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Title: Recent developments on 2D magnetic materials: challenges and opportunities

Abstract

The emergence of two-dimensional (2D) magnetic materials exhibiting strong magnetization at ultrathin limits above room temperature are promising for miniaturization of devices beyond Moore’s law for future energy efficient nano-electronic devices. Here, the current status, different mechanisms for the existence of magnetism, spin current injection and other magnetic properties of monolayer to few-layers of various 2D magnetic materials are reviewed. Some of the promising applications of these materials are spintronics devices such as spin valves, spin tunnel field-effect transistors, and spin filtering magnetic tunnel junctions. Due to the tunable electronic properties of these 2D materials, it's quite interesting to inject the spin current with suitable ferromagnetic contacts. For instance,black phosphorus is a layered material with a small Schottky barrier height capable of injecting spin current. This review includes many recently explored 2D magnetic materials ranging from exfoliated 2D crystals to CVD grown materials from single to several layers, demonstrating tunable layer dependent magnetic properties. We also explore some of the promising theoretical study based on 2D magnetic compounds such as 2D alkali-based chromium chalcogenides, which shows ferromagnetic as well as semiconducting behavior. The layer-dependent magnetic ordering has been observed in layered compounds like 1T-CrTe2, VSe2, CrI3, and Fe3GeTe2, which havemore » great potential for the future applications in magnetic based electronic devices. Finally, we emphasize the challenges, opportunities and future directions of the 2D magnetic materials, where new discoveries might have outstanding impact in transformational scientific breakthroughs towards memory, spintronics, optoelectronics and other multifunctional device applications.« less

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]
  1. Pennsylvania State Univ., University Park, PA (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
  3. Jackson State Univ., Jackson, MS (United States)
Publication Date:
Research Org.:
Louisiana State Univ., Baton Rouge, LA (United States)
Sponsoring Org.:
USDOE Office of Science (SC); National Science Foundation (NSF)
OSTI Identifier:
1867227
Grant/Contract Number:  
SC0002136; DMR-1826886
Resource Type:
Accepted Manuscript
Journal Name:
Emergent Materials
Additional Journal Information:
Journal Volume: 4; Journal Issue: 4; Journal ID: ISSN 2522-5731
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 42 ENGINEERING

Citation Formats

Kumari, Shalini, Pradhan, Dhiren K., Pradhan, Nihar R., and Rack, Philip D. Recent developments on 2D magnetic materials: challenges and opportunities. United States: N. p., 2021. Web. doi:10.1007/s42247-021-00214-5.
Kumari, Shalini, Pradhan, Dhiren K., Pradhan, Nihar R., & Rack, Philip D. Recent developments on 2D magnetic materials: challenges and opportunities. United States. https://doi.org/10.1007/s42247-021-00214-5
Kumari, Shalini, Pradhan, Dhiren K., Pradhan, Nihar R., and Rack, Philip D. Mon . "Recent developments on 2D magnetic materials: challenges and opportunities". United States. https://doi.org/10.1007/s42247-021-00214-5. https://www.osti.gov/servlets/purl/1867227.
@article{osti_1867227,
title = {Recent developments on 2D magnetic materials: challenges and opportunities},
author = {Kumari, Shalini and Pradhan, Dhiren K. and Pradhan, Nihar R. and Rack, Philip D.},
abstractNote = {The emergence of two-dimensional (2D) magnetic materials exhibiting strong magnetization at ultrathin limits above room temperature are promising for miniaturization of devices beyond Moore’s law for future energy efficient nano-electronic devices. Here, the current status, different mechanisms for the existence of magnetism, spin current injection and other magnetic properties of monolayer to few-layers of various 2D magnetic materials are reviewed. Some of the promising applications of these materials are spintronics devices such as spin valves, spin tunnel field-effect transistors, and spin filtering magnetic tunnel junctions. Due to the tunable electronic properties of these 2D materials, it's quite interesting to inject the spin current with suitable ferromagnetic contacts. For instance,black phosphorus is a layered material with a small Schottky barrier height capable of injecting spin current. This review includes many recently explored 2D magnetic materials ranging from exfoliated 2D crystals to CVD grown materials from single to several layers, demonstrating tunable layer dependent magnetic properties. We also explore some of the promising theoretical study based on 2D magnetic compounds such as 2D alkali-based chromium chalcogenides, which shows ferromagnetic as well as semiconducting behavior. The layer-dependent magnetic ordering has been observed in layered compounds like 1T-CrTe2, VSe2, CrI3, and Fe3GeTe2, which have great potential for the future applications in magnetic based electronic devices. Finally, we emphasize the challenges, opportunities and future directions of the 2D magnetic materials, where new discoveries might have outstanding impact in transformational scientific breakthroughs towards memory, spintronics, optoelectronics and other multifunctional device applications.},
doi = {10.1007/s42247-021-00214-5},
journal = {Emergent Materials},
number = 4,
volume = 4,
place = {United States},
year = {Mon Apr 26 00:00:00 EDT 2021},
month = {Mon Apr 26 00:00:00 EDT 2021}
}

