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Title: Polymorph Selection in Zeolite Synthesis Occurs after Nucleation

Journal Article · · Journal of Physical Chemistry Letters

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0020201
OSTI ID:
1857737
Journal Information:
Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 4 Vol. 13; ISSN 1948-7185
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (66)

Towards the Rational Design of Efficient Organic Structure-Directing Agents for Zeolite Synthesis journal October 2013
Regulating Nonclassical Pathways of Silicalite‐1 Crystallization through Controlled Evolution of Amorphous Precursors journal September 2019
Observing a Zeolite Nucleus (Subcrystal) with a Uniform Framework Structure and Its Oriented Attachment without Single‐Molecule Addition journal June 2021
Issues in the Synthesis of Crystalline Molecular Sieves: Towards the Crystallization of Low Framework-Density Structures journal March 2004
Optimization of crystal growth of hierarchical porosity ZSM‐5 zeolite based on coal fly ash “waste utilization” journal September 2020
Thermodynamic properties of quartz, cristobalite and amorphous SiO2: drop calorimetry measurements between 1000 and 1800 K and a review from 0 to 2000 K journal December 1982
Thermodynamic properties of silicalite SiO2 journal June 1987
Characterization of siliceous MFI-type zeolites containing tetra-, tri-, and dipropylammonium fluoride species journal September 1989
The structure-controlling role of organic templates for the synthesis of porosils in the systems SiO2/template/H2O journal January 1992
In situ observation of silicalite nucleation and growth: A light-scattering study journal March 1994
Role of homogeneous nucleation in the formation of primary zeolite particles journal June 1995
An X-ray absorption fine structure study of amorphous precursors of a gallium silicate zeolite journal August 2001
Anomalous crystallization mechanism in the synthesis of nanocrystalline ZSM-5 journal September 2000
UV Raman spectroscopic study on the synthesis mechanism of zeolite X journal February 2001
Kinetics of nucleation and growth of zeolite LTA from clear solution by in situ and ex situ XRPD journal July 2002
Guest/host relationships in zeolite synthesis: ring-substituted piperidines and the remarkable adamantane mimicry by 1-azonio spiro [5.5] undecanes journal June 1998
Zeolites upon heating: Factors governing their thermal stability and structural changes journal September 2006
The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism journal July 2005
Amorphous microporous molecular sieves with different pore dimensions and topologies: Synthesis, characterization and catalytic activity journal February 2006
A contribution to understanding the mechanism of crystallization of silicalite-1 in heterogeneous systems (hydrogels) journal July 2009
Effect of water on topological constraints in silica glass journal February 2019
Coarsening and Spinodal Decomposition of Zeolite Linde Type A Precursor Gels Aged at Low Temperatures journal May 2016
Assembly and Evolution of Amorphous Precursors in Zeolite L Crystallization journal February 2016
Diverse Physical States of Amorphous Precursors in Zeolite Synthesis journal June 2018
Coarse-Grained Model for the Hydrothermal Synthesis of Zeolites journal November 2021
Structural Evolution of Amorphous Precursors toward Crystalline Zeolites Visualized by an in Situ X-ray Pair Distribution Function Approach journal October 2019
Discovering Relationships between OSDAs and Zeolites through Data Mining and Generative Neural Networks journal April 2021
Zeolite and molecular sieve synthesis journal July 1992
Mechanism of Structure Direction in the Synthesis of Pure-Silica Zeolites. 2. Hydrophobic Hydration and Structural Specificity journal August 1995
In situ Small-Angle and Wide-Angle X-ray Scattering Investigation on Nucleation and Crystal Growth of Nanosized Zeolite A journal April 2007
Kinetic and Thermodynamic Studies of Silica Nanoparticle Dissolution journal August 2007
