In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy

Wang, Lixin; Deng, Da; Lev, Leonid C.; Ng, Simon

doi:10.1016/j.jpowsour.2014.04.113

Title: In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy

Authors:: Wang, Lixin; Deng, Da; Lev, Leonid C.; Ng, Simon

Publication Date:: Sat Nov 01 00:00:00 EDT 2014

Sponsoring Org.:: USDOE

OSTI Identifier:: 1810938

Grant/Contract Number:: DEFG36-05GO85005

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Name: Journal of Power Sources Journal Volume: 265 Journal Issue: C; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Wang, Lixin, Deng, Da, Lev, Leonid C., and Ng, Simon. In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy.  Netherlands: N. p., 2014. 
Web.  doi:10.1016/j.jpowsour.2014.04.113.

Copy to clipboard


                    Wang, Lixin, Deng, Da, Lev, Leonid C., & Ng, Simon. In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy.  Netherlands.  https://doi.org/10.1016/j.jpowsour.2014.04.113

Copy to clipboard


                    Wang, Lixin, Deng, Da, Lev, Leonid C., and Ng, Simon. Sat .  
"In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy".  Netherlands.  https://doi.org/10.1016/j.jpowsour.2014.04.113.

Copy to clipboard


                    
@article{osti_1810938,

  title        = {In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy},

  author       = {Wang, Lixin and Deng, Da and Lev, Leonid C. and Ng, Simon},

  abstractNote = {},

  doi          = {10.1016/j.jpowsour.2014.04.113},

  journal      = {Journal of Power Sources},

  number       = C,

  volume       = 265,

  place        = {Netherlands},

  year         = {Sat Nov 01 00:00:00 EDT 2014},

  month        = {Sat Nov 01 00:00:00 EDT 2014}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1016/j.jpowsour.2014.04.113

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Surface films phenomena on vanadium-pentoxide cathodes for Li and Li-ion batteries: in situ AFM imaging
journal, June 2004

Cohen, Yaron S.; Aurbach, Doron
Electrochemistry Communications, Vol. 6, Issue 6
DOI: 10.1016/j.elecom.2004.03.014

Chemical properties of various organic electrolytes for lithium rechargeable batteries
journal, September 1997

Mori, Shoichiro; Asahina, Hitoshi; Suzuki, Hitoshi
Journal of Power Sources, Vol. 68, Issue 1
DOI: 10.1016/S0378-7753(97)02619-0

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999

Aurbach, D.; Markovsky, B.; Weissman, I.
Electrochimica Acta, Vol. 45, Issue 1-2
DOI: 10.1016/S0013-4686(99)00194-2

The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries
journal, January 1994

Aurbach, Doron
Journal of The Electrochemical Society, Vol. 141, Issue 3
DOI: 10.1149/1.2054777

Assembly and Electrochemical Characterization of Nanometer-Scale Electrode|Solid Electrolyte Interfaces
journal, September 2006

Loster, Matthias; Friedrich, K. Andreas; Scherson, Daniel A.
The Journal of Physical Chemistry B, Vol. 110, Issue 37
DOI: 10.1021/jp063255t

In situ atomic force microscopy study of dimensional changes during Li+ ion intercalation/de-intercalation in highly oriented pyrolytic graphite
journal, January 2005

Campana, F. P.; Kötz, R.; Vetter, J.
Electrochemistry Communications, Vol. 7, Issue 1
DOI: 10.1016/j.elecom.2004.11.015

The Electrochemical Decomposition of Propylene Carbonate on Graphite
journal, January 1970

Dey, A. N.; Sullivan, B. P.
Journal of The Electrochemical Society, Vol. 117, Issue 2
DOI: 10.1149/1.2407470

In situ atomic force microscopy nanoindentation of lithiated silicon nanopillars for lithium ion batteries
journal, July 2014

