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Title: The superatomic state beyond conventional magic numbers: Ligated metal chalcogenide superatoms

Abstract

The field of cluster science is drawing increasing attention due to the strong size and composition-dependent properties of clusters and the exciting prospect of clusters serving as the building blocks for materials with tailored properties. However, identifying a unifying central paradigm that provides a framework for classifying and understanding the diverse behaviors is an outstanding challenge. One such central paradigm is the superatom concept that was developed for metallic and ligand-protected metallic clusters. The periodic electronic and geometric closed shells in clusters result in their properties being based on the stability they gain when they achieve closed shells. This stabilization results in the clusters having a well-defined valence allowing them to be classified as superatoms – thus, extending the periodic table to a third dimension. This perspective focuses on extending the superatomic concept to ligated metal-chalcogen clusters that have recently been synthesized in solutions and form assemblies with counterions that have wide-ranging applications. Here we illustrate that the periodic patterns emerge in the electronic structure of ligated metal-chalcogenide clusters. The stabilization gained by the closing of their electronic shells allows for the prediction of their redox properties. Further investigations reveal how the selection of ligands may control the redox propertiesmore » of the superatoms. These ligated clusters may serve as chemical dopants for two-dimensional semiconductors to control their transport characteristics. Superatomic molecules of multiple metal-chalcogen superatoms allow for the formation of nano pn junctions ideal for directed transport and photon harvesting. As a result, the perspective outlines future developments, including the synthesis of magnetic superatoms.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1]
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  1. Virginia Commonwealth Univ., Richmond, VA (United States)
Publication Date:
Research Org.:
Virginia Commonwealth Univ., Richmond, VA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1824338
Alternate Identifier(s):
OSTI ID: 1822545
Grant/Contract Number:  
SC0006420
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 155; Journal Issue: 12; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Cluster; superatoms; electronic structure; electronic properties; chemical dopants; photoelectron spectroscopy; electronic shell; HOMO and LUMO; semiconductors; P-N junctions; free electron model; electronic band structure

Citation Formats

Khanna, Shiv N., Reber, Arthur C., Bista, Dinesh, Sengupta, Turbasu, and Lambert, Ryan. The superatomic state beyond conventional magic numbers: Ligated metal chalcogenide superatoms. United States: N. p., 2021. Web. doi:10.1063/5.0062582.
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Khanna, Shiv N., Reber, Arthur C., Bista, Dinesh, Sengupta, Turbasu, & Lambert, Ryan. The superatomic state beyond conventional magic numbers: Ligated metal chalcogenide superatoms. United States. https://doi.org/10.1063/5.0062582
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Khanna, Shiv N., Reber, Arthur C., Bista, Dinesh, Sengupta, Turbasu, and Lambert, Ryan. Tue . "The superatomic state beyond conventional magic numbers: Ligated metal chalcogenide superatoms". United States. https://doi.org/10.1063/5.0062582. https://www.osti.gov/servlets/purl/1824338.
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@article{osti_1824338,
title = {The superatomic state beyond conventional magic numbers: Ligated metal chalcogenide superatoms},
author = {Khanna, Shiv N. and Reber, Arthur C. and Bista, Dinesh and Sengupta, Turbasu and Lambert, Ryan},
abstractNote = {The field of cluster science is drawing increasing attention due to the strong size and composition-dependent properties of clusters and the exciting prospect of clusters serving as the building blocks for materials with tailored properties. However, identifying a unifying central paradigm that provides a framework for classifying and understanding the diverse behaviors is an outstanding challenge. One such central paradigm is the superatom concept that was developed for metallic and ligand-protected metallic clusters. The periodic electronic and geometric closed shells in clusters result in their properties being based on the stability they gain when they achieve closed shells. This stabilization results in the clusters having a well-defined valence allowing them to be classified as superatoms – thus, extending the periodic table to a third dimension. This perspective focuses on extending the superatomic concept to ligated metal-chalcogen clusters that have recently been synthesized in solutions and form assemblies with counterions that have wide-ranging applications. Here we illustrate that the periodic patterns emerge in the electronic structure of ligated metal-chalcogenide clusters. The stabilization gained by the closing of their electronic shells allows for the prediction of their redox properties. Further investigations reveal how the selection of ligands may control the redox properties of the superatoms. These ligated clusters may serve as chemical dopants for two-dimensional semiconductors to control their transport characteristics. Superatomic molecules of multiple metal-chalcogen superatoms allow for the formation of nano pn junctions ideal for directed transport and photon harvesting. As a result, the perspective outlines future developments, including the synthesis of magnetic superatoms.},
doi = {10.1063/5.0062582},
journal = {Journal of Chemical Physics},
number = 12,
volume = 155,
place = {United States},
year = {Tue Sep 28 00:00:00 EDT 2021},
month = {Tue Sep 28 00:00:00 EDT 2021}
}
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Works referenced in this record:

Multiple valence superatoms
journal, November 2006

  • Reveles, J. U.; Khanna, S. N.; Roach, P. J.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 49
  • DOI: 10.1073/pnas.0608781103

Shape Matching in Superatom Chemistry and Assembly
journal, June 2020

  • Yang, Jingjing; Wang, Feifan; Russell, Jake C.
  • Journal of the American Chemical Society, Vol. 142, Issue 28
  • DOI: 10.1021/jacs.0c04321

Rings, towers, cages of ZnO
journal, May 2007

More than just a support: Graphene as a solid-state ligand for palladium-catalyzed cross-coupling reactions
journal, April 2018

Controlling the Band Gap Energy of Cluster-Assembled Materials
journal, June 2013

  • Mandal, Sukhendu; Reber, Arthur C.; Qian, Meichun
  • Accounts of Chemical Research, Vol. 46, Issue 11
  • DOI: 10.1021/ar3002975

A unified view of ligand-protected gold clusters as superatom complexes
journal, July 2008

  • Walter, M.; Akola, J.; Lopez-Acevedo, O.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 27
  • DOI: 10.1073/pnas.0801001105

Air-Stable Surface Charge Transfer Doping of MoS 2 by Benzyl Viologen
journal, May 2014

  • Kiriya, Daisuke; Tosun, Mahmut; Zhao, Peida
  • Journal of the American Chemical Society, Vol. 136, Issue 22
  • DOI: 10.1021/ja5033327

Production of phosphorene nanoribbons
journal, April 2019

Ligand Effect on the Electronic Structure of Cobalt Sulfide Clusters: A Combined Experimental and Theoretical Study
journal, September 2019

  • Liu, Gaoxiang; Chauhan, Vikas; Aydt, Alexander P.
  • The Journal of Physical Chemistry C, Vol. 123, Issue 41
  • DOI: 10.1021/acs.jpcc.9b04153

Intermediates in the formation of gold clusters. Preparation and x-ray analysis of [Au7(PPh3)7]+ and synthesis and characterization of [Au8(PPh3)6I]PF6
journal, January 1984

  • Van der Velden, J. W. A.; Beurskens, P. T.; Bour, J. J.
  • Inorganic Chemistry, Vol. 23, Issue 2
  • DOI: 10.1021/ic00170a007

Chemistry with ADF
journal, January 2001

  • te Velde, G.; Bickelhaupt, F. M.; Baerends, E. J.
  • Journal of Computational Chemistry, Vol. 22, Issue 9, p. 931-967
  • DOI: 10.1002/jcc.1056

Controlling Molecular Doping in Organic Semiconductors
journal, September 2017

Superatoms: Electronic and Geometric Effects on Reactivity
journal, January 2017

Complementary Active Sites Cause Size-Selective Reactivity of Aluminum Cluster Anions with Water
journal, January 2009

Doping-Induced Superconductivity in the van der Waals Superatomic Crystal Re 6 Se 8 Cl 2
journal, February 2020

Nanoscale Atoms in Solid-State Chemistry
journal, June 2013

Two-Dimensional Hierarchical Semiconductor with Addressable Surfaces
journal, July 2018

  • Choi, Bonnie; Lee, Kihong; Voevodin, Anastasia
  • Journal of the American Chemical Society, Vol. 140, Issue 30
  • DOI: 10.1021/jacs.8b05010

