Gated Molecular Diffusion at Liquid–Liquid Interfaces

Li, Lianshun; Sun, Huilou; Li, Mingwei; Yang, Yang; Russell, Thomas P.; Shi, Shaowei

doi:10.1002/anie.202105500

Title: Gated Molecular Diffusion at Liquid–Liquid Interfaces

Abstract

Abstract The jamming of nanoparticle surfactants (NPSs) at liquid–liquid interface imparts attractive properties to the interfacial assemblies and enables the structuring of liquids. Herein, we report photoresponsive supramolecular microcapsules with jammed NPS assemblies at the oil‐water interface, taking advantage of host–guest molecular recognition. The permeability of the colloidal membrane can be effectively manipulated by switching the NPSs from a jammed state to an unjammed state with a photo trigger, leading to a controlled molecular diffusion and release, affording a versatile platform for the construction of next generation smart microcapsule systems.

Authors:

Li, Lianshun ^[1]; Sun, Huilou ^[1]; Li, Mingwei ^[1]; Yang, Yang ^[1];

^[2];

^[1]

Beijing Univ. of Chemical Technology, Beijing (China). Beijing Advanced Innovation Center for Soft Matter Science and Engineering
Univ. of Massachusetts, Amherst, MA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Wed Jun 30 00:00:00 EDT 2021

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC); US Army Research Office (ARO)

OSTI Identifier:: 1839018

Alternate Identifier(s):: OSTI ID: 1997278

Grant/Contract Number:: AC02-05CH11231; 51903011; W911NF-17-1-0003; AC02-05-CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition); Journal Volume: 60; Journal Issue: 32; Journal ID: ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Li, Lianshun, Sun, Huilou, Li, Mingwei, Yang, Yang, Russell, Thomas P., and Shi, Shaowei. Gated Molecular Diffusion at Liquid–Liquid Interfaces.  United States: N. p., 2021. 
Web.  doi:10.1002/anie.202105500.

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                    Li, Lianshun, Sun, Huilou, Li, Mingwei, Yang, Yang, Russell, Thomas P., & Shi, Shaowei. Gated Molecular Diffusion at Liquid–Liquid Interfaces.  United States.  https://doi.org/10.1002/anie.202105500

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                    Li, Lianshun, Sun, Huilou, Li, Mingwei, Yang, Yang, Russell, Thomas P., and Shi, Shaowei. Wed .  
"Gated Molecular Diffusion at Liquid–Liquid Interfaces".  United States.  https://doi.org/10.1002/anie.202105500.  https://www.osti.gov/servlets/purl/1839018.

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@article{osti_1839018,

  title        = {Gated Molecular Diffusion at Liquid–Liquid Interfaces},

  author       = {Li, Lianshun and Sun, Huilou and Li, Mingwei and Yang, Yang and Russell, Thomas P. and Shi, Shaowei},

  abstractNote = {Abstract The jamming of nanoparticle surfactants (NPSs) at liquid–liquid interface imparts attractive properties to the interfacial assemblies and enables the structuring of liquids. Herein, we report photoresponsive supramolecular microcapsules with jammed NPS assemblies at the oil‐water interface, taking advantage of host–guest molecular recognition. The permeability of the colloidal membrane can be effectively manipulated by switching the NPSs from a jammed state to an unjammed state with a photo trigger, leading to a controlled molecular diffusion and release, affording a versatile platform for the construction of next generation smart microcapsule systems.},

  doi          = {10.1002/anie.202105500},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 32,

  volume       = 60,

  place        = {United States},

  year         = {Wed Jun 30 00:00:00 EDT 2021},

  month        = {Wed Jun 30 00:00:00 EDT 2021}

}

Copy to clipboard

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Light-enabled reversible self-assembly and tunable optical properties of stable hairy nanoparticles
journal, January 2018

Adaptive Structured Pickering Emulsions and Porous Materials Based on Cellulose Nanocrystal Surfactants
journal, September 2018

Self-assembly of nanoparticles at interfaces
journal, January 2007

Self-Assembly and Cross-Linking of Bionanoparticles at Liquid-Liquid Interfaces
journal, April 2005

Crosslinked Capsules of Quantum Dots by Interfacial Assembly and Ligand Crosslinking
journal, September 2005

Synthese von Nano-/Mikrostrukturen an fluiden Grenzflächen
journal, December 2010