Advances in SnO2 for Efficient and Stable n-i-p Perovskite Solar Cells

Park, So Yeon; Zhu, Kai

doi:10.1002/adma.202110438

Title: Advances in SnO₂ for Efficient and Stable n-i-p Perovskite Solar Cells

Journal Article · Mon Mar 07 00:00:00 UTC 2022 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202110438 · OSTI ID:1860238

Park, So Yeon ^[1];

^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)

Perovskite solar cells (PSCs) based on the regular n-i-p device architecture have reached above 25% certified efficiency with continuously reported improvements in recent years. A key common factor for these recent breakthroughs is the development of SnO₂ as an effective electron transport layer in these devices. In this review, we discuss the key advances in SnO₂ development, including various deposition approaches and surface treatment strategies, to enhance the bulk and interface properties of SnO₂ for highly efficient and stable n-i-p PSCs. We also discuss the general materials chemistry associated with SnO₂ along with the corresponding materials challenges and improvement strategies, focusing on defects, intrinsic properties, and impact on device characteristics. Finally, we highlight some SnO2 implementations related to scalable processes and flexible devices, and we also provide our perspective on the future development of efficient and stable large-scale perovskite solar modules.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)

Grant/Contract Number:: AC36-08GO28308; EE0008790

OSTI ID:: 1860238

Report Number(s):: NREL/JA-5900-82290; MainId:83063; UUID:2c92ef7c-e698-49a0-86e5-4b1c99a39122; MainAdminID:64112

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 27 Vol. 34; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (142)

A Simple Way to Simultaneously Release the Interface Stress and Realize the Inner Encapsulation for Highly Efficient and Stable Perovskite Solar Cells Wu, Jionghua; Cui, Yuqi; Yu, Bingchen Advanced Functional Materials, Vol. 29, Issue 49 https://doi.org/10.1002/adfm.201905336	journal	September 2019
Insights into Fullerene Passivation of SnO ₂ Electron Transport Layers in Perovskite Solar Cells Wang, Junke; Datta, Kunal; Weijtens, Christ H. L. Advanced Functional Materials, Vol. 29, Issue 46 https://doi.org/10.1002/adfm.201905883	journal	September 2019
Rubidium Fluoride Modified SnO ₂ for Planar n‐i‐p Perovskite Solar Cells Zhuang, Jing; Mao, Peng; Luan, Yigang Advanced Functional Materials, Vol. 31, Issue 17 https://doi.org/10.1002/adfm.202010385	journal	February 2021
Planar‐Structure Perovskite Solar Cells with Efficiency beyond 21% Jiang, Qi; Chu, Zema; Wang, Pengyang Advanced Materials, Vol. 29, Issue 46 https://doi.org/10.1002/adma.201703852	journal	October 2017
Effective Carrier-Concentration Tuning of SnO ₂ Quantum Dot Electron-Selective Layers for High-Performance Planar Perovskite Solar Cells Yang, Guang; Chen, Cong; Yao, Fang Advanced Materials, Vol. 30, Issue 14 https://doi.org/10.1002/adma.201706023	journal	February 2018
Causes and Solutions of Recombination in Perovskite Solar Cells Chen, Jiangzhao; Park, Nam‐Gyu Advanced Materials, Vol. 31, Issue 47 https://doi.org/10.1002/adma.201803019	journal	September 2018
Novel Molecular Doping Mechanism for n‐Doping of SnO ₂ via Triphenylphosphine Oxide and Its Effect on Perovskite Solar Cells Tu, Bao; Shao, Yangfan; Chen, Wei Advanced Materials, Vol. 31, Issue 15 https://doi.org/10.1002/adma.201805944	journal	January 2019
Defect and Contact Passivation for Perovskite Solar Cells Aydin, Erkan; Bastiani, Michele; Wolf, Stefaan Advanced Materials, Vol. 31, Issue 25 https://doi.org/10.1002/adma.201900428	journal	April 2019
Interfacial Residual Stress Relaxation in Perovskite Solar Cells with Improved Stability Wang, Hao; Zhu, Cheng; Liu, Lang Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201904408	journal	October 2019
Red‐Carbon‐Quantum‐Dot‐Doped SnO ₂ Composite with Enhanced Electron Mobility for Efficient and Stable Perovskite Solar Cells Hui, Wei; Yang, Yingguo; Xu, Quan Advanced Materials, Vol. 32, Issue 4 https://doi.org/10.1002/adma.201906374	journal	December 2019
Solvent Engineering of the Precursor Solution toward Large‐Area Production of Perovskite Solar Cells Chao, Lingfeng; Niu, Tingting; Gao, Weiyin Advanced Materials, Vol. 33, Issue 14 https://doi.org/10.1002/adma.202005410	journal	March 2021
