Chloride Reduction of Mn3+ in Mild Hydrothermal Synthesis of a Charge Ordered Defect Pyrochlore, CsMn2+Mn3+F6, a Canted Antiferromagnet with a Hard Ferromagnetic Component

Klepov, Vladislav V.; Pace, Kristen A.; Berseneva, Anna A.; Felder, Justin B.; Calder, Stuart; Morrison, Gregory; Zhang, Qiang; Kirkham, Melanie J.; Parker, David S.; zur Loye, Hans-Conrad

doi:10.1021/jacs.1c04245

Title: Chloride Reduction of Mn³⁺ in Mild Hydrothermal Synthesis of a Charge Ordered Defect Pyrochlore, CsMn²⁺Mn³⁺F₆, a Canted Antiferromagnet with a Hard Ferromagnetic Component

Journal Article · Mon Jul 26 00:00:00 UTC 2021 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.1c04245 · OSTI ID:1818660

^[1];

^[2]; Berseneva, Anna A. ^[3];

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^[3];

^[4];

^[4]; zur Loye, Hans-Conrad ^[3]

Univ. of South Carolina, Columbia, SC (United States); Northwestern Univ., Evanston, IL (United States)
Univ. of South Carolina, Columbia, SC (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of South Carolina, Columbia, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Geometrically frustrated systems play an important role in studying new physical phenomena and unconventional thermodynamics. Charge ordered defect pyrochlores AM²⁺M³⁺F₆ offer a convenient platform for probing the interplay between electron distribution over M²⁺ and M³⁺ sites and structural distortions; however, they are limited to compounds with M^2+/3+ = V, Fe, Ni, and Cu due to difficulties in the simultaneous stabilization of other 3d elements in the +2 and +3 oxidation states. Herein, we employ Cl– anions under hydrothermal conditions for the mild reduction of Mn₂O₃ in concentrated HF to obtain the CsMn²⁺Mn³⁺F₆ composition as a phase pure sample and study its properties. The magnetism of CsMn₂F₆ was characterized by measuring the magnetic susceptibility and isothermal magnetization data, and a magnetic transition to a canted antiferromagnet state was found at 24.1 K. We determined the magnetic structure of CsMn₂F₆ using powder neutron diffraction, which revealed successive long-range ordering of the Mn²⁺ and Mn³⁺ sites that is accompanied by a second transition. As a result, the role and strength of magnetic exchange interactions were characterized using DFT calculations.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1818660

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 30 Vol. 143; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (79)

