Internal conversion of the anionic GFP chromophore: in and out of the I-twisted S 1 /S 0 conical intersection seam

List, Nanna H.; Jones, Chey M.; Martínez, Todd J.

doi:10.1039/D1SC05849E

Title: Internal conversion of the anionic GFP chromophore: in and out of the I-twisted S ₁ /S ₀ conical intersection seam

Journal Article · 04 January 2022 · Chemical Science

DOI: https://doi.org/10.1039/D1SC05849E · OSTI ID:1834650

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Department of Chemistry and the PULSE Institute, Stanford University, Stanford, CA 94305, USA, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA

The Z – E photoisomerization quantum yield of the HBDI ⁻ chromophore is a result of early, non-statistical dynamics around a less reactive I-twisted intersection and later, statistical behavior around the more reactive, near-enantiomeric counterpart.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); Villum Foundation

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1834650

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 2 Vol. 13; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Internal conversion of the anionic GFP chromophore: in and out of the I-twisted S ₁ /S ₀ conical intersection seam