Tin Oxide Electron‐Selective Layers for Efficient, Stable, and Scalable Perovskite Solar Cells Altinkaya, Cesur; Aydin, Erkan; Ugur, Esma Advanced Materials, Vol. 33, Issue 15 https://doi.org/10.1002/adma.202005504	journal	March 2021
Multifunctional Conjugated Ligand Engineering for Stable and Efficient Perovskite Solar Cells Ma, Ke; Atapattu, Harindi R.; Zhao, Qiuchen Advanced Materials, Vol. 33, Issue 32 https://doi.org/10.1002/adma.202100791	journal	July 2021
Simultaneous Interfacial Modification and Crystallization Control by Biguanide Hydrochloride for Stable Perovskite Solar Cells with PCE of 24.4% Xiong, Zhuang; Chen, Xiao; Zhang, Bo Advanced Materials, Vol. 34, Issue 8 https://doi.org/10.1002/adma.202106118	journal	January 2022
A Low-Temperature, Solution Processable Tin Oxide Electron-Transporting Layer Prepared by the Dual-Fuel Combustion Method for Efficient Perovskite Solar Cells Liu, Xiao; Tsai, Kai-Wei; Zhu, Zonglong Advanced Materials Interfaces, Vol. 3, Issue 13 https://doi.org/10.1002/admi.201600122	journal	April 2016
The Role of the Interfaces in Perovskite Solar Cells Shao, Shuyan; Loi, Maria Antonietta Advanced Materials Interfaces, Vol. 7, Issue 1 https://doi.org/10.1002/admi.201901469	journal	November 2019
Manipulating SnO ₂ Growth for Efficient Electron Transport in Perovskite Solar Cells Qian, Zongyao; Chen, Libao; Wang, Jinpei Advanced Materials Interfaces, Vol. 8, Issue 10 https://doi.org/10.1002/admi.202100128	journal	March 2021
Analytical Study of Solution‐Processed Tin Oxide as Electron Transport Layer in Printed Perovskite Solar Cells Rohnacher, Valentina; Ullrich, Florian; Eggers, Helge Advanced Materials Technologies, Vol. 6, Issue 2 https://doi.org/10.1002/admt.202000282	journal	June 2020
MgO Nanoparticle Modified Anode for Highly Efficient SnO ₂ -Based Planar Perovskite Solar Cells Ma, Junjie; Yang, Guang; Qin, Minchao Advanced Science, Vol. 4, Issue 9 https://doi.org/10.1002/advs.201700031	journal	May 2017
Antisolvent‐ and Annealing‐Free Deposition for Highly Stable Efficient Perovskite Solar Cells via Modified ZnO Wang, Ziyu; Zhu, Xuejie; Feng, Jiangshan Advanced Science, Vol. 8, Issue 13 https://doi.org/10.1002/advs.202002860	journal	May 2021
Interfacial Dynamics and Contact Passivation in Perovskite Solar Cells De Bastiani, Michele; Aydin, Erkan; Allen, Thomas Advanced Electronic Materials, Vol. 5, Issue 1 https://doi.org/10.1002/aelm.201800500	journal	November 2018
Effect of Cation Composition on the Mechanical Stability of Perovskite Solar Cells Rolston, Nicholas; Printz, Adam D.; Tracy, Jared M. Advanced Energy Materials, Vol. 8, Issue 9 https://doi.org/10.1002/aenm.201702116	journal	December 2017
Exploring Inorganic Binary Alkaline Halide to Passivate Defects in Low-Temperature-Processed Planar-Structure Hybrid Perovskite Solar Cells Liu, Xu; Zhang, Yuanfang; Shi, Lei Advanced Energy Materials, Vol. 8, Issue 20 https://doi.org/10.1002/aenm.201800138	journal	April 2018
Spontaneous Interface Ion Exchange: Passivating Surface Defects of Perovskite Solar Cells with Enhanced Photovoltage Li, Zhipeng; Wang, Li; Liu, Ranran Advanced Energy Materials, Vol. 9, Issue 38 https://doi.org/10.1002/aenm.201902142	journal	August 2019
Simultaneous Contact and Grain‐Boundary Passivation in Planar Perovskite Solar Cells Using SnO ₂ ‐KCl Composite Electron Transport Layer Zhu, Pengchen; Gu, Shuai; Luo, Xin Advanced Energy Materials, Vol. 10, Issue 3 https://doi.org/10.1002/aenm.201903083	journal	December 2019
Photocatalytic Self-Doped SnO _{2− x} Nanocrystals Drive Visible-Light-Responsive Color Switching Han, Dan; Jiang, Baolai; Feng, Ji Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201702563	journal	June 2017
Coagulated SnO ₂ Colloids for High-Performance Planar Perovskite Solar Cells with Negligible Hysteresis and Improved Stability Liu, Zhongze; Deng, Kaimo; Hu, Jun Angewandte Chemie International Edition, Vol. 58, Issue 33 https://doi.org/10.1002/anie.201904945	journal	July 2019
Stability Comparison of Perovskite Solar Cells Based on Zinc Oxide and Titania on Polymer Substrates Dkhissi, Yasmina; Meyer, Steffen; Chen, Dehong ChemSusChem, Vol. 9, Issue 7 https://doi.org/10.1002/cssc.201501659	journal	February 2016
Synthesis of Soluble and Size‐Controlled SnO ₂ and CeO ₂ Nanocrystals: Application of a General Concept for the Low‐Temperature, Hydrolytic Synthesis of Organically Capped Oxide Nanoparticles Epifani, Mauro; Arbiol, Jordi; Andreu, Teresa European Journal of Inorganic Chemistry, Vol. 2008, Issue 6 https://doi.org/10.1002/ejic.200700946	journal	February 2008