Water-Splitting Electrocatalysis in Acid Conditions Using Ruthenate-Iridate Pyrochlores Sardar, Kripasindhu; Petrucco, Enrico; Hiley, Craig I. Angewandte Chemie International Edition, Vol. 53, Issue 41 https://doi.org/10.1002/anie.201406668	journal	September 2014
Zur Kenntnis des Systems Cs/Cu/F: �ber CsCuIICuIIIF6 Hoppe, R.; Wingefeld, G. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 519, Issue 12 https://doi.org/10.1002/zaac.19845191220	journal	December 1984
LaMnO3+δRevisited Töpfer, J.; Goodenough, J. B. Journal of Solid State Chemistry, Vol. 130, Issue 1 https://doi.org/10.1006/jssc.1997.7287	journal	April 1997
Flux growth of crystals of some transition metal fluorides: Part 3 Pyrochlores and others Wanklyn, B. M.; Wondre, F. R.; Garrard, B. J. Journal of Materials Science, Vol. 16, Issue 8 https://doi.org/10.1007/BF00542395	journal	August 1981
Flux growth of some fluoride crystals under reducing conditions. IV Garrard, B. J.; Wanklyn, B. M. Journal of Crystal Growth, Vol. 47, Issue 2 https://doi.org/10.1016/0022-0248(79)90237-9	journal	August 1979
NH4CoAlF6: A pyrochlore-related phase existing in both ordered and disordered forms Subramanian, M. A.; Marshall, W. J.; Harlow, R. L. Materials Research Bulletin, Vol. 31, Issue 6 https://doi.org/10.1016/0025-5408(96)00055-4	journal	June 1996
Frustrated magnetic structures: II. Antiferromagnetic structure of the ordered modified pyrochlore NH4FeIIFeIIIF6 at 4.2 K Ferey, G.; Leblanc, M.; De Pape, R. Solid State Communications, Vol. 53, Issue 6 https://doi.org/10.1016/0038-1098(85)90192-9	journal	February 1985
Oxide pyrochlores — A review Subramanian, M. A.; Aravamudan, G.; Subba Rao, G. V. Progress in Solid State Chemistry, Vol. 15, Issue 2 https://doi.org/10.1016/0079-6786(83)90001-8	journal	January 1983
Zur kenntnis der RbNiCrF6-familie [1,2,3]: Neue fluoride AIMIIMIIIF6 (AI = Cs,Rb; MII = Mg,Ni,Cu,Zn; und MIII = Al,V,Fe,Co,Ni) Fleischer, T.; Hoppe, R. Journal of Fluorine Chemistry, Vol. 19, Issue 3-6 https://doi.org/10.1016/S0022-1139(00)83152-8	journal	January 1982
Frustrated rare earth magnetism: Spin glasses, spin liquids and spin ices in pyrochlore oxides Greedan, John E. Journal of Alloys and Compounds, Vol. 408-412 https://doi.org/10.1016/j.jallcom.2004.12.084	journal	February 2006
Synthesis of inorganic fluorides in molten salt fluxes and ionic liquid mediums Fedorov, P. P.; Alexandrov, A. A. Journal of Fluorine Chemistry, Vol. 227 https://doi.org/10.1016/j.jfluchem.2019.109374	journal	November 2019
Crystal structure and phase transition mechanisms in CsFe2F6 Molokeev, M. S.; Bogdanov, E. V.; Misyul, S. V. Journal of Solid State Chemistry, Vol. 200 https://doi.org/10.1016/j.jssc.2013.01.038	journal	April 2013
Simple correction for the sample shape and radial offset effects on SQUID magnetometers: Magnetic measurements on Ln2O3 (Ln=Gd, Dy, Er) standards Morrison, Gregory; zur Loye, Hans-Conrad Journal of Solid State Chemistry, Vol. 221 https://doi.org/10.1016/j.jssc.2014.10.026	journal	January 2015
Heat capacity and magnetic properties of fluoride CsFe2+Fe3+F6 with defect pyrochlore structure Gorev, M. V.; Flerov, I. N.; Tressaud, A. Journal of Solid State Chemistry, Vol. 237 https://doi.org/10.1016/j.jssc.2016.02.045	journal	May 2016
First Mixed-Metal Fluoride Pyrochlores Obtained by Topotactic Oxidation of Ammonium Fluorides under F ₂ Gas Lemoine, Kévin; Moury, Romain; Durand, Etienne Crystal Growth & Design, Vol. 21, Issue 2 https://doi.org/10.1021/acs.cgd.0c01279	journal	December 2020
In Situ Study of the Oxygen-Induced Transformation of Pyrochlore Ce ₂ Zr ₂ O _{7+ x} to the κ-Ce ₂ Zr ₂ O ₈ Phase Urban, Sven; Djerdj, Igor; Dolcet, Paolo Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b03091	journal	October 2017
