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Title: Photonic Bandgap in Achiral Liquid Crystals—A Twist on a Twist

Abstract

Abstract Achiral mesogenic molecules are shown to be able to spontaneously assemble into liquid crystalline smectic phases having either simple or double‐helical structures. At the transition between these phases, the double‐helical structure unwinds. As a consequence, in some temperature range, the pitch of the helix becomes comparable to the wavelength of visible light and the selective reflection of light in the visible range is observed. The photonic bandgap phenomenon is reported for achiral liquid crystals.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [3];  [4]; ORCiD logo [1]
  1. Faculty of Chemistry University of Warsaw Zwirki i Wigury 101 Warsaw 02‐089 Poland
  2. Department of Physics Faculty of Natural Sciences and Mathematics University of Maribor Koroška 160 Maribor 2000 Slovenia, Jozef Stefan Institute Jamova 39 Ljubljana 1000 Slovenia
  3. Department of Chemistry King's College University of Aberdeen Aberdeen AB24 3UE UK
  4. Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Centre (Poland); Slovenian Research Agency (ARRS)
OSTI Identifier:
1813485
Alternate Identifier(s):
OSTI ID: 1813487; OSTI ID: 1819184
Grant/Contract Number:  
DE‐AC02‐05CH11231.; AC02-05CH11231; 2016/22/A/ST5/00319
Resource Type:
Published Article
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 33 Journal Issue: 39; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English
Subject:
36 MATERIALS SCIENCE; chirality; helical structures; liquid crystals; photonic bandgap; twist–bend phases

Citation Formats

Pociecha, Damian, Vaupotič, Nataša, Majewska, Magdalena, Cruickshank, Ewan, Walker, Rebecca, Storey, John M. D., Imrie, Corrie T., Wang, Cheng, and Gorecka, Ewa. Photonic Bandgap in Achiral Liquid Crystals—A Twist on a Twist. Germany: N. p., 2021. Web. doi:10.1002/adma.202103288.
Pociecha, Damian, Vaupotič, Nataša, Majewska, Magdalena, Cruickshank, Ewan, Walker, Rebecca, Storey, John M. D., Imrie, Corrie T., Wang, Cheng, & Gorecka, Ewa. Photonic Bandgap in Achiral Liquid Crystals—A Twist on a Twist. Germany. https://doi.org/10.1002/adma.202103288
Pociecha, Damian, Vaupotič, Nataša, Majewska, Magdalena, Cruickshank, Ewan, Walker, Rebecca, Storey, John M. D., Imrie, Corrie T., Wang, Cheng, and Gorecka, Ewa. Mon . "Photonic Bandgap in Achiral Liquid Crystals—A Twist on a Twist". Germany. https://doi.org/10.1002/adma.202103288.
@article{osti_1813485,
title = {Photonic Bandgap in Achiral Liquid Crystals—A Twist on a Twist},
author = {Pociecha, Damian and Vaupotič, Nataša and Majewska, Magdalena and Cruickshank, Ewan and Walker, Rebecca and Storey, John M. D. and Imrie, Corrie T. and Wang, Cheng and Gorecka, Ewa},
abstractNote = {Abstract Achiral mesogenic molecules are shown to be able to spontaneously assemble into liquid crystalline smectic phases having either simple or double‐helical structures. At the transition between these phases, the double‐helical structure unwinds. As a consequence, in some temperature range, the pitch of the helix becomes comparable to the wavelength of visible light and the selective reflection of light in the visible range is observed. The photonic bandgap phenomenon is reported for achiral liquid crystals.},
doi = {10.1002/adma.202103288},
journal = {Advanced Materials},
number = 39,
volume = 33,
place = {Germany},
year = {Mon Aug 16 00:00:00 EDT 2021},
month = {Mon Aug 16 00:00:00 EDT 2021}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adma.202103288

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