Automated Scalable Spray Coating of SnO ₂ for the Fabrication of Low‐Temperature Perovskite Solar Cells and Modules Taheri, Babak; Calabrò, Emanuele; Matteocci, Fabio Energy Technology, Vol. 8, Issue 5 https://doi.org/10.1002/ente.201901284	journal	February 2020
Solar cell efficiency tables (version 56) Green, Martin A.; Dunlop, Ewan D.; Hohl‐Ebinger, Jochen Progress in Photovoltaics: Research and Applications, Vol. 28, Issue 7 https://doi.org/10.1002/pip.3303	journal	July 2020
SnO ₂ : A Wonderful Electron Transport Layer for Perovskite Solar Cells Jiang, Qi; Zhang, Xingwang; You, Jingbi Small, Vol. 14, Issue 31 https://doi.org/10.1002/smll.201801154	journal	June 2018
Low‐Cost and Highly Efficient Carbon‐Based Perovskite Solar Cells Exhibiting Excellent Long‐Term Operational and UV Stability Arora, Neha; Dar, M. Ibrahim; Akin, Seckin Small, Vol. 15, Issue 49 https://doi.org/10.1002/smll.201904746	journal	October 2019
Stable Large-Area (10 × 10 cm ² ) Printable Mesoscopic Perovskite Module Exceeding 10% Efficiency Hu, Yue; Si, Si; Mei, Anyi Solar RRL, Vol. 1, Issue 2 https://doi.org/10.1002/solr.201600019	journal	January 2017
Dynamic Antisolvent Engineering for Spin Coating of 10 × 10 cm ² Perovskite Solar Module Approaching 18% Bu, Tongle; Liu, Xueping; Li, Jing Solar RRL, Vol. 4, Issue 2 https://doi.org/10.1002/solr.201900263	journal	July 2019
Low‐Temperature Electron Beam Deposition of Zn‐SnO _x for Stable and Flexible Perovskite Solar Cells Song, Zonglong; Bi, Wenbo; Zhuang, Xinmeng Solar RRL, Vol. 4, Issue 2 https://doi.org/10.1002/solr.201900266	journal	August 2019
Electron Transporting Bilayer of SnO ₂ and TiO ₂ Nanocolloid Enables Highly Efficient Planar Perovskite Solar Cells Hu, Manman; Zhang, Luozheng; She, Suyang Solar RRL, Vol. 4, Issue 1 https://doi.org/10.1002/solr.201900331	journal	October 2019
Improving the Stability of Ambient Processed, SnO ₂ ‐Based, Perovskite Solar Cells by the UV‐Treatment of Sub‐Cells Mathiazhagan, Gayathri; Seeber, Aaron; Gengenbach, Thomas Solar RRL, Vol. 4, Issue 9 https://doi.org/10.1002/solr.202000262	journal	July 2020
Interfacial Engineering via Self‐Assembled Thiol Silane for High Efficiency and Stability Perovskite Solar Cells Shi, Yunfan; Zhang, Huijie; Tong, Xiaolan Solar RRL, Vol. 5, Issue 7 https://doi.org/10.1002/solr.202100128	journal	April 2021
Up-Scalable Fabrication of SnO2 with Multifunctional Interface for High Performance Perovskite Solar Modules Tong, Guoqing; Ono, Luis K.; Liu, Yuqiang Nano-Micro Letters, Vol. 13, Issue 1 https://doi.org/10.1007/s40820-021-00675-7	journal	January 2021
Facilitating the formation of SnO2 film via hydroxyl groups for efficient perovskite solar cells Bai, Yuchi; Xing, Dongliang; Luo, Huiming Applied Surface Science, Vol. 552 https://doi.org/10.1016/j.apsusc.2021.149459	journal	June 2021
A synchronous defect passivation strategy for constructing high-performance and stable planar perovskite solar cells Sun, Yansen; Pang, Zhenyu; Quan, Yingnan Chemical Engineering Journal, Vol. 413 https://doi.org/10.1016/j.cej.2020.127387	journal	June 2021
Batch chemical bath deposition of large-area SnO2 film with mercaptosuccinic acid decoration for homogenized and efficient perovskite solar cells Zhang, Jibo; Bai, Cong; Dong, Yao Chemical Engineering Journal, Vol. 425 https://doi.org/10.1016/j.cej.2021.131444	journal	December 2021
Introduction of LiCl into SnO2 electron transport layer for efficient planar perovskite solar cells Huang, Yinyi; Li, Shina; Wu, Chaorong Chemical Physics Letters, Vol. 745 https://doi.org/10.1016/j.cplett.2020.137220	journal	April 2020
An Interlayer with Strong Pb-Cl Bond Delivers Ultraviolet-Filter-Free, Efficient, and Photostable Perovskite Solar Cells Hang, Pengjie; Xie, Jiangsheng; Li, Ge iScience, Vol. 21 https://doi.org/10.1016/j.isci.2019.10.021	journal	November 2019
Toward Highly Thermal Stable Perovskite Solar Cells by Rational Design of Interfacial Layer Yang, Weitao; Zhong, Danming; Shi, Minmin iScience, Vol. 22 https://doi.org/10.1016/j.isci.2019.11.007	journal	December 2019
SnO2-based electron transporting layer materials for perovskite solar cells: A review of recent progress Chen, Yichuan; Meng, Qi; Zhang, Linrui Journal of Energy Chemistry, Vol. 35 https://doi.org/10.1016/j.jechem.2018.11.011	journal	August 2019