Covalency-driven Structural Evolution in the Polar Pyrochlore Series Cd ₂ Nb ₂ O _{7– x} S _x Laurita, Geneva; Hickox-Young, Daniel; Husremovic, Samra Chemistry of Materials, Vol. 31, Issue 18 https://doi.org/10.1021/acs.chemmater.9b02466	journal	August 2019
K ₄ Fe ₃ F ₁₂ : An Fe ²⁺ /Fe ³⁺ Charge-Ordered, Ferrimagnetic Fluoride with a Cation-Deficient, Layered Perovskite Structure Kim, Sun Woo; Zhang, Ronghuan; Halasyamani, P. Shiv Inorganic Chemistry, Vol. 54, Issue 13 https://doi.org/10.1021/acs.inorgchem.5b01006	journal	June 2015
Mild Hydrothermal Synthesis of the Complex Hafnium-Containing Fluorides Cs ₂ [M(H ₂ O) ₆ ][Hf ₂ F ₁₂ ] (M = Ni, Co, Zn), CuHfF ₆ (H ₂ O) ₄ , and Cs ₂ Hf ₃ Mn ₃ F ₂₀ Based on HfF ₇ and HfF ₆ Coordination Polyhedra Ayer, Gyanendra B.; Klepov, Vladislav V.; Smith, Mark D. Inorganic Chemistry, Vol. 58, Issue 19 https://doi.org/10.1021/acs.inorgchem.9b01958	journal	September 2019
Os ⁴⁺ Instability in the Pyrochlore Structure: Tl _{2– x} Bi _x Os ₂ O _{7– y} Converse, Elizabeth Sobalvarro; Li, Jun; Haskel, Daniel Inorganic Chemistry, Vol. 59, Issue 2 https://doi.org/10.1021/acs.inorgchem.9b02939	journal	January 2020
Mild Hydrothermal Crystal Growth, Structure, and Magnetic Properties of Ternary U(IV) Containing Fluorides: LiUF ₅ , KU ₂ F ₉ , K ₇ U ₆ F ₃₁ , RbUF ₅ , RbU ₂ F ₉ , and RbU ₃ F ₁₃ Yeon, Jeongho; Smith, Mark D.; Tapp, Joshua Inorganic Chemistry, Vol. 53, Issue 12 https://doi.org/10.1021/ic5008507	journal	May 2014
An FeF ₃ ·0.5H ₂ O Polytype: A Microporous Framework Compound with Intersecting Tunnels for Li and Na Batteries Li, Chilin; Yin, Congling; Gu, Lin Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja402061q	journal	July 2013
Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na ₄ MU ₆ F ₃₀ (M = Mn ²⁺ , Co ²⁺ , Ni ²⁺ , Cu ²⁺ , and Zn ²⁺ ) Crystal Growth, Structures, and Magnetic Properties Yeon, Jeongho; Smith, Mark D.; Tapp, Joshua Journal of the American Chemical Society, Vol. 136, Issue 10 https://doi.org/10.1021/ja412725r	journal	February 2014
Highly Versatile Rare Earth Tantalate Pyrochlore Nanophosphors Nyman, May; Rodriguez, Mark A.; Shea-Rohwer, Lauren E. Journal of the American Chemical Society, Vol. 131, Issue 33 https://doi.org/10.1021/ja903823w	journal	August 2009
Tailoring Lattice Oxygen Binding in Ruthenium Pyrochlores to Enhance Oxygen Evolution Activity Kuznetsov, Denis A.; Naeem, Muhammad A.; Kumar, Priyank V. Journal of the American Chemical Society, Vol. 142, Issue 17 https://doi.org/10.1021/jacs.0c01135	journal	March 2020
Periodic Tendril Perversion and Helices in the AMoO ₂ F ₃ (A = K, Rb, NH ₄ , Tl) Family Hancock, Justin C.; Nisbet, Matthew L.; Zhang, Weiguo Journal of the American Chemical Society, Vol. 142, Issue 13 https://doi.org/10.1021/jacs.0c01218	journal	March 2020
RbMgCO ₃ F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Tran, T. Thao; He, Jiangang; Rondinelli, James M. Journal of the American Chemical Society, Vol. 137, Issue 33 https://doi.org/10.1021/jacs.5b06519	journal	August 2015
Superconductivity gets an iron boost Mazin, Igor I. Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08914	journal	March 2010
Coulomb spin liquid in anion-disordered pyrochlore Tb2Hf2O7 Sibille, Romain; Lhotel, Elsa; Ciomaga Hatnean, Monica Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00905-w	journal	October 2017
Multiple Coulomb phase in the fluoride pyrochlore CsNiCrF6 Fennell, T.; Harris, M. J.; Calder, S. Nature Physics, Vol. 15, Issue 1 https://doi.org/10.1038/s41567-018-0309-3	journal	October 2018
