Antagonistic Role of Aqueous Complexation in the Solvent Extraction and Separation of Rare Earth Ions

Sun, Pan; Binter, Erik A.; Liang, Zhu; Brown, M. Alex; Gelis, Artem V.; Benjamin, Ilan; Bera, Mrinal K.; Lin, Binhua; Bu, Wei; Schlossman, Mark L.

doi:10.1021/acscentsci.1c00960

Title: Antagonistic Role of Aqueous Complexation in the Solvent Extraction and Separation of Rare Earth Ions

Journal Article · Mon Oct 25 00:00:00 UTC 2021 · ACS Central Science

DOI: https://doi.org/10.1021/acscentsci.1c00960 · OSTI ID:1827482

^[1];

^[2];

^[3];

^[4];

^[5];

^[1];

^[2]

NSF’s ChemMatCARS, Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States
Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607, United States
Chemical and Fuel Cycle Technologies Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
Radiochemistry Program, Department of Chemistry and Biochemistry, University of Nevada, Las Vegas, Nevada 89141, United States
Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, United States

Not Available

View Journal Article

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Univ. of Illinois, Chicago, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; NE0008779; SC0018200

OSTI ID:: 1827482

Journal Information:: ACS Central Science, Journal Name: ACS Central Science Journal Issue: 11 Vol. 7; ISSN 2374-7943

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (45)