McAllister, Quinn P.; Strawhecker, Kenneth E.; Becker, Collin R.
Journal of Power Sources, Vol. 257
DOI: 10.1016/j.jpowsour.2014.01.077

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries
journal, January 1999

Bar-Tow, D.
Journal of The Electrochemical Society, Vol. 146, Issue 3
DOI: 10.1149/1.1391688

AFM study of surface film formation on a composite graphite electrode in lithium-ion batteries
journal, June 2003

Jeong, Soon-Ki; Inaba, Minoru; Iriyama, Yasutoshi
Journal of Power Sources, Vol. 119-121
DOI: 10.1016/S0378-7753(03)00288-X

In situ AFM studies of SEI formation at a Sn electrode
journal, November 2009

Lucas, Ivan T.; Pollak, Elad; Kostecki, Robert
Electrochemistry Communications, Vol. 11, Issue 11
DOI: 10.1016/j.elecom.2009.09.019

Visualization of Electrode–Electrolyte Interfaces in LiPF ₆ /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM
journal, March 2014

Zeng, Zhiyuan; Liang, Wen-I; Liao, Hong-Gang
Nano Letters, Vol. 14, Issue 4
DOI: 10.1021/nl403922u

Cathodic decomposition reactions of propylene carbonate
journal, December 1976

Eichinger, G.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 74, Issue 2
DOI: 10.1016/S0022-0728(76)80234-3

Li-ion dynamics and reactivity on the nanoscale
journal, November 2011

Kalinin, Sergei; Balke, Nina; Jesse, Stephen
Materials Today, Vol. 14, Issue 11
DOI: 10.1016/S1369-7021(11)70280-2

Similar Records in DOE PAGES and OSTI.GOV collections:

In Situ X-ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode

Journal Article Chattopadhyay, Sudeshna ; Lipson, Albert L. ; Karmel, Hunter J. ; ... - Chemistry of Materials
https://doi.org/10.1021/cm301584r
In Situ Measurement of Solid Electrolyte Interphase Evolution on Silicon Anodes Using Atomic Force Microscopy

Journal Article Yoon, Insun ; Abraham, Daniel P. ; Lucht, Brett L. ; ... - Advanced Energy Materials

In situ measurements of the growth of solid electrolyte interphase (SEI) layer on silicon and the lithiation-induced volume changes in silicon in lithium ion half-cells are reported. Thin film amorphous silicon electrodes are fabricated in a configuration that allows unambiguous separation of the total thickness change into contribution from SEI thickness and silicon volume change. Electrodes are assembled into a custom-designed electrochemical cell, which is integrated with an atomic force microscope. The electrodes are subjected to constant potential lithiation/delithiation at a sequence of potential values and the thickness measurements are made at each potential after equilibrium is reached. Experiments aremore »« less
https://doi.org/10.1002/aenm.201600099
Solid–Electrolyte Interphase Formation and Electrolyte Reduction at Li-Ion Battery Graphite Anodes: Insights from First-Principles Molecular Dynamics

Journal Article Ganesh, P. ; Kent, P. R. C. ; Jiang, De-en - Journal of Physical Chemistry. C

Understanding the nature and formation of the solid–electrolyte interphase (SEI) formed in electrochemical storage devices, such as Li-ion batteries, is most important for improving functionality. Few experiments exist that adequately probe the SEI, particularly in situ. We perform predictive ab initio molecular dynamics simulations of the anode–electrolyte interface for several electrolytes and interface functionalizations. These show strongly differing effects on the reducibility of the electrolyte. Electrolyte reduction occurs rapidly, on a picosecond time scale. Orientational ordering of electrolyte near the interface precedes reduction. The reduced species depend strongly on surface functionalization and presence of LiPF6 salt. While LiPF6 salt inmore »« less
https://doi.org/10.1021/jp3086304
Solid–Electrolyte Interphase Formation and Electrolyte Reduction at Li-Ion Battery Graphite Anodes: Insights from First-Principles Molecular Dynamics