RbFe ²⁺ Fe ³ ⁺ F ₆ : Synthesis, structure, and characterization of a new charge-ordered magnetically frustrated pyrochlore-related mixed-metal fluoride Kim, Sun Woo; Kim, Sang-Hwan; Halasyamani, P. Shiv Chem. Sci., Vol. 3, Issue 3 https://doi.org/10.1039/C2SC00765G	journal	January 2012
RE ₃ Sb ₃ Zn ₂ O ₁₄ (RE = La, Pr, Nd, Sm, Eu, Gd): a new family of pyrochlore derivatives with rare earth ions on a 2D Kagome lattice Sanders, M. B.; Krizan, J. W.; Cava, R. J. Journal of Materials Chemistry C, Vol. 4, Issue 3 https://doi.org/10.1039/C5TC03798K	journal	January 2016
Pyrochlore phase Ce ₂ Sn ₂ O ₇ via an atom-confining strategy for reversible lithium storage Xu, Jijian; Wang, Dong; Kong, Shuyi Journal of Materials Chemistry A, Vol. 8, Issue 11 https://doi.org/10.1039/C9TA13602A	journal	January 2020
Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs ₂ PuSi ₆ O ₁₅ Pace, Kristen A.; Klepov, Vladislav V.; Christian, Matthew S. Chemical Communications, Vol. 56, Issue 66 https://doi.org/10.1039/D0CC02674C	journal	January 2020
Quaternary cerium( iv ) containing fluorides exhibiting Ce ₃ F ₁₆ sheets and Ce ₆ F ₃₀ frameworks Ayer, Gyanendra B.; Klepov, Vladislav V.; Pace, Kristen A. Dalton Transactions, Vol. 49, Issue 18 https://doi.org/10.1039/D0DT00616E	journal	January 2020
Tolerance factor, phase stability and order–disorder of the pyrochlore structure Song, Zhen; Liu, Quanlin Inorganic Chemistry Frontiers, Vol. 7, Issue 7 https://doi.org/10.1039/D0QI00016G	journal	January 2020
Synthesis and crystal structure of caesium diaquatetrafluoromanganate( III ) Bukovec, Peter; Kaučič, Venčeslav J. Chem. Soc., Dalton Trans., Issue 9 https://doi.org/10.1039/DT9770000945	journal	January 1977
Magnetic and structural properties of ferromagnetic Fe ₅ PB ₂ and Fe ₅ SiB ₂ and effects of Co and Mn substitutions McGuire, Michael A.; Parker, David S. Journal of Applied Physics, Vol. 118, Issue 16 https://doi.org/10.1063/1.4934496	journal	October 2015
Extended magnetic exchange interactions in the high-temperature ferromagnet MnBi Williams, T. J.; Taylor, A. E.; Christianson, A. D. Applied Physics Letters, Vol. 108, Issue 19 https://doi.org/10.1063/1.4948933	journal	May 2016
Discovery of ferromagnetism with large magnetic anisotropy in ZrMnP and HfMnP Lamichhane, Tej N.; Taufour, Valentin; Masters, Morgan W. Applied Physics Letters, Vol. 109, Issue 9 https://doi.org/10.1063/1.4961933	journal	August 2016
WIEN2k: An APW+lo program for calculating the properties of solids Blaha, Peter; Schwarz, Karlheinz; Tran, Fabien The Journal of Chemical Physics, Vol. 152, Issue 7 https://doi.org/10.1063/1.5143061	journal	February 2020
NaSrCo ₂ F ₇ , a Co ²⁺ pyrochlore antiferromagnet Krizan, J. W.; Cava, R. J. Journal of Physics: Condensed Matter, Vol. 27, Issue 29 https://doi.org/10.1088/0953-8984/27/29/296002	journal	July 2015
Charge ordering and magnetic frustration in CsFe ₂ F ₆ Liu, Shanshan; Xu, Yuanhui; Cui, Yanli Journal of Physics: Condensed Matter, Vol. 29, Issue 31 https://doi.org/10.1088/1361-648X/aa76be	journal	June 2017
Semihard Iron-Based Permanent-Magnet Materials Yin, Li; Juneja, Rinkle; Lindsay, Lucas Physical Review Applied, Vol. 15, Issue 2 https://doi.org/10.1103/PhysRevApplied.15.024012	journal	February 2021
Tuning the Magnetic Properties and Structural Stabilities of the 2-17-3 Magnets Sm 2 Fe 17 X 3 ( X = C , N) by Substituting La or Ce for Sm Pandey, Tribhuwan; Du, Mao-Hua; Parker, David S. Physical Review Applied, Vol. 9, Issue 3 https://doi.org/10.1103/PhysRevApplied.9.034002	journal	March 2018
Evidence of Ba-substitution induced spin-canting in the magnetic Weyl semimetal Eu Cd 2 As 2 Sanjeewa, L. D.; Xing, J.; Taddei, K. M. Physical Review B, Vol. 102, Issue 10 https://doi.org/10.1103/PhysRevB.102.104404	journal	September 2020