Solvent Extraction: Structure of the Liquid–Liquid Interface Containing a Diamide Ligand Scoppola, Ernesto; Watkins, Erik B.; Campbell, Richard A. Angewandte Chemie, Vol. 128, Issue 32 https://doi.org/10.1002/ange.201603395	journal	March 2016
Technology development for rare earth cleaner hydrometallurgy in China Huang, Xiao-Wei; Long, Zhi-Qi; Wang, Liang-Shi Rare Metals, Vol. 34, Issue 4 https://doi.org/10.1007/s12598-015-0473-x	journal	March 2015
Interfacial activity, extractant selectivity, and reversed micellization in hydrometallurgical liquid/liquid extraction systems Gaonkar, Anilkumar G.; Neuman, Ronald D. Journal of Colloid and Interface Science, Vol. 119, Issue 1 https://doi.org/10.1016/0021-9797(87)90264-5	journal	September 1987
Fractional extraction of the lanthanides as their di-alkyl orthophosphates Peppard, D. F.; Mason, G. W.; Maier, J. L. Journal of Inorganic and Nuclear Chemistry, Vol. 4, Issue 5-6 https://doi.org/10.1016/0022-1902(57)80016-5	journal	January 1957
Liquid-liquid extraction of rare-earth elements from aqueous acid solutions by acid organophosphorus compounds Sato, Taichi Hydrometallurgy, Vol. 22, Issue 1-2 https://doi.org/10.1016/0304-386X(89)90045-5	journal	June 1989
Interfacial activity of metal ion extractant Prochaska, Krystyna Advances in Colloid and Interface Science, Vol. 95, Issue 1 https://doi.org/10.1016/S0001-8686(00)00084-1	journal	January 2002
The liquid surface/interface spectrometer at ChemMatCARS synchrotron facility at the Advanced Photon Source Lin, Binhua; Meron, Mati; Gebhardt, Jeff Physica B: Condensed Matter, Vol. 336, Issue 1-2 https://doi.org/10.1016/S0921-4526(03)00272-2	journal	August 2003
Liquid–liquid extraction: An adsorption isotherm at divided interface? Testard, Fabienne; Berthon, Laurence; Zemb, Thomas Comptes Rendus Chimie, Vol. 10, Issue 10-11 https://doi.org/10.1016/j.crci.2007.04.014	journal	October 2007
A critical review on solvent extraction of rare earths from aqueous solutions Xie, Feng; Zhang, Ting An; Dreisinger, David Minerals Engineering, Vol. 56 https://doi.org/10.1016/j.mineng.2013.10.021	journal	February 2014
Liquid Surfaces and Interfaces: Synchrotron X-ray Methods Pershan, Peter S.; Schlossman, Mark https://doi.org/10.1017/CBO9781139045872	book	September 2012
High Precision Droplet-Based Microfluidic Determination of Americium(III) and Lanthanide(III) Solvent Extraction Separation Kinetics Launiere, C. A.; Gelis, A. V. Industrial & Engineering Chemistry Research, Vol. 55, Issue 7 https://doi.org/10.1021/acs.iecr.5b04691	journal	February 2016
Lanthanide Chemistry: From Coordination in Chemical Complexes Shaping Our Technology to Coordination in Enzymes Shaping Bacterial Metabolism Martinez-Gomez, Norma Cecilia; Vu, Huong N.; Skovran, Elizabeth Inorganic Chemistry, Vol. 55, Issue 20 https://doi.org/10.1021/acs.inorgchem.6b00919	journal	September 2016
Thermodynamic Signatures of the Origin of Anti -Hofmeister Selectivity for Phosphate at Aqueous Interfaces Grooms, Alexander J.; Neal, Jennifer F.; Ng, Ka Chon The Journal of Physical Chemistry A, Vol. 124, Issue 27 https://doi.org/10.1021/acs.jpca.0c02515	journal	May 2020
Molecular Recognition and Hydration Energy Mismatch Combine To Inform Ion Binding Selectivity at Aqueous Interfaces Neal, Jennifer F.; Saha, Ankur; Zerkle, Mia M. The Journal of Physical Chemistry A, Vol. 124, Issue 49 https://doi.org/10.1021/acs.jpca.0c09568	journal	November 2020
Stoichiometry of Lanthanide–Phosphate Complexes at the Water Surface Studied Using Vibrational Sum Frequency Generation Spectroscopy and DFT Calculations Kusaka, Ryoji; Watanabe, Masayuki The Journal of Physical Chemistry B, Vol. 125, Issue 24 https://doi.org/10.1021/acs.jpcb.1c04583	journal	June 2021
Two-Step Adsorption of PtCl ₆ ^2– Complexes at a Charged Langmuir Monolayer: Role of Hydration and Ion Correlations Uysal, Ahmet; Rock, William; Qiao, Baofu The Journal of Physical Chemistry C, Vol. 121, Issue 45 https://doi.org/10.1021/acs.jpcc.7b09350	journal	November 2017
Heavy Anionic Complex Creates a Unique Water Structure at a Soft Charged Interface Rock, William; Qiao, Baofu; Zhou, Tiecheng The Journal of Physical Chemistry C, Vol. 122, Issue 51 https://doi.org/10.1021/acs.jpcc.8b08419	journal	November 2018
The Role of Specific Ion Effects in Ion Transport: The Case of Nitrate and Thiocyanate Lovering, Kaitlin; Nayak, Srikanth; Bu, Wei The Journal of Physical Chemistry C, Vol. 124, Issue 1 https://doi.org/10.1021/acs.jpcc.9b09288	journal	December 2019
Anions Enhance Rare Earth Adsorption at Negatively Charged Surfaces Nayak, Srikanth; Lovering, Kaitlin; Bu, Wei The Journal of Physical Chemistry Letters, Vol. 11, Issue 11 https://doi.org/10.1021/acs.jpclett.0c01091	journal	May 2020
Atomic Number Dependent “Structural Transitions” in Ordered Lanthanide Monolayers: Role of the Hydration Shell Miller, Mitchell; Chu, Miaoqi; Lin, Binhua Langmuir, Vol. 33, Issue 6 https://doi.org/10.1021/acs.langmuir.6b04609	journal	January 2017
Hydrogen-Bond-Driven Chemical Separations: Elucidating the Interfacial Steps of Self-Assembly in Solvent Extraction Chowdhury, Azhad U.; Lin, Lu; Doughty, Benjamin ACS Applied Materials & Interfaces, Vol. 12, Issue 28 https://doi.org/10.1021/acsami.0c06176	journal	June 2020
Origins of Clustering of Metalate–Extractant Complexes in Liquid–Liquid Extraction Nayak, Srikanth; Kumal, Raju R.; Liu, Zhu ACS Applied Materials & Interfaces, Vol. 13, Issue 20 https://doi.org/10.1021/acsami.0c23158	journal	April 2021
