Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization

Kirk, Martin L.; Shultz, David A.; Hewitt, Patrick; Stasiw, Daniel E.; Chen, Ju; van der Est, Art

doi:10.1039/D1SC02965G

Title: Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization

Journal Article · Wed Oct 27 00:00:00 UTC 2021 · Chemical Science

DOI: https://doi.org/10.1039/D1SC02965G · OSTI ID:1825120

^[1]; Shultz, David A. ^[2]; Hewitt, Patrick ^[2]; Stasiw, Daniel E. ^[2]; Chen, Ju ^[1]; van der Est, Art ^[3]

Department of Chemistry and Chemical Biology, The University of New Mexico, MSC03 2060, 1 University of New Mexico, Albuquerque, NM 87131-0001, USA
Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA
Department of Chemistry, Brock University, St. Catharines, Ontario, Canada L2S 3A1

A change in the sign of the ground state electron spin polarization (ESP) is reported in complexes where an organic radical (nitronylnitroxide, NN) is covalently attached to a donor–acceptor chromophore via two different meta -phenylene bridges.

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Research Organization:: North Carolina State Univ., Raleigh, NC (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0020199

OSTI ID:: 1825120

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 41 Vol. 12; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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