Intercalation without altercation
journal, November 2017

  • Khanna, Shiv N.; Reber, Arthur C.
  • Nature Chemistry, Vol. 9, Issue 12
  • DOI: 10.1038/nchem.2895

Superatom Fusion and the Nature of Quantum Confinement
journal, June 2018

A Magnetic Superatomic Dimer with an Intense Internal Electric Dipole Moment
journal, January 2021

  • Bista, Dinesh; Sengupta, Turbasu; Reber, Arthur C.
  • The Journal of Physical Chemistry A, Vol. 125, Issue 3
  • DOI: 10.1021/acs.jpca.0c10262

Spin Accommodation and Reactivity of Aluminum Based Clusters with O 2
journal, December 2007

  • Reber, Arthur C.; Khanna, Shiv N.; Roach, Patrick J.
  • Journal of the American Chemical Society, Vol. 129, Issue 51
  • DOI: 10.1021/ja075998d

Magnetism from the Atom to the Bulk in Iron, Cobalt, and Nickel Clusters
journal, September 1994

Nature of Valence Transition and Spin Moment in Ag n V + Clusters
journal, May 2014

  • Medel, Victor M.; Reber, Arthur C.; Chauhan, Vikas
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja412064c

Metal Chalcogenide Clusters with Closed Electronic Shells and the Electronic Properties of Alkalis and Halogens
journal, January 2017

  • Chauhan, Vikas; Reber, Arthur C.; Khanna, Shiv N.
  • Journal of the American Chemical Society, Vol. 139, Issue 5
  • DOI: 10.1021/jacs.6b09416

Effect of O 2 and CO Exposure on the Photoelectron Spectroscopy of Size-Selected Pd n Clusters Supported on TiO 2 (110)
journal, January 2016

  • Reber, Arthur C.; Khanna, Shiv N.; Roberts, F. Sloan
  • The Journal of Physical Chemistry C, Vol. 120, Issue 4
  • DOI: 10.1021/acs.jpcc.5b08611

Transforming Ni 9 Te 6 from Electron Donor to Acceptor via Ligand Exchange
journal, August 2016

  • Chauhan, Vikas; Reber, Arthur C.; Khanna, Shiv N.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 33
  • DOI: 10.1021/acs.jpca.6b05701

Synthesis and structural characterization of an AI77 cluster
journal, May 1997

  • Ecker, A.; Weckert, E.; Schnöckel, H.
  • Nature, Vol. 387, Issue 6631
  • DOI: 10.1038/387379a0

Aluminum cluster anions: Photoelectron spectroscopy and ab initio simulations
journal, November 2000

Effect of N- and P-Type Doping on the Oxygen-Binding Energy and Oxygen Spillover of Supported Palladium Clusters
journal, August 2014

  • Reber, Arthur C.; Khanna, Shiv N.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 35
  • DOI: 10.1021/jp5045145

Stability of polyatomic molecules in degenerate electronic states - I—Orbital degeneracy
journal, July 1937

  • Jahn, H. A.; Teller, E.
  • Proceedings of the Royal Society of London. Series A - Mathematical and Physical Sciences, Vol. 161, Issue 905, p. 220-235
  • DOI: 10.1098/rspa.1937.0142

Effect of Embedding Platinum Clusters in Alumina on Sintering, Coking, and Activity
journal, September 2017

  • Reber, Arthur C.; Khanna, Shiv N.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 39
  • DOI: 10.1021/acs.jpcc.7b07452

Molecular models of the superconducting chevrel phases: syntheses and structures of [Mo6X8(PEt3)6] and [PPN][Mo6X8(PEt3)6] (X = S, Se; PPN = (Ph3P)2N)
journal, February 1990

  • Saito, Taro; Yamamoto, Naohiro; Nagase, Toshimi
  • Inorganic Chemistry, Vol. 29, Issue 4
  • DOI: 10.1021/ic00329a039

Evolution of the Spin Magnetic Moments and Atomic Valence of Vanadium in VCu x + , VAg x + , and VAu x + Clusters ( x = 3–14)
journal, April 2017

  • Blades, William H.; Reber, Arthur C.; Khanna, Shiv N.
  • The Journal of Physical Chemistry A, Vol. 121, Issue 15
  • DOI: 10.1021/acs.jpca.7b01030