Works referenced in this record:

Re-epithelialization and immune cell behaviour in an ex vivo human skin model
journal, January 2020


Spin caloritronics
journal, April 2012

  • Bauer, Gerrit E. W.; Saitoh, Eiji; van Wees, Bart J.
  • Nature Materials, Vol. 11, Issue 5
  • DOI: 10.1038/nmat3301

Spintronics: A Spin-Based Electronics Vision for the Future
journal, November 2001

  • Wolf, S. A.; Awschalom, D. D.; Buhrman, R. A.
  • Science, Vol. 294, Issue 5546, p. 1488-1495
  • DOI: 10.1126/science.1065389

Studies on dielectric, optical, magnetic, magnetic domain structure, and resistance switching characteristics of highly c-axis oriented NZFO thin films
journal, July 2017

  • Pradhan, Dhiren K.; Kumari, Shalini; Li, Linglong
  • Journal of Applied Physics, Vol. 122, Issue 3
  • DOI: 10.1063/1.4994312

Correlation of dielectric, electrical and magnetic properties near the magnetic phase transition temperature of cobalt zinc ferrite
journal, January 2017

  • Pradhan, Dhiren K.; Kumari, Shalini; Puli, Venkata S.
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 1
  • DOI: 10.1039/C6CP06133H

Studies on structural, dielectric, and transport properties of Ni 0.65 Zn 0.35 Fe 2 O 4
journal, June 2014

  • Pradhan, Dhiren K.; Misra, Pankaj; Puli, Venkata S.
  • Journal of Applied Physics, Vol. 115, Issue 24
  • DOI: 10.1063/1.4885420

Magnetoelectric Composites: Applications, Coupling Mechanisms, and Future Directions
journal, October 2020

  • Pradhan, Dhiren K.; Kumari, Shalini; Rack, Philip D.
  • Nanomaterials, Vol. 10, Issue 10
  • DOI: 10.3390/nano10102072

Science and research policy at the end of Moore’s law
journal, January 2018

  • Khan, Hassan N.; Hounshell, David A.; Fuchs, Erica R. H.
  • Nature Electronics, Vol. 1, Issue 1
  • DOI: 10.1038/s41928-017-0005-9

A review on mechanics and mechanical properties of 2D materials—Graphene and beyond
journal, May 2017

  • Akinwande, Deji; Brennan, Christopher J.; Bunch, J. Scott
  • Extreme Mechanics Letters, Vol. 13
  • DOI: 10.1016/j.eml.2017.01.008

Valleytronics in 2D materials
journal, August 2016


2D materials: to graphene and beyond
journal, January 2011

  • Mas-Ballesté, Rubén; Gómez-Navarro, Cristina; Gómez-Herrero, Julio
  • Nanoscale, Vol. 3, Issue 1
  • DOI: 10.1039/C0NR00323A

Metal to Insulator Quantum-Phase Transition in Few-Layered ReS 2
journal, November 2015


An Optoelectronic Switch Based on Intrinsic Dual Schottky Diodes in Ambipolar MoSe 2 Field-Effect Transistors
journal, October 2015

  • Pradhan, Nihar R.; Lu, Zhengguang; Rhodes, Daniel
  • Advanced Electronic Materials, Vol. 1, Issue 11
  • DOI: 10.1002/aelm.201500215