Magnetic excitations in a highly frustrated pyrochlore antiferromagnet Harris, M. J.; Zinkin, M. P.; Zeiske, T. Physical Review B, Vol. 52, Issue 2 https://doi.org/10.1103/PhysRevB.52.R707	journal	July 1995
Magnetic and specific heat studies of the cation-ordered pyrochlore NH 4 CoAlF 6 Raju, N. P.; Greedan, J. E.; Subramanian, M. A. Physical Review B, Vol. 58, Issue 9 https://doi.org/10.1103/PhysRevB.58.5550	journal	September 1998
Local lattice disorder in the geometrically frustrated spin-glass pyrochlore Y 2 Mo 2 O 7 Booth, C. H.; Gardner, J. S.; Kwei, G. H. Physical Review B, Vol. 62, Issue 2 https://doi.org/10.1103/PhysRevB.62.R755	journal	July 2000
Low-temperature spin freezing in the Dy 2 Ti 2 O 7 spin ice Snyder, J.; Ueland, B. G.; Slusky, J. S. Physical Review B, Vol. 69, Issue 6 https://doi.org/10.1103/PhysRevB.69.064414	journal	February 2004
Vibrational properties of MnO and NiO from DFT + U -based density functional perturbation theory Floris, A.; de Gironcoli, S.; Gross, E. K. U. Physical Review B, Vol. 84, Issue 16 https://doi.org/10.1103/PhysRevB.84.161102	journal	October 2011
Liquidlike correlations in single-crystalline Y 2 Mo 2 O 7 : An unconventional spin glass Silverstein, H. J.; Fritsch, K.; Flicker, F. Physical Review B, Vol. 89, Issue 5 https://doi.org/10.1103/PhysRevB.89.054433	journal	February 2014
NaCaN i 2 F 7 : A frustrated high-temperature pyrochlore antiferromagnet with S = 1 N i 2 + Krizan, J. W.; Cava, R. J. Physical Review B, Vol. 92, Issue 1 https://doi.org/10.1103/PhysRevB.92.014406	journal	July 2015
Electrical conduction mediated by fluorine atoms in the pyrochlore fluorides RbV 2 F 6 and CsV 2 F 6 with mixed-valent V atoms Ueda, Hiroaki; Yamada, Kihiro; Yamauchi, Hirotaka Physical Review B, Vol. 93, Issue 19 https://doi.org/10.1103/PhysRevB.93.195168	journal	May 2016
Single-ion properties of the S eff = 1 2 XY antiferromagnetic pyrochlores Na A ′ Co 2 F 7 ( A ′ = Ca 2 + , Sr 2 + ) Ross, K. A.; Brown, J. M.; Cava, R. J. Physical Review B, Vol. 95, Issue 14 https://doi.org/10.1103/PhysRevB.95.144414	journal	April 2017
Magnetic order and interactions in ferrimagnetic Mn 3 Si 2 Te 6 May, Andrew F.; Liu, Yaohua; Calder, Stuart Physical Review B, Vol. 95, Issue 17 https://doi.org/10.1103/PhysRevB.95.174440	journal	May 2017
Negative thermal expansion and magnetoelastic coupling in the breathing pyrochlore lattice material LiGaCr 4 S 8 Pokharel, G.; May, A. F.; Parker, D. S. Physical Review B, Vol. 97, Issue 13 https://doi.org/10.1103/PhysRevB.97.134117	journal	April 2018
Anharmonic Magnon Excitations in Noncollinear and Charge-Ordered RbFe 2 + Fe 3 + F 6 Songvilay, M.; Rodriguez, E. E.; Lindsay, R. Physical Review Letters, Vol. 121, Issue 8 https://doi.org/10.1103/PhysRevLett.121.087201	journal	August 2018
Order out of a Coulomb Phase and Higgs Transition: Frustrated Transverse Interactions of Nd 2 Zr 2 O 7 Xu, J.; Benton, Owen; Islam, A. T. M. N. Physical Review Letters, Vol. 124, Issue 9 https://doi.org/10.1103/PhysRevLett.124.097203	journal	March 2020
Magnetic structure of the spin-liquid state in a frustrated pyrochlore Harris, M. J.; Zinkin, M. P.; Tun, Z. Physical Review Letters, Vol. 73, Issue 1 https://doi.org/10.1103/PhysRevLett.73.189	journal	July 1994
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Magnetic properties of single crystalline itinerant ferromagnet AlFe 2 B 2 Lamichhane, Tej N.; Xiang, Li; Lin, Qisheng Physical Review Materials, Vol. 2, Issue 8 https://doi.org/10.1103/PhysRevMaterials.2.084408	journal	August 2018
A-type antiferromagnetic order in MnBi 4 Te 7 and MnBi 6 Te 10 single crystals Yan, J. -Q.; Liu, Y. H.; Parker, D. S. Physical Review Materials, Vol. 4, Issue 5 https://doi.org/10.1103/PhysRevMaterials.4.054202	journal	May 2020
