Superconductivity in a quintuple-layer square-planar nickelate

Pan, Grace A.; Segedin, Dan Ferenc; LaBollita, Harrison; Song, Qi; Nica, Emilian M.; Goodge, Berit H.; Pierce, Andrew T.; Doyle, Spencer; Novakov, Steve; Carrizales, Denisse Córdova; N’Diaye, Alpha T.; Shafer, Padraic; Paik, Hanjong; Heron, John T.; Mason, Jarad A.; Yacoby, Amir; Kourkoutis, Lena F.; Erten, Onur; Brooks, Charles M.; Botana, Antia S.; Mundy, Julia A.

doi:10.1038/s41563-021-01142-9

Title: Superconductivity in a quintuple-layer square-planar nickelate

Abstract

Since the discovery of high-temperature superconductivity in the copper oxide materials, there have been sustained efforts to both understand the origins of this phase and discover new cuprate-like superconducting materials. One prime materials platform has been the rare-earth nickelates and indeed superconductivity was recently discovered in the doped compound Nd_0.8Sr_0.2NiO₂. Undoped NdNiO₂ belongs to a series of layered square-planar nickelates with chemical formula Nd_n+1Ni_nO_2n+2 and is known as the 'infinite-layer' (n=∞) nickelate. Furthermore, we report the synthesis of the quintuple-layer (n=5) member of this series, Nd₆Ni₅O₁₂, in which optimal cuprate-like electron filling (d^8.8) is achieved without chemical doping. We observe a superconducting transition beginning at ~13 K. Electronic structure calculations, in tandem with magnetoresistive and spectroscopic measurements, suggest that Nd₆Ni₅O₁₂ interpolates between cuprate-like and infinite-layer nickelate-like behavior. In engineering a distinct superconducting nickelate, we identify the square-planar nickelates as a new family of superconductors which can be tuned via both doping and dimensionality.

Authors:

^[1]; Segedin, Dan Ferenc ^[1]; LaBollita, Harrison ^[2]; Song, Qi ^[1]; Nica, Emilian M. ^[2];

^[3]; Pierce, Andrew T. ^[1]; Doyle, Spencer ^[1];

^[4]; Carrizales, Denisse Córdova ^[1];

^[5];

^[5]; Paik, Hanjong ^[3];

^[4];

^[1]; Yacoby, Amir ^[1];

^[3]; Erten, Onur ^[2]; Brooks, Charles M. ^[1];

^[2] more »

Harvard Univ., Cambridge, MA (United States)
Arizona State Univ., Tempe, AZ (United States)
Cornell Univ., Ithaca, NY (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Mon Nov 22 00:00:00 EST 2021

Research Org.:: Harvard Univ., Cambridge, MA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

OSTI Identifier:: 1831815

Alternate Identifier(s):: OSTI ID: 1866840; OSTI ID: 1868055; OSTI ID: 1963160

Grant/Contract Number:: SC0021925; AC02-05CH11231; SC0020128

Resource Type:: Accepted Manuscript

Journal Name:: Nature Materials

Additional Journal Information:: Journal Volume: 21; Journal ID: ISSN 1476-1122

Publisher:: Springer Nature - Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Pan, Grace A., Segedin, Dan Ferenc, LaBollita, Harrison, Song, Qi, Nica, Emilian M., Goodge, Berit H., Pierce, Andrew T., Doyle, Spencer, Novakov, Steve, Carrizales, Denisse Córdova, N’Diaye, Alpha T., Shafer, Padraic, Paik, Hanjong, Heron, John T., Mason, Jarad A., Yacoby, Amir, Kourkoutis, Lena F., Erten, Onur, Brooks, Charles M., Botana, Antia S., and Mundy, Julia A. Superconductivity in a quintuple-layer square-planar nickelate.  United States: N. p., 2021. 
Web.  doi:10.1038/s41563-021-01142-9.

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                    Pan, Grace A., Segedin, Dan Ferenc, LaBollita, Harrison, Song, Qi, Nica, Emilian M., Goodge, Berit H., Pierce, Andrew T., Doyle, Spencer, Novakov, Steve, Carrizales, Denisse Córdova, N’Diaye, Alpha T., Shafer, Padraic, Paik, Hanjong, Heron, John T., Mason, Jarad A., Yacoby, Amir, Kourkoutis, Lena F., Erten, Onur, Brooks, Charles M., Botana, Antia S., & Mundy, Julia A. Superconductivity in a quintuple-layer square-planar nickelate.  United States.  https://doi.org/10.1038/s41563-021-01142-9

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                    Pan, Grace A., Segedin, Dan Ferenc, LaBollita, Harrison, Song, Qi, Nica, Emilian M., Goodge, Berit H., Pierce, Andrew T., Doyle, Spencer, Novakov, Steve, Carrizales, Denisse Córdova, N’Diaye, Alpha T., Shafer, Padraic, Paik, Hanjong, Heron, John T., Mason, Jarad A., Yacoby, Amir, Kourkoutis, Lena F., Erten, Onur, Brooks, Charles M., Botana, Antia S., and Mundy, Julia A. Mon .  
"Superconductivity in a quintuple-layer square-planar nickelate".  United States.  https://doi.org/10.1038/s41563-021-01142-9.  https://www.osti.gov/servlets/purl/1831815.

