Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent

Hamad, Khaleel I.; Xing, Yangchuan

doi:10.1115/1.4045565

Title: Improving Retention Rate of LiNi_0.8Co_0.15Al_0.05O₂ Cathode Material Synthesized Using Glycerol Solvent

Abstract

This paper reports an enhanced retention rate of LiNi_0.8Co_0.15Al_0.05O₂ (NCA) cathode material for Li-ion batteries synthesized with glycerol as a solvent and a reactant. Glycerol is a fuel and the heat released during synthesis could be considered as an additional free energy source for material preparation. Scanning electron microscopy (SEM) images and X-ray diffraction (XRD) results show an early stage of crystallization of the produced powder. Early crystallization in the NCA material at low temperatures was believed to hinder cationic mixing that would occur at higher temperatures during calcination. As a result, cycling of the NCA material shows a very stable capacity. The NCA material displays 97% capacity retention at 1C (1C = 200 mA/g) after 50 cycles, 87.6% at 0.3C after 100 cycles, and 93.6% at 0.1C after 70 cycles, which are better than those reported previously.

Authors:

Hamad, Khaleel I. ^[1]; Xing, Yangchuan ^[1]

Univ. of Missouri, Columbia, MO (United States)

Publication Date:: Sat Jan 11 00:00:00 EST 2020

Research Org.:: Univ. of Missouri, Columbia, MO (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1822916

Grant/Contract Number:: EE0007282

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Electrochemical Energy Conversion and Storage

Additional Journal Information:: Journal Volume: 17; Journal Issue: 3; Journal ID: ISSN 2381-6872

Publisher:: ASME

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Li-ion battery; NCA cathode material; glycerol; capacity retention; batteries; innovative material synthesis and manufacturing methods

Citation Formats


                    Hamad, Khaleel I., and Xing, Yangchuan. Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent.  United States: N. p., 2020. 
Web.  doi:10.1115/1.4045565.

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                    Hamad, Khaleel I., & Xing, Yangchuan. Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent.  United States.  https://doi.org/10.1115/1.4045565

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                    Hamad, Khaleel I., and Xing, Yangchuan. Sat .  
"Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent".  United States.  https://doi.org/10.1115/1.4045565.  https://www.osti.gov/servlets/purl/1822916.

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@article{osti_1822916,

  title        = {Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent},

  author       = {Hamad, Khaleel I. and Xing, Yangchuan},

  abstractNote = {This paper reports an enhanced retention rate of LiNi0.8Co0.15Al0.05O2 (NCA) cathode material for Li-ion batteries synthesized with glycerol as a solvent and a reactant. Glycerol is a fuel and the heat released during synthesis could be considered as an additional free energy source for material preparation. Scanning electron microscopy (SEM) images and X-ray diffraction (XRD) results show an early stage of crystallization of the produced powder. Early crystallization in the NCA material at low temperatures was believed to hinder cationic mixing that would occur at higher temperatures during calcination. As a result, cycling of the NCA material shows a very stable capacity. The NCA material displays 97% capacity retention at 1C (1C = 200 mA/g) after 50 cycles, 87.6% at 0.3C after 100 cycles, and 93.6% at 0.1C after 70 cycles, which are better than those reported previously.},

  doi          = {10.1115/1.4045565},

  journal      = {Journal of Electrochemical Energy Conversion and Storage},

  number       = 3,

  volume       = 17,

  place        = {United States},

  year         = {Sat Jan 11 00:00:00 EST 2020},

  month        = {Sat Jan 11 00:00:00 EST 2020}

}

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Title: Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent

Abstract

Citation Formats

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Preparation of FePO4 by liquid-phase method and modification on the surface of LiNi0.80Co0.15Al0.05O2 cathode material journal, January 2018

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Study of full concentration-gradient Li(Ni0.8Co0.1Mn0.1)O2 cathode material for lithium ion batteries
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Enhanced elevated-temperature performance of Li(Ni0.8Co0.15Al0.05)O2 electrodes coated with Li2O-2B2O3 glass
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Synthesis cathode material LiNi _0.80 Co _0.15 Al _0.05 O ₂ with two step solid-state method under air stream
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