Energy level engineering of charge selective contact and halide perovskite by modulating band offset: Mechanistic insights Raoui, Yassine; Ez-Zahraouy, Hamid; Kazim, Samrana Journal of Energy Chemistry, Vol. 54 https://doi.org/10.1016/j.jechem.2020.06.030	journal	March 2021
Flexible Perovskite Solar Cells Jung, Hyun Suk; Han, Gill Sang; Park, Nam-Gyu Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.07.023	journal	August 2019
Influence of Charge Transport Layers on Capacitance Measured in Halide Perovskite Solar Cells Awni, Rasha A.; Song, Zhaoning; Chen, Cong Joule, Vol. 4, Issue 3 https://doi.org/10.1016/j.joule.2020.01.012	journal	March 2020
Solvothermal synthesis of highly crystalline SnO2 nanoparticles for flexible perovskite solar cells application Xie, Haixia; Yin, Xingtian; Chen, Peng Materials Letters, Vol. 234 https://doi.org/10.1016/j.matlet.2018.09.117	journal	January 2019
Low-temperature solution-processed Li-doped SnO2 as an effective electron transporting layer for high-performance flexible and wearable perovskite solar cells Park, Minwoo; Kim, Jae-Yup; Son, Hae Jung Nano Energy, Vol. 26 https://doi.org/10.1016/j.nanoen.2016.04.060	journal	August 2016
Mesoporous SnO2 electron selective contact enables UV-stable perovskite solar cells Roose, Bart; Baena, Juan-Pablo Correa; Gödel, Karl C. Nano Energy, Vol. 30 https://doi.org/10.1016/j.nanoen.2016.10.055	journal	December 2016
Energetically favored formation of SnO2 nanocrystals as electron transfer layer in perovskite solar cells with high efficiency exceeding 19% Dong, Qingshun; Shi, Yantao; Zhang, Chunyang Nano Energy, Vol. 40 https://doi.org/10.1016/j.nanoen.2017.08.041	journal	October 2017
Highly efficient perovskite solar cells for light harvesting under indoor illumination via solution processed SnO2/MgO composite electron transport layers Dagar, Janardan; Castro-Hermosa, Sergio; Lucarelli, Giulia Nano Energy, Vol. 49 https://doi.org/10.1016/j.nanoen.2018.04.027	journal	July 2018
Effect of the conduction band offset on interfacial recombination behavior of the planar perovskite solar cells Ding, Chao; Zhang, Yaohong; Liu, Feng Nano Energy, Vol. 53 https://doi.org/10.1016/j.nanoen.2018.08.031	journal	November 2018
Benefits of fullerene/SnO 2 bilayers as electron transport layer for efficient planar perovskite solar cells Chen, Yun; Xu, Cong; Xiong, Jian Organic Electronics, Vol. 58 https://doi.org/10.1016/j.orgel.2018.03.041	journal	July 2018
Vacuum thermal-evaporated SnO2 as uniform electron transport layer and novel management of perovskite intermediates for efficient and stable planar perovskite solar cells Guo, Yuxiao; Yin, Xingtian; Liu, Jie Organic Electronics, Vol. 65 https://doi.org/10.1016/j.orgel.2018.11.021	journal	February 2019
SnO2: A comprehensive review on structures and gas sensors Das, Soumen; Jayaraman, V. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.06.003	journal	October 2014
SnO2/ZnO as double electron transport layer for halide perovskite solar cells Khan, Ubaid; Iqbal, Tahseen; Khan, Mehreen Solar Energy, Vol. 223 https://doi.org/10.1016/j.solener.2021.05.059	journal	July 2021
High-Efficiency Perovskite Solar Cells Kim, Jin Young; Lee, Jin-Wook; Jung, Hyun Suk Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.0c00107	journal	July 2020
Insight into Perovskite Solar Cells Based on SnO ₂ Compact Electron-Selective Layer Dong, Qingshun; Shi, Yantao; Wang, Kai The Journal of Physical Chemistry C, Vol. 119, Issue 19 https://doi.org/10.1021/acs.jpcc.5b00541	journal	May 2015
Ultrathin Buffer Layers of SnO ₂ by Atomic Layer Deposition: Perfect Blocking Function and Thermal Stability Kavan, Ladislav; Steier, Ludmilla; Grätzel, Michael The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b09965	journal	December 2016
Metal Oxide-Induced Instability and Its Mitigation in Halide Perovskite Solar Cells Thampy, Sampreetha; Xu, Weijie; Hsu, Julia W. P. The Journal of Physical Chemistry Letters, Vol. 12, Issue 35 https://doi.org/10.1021/acs.jpclett.1c02371	journal	August 2021
Simultaneous Ligand Exchange Fabrication of Flexible Perovskite Solar Cells using Newly Synthesized Uniform Tin Oxide Quantum Dots Park, So Yeon; Baek, Mi Yeon; Ju, Yeonkyeon The Journal of Physical Chemistry Letters, Vol. 9, Issue 18 https://doi.org/10.1021/acs.jpclett.8b02408	journal	August 2018
Tailoring the Interfacial Chemical Interaction for High-Efficiency Perovskite Solar Cells Zuo, Lijian; Chen, Qi; De Marco, Nicholas Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04015	journal	December 2016
