co0.1Mn0.05O2 exhibit superior rate capability and long-term cycling (up to 4.8 V versus Li+/Li) compared to state-of-the-art ASSBs. In particular, the ASSB with LiNi0.85Co0.1Mn0.05O2 exhibits a long life of >3,000 cycles with 80% capacity retention at room temperature. Additionally, high cathode loadings are also demonstrated in ASSBs with stable capacity retention of >4 mAh cm-2 (~190 mAh g-1).
- Authors:
-
[1];
[2];
[3];
[4];
[2];
[1]
- Univ. of Waterloo, ON (Canada). Waterloo Inst. for Nanotechnology; Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)
- Justus Liebig Univ., Giessen (Germany)
- Univ. of Waterloo, ON (Canada). Waterloo Inst. for Nanotechnology
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1869086
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Energy
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 1; Journal ID: ISSN 2058-7546
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; batteries; electronic properties and materials
Citation Formats
Zhou, Laidong, Zuo, Tong-Tong, Kwok, Chun Yuen, Kim, Se Young, Assoud, Abdeljalil, Zhang, Qiang, Janek, Jürgen, and Nazar, Linda F. High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes. United States: N. p., 2022.
Web. doi:10.1038/s41560-021-00952-0.
Zhou, Laidong, Zuo, Tong-Tong, Kwok, Chun Yuen, Kim, Se Young, Assoud, Abdeljalil, Zhang, Qiang, Janek, Jürgen, & Nazar, Linda F. High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes. United States. https://doi.org/10.1038/s41560-021-00952-0
Zhou, Laidong, Zuo, Tong-Tong, Kwok, Chun Yuen, Kim, Se Young, Assoud, Abdeljalil, Zhang, Qiang, Janek, Jürgen, and Nazar, Linda F. Mon .
"High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes". United States. https://doi.org/10.1038/s41560-021-00952-0. https://www.osti.gov/servlets/purl/1869086.
@article{osti_1869086,
title = {High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes},
author = {Zhou, Laidong and Zuo, Tong-Tong and Kwok, Chun Yuen and Kim, Se Young and Assoud, Abdeljalil and Zhang, Qiang and Janek, Jürgen and Nazar, Linda F.},
abstractNote = {All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of lithium mixed-metal chlorospinels, Li2InxSc0.666-xCl4 (0 ≤ x ≤ 0.666), with high ionic conductivity (up to 2.0 mS cm-1) owing to a highly disordered Li-ion distribution, and low electronic conductivity (4.7 × 10-10 S cm-1), which are implemented for high-performance ASSBs. Owing to the excellent interfacial stability of the SE against uncoated high-voltage cathode materials, ASSBs utilizing LiCoO2 or LiNi0.85Co0.1Mn0.05O2 exhibit superior rate capability and long-term cycling (up to 4.8 V versus Li+/Li) compared to state-of-the-art ASSBs. In particular, the ASSB with LiNi0.85Co0.1Mn0.05O2 exhibits a long life of >3,000 cycles with 80% capacity retention at room temperature. Additionally, high cathode loadings are also demonstrated in ASSBs with stable capacity retention of >4 mAh cm-2 (~190 mAh g-1).},
doi = {10.1038/s41560-021-00952-0},
journal = {Nature Energy},
number = 1,
volume = 7,
place = {United States},
year = {Mon Jan 03 00:00:00 EST 2022},
month = {Mon Jan 03 00:00:00 EST 2022}
}
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