Ionic radii in aqueous solutions Marcus, Yizhak Chemical Reviews, Vol. 88, Issue 8 https://doi.org/10.1021/cr00090a003	journal	December 1988
Kinetics of Extraction of zinc Dithizonate Honaker, Carl B.; Freiser, Henry The Journal of Physical Chemistry, Vol. 66, Issue 1 https://doi.org/10.1021/j100807a027	journal	January 1962
Role of the interface in the extraction kinetics of zinc and nickel ions with alkyl-substituted dithizones Watarai, Hitoshi; Freiser, Henry Journal of the American Chemical Society, Vol. 105, Issue 2 https://doi.org/10.1021/ja00340a007	journal	January 1983
Toward Mechanistic Understanding of Nuclear Reprocessing Chemistries by Quantifying Lanthanide Solvent Extraction Kinetics via Microfluidics with Constant Interfacial Area and Rapid Mixing Nichols, Kevin P.; Pompano, Rebecca R.; Li, Liang Journal of the American Chemical Society, Vol. 133, Issue 39 https://doi.org/10.1021/ja206020u	journal	October 2011
Interfacial Supramolecular Structures of Amphiphilic Receptors Drive Aqueous Phosphate Recognition Neal, Jennifer F.; Zhao, Wei; Grooms, Alexander J. Journal of the American Chemical Society, Vol. 141, Issue 19 https://doi.org/10.1021/jacs.9b02148	journal	April 2019
Observation of a Rare Earth Ion–Extractant Complex Arrested at the Oil–Water Interface During Solvent Extraction Bu, Wei; Yu, Hao; Luo, Guangming The Journal of Physical Chemistry B, Vol. 118, Issue 36 https://doi.org/10.1021/jp505661e	journal	August 2014
Ionic Specificity in pH Regulated Charged Interfaces: Fe 3+ versus La 3+ Wang, Wenjie; Park, Rebecca Y.; Meyer, David H. Langmuir, Vol. 27, Issue 19 https://doi.org/10.1021/la201880g	journal	October 2011
Neutron Reflection Study of the Adsorption of the Phosphate Surfactant NaDEHP onto Alumina from Water Welbourn, Rebecca J. L.; Lee, Seung Yeon; Gutfreund, Philipp Langmuir, Vol. 31, Issue 11 https://doi.org/10.1021/la504837s	journal	March 2015
Ammonium Bis(ethylhexyl) Phosphate: A New Surfactant for Microemulsions Steytler, David C.; Sargeant, D. Lee; Welsh, Gabriel E. Langmuir, Vol. 12, Issue 22 https://doi.org/10.1021/la9605091	journal	January 1996
Structure of a liquid/liquid interface during solvent extraction combining X-ray and neutron reflectivity measurements Scoppola, E.; Watkins, E.; Li Destri, G. Physical Chemistry Chemical Physics, Vol. 17, Issue 23 https://doi.org/10.1039/C5CP01809A	journal	January 2015
Selective recovery of rare earth elements from ion-adsorption rare earth element ores by stepwise extraction with HEH(EHP) and HDEHP Huang, Xiaowei; Dong, Jinshi; Wang, Liangshi Green Chemistry, Vol. 19, Issue 5 https://doi.org/10.1039/C6GC03388A	journal	January 2017
The structure of a lanthanide complex at an extractant/water interface studied using heterodyne-detected vibrational sum frequency generation Kusaka, Ryoji; Watanabe, Masayuki Physical Chemistry Chemical Physics, Vol. 20, Issue 4 https://doi.org/10.1039/C7CP06758E	journal	January 2018
A general model to account for the liquid/liquid kinetics of extraction of metals by organic acids Hughes, Michael A.; Rod, Vladimir Faraday Discussions of the Chemical Society, Vol. 77 https://doi.org/10.1039/dc9847700075	journal	January 1984
A synchrotron x-ray liquid surface spectrometer Schlossman, Mark L.; Synal, Dennis; Guan, Yongmin Review of Scientific Instruments, Vol. 68, Issue 12 https://doi.org/10.1063/1.1148399	journal	December 1997
X-ray fluorescence from a model liquid/liquid solvent extraction system Bu, Wei; Hou, Binyang; Mihaylov, Miroslav Journal of Applied Physics, Vol. 110, Issue 10 https://doi.org/10.1063/1.3661983	journal	November 2011
Nanoscale view of assisted ion transport across the liquid–liquid interface Liang, Zhu; Bu, Wei; Schweighofer, Karl J. Proceedings of the National Academy of Sciences, Vol. 116, Issue 37 https://doi.org/10.1073/pnas.1701389115	journal	March 2018
The Kinetics of Zinc, Cobalt and Nickel Extraction in the D2ehpa-Heptane-Hc104 System Using the Rotating Diffusion cell Technique Dreisinger, D. B.; Charles Cooper, W. Solvent Extraction and Ion Exchange, Vol. 7, Issue 2 https://doi.org/10.1080/07360298908962312	journal	January 1989
Kinetics and Interfacial Phenomena Szymanowski, Jan Solvent Extraction and Ion Exchange, Vol. 18, Issue 4 https://doi.org/10.1080/07366290008934705	journal	July 2000
Review Article: A Review of the Development and Operational Characteristics of the TALSPEAK Process Nilsson, Mikael; Nash, Kenneth L. Solvent Extraction and Ion Exchange, Vol. 25, Issue 6 https://doi.org/10.1080/07366290701634636	journal	October 2007
The Kinetics of Cobalt and Nickel Extraction Using Hehehp Drelsinger, D. B.; Cooper, U. Charles Solvent Extraction and Ion Exchange, Vol. 4, Issue 2 https://doi.org/10.1080/07366298608917869	journal	January 1986
Electrostatic Origin of Element Selectivity during Rare Earth Adsorption Miller, Mitchell; Liang, Yihao; Li, Honghao Physical Review Letters, Vol. 122, Issue 5 https://doi.org/10.1103/PhysRevLett.122.058001	journal	February 2019
Rare earth elements: Mendeleev’s bane, modern marvels Cheisson, Thibault; Schelter, Eric J. Science, Vol. 363, Issue 6426 https://doi.org/10.1126/science.aau7628	journal	January 2019
Different Adsorption Behavior of Rare Earth and Metallic Ion Complexes on Langmuir Monolayers Probed by Sum-Frequency Generation Spectroscopy Sung, Woongmo; Vaknin, David; Kim, Doseok Journal of the Optical Society of Korea, Vol. 17, Issue 1 https://doi.org/10.3807/JOSK.2013.17.1.010	journal	February 2013