Thermochemistry of Microporous and Mesoporous Materials journal September 2009
Mechanism of Structure Direction in the Synthesis of Si-ZSM-5: An Investigation by Intermolecular 1H-29Si CP MAS NMR journal April 1994
A Structural Resolution Cryo-TEM Study of the Early Stages of MFI Growth journal December 2008
Reaction Kinetics Regulated Formation of Short-Range Order in an Amorphous Matrix during Zeolite Crystallization journal July 2021
Structure-Directing Behaviors of Tetraethylammonium Cations toward Zeolite Beta Revealed by the Evolution of Aluminosilicate Species Formed during the Crystallization Process journal November 2015
Comment on “Identification of Precursor Species in the Formation of MFI Zeolite in the TPAOH−TEOS−H 2 O System” journal February 2002
Thermodynamics of Pure-Silica Molecular Sieve Synthesis journal April 2002
Structure of the Silica Phase Extracted from Silica/(TPA)OH Solutions Containing Nanoparticles journal September 2003
Local Order of Amorphous Zeolite Precursors from 29 Si{ 1 H} CPMAS and 27 Al and 23 Na MQMAS NMR and Evidence for the Nature of Medium-Range Order from Neutron Diffraction journal June 2004
Spontaneous Formation of Silica Nanoparticles in Basic Solutions of Small Tetraalkylammonium Cations journal July 2004
Evolution of Self-Assembled Silica−Tetrapropylammonium Nanoparticles at Elevated Temperatures journal July 2005
Elucidation of Medium-Range Structure in a Dry Gel-Forming *BEA-Type Zeolite journal June 2007
Aggregative Growth of Silicalite-1 journal April 2007
Investigation of Silicalite-1 Crystallization Using Attenuated Total Reflection/Fourier Transform Infrared Spectroscopy journal October 2007
MFI Fingerprint: How Pentasil-Induced IR Bands Shift during Zeolite Nanogrowth journal May 2008
Characterization of Nanosized Material Extracted from Clear Suspensions for MFI Zeolite Synthesis
  • Ravishankar, Raman; Kirschhock, Christine E. A.; Knops-Gerrits, Peter-Paul
  • The Journal of Physical Chemistry B, Vol. 103, Issue 24 https://doi.org/10.1021/jp990296z
journal June 1999
Identification of Precursor Species in the Formation of MFI Zeolite in the TPAOH−TEOS−H 2 O System journal June 1999
Mechanism of Transformation of Precursors into Nanoslabs in the Early Stages of MFI and MEL Zeolite Formation from TPAOH−TEOS−H 2 O and TBAOH−TEOS−H 2 O Mixtures journal June 1999
Aggregation Mechanism of Nanoslabs with Zeolite MFI-Type Structure journal December 1999
Physical Basis for the Formation and Stability of Silica Nanoparticles in Basic Solutions of Monovalent Cations journal September 2005
Silicalite, a new hydrophobic crystalline silica molecular sieve journal February 1978
Supramolecular self-assembled molecules as organic directing agent for synthesis of zeolites journal September 2004
Mechanistic principles of nanoparticle evolution to zeolite crystals journal April 2006
A new approach to the determination of atomic-architecture of amorphous zeolite precursors by high-energy X-ray diffraction technique journal January 2006
Tailoring the physicochemical properties of zeolite catalysts journal January 2014
Synthesis of new zeolite structures journal January 2015
In situ observation of homogeneous nucleation of nanosized zeolite A journal January 2006
Evidence for X-ray-amorphous zeolites journal January 1981
Spontaneous nucleation and growth of pure silica zeolite-? free of connectivity defects journal January 1996
Formation of Crystal Nuclei in Liquid Metals journal October 1950
Possible resolution of the Kauzmann paradox in supercooled liquids journal July 2003
Capturing Ultrasmall EMT Zeolite from Template-Free Systems journal December 2011
A priori control of zeolite phase competition and intergrowth with high-throughput simulations journal October 2021
Nucleation Rates of Zeolite A Crystals from Clear Aluminosilicate Solutions. journal January 2003
Nucleation of open framework materials: Navigating the voids journal May 2016

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