Ambipolar Molybdenum Diselenide Field-Effect Transistors: Field-Effect and Hall Mobilities
journal, July 2014

  • Pradhan, Nihar R.; Rhodes, Daniel; Xin, Yan
  • ACS Nano, Vol. 8, Issue 8, p. 7923-7929
  • DOI: 10.1021/nn501693d

Field-Effect Transistors Based on Few-Layered α-MoTe 2
journal, May 2014

  • Pradhan, Nihar R.; Rhodes, Daniel; Feng, Simin
  • ACS Nano, Vol. 8, Issue 6
  • DOI: 10.1021/nn501013c

Ferromagnetic two-dimensional crystals: Single layers of K 2 CuF 4
journal, November 2013


Prospects and Opportunities of 2D van der Waals Magnetic Systems
journal, March 2020

  • Wang, Meng‐Chien; Huang, Che‐Chun; Cheung, Chi‐Ho
  • Annalen der Physik, Vol. 532, Issue 5
  • DOI: 10.1002/andp.201900452

Ferromagnetic and Half-Metallic FeC 2 Monolayer Containing C 2 Dimers
journal, September 2016

  • Zhao, Tianshan; Zhou, Jian; Wang, Qian
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 39
  • DOI: 10.1021/acsami.6b07482

Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures
journal, May 2018


Van der Waals heterostructures
journal, July 2013

  • Geim, A. K.; Grigorieva, I. V.
  • Nature, Vol. 499, Issue 7459, p. 419-425
  • DOI: 10.1038/nature12385

Strongly enhanced charge-density-wave order in monolayer NbSe2
journal, July 2015

  • Xi, Xiaoxiang; Zhao, Liang; Wang, Zefang
  • Nature Nanotechnology, Vol. 10, Issue 9, p. 765-769
  • DOI: 10.1038/nnano.2015.143

Magnetic Properties of Layered Itinerant Electron Ferromagnet Fe 3 GeTe 2
journal, December 2013

  • Chen, Bin; Yang, JinHu; Wang, HangDong
  • Journal of the Physical Society of Japan, Vol. 82, Issue 12
  • DOI: 10.7566/JPSJ.82.124711

Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals
journal, April 2017


Long range intrinsic ferromagnetism in two dimensional materials and dissipationless future technologies
journal, December 2018

  • Shabbir, Babar; Nadeem, Muhammad; Dai, Zhigao
  • Applied Physics Reviews, Vol. 5, Issue 4
  • DOI: 10.1063/1.5040694

Robust ferromagnetism in monolayer chromium nitride
journal, June 2014

  • Zhang, Shunhong; Li, Yawei; Zhao, Tianshan
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep05241

Structural absorption by barbule microstructures of super black bird of paradise feathers
journal, January 2018


Room-temperature ferromagnetism in the two-dimensional layered Cu 2 MoS 4 nanosheets
journal, January 2017

  • Zhang, Ke; Khan, Rashid; Guo, Hongyan
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 3
  • DOI: 10.1039/C6CP07270D

Recent advances in two-dimensional ferromagnetism: materials synthesis, physical properties and device applications
journal, January 2020

  • Huang, Pu; Zhang, Peng; Xu, Shaogang
  • Nanoscale, Vol. 12, Issue 4
  • DOI: 10.1039/C9NR08890C

Strong room-temperature ferromagnetism in VSe2 monolayers on van der Waals substrates
journal, February 2018


Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit
journal, June 2017

  • Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén
  • Nature, Vol. 546, Issue 7657
  • DOI: 10.1038/nature22391

Topological Magnetic-Spin Textures in Two-Dimensional van der Waals Cr 2 Ge 2 Te 6
journal, September 2019


Intrinsic Ferromagnetic Semiconductors in Two-Dimensional Alkali-Based Chromium Chalcogenides
journal, November 2020

  • Xu, Wangping; Ali, Sajjad; Jin, Yuanjun
  • ACS Applied Electronic Materials, Vol. 2, Issue 12
  • DOI: 10.1021/acsaelm.0c00686

Two-dimensional Janus transition-metal dichalcogenides with intrinsic ferromagnetism and half-metallicity
journal, September 2018


2D Intrinsic Ferromagnets from van der Waals Antiferromagnets
journal, February 2018