SnO ₂ /TiO ₂ Electron Transporting Bilayers: A Route to Light Stable Perovskite Solar Cells Abuhelaiqa, Mousa; Shibayama, Naoyuki; Gao, Xiao-Xin ACS Applied Energy Materials, Vol. 4, Issue 4 https://doi.org/10.1021/acsaem.0c03185	journal	March 2021
Laser-Scribing Optimization for Sprayed SnO ₂ -Based Perovskite Solar Modules on Flexible Plastic Substrates Taheri, Babak; De Rossi, Francesca; Lucarelli, Giulia ACS Applied Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1021/acsaem.1c00140	journal	May 2021
Numerical Simulation of Planar Heterojunction Perovskite Solar Cells Based on SnO ₂ Electron Transport Layer Zhao, Peng; Lin, Zhenhua; Wang, Jiaping ACS Applied Energy Materials, Vol. 2, Issue 6 https://doi.org/10.1021/acsaem.9b00755	journal	May 2019
Amorphous Tin Oxide as a Low-Temperature-Processed Electron-Transport Layer for Organic and Hybrid Perovskite Solar Cells Barbé, Jérémy; Tietze, Max L.; Neophytou, Marios ACS Applied Materials & Interfaces, Vol. 9, Issue 13 https://doi.org/10.1021/acsami.6b13675	journal	March 2017
UV-Sintered Low-Temperature Solution-Processed SnO ₂ as Robust Electron Transport Layer for Efficient Planar Heterojunction Perovskite Solar Cells Huang, Like; Sun, Xiaoxiang; Li, Chang ACS Applied Materials & Interfaces, Vol. 9, Issue 26 https://doi.org/10.1021/acsami.7b04392	journal	June 2017
Low-Temperature Plasma-Assisted Atomic-Layer-Deposited SnO ₂ as an Electron Transport Layer in Planar Perovskite Solar Cells Kuang, Yinghuan; Zardetto, Valerio; van Gils, Roderick ACS Applied Materials & Interfaces, Vol. 10, Issue 36 https://doi.org/10.1021/acsami.8b09515	journal	August 2018
Enhancing Efficiency and Stability of Perovskite Solar Cells via a Self-Assembled Dopamine Interfacial Layer Hou, Meihui; Zhang, Haijuan; Wang, Ze ACS Applied Materials & Interfaces, Vol. 10, Issue 36 https://doi.org/10.1021/acsami.8b10332	journal	August 2018
Graphene-Modified Tin Dioxide for Efficient Planar Perovskite Solar Cells with Enhanced Electron Extraction and Reduced Hysteresis Zhu, Menghua; Liu, Weiwei; Ke, Weijun ACS Applied Materials & Interfaces, Vol. 11, Issue 1 https://doi.org/10.1021/acsami.8b15665	journal	December 2018
Low-Temperature Plasma-Enhanced Atomic Layer Deposition of Tin(IV) Oxide from a Functionalized Alkyl Precursor: Fabrication and Evaluation of SnO ₂ -Based Thin-Film Transistor Devices Mai, Lukas; Zanders, David; Subaşı, Ersoy ACS Applied Materials & Interfaces, Vol. 11, Issue 3 https://doi.org/10.1021/acsami.8b16443	journal	January 2019
Altered Stability and Degradation Pathway of CH ₃ NH ₃ PbI ₃ in Contact with Metal Oxide Thampy, Sampreetha; Zhang, Boya; Hong, Ki-Ha ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00041	journal	March 2020
Bifunctional Surface Engineering on SnO ₂ Reduces Energy Loss in Perovskite Solar Cells Jung, Eui Hyuk; Chen, Bin; Bertens, Koen ACS Energy Letters, Vol. 5, Issue 9 https://doi.org/10.1021/acsenergylett.0c01566	journal	August 2020
Copper Thiocyanate Inorganic Hole-Transporting Material for High-Efficiency Perovskite Solar Cells Madhavan, Vinod E.; Zimmermann, Iwan; Roldán-Carmona, Cristina ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00501	journal	November 2016
Water Vapor Treatment of Low-Temperature Deposited SnO ₂ Electron Selective Layers for Efficient Flexible Perovskite Solar Cells Wang, Changlei; Guan, Lei; Zhao, Dewei ACS Energy Letters, Vol. 2, Issue 9 https://doi.org/10.1021/acsenergylett.7b00644	journal	August 2017
Novel Plasma-Assisted Low-Temperature-Processed SnO ₂ Thin Films for Efficient Flexible Perovskite Photovoltaics Subbiah, Anand S.; Mathews, Nripan; Mhaisalkar, Subodh ACS Energy Letters, Vol. 3, Issue 7 https://doi.org/10.1021/acsenergylett.8b00692	journal	May 2018
Spin-Coating Process for 10 cm × 10 cm Perovskite Solar Modules Enabled by Self-Assembly of SnO ₂ Nanocolloids Han, Gill Sang; Kim, Jio; Bae, Seunghwan ACS Energy Letters, Vol. 4, Issue 8 https://doi.org/10.1021/acsenergylett.9b00953	journal	June 2019
Precursor Engineering for a Large-Area Perovskite Solar Cell with >19% Efficiency Lee, Do-Kyoung; Jeong, Dong-Nyuk; Ahn, Tae Kyu ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01735	journal	September 2019
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Low-Temperature Solution-Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells Ke, Weijun; Fang, Guojia; Liu, Qin Journal of the American Chemical Society, Vol. 137, Issue 21 https://doi.org/10.1021/jacs.5b01994	journal	May 2015