Similar Records

THE SEPARATION OF THE RARE EARTHS BY SOLVENT EXTRACTION AND REVERSED-PHASE CHROMATOGRAPHY FROM COMPLEXED AQUEOUS SOLUTIONS.

Journal Article · Thu Oct 31 04:00:00 UTC 1968 · pp 54-9 of Solvent Extraction Chemistry. Dyrssen, D. Liljenzin, J.- O. Rydberg, J. (eds.). New York, John Wiley and Sons, Inc., 1967. · OSTI ID:4582496

Werner, G

SEPARATION OF MONAZITE RARE EARTHS BY SOLVENT EXTRACTION

Journal Article · Sat Feb 01 04:00:00 UTC 1958 · Industrial and Engineering Chemistry (U.S.) Formerly J. Ind. Eng. Chem. Superseded by Chem. Technol. · OSTI ID:4308689

Bochinski, J; Smutz, M; Spedding, F H

The Separation of Thorium and Rare Earth Salts by Solvent Extraction

Journal Article · Mon May 01 04:00:00 UTC 1950 · J. Phys. and Colloid Chem. · OSTI ID:4439902

Asselin, G F; Audrieth, L F; Comings, E W

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Interfaces
Ions
Lanthanides
Solution chemistry
Surface tension

Title: Antagonistic Role of Aqueous Complexation in the Solvent Extraction and Separation of Rare Earth Ions

Citation Formats

References (45)

Similar Records

Related Subjects