Monitoring the growth dynamics of colloidal gold-silver core-shell nanoparticles using in situ second harmonic generation and extinction spectroscopy

Ranasinghe, Jeewan C.; Dikkumbura, Asela S.; Hamal, Prakash; Chen, Min; Khoury, Rami A.; Smith, Holden T.; Lopata, Kenneth; Haber, Louis H.

doi:10.1063/1.5127941

Title: Monitoring the growth dynamics of colloidal gold-silver core-shell nanoparticles using in situ second harmonic generation and extinction spectroscopy

Journal Article · 13 December 2019 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.5127941 · OSTI ID:1803180

Ranasinghe, Jeewan C. ^[1]; Dikkumbura, Asela S. ^[2]; Hamal, Prakash ^[2]; Chen, Min ^[2]; Khoury, Rami A. ^[2]; Smith, Holden T. ^[2];

^[2];

^[2]

Louisiana State Univ., Baton Rouge, LA (United States); OSTI
Louisiana State Univ., Baton Rouge, LA (United States)

The growth dynamics of gold-silver core-shell (Au@Ag) nanoparticles are studied using in situ time-dependent second harmonic generation (SHG) and extinction spectroscopy to investigate the nanoparticle shell formation. The silver shell is grown by reduction of silver cations onto a 14 nm gold core using ascorbic acid in colloidal aqueous solution under varying reaction concentrations producing Au@Ag nanoparticles of final sizes ranging from 51 to 78 nm in diameter. The in situ extinction spectra show a rapid increase in intensity on the timescale of 5–6 s with blue shifting and narrowing of the plasmonic peak during the silver shell formation. The in situ SHG signals show an abrupt rise at early times of the reaction, followed by a time-dependent biexponential decrease, where the faster SHG lifetime corresponds to the timescale of the shell growth, and where the slower SHG lifetime is attributed to changes in the nanoparticle surface charge density. A large enhancement in the SHG signal at early stages of the reaction is caused by plasmonic hot spots due to the nanoparticle surface morphology, which becomes smoother as the reaction proceeds. The final extinction spectra are compared to finite-difference time-domain (FDTD) calculations, showing general agreement with experiment, where the plasmon peak red shifts and increases in spectral width as the silver shell thickness increases. These in situ SHG and extinction spectroscopy results, combined with FDTD calculations, help characterize the complicated processes involved in colloidal nanoparticle shell formation in real time for developing potential plasmon-enhanced nanomaterial applications.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0017868

OSTI ID:: 1803180

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 22 Vol. 151; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (75)

