Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes
Abstract
We report the synthesis of tetrameric Cu(I) and Ag(I) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip)3]1- and [NP(1,2-bis-tBu-diamidoethane)(NEt2)]1- ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.
- Authors:
-
[1];
[2]
- Georgia Institute of Technology, Atlanta, GA (United States). Dept. of Chemistry and Biochemistry
- Georgia Institute of Technology, Atlanta, GA (United States). Dept. of Chemistry and Biochemistry. Nuclear and Radiological Engineering Program
- Publication Date:
- Research Org.:
- Georgia Institute of Technology, Atlanta, GA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1803769
- Alternate Identifier(s):
- OSTI ID: 1608730
- Grant/Contract Number:
- SC0019385
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 49; Journal Issue: 17; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Aguirre Quintana, Luis M., Jiang, Ningxin, Bacsa, John, and La Pierre, Henry S. Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes. United States: N. p., 2020.
Web. doi:10.1039/d0dt00842g.
Aguirre Quintana, Luis M., Jiang, Ningxin, Bacsa, John, & La Pierre, Henry S. Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes. United States. https://doi.org/10.1039/d0dt00842g
Aguirre Quintana, Luis M., Jiang, Ningxin, Bacsa, John, and La Pierre, Henry S. Wed .
"Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes". United States. https://doi.org/10.1039/d0dt00842g. https://www.osti.gov/servlets/purl/1803769.
@article{osti_1803769,
title = {Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes},
author = {Aguirre Quintana, Luis M. and Jiang, Ningxin and Bacsa, John and La Pierre, Henry S.},
abstractNote = {We report the synthesis of tetrameric Cu(I) and Ag(I) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip)3]1- and [NP(1,2-bis-tBu-diamidoethane)(NEt2)]1- ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.},
doi = {10.1039/d0dt00842g},
journal = {Dalton Transactions},
number = 17,
volume = 49,
place = {United States},
year = {Wed Apr 01 00:00:00 EDT 2020},
month = {Wed Apr 01 00:00:00 EDT 2020}
}
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