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@article{osti_1831815,

  title        = {Superconductivity in a quintuple-layer square-planar nickelate},

  author       = {Pan, Grace A. and Segedin, Dan Ferenc and LaBollita, Harrison and Song, Qi and Nica, Emilian M. and Goodge, Berit H. and Pierce, Andrew T. and Doyle, Spencer and Novakov, Steve and Carrizales, Denisse Córdova and N’Diaye, Alpha T. and Shafer, Padraic and Paik, Hanjong and Heron, John T. and Mason, Jarad A. and Yacoby, Amir and Kourkoutis, Lena F. and Erten, Onur and Brooks, Charles M. and Botana, Antia S. and Mundy, Julia A.},

  abstractNote = {Since the discovery of high-temperature superconductivity in the copper oxide materials, there have been sustained efforts to both understand the origins of this phase and discover new cuprate-like superconducting materials. One prime materials platform has been the rare-earth nickelates and indeed superconductivity was recently discovered in the doped compound Nd0.8Sr0.2NiO2. Undoped NdNiO2 belongs to a series of layered square-planar nickelates with chemical formula Ndn+1NinO2n+2 and is known as the 'infinite-layer' (n=∞) nickelate. Furthermore, we report the synthesis of the quintuple-layer (n=5) member of this series, Nd6Ni5O12, in which optimal cuprate-like electron filling (d8.8) is achieved without chemical doping. We observe a superconducting transition beginning at ~13 K. Electronic structure calculations, in tandem with magnetoresistive and spectroscopic measurements, suggest that Nd6Ni5O12 interpolates between cuprate-like and infinite-layer nickelate-like behavior. In engineering a distinct superconducting nickelate, we identify the square-planar nickelates as a new family of superconductors which can be tuned via both doping and dimensionality.},

  doi          = {10.1038/s41563-021-01142-9},

  journal      = {Nature Materials},

  number       = ,

  volume       = 21,

  place        = {United States},

  year         = {Mon Nov 22 00:00:00 EST 2021},

  month        = {Mon Nov 22 00:00:00 EST 2021}

}

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DOI: 10.3762/bjnano.10.199

Electronic properties of several two dimensional halides from ab initio calculations
journal, January 2019

Barhoumi, Mohamed; Abboud, Ali; Debbichi, Lamjed
Beilstein Journal of Nanotechnology, Vol. 10
DOI: 10.3762/bjnano.10.82

Adsorption of iron tetraphenylporphyrin on (111) surfaces of coinage metals: a density functional theory study
journal, November 2017

Tang, Hao; Tarrat, Nathalie; Langlais, Véronique
Beilstein Journal of Nanotechnology, Vol. 8
DOI: 10.3762/bjnano.8.248

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Title: Superconductivity in a quintuple-layer square-planar nickelate

Abstract

Citation Formats

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Single particle tunneling spectrum of superconducting Nd1-xSrxNiO2 thin films
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Absence of superconductivity in bulk Nd1−xSrxNiO2
journal, April 2020

Orbital mixture effect on the Fermi-surface– $T_{c}$ correlation in the cuprate superconductors: Bilayer vs. single layer
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Electronic structure of the parent compound of superconducting infinite-layer nickelates
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Synthesis and characterization of bulk ${Nd}_{1 - x} {Sr}_{x} Ni O_{2}$ and ${Nd}_{1 - x} {Sr}_{x} Ni O_{3}$
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Correlations between Density-Based Bond Orders and Orbital-Based Bond Energies for Chemical Bonding Analysis
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Low-Temperature Catalytic NO Reduction with CO by Subnanometric Pt Clusters
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Changes in the Electronic States of Low-Temperature Solid n-Tetradecane: Decrease in the HOMO–LUMO Gap
journal, February 2017

Toward a More Rational Design of the Direct Synthesis of Aniline: A Density Functional Theory Study
journal, July 2017

Water Adsorption and Insertion in MOF-5
journal, August 2017

Room-Temperature Activation of CO₂ by Dual Defect-Stabilized Nanoscale Hematite (Fe_2−δO_3–v): Concurrent Role of Fe and O Vacancies
journal, November 2017

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Theoretical Insights into 1D Transition-Metal Nanoalloys Grown on the NiAl(110) Surface
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