Single-Electron Currents in Designer Single-Cluster Devices
journal, August 2020

  • Gunasekaran, Suman; Reed, Douglas A.; Paley, Daniel W.
  • Journal of the American Chemical Society, Vol. 142, Issue 35
  • DOI: 10.1021/jacs.0c04970

Al Cluster Superatoms as Halogens in Polyhalides and as Alkaline Earths in Iodide Salts
journal, January 2005

Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells
journal, March 1961

  • Shockley, William; Queisser, Hans J.
  • Journal of Applied Physics, Vol. 32, Issue 3, p. 510-519
  • DOI: 10.1063/1.1736034

Ferromagnetic Ordering in Superatomic Solids
journal, November 2014

  • Lee, Chul-Ho; Liu, Lian; Bejger, Christopher
  • Journal of the American Chemical Society, Vol. 136, Issue 48
  • DOI: 10.1021/ja5098622

Metallic and molecular orbital concepts in XMg 8 clusters, X = Be-F
journal, April 2012

  • Medel, Victor M.; Reber, Arthur C.; Ulises Reveles, J.
  • The Journal of Chemical Physics, Vol. 136, Issue 13
  • DOI: 10.1063/1.3700086

van der Waals Solids from Self-Assembled Nanoscale Building Blocks
journal, January 2016

Modern Aspects of the Jahn−Teller Effect Theory and Applications To Molecular Problems
journal, April 2001

Designer magnetic superatoms
journal, June 2009

  • Reveles, J. Ulises; Clayborne, Peneé A.; Reber, Arthur C.
  • Nature Chemistry, Vol. 1, Issue 4
  • DOI: 10.1038/nchem.249

Donor/Acceptor Concepts for Developing Efficient Suzuki Cross-Coupling Catalysts Using Graphene-Supported Ni, Cu, Fe, Pd, and Bimetallic Pd/Ni Clusters
journal, October 2018

  • Yang, Y.; Reber, A. C.; Gilliland, S. E.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 44
  • DOI: 10.1021/acs.jpcc.8b07538

Transforming Redox Properties of Clusters Using Phosphine Ligands
journal, March 2019

  • Reber, Arthur C.; Bista, Dinesh; Chauhan, Vikas
  • The Journal of Physical Chemistry C, Vol. 123, Issue 14
  • DOI: 10.1021/acs.jpcc.9b00039

Carbonyl Bond Cleavage by Complementary Active Sites
journal, April 2013

  • Woodward, W. Hunter; Reber, A. C.; Smith, Jordan C.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 15
  • DOI: 10.1021/jp303668b

Nano-scaling law: geometric foundation of thiolated gold nanomolecules
journal, January 2012

Superatom Compounds, Clusters, and Assemblies:  Ultra Alkali Motifs and Architectures
journal, August 2007

  • Reber, Arthur C.; Khanna, Shiv N.; Castleman, A. Welford
  • Journal of the American Chemical Society, Vol. 129, Issue 33
  • DOI: 10.1021/ja071647n

Molybdenum cluster chalcogenides Mo6X8: intercalation of lithium via electron/ion transfer
journal, June 1987

  • Gocke, E.; Schoellhorn, R.; Aselmann, G.
  • Inorganic Chemistry, Vol. 26, Issue 11
  • DOI: 10.1021/ic00258a034

Stabilization of Catalytic Surfaces through Core–Shell Structures: Ag–Ir/Al 2 O 3 Case Study
journal, November 2020

Electronic Structure of Ligand-Passivated Gold and Silver Nanoclusters
journal, December 2010

  • Aikens, Christine M.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 2
  • DOI: 10.1021/jz101499g

Edge-Induced Active Sites Enhance the Reactivity of Large Aluminum Cluster Anions with Alcohols
journal, July 2012

  • Reber, Arthur C.; Roach, Patrick J.; Woodward, W. Hunter
  • The Journal of Physical Chemistry A, Vol. 116, Issue 30
  • DOI: 10.1021/jp3047196

Multiple-Valence Aluminum and the Electronic and Geometric Structure of Al n O m Clusters
journal, May 2019