Characterization of the High-Pressure Structures and Phase Transformations in SnO ₂ . A Density Functional Theory Study Gracia, L.; Beltrán, A.; Andrés, J. The Journal of Physical Chemistry B, Vol. 111, Issue 23 https://doi.org/10.1021/jp067443v	journal	June 2007
Band Gap Engineering of SnO ₂ by Epitaxial Strain: Experimental and Theoretical Investigations Zhou, Wei; Liu, Yanyu; Yang, Yuzhe The Journal of Physical Chemistry C, Vol. 118, Issue 12 https://doi.org/10.1021/jp500546r	journal	March 2014
Anomalous Hysteresis in Perovskite Solar Cells Snaith, Henry J.; Abate, Antonio; Ball, James M. The Journal of Physical Chemistry Letters, Vol. 5, Issue 9 https://doi.org/10.1021/jz500113x	journal	April 2014
Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies Bach, U.; Lupo, D.; Comte, P. Nature, Vol. 395, Issue 6702 https://doi.org/10.1038/26936	journal	October 1998
Efficient planar heterojunction perovskite solar cells by vapour deposition Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J. Nature, Vol. 501, Issue 7467, p. 395-398 https://doi.org/10.1038/nature12509	journal	September 2013
Maximizing and stabilizing luminescence from halide perovskites with potassium passivation Abdi-Jalebi, Mojtaba; Andaji-Garmaroudi, Zahra; Cacovich, Stefania Nature, Vol. 555, Issue 7697 https://doi.org/10.1038/nature25989	journal	March 2018
Enhanced electron extraction using SnO2 for high-efficiency planar-structure HC(NH2)2PbI3-based perovskite solar cells Jiang, Qi; Zhang, Liuqi; Wang, Haolin Nature Energy, Vol. 2, Issue 1 https://doi.org/10.1038/nenergy.2016.177	journal	November 2016
High efficiency planar-type perovskite solar cells with negligible hysteresis using EDTA-complexed SnO2 Yang, Dong; Yang, Ruixia; Wang, Kai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05760-x	journal	August 2018
Universal passivation strategy to slot-die printed SnO2 for hysteresis-free efficient flexible perovskite solar module Bu, Tongle; Li, Jing; Zheng, Fei Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07099-9	journal	November 2018
Strain engineering in perovskite solar cells and its impacts on carrier dynamics Zhu, Cheng; Niu, Xiuxiu; Fu, Yuhao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08507-4	journal	February 2019
Interpenetrating interfaces for efficient perovskite solar cells with high operational stability and mechanical robustness Dong, Qingshun; Zhu, Chao; Chen, Min Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21292-3	journal	February 2021
Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S. Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0067-y	journal	January 2018
Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth Jang, Yeoun-Woo; Lee, Seungmin; Yeom, Kyung Mun Nature Energy, Vol. 6, Issue 1 https://doi.org/10.1038/s41560-020-00749-7	journal	January 2021
A holistic approach to interface stabilization for efficient perovskite solar modules with over 2,000-hour operational stability Liu, Zonghao; Qiu, Longbin; Ono, Luis K. Nature Energy, Vol. 5, Issue 8 https://doi.org/10.1038/s41560-020-0653-2	journal	July 2020
Surface passivation of perovskite film for efficient solar cells Jiang, Qi; Zhao, Yang; Zhang, Xingwang Nature Photonics, Vol. 13, Issue 7 https://doi.org/10.1038/s41566-019-0398-2	journal	April 2019
Efficient perovskite solar cells via improved carrier management Yoo, Jason J.; Seo, Gabkyung; Chua, Matthew R. Nature, Vol. 590, Issue 7847 https://doi.org/10.1038/s41586-021-03285-w	journal	February 2021
Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes Min, Hanul; Lee, Do Yoon; Kim, Junu Nature, Vol. 598, Issue 7881 https://doi.org/10.1038/s41586-021-03964-8	journal	October 2021
Effect of Unsaturated Sn Atoms on Gas-Sensing Property in Hydrogenated SnO2 Nanocrystals and Sensing Mechanism Yuan, Y.; Wang, Y.; Wang, M. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-00891-5	journal	April 2017
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Highly efficient planar perovskite solar cells through band alignment engineering Correa Baena, Juan Pablo; Steier, Ludmilla; Tress, Wolfgang Energy & Environmental Science, Vol. 8, Issue 10 https://doi.org/10.1039/C5EE02608C	journal	January 2015
Enhanced UV-light stability of planar heterojunction perovskite solar cells with caesium bromide interface modification Li, Wenzhe; Zhang, Wei; Van Reenen, Stephan Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE03522H	journal	January 2016
