High‐efficiency adsorption of various heavy metals by tea residue biochar loaded with nanoscale zero‐valent iron

Liu, Shuang; Zhang, Shuaizhong; Fan, Minghao; Yuan, Yongkai; Sun, Xun; Wang, Dongfeng; Xu, Ying

doi:10.1002/ep.13706

Title: High‐efficiency adsorption of various heavy metals by tea residue biochar loaded with nanoscale zero‐valent iron

Journal Article · 05 July 2021 · Environmental Progress and Sustainable Energy

DOI: https://doi.org/10.1002/ep.13706 · OSTI ID:1805101

Liu, Shuang ^[1]; Zhang, Shuaizhong ^[1]; Fan, Minghao ^[1]; Yuan, Yongkai ^[1]; Sun, Xun ^[1]; Wang, Dongfeng ^[1];

^[1]

College of Food Science and Engineering Ocean University of China Qingdao Shandong China

Abstract Nanoscale zero‐valent iron (nZVI) loaded on tea residue biochar activated with phosphoric acid composites was synthesized. This adsorbent can efficiently adsorb multiple heavy metal ions such as Pb (II), Cr (III), Cu (II), and Ni (II) simultaneously. The adsorption process was found to follow the pseudo‐second‐order kinetic model. Equilibrium adsorption capacities reached 288.18, 162.34, 242.72, and 267.22 mg·g ⁻¹ for Pb(II), Cr(III), Cu(II), and Ni(II), respectively. The common interfering ions exhibited lower influence on its adsorption capacity. The adsorption mechanism includes reduction, ion exchange, surface complexation and precipitation. Furthermore, the waste adsorbent was converted into a catalyst in situ, which could catalyze the degradation of Congo red by establishing an electron transfer pathway. This research provides a new concept for the sustainable utilization of industrial tea residues and the harmless treatment of waste nZVI composite adsorbents.

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Sponsoring Organization:: USDOE

OSTI ID:: 1805101

Journal Information:: Environmental Progress and Sustainable Energy, Journal Name: Environmental Progress and Sustainable Energy Journal Issue: 6 Vol. 40; ISSN 1944-7442

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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