  • Armstrong, Albert; Reber, Arthur C.; Khanna, Shiv N.
  • The Journal of Physical Chemistry A, Vol. 123, Issue 24
  • DOI: 10.1021/acs.jpca.9b01729

Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re 6 S 8 ] 2+ and [Re 6 Se 8 ] 2+
journal, December 1999

  • Gray, Thomas G.; Rudzinski, Christina M.; Nocera, Daniel G.
  • Inorganic Chemistry, Vol. 38, Issue 26
  • DOI: 10.1021/ic991195i

The gold–sulfur interface at the nanoscale
journal, May 2012

Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
journal, June 2018

Al Valence Controls the Coordination and Stability of Cationic Aluminum–Oxygen Clusters in Reactions of Al n + with Oxygen
journal, August 2019

  • Armstrong, Albert; Zhang, Hanyu; Reber, Arthur C.
  • The Journal of Physical Chemistry A, Vol. 123, Issue 34
  • DOI: 10.1021/acs.jpca.9b05646

Single-crystal-to-single-crystal intercalation of a low-bandgap superatomic crystal
journal, August 2017

  • O'Brien, Evan S.; Trinh, M. Tuan; Kann, Rose L.
  • Nature Chemistry, Vol. 9, Issue 12
  • DOI: 10.1038/nchem.2844

Reactivity of Aluminum Cluster Anions with Water: Origins of Reactivity and Mechanisms for H 2 Release
journal, May 2010

  • Reber, Arthur C.; Khanna, Shiv N.; Roach, Patrick J.
  • The Journal of Physical Chemistry A, Vol. 114, Issue 20
  • DOI: 10.1021/jp911136s

Clusters, Superatoms, and Building Blocks of New Materials
journal, January 2009

  • Castleman, A. W.; Khanna, S. N.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 7
  • DOI: 10.1021/jp806850h

Water-soluble Re 6 -clusters with aromatic phosphine ligands – from synthesis to potential biomedical applications
journal, January 2019

  • Ivanov, Anton A.; Konovalov, Dmitry I.; Pozmogova, Tatiana N.
  • Inorganic Chemistry Frontiers, Vol. 6, Issue 4
  • DOI: 10.1039/c8qi01216d

Tuning the Effective Work Function of Gold and Silver Using ω-Functionalized Alkanethiols: Varying Surface Composition through Dilution and Choice of Terminal Groups
journal, October 2009

  • Alloway, Dana M.; Graham, Amy L.; Yang, Xi
  • The Journal of Physical Chemistry C, Vol. 113, Issue 47
  • DOI: 10.1021/jp909494r

Cluster-Assembled Materials
journal, January 2009

  • Claridge, Shelley A.; Castleman, A. W.; Khanna, Shiv N.
  • ACS Nano, Vol. 3, Issue 2
  • DOI: 10.1021/nn800820e

Superatoms in materials science
journal, February 2020

  • Doud, Evan A.; Voevodin, Anastasia; Hochuli, Taylor J.
  • Nature Reviews Materials, Vol. 5, Issue 5
  • DOI: 10.1038/s41578-019-0175-3

Electronic Population Analysis on LCAO–MO Molecular Wave Functions. I
journal, October 1955

  • Mulliken, R. S.
  • The Journal of Chemical Physics, Vol. 23, Issue 10
  • DOI: 10.1063/1.1740588

Thiolate-Protected Au 25 Superatoms as Building Blocks: Dimers and Crystals
journal, April 2010

  • Akola, Jaakko; Kacprzak, Katarzyna A.; Lopez-Acevedo, Olga
  • The Journal of Physical Chemistry C, Vol. 114, Issue 38
  • DOI: 10.1021/jp1015438

Boron Substitution in Aluminum Cluster Anions: Magic Clusters and Reactivity with Oxygen
journal, May 2014

  • Smith, Jordan C.; Reber, Arthur C.; Khanna, Shiv N.
  • The Journal of Physical Chemistry A, Vol. 118, Issue 37
  • DOI: 10.1021/jp501934t

Strong Effect of Organic Ligands on the Electronic Structure of Metal-Chalcogenide Clusters
journal, June 2018

Structure and electronic properties of medium-sized GanNn clusters (n=4–12)
journal, April 2006