Size control over spherical silver nanoparticles by ascorbic acid reduction Qin, Yaqiong; Ji, Xiaohui; Jing, Jing Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 372, Issue 1-3 https://doi.org/10.1016/j.colsurfa.2010.10.013	journal	December 2010
Get charged up: Nonlinear optical voltammetry for quantifying the thermodynamics and electrostatics of metal cations at aqueous/oxide interfaces Hayes, Patrick L.; Malin, Jessica N.; Jordan, David S. Chemical Physics Letters, Vol. 499, Issue 4-6 https://doi.org/10.1016/j.cplett.2010.09.060	journal	October 2010
Probing the colloidal gold nanoparticle/aqueous interface with second harmonic generation Haber, Louis H.; Kwok, Sheldon J. J.; Semeraro, Monica Chemical Physics Letters, Vol. 507, Issue 1-3 https://doi.org/10.1016/j.cplett.2011.03.042	journal	April 2011
Core–shell gold/silver nanoparticles: Synthesis and optical properties Lu, Lu; Burkey, Gwendolyn; Halaciuga, Ionel Journal of Colloid and Interface Science, Vol. 392 https://doi.org/10.1016/j.jcis.2012.09.057	journal	February 2013
Comparison of the Energetics of Avidin, Streptavidin, NeutrAvidin, and Anti-Biotin Antibody Binding to Biotinylated Lipid Bilayer Examined by Second-Harmonic Generation Nguyen, Trang T.; Sly, Krystal L.; Conboy, John C. Analytical Chemistry, Vol. 84, Issue 1 https://doi.org/10.1021/ac202375n	journal	December 2011
Seeding a New Kind of Garden: Synthesis of Architecturally Defined Multimetallic Nanostructures by Seed-Mediated Co-Reduction Weiner, Rebecca G.; Kunz, Meredith R.; Skrabalak, Sara E. Accounts of Chemical Research, Vol. 48, Issue 10 https://doi.org/10.1021/acs.accounts.5b00300	journal	September 2015
Ternary Silver Halide Nanocrystals Abeyweera, Sasitha C.; Rasamani, Kowsalya D.; Sun, Yugang Accounts of Chemical Research, Vol. 50, Issue 7 https://doi.org/10.1021/acs.accounts.7b00194	journal	June 2017
Kinetic Modeling of Accelerated Stability Testing Enabled by Second Harmonic Generation Microscopy Song, Zhengtian; Sarkar, Sreya; Vogt, Andrew D. Analytical Chemistry, Vol. 90, Issue 7 https://doi.org/10.1021/acs.analchem.7b04260	journal	February 2018
Quantification of Interface-Dependent Plasmon Quality Factors Using Single-Beam Nonlinear Optical Interferometry Zhao, Tian; Steves, Megan A.; Chapman, Brian S. Analytical Chemistry, Vol. 90, Issue 22 https://doi.org/10.1021/acs.analchem.8b04101	journal	October 2018
Bimetallic Nanocrystals: Syntheses, Properties, and Applications Gilroy, Kyle D.; Ruditskiy, Aleksey; Peng, Hsin-Chieh Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.6b00211	journal	July 2016
Thermodynamics of Indomethacin Adsorption to Phospholipid Membranes Fearon, Amanda D.; Stokes, Grace Y. The Journal of Physical Chemistry B, Vol. 121, Issue 46 https://doi.org/10.1021/acs.jpcb.7b08359	journal	November 2017
Determination of the Surface Charge Density of Colloidal Gold Nanoparticles Using Second Harmonic Generation Kumal, Raju R.; Karam, Tony E.; Haber, Louis H. The Journal of Physical Chemistry C, Vol. 119, Issue 28 https://doi.org/10.1021/acs.jpcc.5b00568	journal	June 2015
Bimodal or Trimodal? The Influence of Starting pH on Site Identity and Distribution at the Low Salt Aqueous/Silica Interface Darlington, Akemi M.; Gibbs-Davis, Julianne M. The Journal of Physical Chemistry C, Vol. 119, Issue 29 https://doi.org/10.1021/acs.jpcc.5b02480	journal	July 2015
Enhanced Photothermal Effects and Excited-State Dynamics of Plasmonic Size-Controlled Gold–Silver–Gold Core–Shell–Shell Nanoparticles Karam, Tony E.; Smith, Holden T.; Haber, Louis H. The Journal of Physical Chemistry C, Vol. 119, Issue 32 https://doi.org/10.1021/acs.jpcc.5b05110	journal	July 2015
Second Harmonic and Sum-Frequency Generation from Aqueous Interfaces Is Modulated by Interference Gonella, Grazia; Lütgebaucks, Cornelis; de Beer, Alex G. F. The Journal of Physical Chemistry C, Vol. 120, Issue 17 https://doi.org/10.1021/acs.jpcc.5b12453	journal	April 2016
Ultrafast Excited-State Dynamics in Shape- and Composition-Controlled Gold–Silver Bimetallic Nanostructures Zarick, Holly F.; Boulesbaa, Abdelaziz; Talbert, Eric M. The Journal of Physical Chemistry C, Vol. 121, Issue 8 https://doi.org/10.1021/acs.jpcc.6b12669	journal	February 2017