Low-temperature SnO ₂ -based electron selective contact for efficient and stable perovskite solar cells Song, Jiaxing; Zheng, Enqiang; Bian, Ji Journal of Materials Chemistry A, Vol. 3, Issue 20 https://doi.org/10.1039/C5TA01207D	journal	January 2015
Effects of annealing temperature of tin oxide electron selective layers on the performance of perovskite solar cells Ke, Weijun; Zhao, Dewei; Cimaroli, Alexander J. Journal of Materials Chemistry A, Vol. 3, Issue 47 https://doi.org/10.1039/C5TA06574G	journal	January 2015
Exploring and controlling intrinsic defect formation in SnO ₂ thin films Porte, Yoann; Maller, Robert; Faber, Hendrik Journal of Materials Chemistry C, Vol. 4, Issue 4 https://doi.org/10.1039/C5TC03520A	journal	January 2016
Band gap and work function tailoring of SnO ₂ for improved transparent conducting ability in photovoltaics Ganose, Alex M.; Scanlon, David O. Journal of Materials Chemistry C, Vol. 4, Issue 7 https://doi.org/10.1039/C5TC04089B	journal	January 2016
Hysteresis-free low-temperature-processed planar perovskite solar cells with 19.1% efficiency Yoon, Heetae; Kang, Seong Min; Lee, Jong-Kwon Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE01037G	journal	January 2016
Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide Anaraki, Elham Halvani; Kermanpur, Ahmad; Steier, Ludmilla Energy & Environmental Science, Vol. 9, Issue 10 https://doi.org/10.1039/C6EE02390H	journal	January 2016
Low-temperature plasma-enhanced atomic layer deposition of tin oxide electron selective layers for highly efficient planar perovskite solar cells Wang, Changlei; Zhao, Dewei; Grice, Corey R. Journal of Materials Chemistry A, Vol. 4, Issue 31 https://doi.org/10.1039/C6TA04503K	journal	January 2016
Interface engineering in planar perovskite solar cells: energy level alignment, perovskite morphology control and high performance achievement Yang, Guang; Wang, Changlei; Lei, Hongwei Journal of Materials Chemistry A, Vol. 5, Issue 4 https://doi.org/10.1039/C6TA08783C	journal	January 2017
Identifying and suppressing interfacial recombination to achieve high open-circuit voltage in perovskite solar cells Correa-Baena, Juan-Pablo; Tress, Wolfgang; Domanski, Konrad Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/C7EE00421D	journal	January 2017
New-generation integrated devices based on dye-sensitized and perovskite solar cells Yun, Sining; Qin, Yong; Uhl, Alexander R. Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C7EE03165C	journal	January 2018
Solution-processed SnO ₂ thin film for a hysteresis-free planar perovskite solar cell with a power conversion efficiency of 19.2% Jung, Kwang-Ho; Seo, Ja-Young; Lee, Seonhee Journal of Materials Chemistry A, Vol. 5, Issue 47 https://doi.org/10.1039/C7TA08040A	journal	January 2017
Fullerene derivative anchored SnO ₂ for high-performance perovskite solar cells Liu, Kuan; Chen, Shuang; Wu, Jionghua Energy & Environmental Science, Vol. 11, Issue 12 https://doi.org/10.1039/C8EE02172D	journal	January 2018
Thermally stable, planar hybrid perovskite solar cells with high efficiency Choi, Kyoungwon; Lee, Junwoo; Kim, Hong Il Energy & Environmental Science, Vol. 11, Issue 11 https://doi.org/10.1039/C8EE02242A	journal	January 2018
Scalable slot-die coating of high performance perovskite solar cells Whitaker, James B.; Kim, Dong Hoe; Larson, Bryon W. Sustainable Energy & Fuels, Vol. 2, Issue 11 https://doi.org/10.1039/C8SE00368H	journal	January 2018
La-doped BaSnO ₃ electron transport layer for perovskite solar cells Myung, Chang Woo; Lee, Geunsik; Kim, Kwang S. Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/C8TA08764D	journal	January 2018
Highly efficient Zn ₂ SnO ₄ perovskite solar cells through band alignment engineering Dou, Jie; Zhang, Ying; Wang, Qiong Chemical Communications, Vol. 55, Issue 97 https://doi.org/10.1039/C9CC07398A	journal	January 2019
The impact of energy alignment and interfacial recombination on the internal and external open-circuit voltage of perovskite solar cells Stolterfoht, Martin; Caprioglio, Pietro; Wolff, Christian M. Energy & Environmental Science, Vol. 12, Issue 9 https://doi.org/10.1039/C9EE02020A	journal	January 2019
Increasing efficiency of perovskite solar cells using low concentrating photovoltaic systems Baig, Hasan; Kanda, Hiroyuki; Asiri, Abdullah M. Sustainable Energy & Fuels, Vol. 4, Issue 2 https://doi.org/10.1039/C9SE00550A	journal	January 2020