  • Miao, Naihua; Xu, Bin; Zhu, Linggang
  • Journal of the American Chemical Society, Vol. 140, Issue 7
  • DOI: 10.1021/jacs.7b12976

Chromium sulfide halide monolayers: intrinsic ferromagnetic semiconductors with large spin polarization and high carrier mobility
journal, January 2018

  • Guo, Yilv; Zhang, Yehui; Yuan, Shijun
  • Nanoscale, Vol. 10, Issue 37
  • DOI: 10.1039/C8NR06368K

Electronic structure and magnetism of transition metal dihalides: Bulk to monolayer
journal, April 2019


Robust intrinsic ferromagnetism and half semiconductivity in stable two-dimensional single-layer chromium trihalides
journal, January 2015

  • Zhang, Wei-Bing; Qu, Qian; Zhu, Peng
  • Journal of Materials Chemistry C, Vol. 3, Issue 48
  • DOI: 10.1039/C5TC02840J

Newtype single-layer magnetic semiconductor in transition-metal dichalcogenides VX2 (X = S, Se and Te)
journal, September 2016

  • Fuh, Huei-Ru; Chang, Ching-Ray; Wang, Yin-Kuo
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep32625

Single-layer metal halides MX 2 (X = Cl, Br, I): stability and tunable magnetism from first principles and Monte Carlo simulations
journal, January 2017

  • Kulish, Vadym V.; Huang, Wei
  • Journal of Materials Chemistry C, Vol. 5, Issue 34
  • DOI: 10.1039/C7TC02664A

Ferromagnetism in MnX2 (X = S, Se) monolayers
journal, January 2014

  • Kan, Min; Adhikari, Subash; Sun, Qiang
  • Physical Chemistry Chemical Physics, Vol. 16, Issue 10
  • DOI: 10.1039/c3cp55146f

Computational discovery of ferromagnetic semiconducting single-layer CrSnTe 3
journal, July 2015


Unique Thickness-Dependent Properties of the van der Waals Interlayer Antiferromagnet MnBi 2 Te 4 Films
journal, March 2019


Strain-tunable magnetic anisotropy in monolayer CrCl 3 , CrBr 3 , and CrI 3
journal, October 2018


Unusual Dirac half-metallicity with intrinsic ferromagnetism in vanadium trihalide monolayers
journal, January 2016

  • He, Junjie; Ma, Shuangying; Lyu, Pengbo
  • Journal of Materials Chemistry C, Vol. 4, Issue 13
  • DOI: 10.1039/C6TC00409A

Prediction of manganese trihalides as two-dimensional Dirac half-metals
journal, March 2018


Room temperature ferromagnetism in ultra-thin van der Waals crystals of 1T-CrTe2
journal, August 2020


Anomalous collapses of Nares Strait ice arches leads to enhanced export of Arctic sea ice
journal, January 2021


Intrinsic Van Der Waals Magnetic Materials from Bulk to the 2D Limit: New Frontiers of Spintronics
journal, May 2019


Low Schottky Barrier Black Phosphorus Field-Effect Devices with Ferromagnetic Tunnel Contacts
journal, January 2015

  • Kamalakar, M. Venkata; Madhushankar, B. N.; Dankert, André
  • Small, Vol. 11, Issue 18
  • DOI: 10.1002/smll.201402900

Black phosphorus field-effect transistors
journal, March 2014


Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility
journal, March 2014

  • Liu, Han; Neal, Adam T.; Zhu, Zhen
  • ACS Nano, Vol. 8, Issue 4
  • DOI: 10.1021/nn501226z

Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus
journal, June 2014


Magnetic susceptibility and electrical properties of VSe2 single crystals
journal, October 1976


Anomalous electrical and magnetic properties of vanadium diselenide
journal, December 1976


Magnetic microstructure and magnetic properties of uniaxial itinerant ferromagnet Fe3GeTe2
journal, August 2016

  • León-Brito, N.; Bauer, E. D.; Ronning, F.
  • Journal of Applied Physics, Vol. 120, Issue 8
  • DOI: 10.1063/1.4961592

