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Title: Iron redox analysis of silicate-based minerals and glasses using synchrotron X-ray absorption and laboratory X-ray emission spectroscopy

Journal Article · · Journal of Non-Crystalline Solids

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
SC0012704
OSTI ID:
1838401
Journal Information:
Journal of Non-Crystalline Solids, Journal Name: Journal of Non-Crystalline Solids Journal Issue: C Vol. 577; ISSN 0022-3093
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English

References (78)

In-situ X-Ray Absorption Near Edge Structure Spectroscopy of a Solid Catalyst using a Laboratory-Based Set-up journal January 2019
Valence‐to‐core X‐ray emission spectroscopy of titanium compounds using energy dispersive detectors journal July 2020
The effect of dissolved water on the oxidation state of iron in natural silicate liquids journal June 1995
The compressibility of silicate liquids containing Fe2O3 and the effect of composition, temperature, oxygen fugacity and pressure on their redox states journal July 1991
High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: implications for the oxidation state of the upper mantle journal March 1991
X-ray K-edge absorption spectra of Fe minerals and model compounds: Near-edge structure journal January 1983
The effect of oxidation state on the viscosity of melts in the system Na2O-FeO-Fe2O3-SiO2 journal February 1987
Upper mantle oxidation state: Ferric iron contents of Iherzolite spinels by 57Fe Mössbauer spectroscopy and resultant oxygen fugacities journal June 1989
Ferric-ferrous equilibria in Na2O-FeO-Fe2O3-SiO2 melts: Effects of analytical techniques on derived partial molar volumes journal September 1989
X-ray microprobe analysis of iron oxidation states in silicates and oxides using X-ray absorption near edge structure (XANES) journal December 1994
Oxidation state of iron in silicate glasses and melts: a thermochemical model journal April 2001
High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information journal January 2005
Modern X-ray spectroscopy: XAS and XES in the laboratory journal November 2020
Determination of the iron oxidation state in basaltic glasses using XANES at the K-edge journal July 2005
Micro-Raman determination of iron redox state in dry natural glasses: Application to peralkaline rhyolites and basalts journal February 2009
High-precision determination of iron oxidation state in silicate glasses using XANES journal November 2009
Effect of oxygen fugacity on the coordination and oxidation state of iron in alkali bearing silicate melts journal September 2015
Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses journal March 2017
NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations journal September 2010
Robust optic alignment in a tilt-free implementation of the Rowland circle spectrometer journal February 2017
Structural engineering of hydrated vanadium oxide cathode by K+ incorporation for high-capacity and long-cycling aqueous zinc ion batteries journal August 2020
Spin state of ferric iron in MgSiO3 perovskite and its effect on elastic properties journal January 2010
Separate zones of sulfate and sulfide release from subducted mafic oceanic crust journal October 2015
A re-assessment of the oxidation state of iron in MORB glasses journal February 2018
The Fe3+/ΣFe ratios of MORB glasses and their implications for mantle melting journal February 2005
The effect of redox state on the local structural environment of iron in silicate glasses: a combined XAFS spectroscopy, molecular dynamics, and bond valence study journal October 2004
Diluted Fe 3+ in silicate glasses: Structural effects of Fe-redox state and matrix composition. An optical absorption and X-band/Q-band EPR study journal November 2015
Fe-oxidation state in alkali-trisilicate glasses - A Raman spectroscopic study journal September 2017
Laboratory-scale X-ray absorption spectroscopy approach for actinide research: Experiment at the uranium L3-edge journal August 2018
Fast and reversible zinc ion intercalation in Al-ion modified hydrated vanadate journal April 2020
Determination of Hexavalent Chromium Fractions in Plastics Using Laboratory-Based, High-Resolution X-ray Emission Spectroscopy journal April 2018
Factors Defining the Intercalation Electrochemistry of CaFe 2 O 4 -Type Manganese Oxides journal August 2020
Aminophosphines as Versatile Precursors for the Synthesis of Metal Phosphide Nanocrystals journal July 2018
Probing Surface Defects of InP Quantum Dots Using Phosphorus Kα and Kβ X-ray Emission Spectroscopy journal August 2018
Spectroscopic and Quantum Chemical Investigation of Benzene-1,2-dithiolate-Coordinated Diiron Complexes with Relevance to Dinitrogen Activation journal March 2019
Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex journal November 2019