Reduced methylammonium triple-cation Rb _0.05 (FAPbI ₃ ) _0.95 (MAPbBr ₃ ) _0.05 perovskite solar cells based on a TiO ₂ /SnO ₂ bilayer electron transport layer approaching a stabilized 21% efficiency: the role of antisolvents Mali, Sawanta S.; Patil, Jyoti V.; Arandiyan, Hamidreza Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/C9TA05422G	journal	January 2019
Interfacial engineering of a ZnO electron transporting layer using self-assembled monolayers for high performance and stable perovskite solar cells Han, Jinyoung; Kwon, Hannah; Kim, Eunah Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/C9TA12750J	journal	January 2020
High-efficiency perovskite solar cells with poly(vinylpyrrolidone)-doped SnO ₂ as an electron transport layer Zhang, Meiying; Wu, Fengmin; Chi, Dan Materials Advances, Vol. 1, Issue 4 https://doi.org/10.1039/D0MA00028K	journal	January 2020
Chlorine-doped SnO ₂ hydrophobic surfaces for large grain perovskite solar cells Gong, Wenxiao; Guo, Heng; Zhang, Haiyan Journal of Materials Chemistry C, Vol. 8, Issue 33 https://doi.org/10.1039/D0TC00515K	journal	January 2020
Alkali chloride doped SnO ₂ electron-transporting layers for boosting charge transfer and passivating defects in all-inorganic CsPbBr ₃ perovskite solar cells Xie, Guixiang; Lu, Xiaochun; Duan, Jialong Journal of Materials Chemistry A, Vol. 9, Issue 26 https://doi.org/10.1039/D1TA02672K	journal	January 2021
Advances in SnO ₂ -based perovskite solar cells: from preparation to photovoltaic applications Wu, Pengfei; Wang, Shirong; Li, Xianggao Journal of Materials Chemistry A, Vol. 9, Issue 35 https://doi.org/10.1039/D1TA04130D	journal	January 2021
KF-Doped SnO ₂ as an electron transport layer for efficient inorganic CsPbI ₂ Br perovskite solar cells with enhanced open-circuit voltages Zhang, Senya; Gu, Hao; Chen, Shan-Ci Journal of Materials Chemistry C, Vol. 9, Issue 12 https://doi.org/10.1039/D1TC00277E	journal	January 2021
Acidic and basic properties of hydroxylated metal oxide surfaces Boehm, H. P. Discussions of the Faraday Society, Vol. 52 https://doi.org/10.1039/df9715200264	journal	January 1971
Quasi-Fermi level splitting and sub-bandgap absorptivity from semiconductor photoluminescence Katahara, John K.; Hillhouse, Hugh W. Journal of Applied Physics, Vol. 116, Issue 17 https://doi.org/10.1063/1.4898346	journal	November 2014
Origins of Coexistence of Conductivity and Transparency in SnO 2 Kılıç, Çetin; Zunger, Alex Physical Review Letters, Vol. 88, Issue 9 https://doi.org/10.1103/PhysRevLett.88.095501	journal	February 2002
Charge Carrier Separation in Solar Cells Wurfel, Uli; Cuevas, Andres; Wurfel, Peter IEEE Journal of Photovoltaics, Vol. 5, Issue 1 https://doi.org/10.1109/JPHOTOV.2014.2363550	journal	January 2015
Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells Zuo, Lijian; Guo, Hexia; deQuilettes, Dane W. Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1700106	journal	August 2017
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Interfacial toughening with self-assembled monolayers enhances perovskite solar cell reliability Dai, Zhenghong; Yadavalli, Srinivas K.; Chen, Min Science, Vol. 372, Issue 6542 https://doi.org/10.1126/science.abf5602	journal	May 2021
Conformal quantum dot–SnO ₂ layers as electron transporters for efficient perovskite solar cells Kim, Minjin; Jeong, Jaeki; Lu, Haizhou Science, Vol. 375, Issue 6578 https://doi.org/10.1126/science.abh1885	journal	January 2022
Physical Properties of SnO[sub 2] Materials Jarzebski, Z. M. Journal of The Electrochemical Society, Vol. 123, Issue 7 https://doi.org/10.1149/1.2133010	journal	January 1976
Dye-Sensitized Solid-State Heterojunction Solar Cells Grätzel, Michael MRS Bulletin, Vol. 30, Issue 1 https://doi.org/10.1557/mrs2005.4	journal	January 2005
Effect of Oxygen Source on the Various Properties of SnO2 Thin Films Deposited by Plasma-Enhanced Atomic Layer Deposition Won, Jong Hyeon; Han, Seong Ho; Park, Bo Keun Coatings, Vol. 10, Issue 7 https://doi.org/10.3390/coatings10070692	journal	July 2020
Morphological Effects in SnO2 Chemiresistors for Ethanol Detection: A Review in Terms of Central Performances and Outliers Ponzoni, Andrea Sensors, Vol. 21, Issue 1 https://doi.org/10.3390/s21010029	journal	December 2020

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Title: Advances in SnO₂ for Efficient and Stable n-i-p Perovskite Solar Cells