Journal Article Ganesh, P. ; Kent, P. R. C. ; Jiang, De-en - Journal of Physical Chemistry. C
https://doi.org/10.1021/jp3086304
Mesoscale Elucidation of Solid Electrolyte Interphase Layer Formation in Li-Ion Battery Anode

Journal Article Hao, Feng ; Liu, Zhixiao ; Balbuena, Perla B. ; ... - Journal of Physical Chemistry. C

Capacity fade in lithium-ion batteries largely originates from the undesired electrolyte decomposition, which results in the formation of solid electrolyte interphase (SEI) and the anode surface passivation. In this work, a mesoscale interfacial modeling approach is developed to investigate the formation and growth of the SEI film on a typical graphite based anode over several cycles. It is found that lithium diffusion kinetics in the SEI film significantly affects the SEI growth rate. A lower lithium diffusion barrier leads to a higher growth rate. The present model demonstrates that the SEI thickness is a linear function of the square rootmore »« less
Cited by 33
https://doi.org/10.1021/acs.jpcc.7b09465

Full Text Available

Similar Records

Title: In-situ investigation of solid-electrolyte interphase formation on the anode of Li-ion batteries with Atomic Force Microscopy

Citation Formats

Surface films phenomena on vanadium-pentoxide cathodes for Li and Li-ion batteries: in situ AFM imaging journal, June 2004

Chemical properties of various organic electrolytes for lithium rechargeable batteries journal, September 1997

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries journal, September 1999

The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries journal, January 1994

Assembly and Electrochemical Characterization of Nanometer-Scale Electrode|Solid Electrolyte Interfaces journal, September 2006

In situ atomic force microscopy study of dimensional changes during Li+ ion intercalation/de-intercalation in highly oriented pyrolytic graphite journal, January 2005

The Electrochemical Decomposition of Propylene Carbonate on Graphite journal, January 1970

In situ atomic force microscopy nanoindentation of lithiated silicon nanopillars for lithium ion batteries journal, July 2014

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries journal, January 1999

AFM study of surface film formation on a composite graphite electrode in lithium-ion batteries journal, June 2003

In situ AFM studies of SEI formation at a Sn electrode journal, November 2009

Visualization of Electrode–Electrolyte Interfaces in LiPF 6 /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM journal, March 2014

Cathodic decomposition reactions of propylene carbonate journal, December 1976

Li-ion dynamics and reactivity on the nanoscale journal, November 2011

Surface films phenomena on vanadium-pentoxide cathodes for Li and Li-ion batteries: in situ AFM imaging
journal, June 2004

Chemical properties of various organic electrolytes for lithium rechargeable batteries
journal, September 1997

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999

The Correlation Between the Surface Chemistry and the Performance of Li-Carbon Intercalation Anodes for Rechargeable ‘Rocking-Chair’ Type Batteries
journal, January 1994

Assembly and Electrochemical Characterization of Nanometer-Scale Electrode|Solid Electrolyte Interfaces
journal, September 2006

In situ atomic force microscopy study of dimensional changes during Li+ ion intercalation/de-intercalation in highly oriented pyrolytic graphite
journal, January 2005

The Electrochemical Decomposition of Propylene Carbonate on Graphite
journal, January 1970

In situ atomic force microscopy nanoindentation of lithiated silicon nanopillars for lithium ion batteries
journal, July 2014

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries
journal, January 1999

AFM study of surface film formation on a composite graphite electrode in lithium-ion batteries
journal, June 2003

In situ AFM studies of SEI formation at a Sn electrode
journal, November 2009

Visualization of Electrode–Electrolyte Interfaces in LiPF ₆ /EC/DEC Electrolyte for Lithium Ion Batteries via in Situ TEM
journal, March 2014

Cathodic decomposition reactions of propylene carbonate
journal, December 1976

Li-ion dynamics and reactivity on the nanoscale
journal, November 2011