Probing Sulfur Chemical and Electronic Structure with Experimental Observation and Quantitative Theoretical Prediction of Kα and Valence-to-Core Kβ X-ray Emission Spectroscopy journal June 2020
Sulfur Speciation in Biochars by Very High Resolution Benchtop Kα X-ray Emission Spectroscopy journal May 2018
Tailoring Energy and Power Density through Controlling the Concentration of Oxygen Vacancies in V 2 O 5 /PEDOT Nanocable-Based Supercapacitors journal April 2019
Probing Valence Orbital Composition with Iron Kβ X-ray Emission Spectroscopy journal July 2010
Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido Complex journal June 2017
Probing the 3d Spin Momentum with X-ray Emission Spectroscopy:  The Case of Molecular-Spin Transitions journal June 2006
Valence and spin states of iron are invisible in Earth’s lower mantle journal March 2018
Emergent superconductivity in an iron-based honeycomb lattice initiated by pressure-driven spin-crossover journal May 2018
Oxidising agents in sub-arc mantle melts link slab devolatilisation and arc magmas journal August 2018
Valence-to-core X-ray emission spectroscopy of vanadium oxide and lithiated vanadyl phosphate materials journal January 2020
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal January 2005
The oxidation state of iron determined by Fe K-edge XANES—application to iron gall ink in historical manuscripts journal January 2009
High resolution x‐ray absorption spectroscopy with absolute energy calibration for the determination of absorption edge energies journal March 1996
Electronic State of Iron in Hemoglobin, Myoglobin, and Derivatives, as Inferred from X‐Ray Fluorescence Spectra journal March 1972
Corresponding Orbitals and the Nonorthogonality Problem in Molecular Quantum Mechanics journal September 1967
Maximum Overlap Atomic and Molecular Orbitals journal July 1961
A novel von Hamos spectrometer for efficient X-ray emission spectroscopy in the laboratory journal May 2014
A laboratory-based hard x-ray monochromator for high-resolution x-ray emission spectroscopy and x-ray absorption near edge structure measurements journal November 2014
Laboratory von Hámos X-ray spectroscopy for routine sample characterization journal October 2016
A laboratory spectrometer for high throughput X-ray emission spectroscopy in catalysis research journal November 2018
An improved laboratory-based x-ray absorption fine structure and x-ray emission spectrometer for analytical applications in materials chemistry research journal February 2019
Johann-type laboratory-scale x-ray absorption spectrometer with versatile detection modes journal March 2019
NWChem: Past, present, and future journal May 2020
Effective intermediate-spin iron in O 2 -transporting heme proteins journal July 2017
Hard x-ray emission spectroscopy: a powerful tool for the characterization of magnetic semiconductors journal January 2014
Observation of iron spin-states using tabletop x-ray emission spectroscopy and microcalorimeter sensors journal December 2015
Charge-transfer effect on the linewidth of Fe K α x-ray fluorescence spectra journal October 1994
Benchmark results and theoretical treatments for valence-to-core x-ray emission spectroscopy in transition metal compounds journal September 2017
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
Identification of the iron oxidation state and coordination geometry in iron oxide- and zeolite-based catalysts using pre-edge XAS analysis journal February 2015
A mail-in and user facility for X-ray absorption near-edge structure: the CEI-XANES laboratory X-ray spectrometer at the University of Washington journal October 2019
Resonant X-ray spectroscopy to study K absorption pre-edges in 3d transition metal compounds journal March 2009
Laboratory-Based X-ray Absorption Spectroscopy on a Working Pouch Cell Battery at Industrially-Relevant Charging Rates journal January 2019
Wet Chemical and UV-Vis Spectrometric Iron Speciation in Quenched Low and Intermediate Level Nuclear Waste Glasses journal January 2015
Fe (super 3+) distribution in oxidized olivine; a synchrotron micro-XANES study journal December 1998
Oxidation state and coordination of Fe in minerals: An Fe K- XANES spectroscopic study journal May 2001
XANES calibrations for the oxidation state of iron in a silicate glass journal July 2003
A Mössbauer study of the oxidation state of Fe in silicate melts journal November 2004
Accurate predictions of iron redox state in silicate glasses: A multivariate approach using X-ray absorption spectroscopy journal March 2016
Determination of the oxidation state of iron in Mid-Ocean Ridge basalt glasses by Raman spectroscopy journal July 2019
A feasibility investigation of speciation by Fe K-edge XANES using a laboratory X-ray absorption spectrometer journal April 2020
Effect of Batch Melting Temperature and Raw Material on Iron Redox State in Sodium Silicate Glasses journal March 2011