Atoms in molecules
journal, January 1985

Doping of organic semiconductors
journal, December 2012

Influence of the exchange screening parameter on the performance of screened hybrid functionals
journal, December 2006

  • Krukau, Aliaksandr V.; Vydrov, Oleg A.; Izmaylov, Artur F.
  • The Journal of Chemical Physics, Vol. 125, Issue 22
  • DOI: 10.1063/1.2404663

Ligand-Induced Active Sites: Reactivity of Iodine-Protected Aluminum Superatoms with Methanol
journal, December 2012

  • Abreu, Marissa Baddick; Powell, Christopher; Reber, Arthur C.
  • Journal of the American Chemical Society, Vol. 134, Issue 50
  • DOI: 10.1021/ja309473s

Observation of icosahedral shells and subshells in calcium clusters
journal, August 1991

Ni 9 Te 6 (PEt 3 ) 8 C 60 Is a Superatomic Superalkali Superparamagnetic Cluster Assembled Material (S 3 -CAM)
journal, February 2016

  • Chauhan, Vikas; Sahoo, Sanjubala; Khanna, Shiv N.
  • Journal of the American Chemical Society, Vol. 138, Issue 6
  • DOI: 10.1021/jacs.5b10986

Aluminum clusters: ionization thresholds and reactivity toward deuterium, water, oxygen, methanol, methane, and carbon monoxide
journal, January 1988

  • Cox, D. M.; Trevor, D. J.; Whetten, R. L.
  • The Journal of Physical Chemistry, Vol. 92, Issue 2
  • DOI: 10.1021/j100313a036

Probing the Magic Numbers of Aluminum–Magnesium Cluster Anions and Their Reactivity toward Oxygen
journal, March 2013

  • Luo, Zhixun; Grover, Cameron J.; Reber, Arthur C.
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja310467n

Is my chemical universe localized or delocalized? is there a future for chemical concepts?
journal, January 2007

  • Shaik, Sason
  • New Journal of Chemistry, Vol. 31, Issue 12
  • DOI: 10.1039/b711641c

Hund's rule in superatoms with transition metal impurities
journal, June 2011

  • Medel, V. M.; Reveles, J. U.; Khanna, S. N.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 25
  • DOI: 10.1073/pnas.1100129108

Co6Se8(PEt3)6 superatoms as tunable chemical dopants for two-dimensional semiconductors
journal, July 2018

Thermal metal cluster anion reactions: Behavior of aluminum clusters with oxygen
journal, August 1989

  • Leuchtner, R. E.; Harms, A. C.; Castleman, A. W.
  • The Journal of Chemical Physics, Vol. 91, Issue 4
  • DOI: 10.1063/1.456988

When Gold Is Not Noble:  Nanoscale Gold Catalysts
journal, December 1999

  • Sanchez, A.; Abbet, S.; Heiz, U.
  • The Journal of Physical Chemistry A, Vol. 103, Issue 48
  • DOI: 10.1021/jp9935992

Formation of Al13I-: Evidence for the Superhalogen Character of Al13
journal, April 2004

Symmetry and magnetism in Ni 9 Te 6 clusters ligated by CO or phosphine ligands
journal, January 2017

  • Reber, Arthur C.; Chauhan, Vikas; Khanna, Shiv N.
  • The Journal of Chemical Physics, Vol. 146, Issue 2
  • DOI: 10.1063/1.4973609

Structural and Electronic Properties of (Al 2 O 3 ) n Clusters with n = 1–10 from First Principles Calculations
journal, August 2011

  • Rahane, Amol B.; Deshpande, Mrinalini D.; Kumar, Vijay
  • The Journal of Physical Chemistry C, Vol. 115, Issue 37
  • DOI: 10.1021/jp2050614

Patterning Superatom Dopants on Transition Metal Dichalcogenides
journal, April 2016

Conductance of Single Cobalt Chalcogenide Cluster Junctions
journal, June 2011

  • Boardman, Brycelyn M.; Widawsky, Jonathan R.; Park, Young S.
  • Journal of the American Chemical Society, Vol. 133, Issue 22
  • DOI: 10.1021/ja201334s
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