Magnetic pyrochlore oxides Gardner, Jason S.; Gingras, Michel J. P.; Greedan, John E. Reviews of Modern Physics, Vol. 82, Issue 1 https://doi.org/10.1103/RevModPhys.82.53	journal	January 2010
OLEX2 : a complete structure solution, refinement and analysis program Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889808042726	journal	January 2009
Magnetic symmetry in the Bilbao Crystallographic Server: a computer program to provide systematic absences of magnetic neutron diffraction Gallego, Samuel V.; Tasci, Emre S.; de la Flor, Gemma Journal of Applied Crystallography, Vol. 45, Issue 6 https://doi.org/10.1107/S0021889812042185	journal	November 2012
Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups Aroyo, Mois I.; Kirov, Asen; Capillas, Cesar Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 2 https://doi.org/10.1107/S0108767305040286	journal	March 2006
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M. Journal of Applied Crystallography, Vol. 48, Issue 1 https://doi.org/10.1107/S1600576714022985	journal	January 2015
On the effective ionic radii for ammonium Sidey, Vasyl Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 4 https://doi.org/10.1107/S2052520616008064	journal	August 2016
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
Magnetic Coulomb Phase in the Spin Ice Ho2Ti2O7 Fennell, T.; Deen, P. P.; Wildes, A. R. Science, Vol. 326, Issue 5951 https://doi.org/10.1126/science.1177582	journal	September 2009
Colossal Magnetoresistance Without Mn3+/Mn4+ Double Exchange in the Stoichiometric Pyrochlore Tl2Mn2O7 Subramanian, M. A.; Toby, B. H.; Ramirez, A. P. Science, Vol. 273, Issue 5271 https://doi.org/10.1126/science.273.5271.81	journal	July 1996
Magnetic properties of Pr2–x Fe1 + x SbO7 and Bi2–x Ln x FeSbO7 (Ln = La, Pr) pyrochlore solid solutions Egorysheva, A. V.; Ellert, O. G.; Gaitko, O. M. Inorganic Materials, Vol. 52, Issue 10 https://doi.org/10.1134/S0020168516100071	journal	September 2016
Symmetry-Based Computational Tools for Magnetic Crystallography Perez-Mato, J. M.; Gallego, S. V.; Tasci, E. S. Annual Review of Materials Research, Vol. 45, Issue 1 https://doi.org/10.1146/annurev-matsci-070214-021008	journal	July 2015
Jahn-Teller Phenomena in Solids Goodenough, J. B. Annual Review of Materials Science, Vol. 28, Issue 1 https://doi.org/10.1146/annurev.matsci.28.1.1	journal	August 1998
Structural Chemistry and Jahn-Teller Effect in Fluoromanganates(Iii) Massa,, Werner Reviews in Inorganic Chemistry, Vol. 19, Issue 1-2 https://doi.org/10.1515/REVIC.1999.19.1-2.117	journal	January 1999
¹¹⁹ Sn Mössbauer spectroscopy of solvothermally synthesized fluorides A SnF ₃ ( A = Na, K, Rb, Cs) Gerke, Birgit; Tran, Thanh Thao; Pöttgen, Rainer Zeitschrift für Naturforschung B, Vol. 70, Issue 10 https://doi.org/10.1515/znb-2015-0099	journal	August 2015
Bilbao Crystallographic Server: I. Databases and crystallographic computing programs Aroyo, Mois Ilia; Perez-Mato, Juan Manuel; Capillas, Cesar Zeitschrift für Kristallographie - Crystalline Materials, Vol. 221, Issue 1 https://doi.org/10.1524/zkri.2006.221.1.15	journal	January 2006

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Chemical structure
Magnetic properties
Phase transitions
Transition metals

Title: Chloride Reduction of Mn3+ in Mild Hydrothermal Synthesis of a Charge Ordered Defect Pyrochlore, CsMn2+Mn3+F6, a Canted Antiferromagnet with a Hard Ferromagnetic Component

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Title: Chloride Reduction of Mn³⁺ in Mild Hydrothermal Synthesis of a Charge Ordered Defect Pyrochlore, CsMn²⁺Mn³⁺F₆, a Canted Antiferromagnet with a Hard Ferromagnetic Component