Fe3GeTe2 and Ni3GeTe2 – Two New Layered Transition-Metal Compounds: Crystal Structures, HRTEM Investigations, and Magnetic and Electrical Properties
journal, April 2006

  • Deiseroth, Hans-Jörg; Aleksandrov, Krasimir; Reiner, Christof
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 8
  • DOI: 10.1002/ejic.200501020

Magnetic ground state of semiconducting transition-metal trichalcogenide monolayers
journal, June 2015


Tunable Magnetism and Transport Properties in Nitride MXenes
journal, June 2017


New two-dimensional Mn-based MXenes with room-temperature ferromagnetism and half-metallicity
journal, January 2016

  • He, Junjie; Lyu, Pengbo; Nachtigall, Petr
  • Journal of Materials Chemistry C, Vol. 4, Issue 47
  • DOI: 10.1039/C6TC03917K

Room-Temperature Ferromagnetism in Two-Dimensional Fe 2 Si Nanosheet with Enhanced Spin-Polarization Ratio
journal, April 2017


Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness
journal, January 2017


Stability and magnetism of strongly correlated single-layer VS 2
journal, February 2016


Ultrathin nanosheets of CrSiTe 3 : a semiconducting two-dimensional ferromagnetic material
journal, January 2016

  • Lin, Ming-Wei; Zhuang, Houlong L.; Yan, Jiaqiang
  • Journal of Materials Chemistry C, Vol. 4, Issue 2
  • DOI: 10.1039/C5TC03463A

Fe 2 C monolayer: An intrinsic ferromagnetic MXene
journal, July 2017


Novel two-dimensional ferromagnetic semiconductors: Ga-based transition-metal trichalcogenide monolayers
journal, January 2018

  • Yu, Maolin; Liu, Xiaofei; Guo, Wanlin
  • Physical Chemistry Chemical Physics, Vol. 20, Issue 9
  • DOI: 10.1039/C7CP07912E

Robust half-metallic ferromagnetism in Cr 3 C 2 MXene
journal, July 2017


Near-room-temperature Chern insulator and Dirac spin-gapless semiconductor: nickel chloride monolayer
journal, January 2017


Quantum anomalous Hall effect in ferromagnetic transition metal halides
journal, January 2017


Competing antiferromagnetism in a quasi-2D itinerant ferromagnet: Fe 3 GeTe 2
journal, November 2016


Your new travel guide to the flatlands
journal, April 2017


Tunneling Spin Valves Based on Fe 3 GeTe 2 /hBN/Fe 3 GeTe 2 van der Waals Heterostructures
journal, June 2018


Spin tunnel field-effect transistors based on two-dimensional van der Waals heterostructures
journal, April 2019


Electronic analog of the electro‐optic modulator
journal, February 1990

  • Datta, Supriyo; Das, Biswajit
  • Applied Physics Letters, Vol. 56, Issue 7
  • DOI: 10.1063/1.102730

Challenges for semiconductor spintronics
journal, March 2007

  • Awschalom, David D.; Flatté, Michael E.
  • Nature Physics, Vol. 3, Issue 3
  • DOI: 10.1038/nphys551

Toward Barrier Free Contact to Molybdenum Disulfide Using Graphene Electrodes
journal, April 2015

  • Liu, Yuan; Wu, Hao; Cheng, Hung-Chieh
  • Nano Letters, Vol. 15, Issue 5
  • DOI: 10.1021/nl504957p

Air-Stable Transport in Graphene-Contacted, Fully Encapsulated Ultrathin Black Phosphorus-Based Field-Effect Transistors
journal, February 2015


Anomalous Temperature Dependence in Metal–Black Phosphorus Contact
journal, December 2017


Raman and electrical transport properties of few-layered arsenic-doped black phosphorus
journal, January 2019

  • Pradhan, Nihar R.; Garcia, Carlos; Lucking, Michael C.
  • Nanoscale, Vol. 11, Issue 39
  • DOI: 10.1039/C9NR04598H

Multi-terminal transport measurements of MoS2 using a van der Waals heterostructure device platform
journal, April 2015

  • Cui, Xu; Lee, Gwan-Hyoung; Kim, Young Duck
  • Nature Nanotechnology, Vol. 10, Issue 6
  • DOI: 10.1038/nnano.2015.70