Capturing Plasmon–Molecule Dynamics in Dye Monolayers on Metal Nanoparticles Using Classical Electrodynamics with Quantum Embedding Smith, Holden T.; Karam, Tony E.; Haber, Louis H. The Journal of Physical Chemistry C, Vol. 121, Issue 31 https://doi.org/10.1021/acs.jpcc.7b03440	journal	July 2017
Impacts of Salt, Buffer, and Lipid Nature on Molecular Adsorption and Transport in Liposomes As Observed by Second Harmonic Generation Kumal, Raju R.; Nguyenhuu, Huy; Winter, James E. The Journal of Physical Chemistry C, Vol. 121, Issue 29 https://doi.org/10.1021/acs.jpcc.7b05058	journal	July 2017
Two-Photon Photoluminescence and Photothermal Properties of Hollow Gold Nanospheres for Efficient Theranostic Applications Vickers, Evan T.; Garai, Monalisa; Bonabi Naghadeh, Sara The Journal of Physical Chemistry C, Vol. 122, Issue 25 https://doi.org/10.1021/acs.jpcc.7b09055	journal	November 2017
Near-Infrared Photothermal Release of siRNA from the Surface of Colloidal Gold–Silver–Gold Core–Shell–Shell Nanoparticles Studied with Second-Harmonic Generation Kumal, Raju R.; Abu-Laban, Mohammad; Hamal, Prakash The Journal of Physical Chemistry C, Vol. 122, Issue 34 https://doi.org/10.1021/acs.jpcc.8b06117	journal	July 2018
Understanding the Optical Properties of Au@Ag Bimetallic Nanoclusters through Time-Resolved and Nonlinear Spectroscopy Ho-Wu, Rosina; Sahu, Prabhat Kumar; Wu, Nancy The Journal of Physical Chemistry C, Vol. 122, Issue 42 https://doi.org/10.1021/acs.jpcc.8b06360	journal	September 2018
Monitoring the Seed-Mediated Growth of Gold Nanoparticles Using in Situ Second Harmonic Generation and Extinction Spectroscopy Khoury, Rami A.; Ranasinghe, Jeewan C.; Dikkumbura, Asela S. The Journal of Physical Chemistry C, Vol. 122, Issue 42 https://doi.org/10.1021/acs.jpcc.8b07176	journal	September 2018
Surface Potential of a Planar Charged Lipid–Water Interface. What Do Vibrating Plate Methods, Second Harmonic and Sum Frequency Measure? Dreier, L. B.; Bernhard, C.; Gonella, G. The Journal of Physical Chemistry Letters, Vol. 9, Issue 19 https://doi.org/10.1021/acs.jpclett.8b02093	journal	September 2018
Beyond the Gouy–Chapman Model with Heterodyne-Detected Second Harmonic Generation Ohno, Paul E.; Chang, HanByul; Spencer, Austin P. The Journal of Physical Chemistry Letters, Vol. 10, Issue 10 https://doi.org/10.1021/acs.jpclett.9b00727	journal	April 2019
Monitoring the Photocleaving Dynamics of Colloidal MicroRNA-Functionalized Gold Nanoparticles Using Second Harmonic Generation Kumal, Raju R.; Landry, Corey R.; Abu-Laban, Mohammad Langmuir, Vol. 31, Issue 36 https://doi.org/10.1021/acs.langmuir.5b02199	journal	September 2015
Bumpy Hollow Gold Nanospheres for Theranostic Applications: Effect of Surface Morphology on Photothermal Conversion Efficiency Lindley, Sarah A.; Zhang, Jin Z. ACS Applied Nano Materials, Vol. 2, Issue 2 https://doi.org/10.1021/acsanm.8b02331	journal	January 2019
Crystal Structures and Growth Mechanisms of Au@Ag Core−Shell Nanoparticles Prepared by the Microwave−Polyol Method Tsuji, Masaharu; Miyamae, Nobuhiro; Lim, Seongyop Crystal Growth & Design, Vol. 6, Issue 8 https://doi.org/10.1021/cg060103e	journal	August 2006
Evidence for Seed-Mediated Nucleation in the Chemical Reduction of Gold Salts to Gold Nanoparticles Jana, Nikhil R.; Gearheart, Latha; Murphy, Catherine J. Chemistry of Materials, Vol. 13, Issue 7 https://doi.org/10.1021/cm000662n	journal	July 2001
Minimizing Formaldehyde Use in the Synthesis of Gold−Silver Core−Shell Nanoparticles Norris, Christopher B.; Joseph, Paul R.; Mackiewicz, Marilyn R. Chemistry of Materials, Vol. 22, Issue 12 https://doi.org/10.1021/cm9035693	journal	June 2010
Seeding of Colloidal Au Nanoparticle Solutions. 2. Improved Control of Particle Size and Shape Brown, Kenneth R.; Walter, Daniel G.; Natan, Michael J. Chemistry of Materials, Vol. 12, Issue 2 https://doi.org/10.1021/cm980065p	journal	February 2000
Second Harmonic Spectroscopy of Aqueous Nano- and Microparticle Interfaces Eisenthal, Kenneth B. Chemical Reviews, Vol. 106, Issue 4 https://doi.org/10.1021/cr0403685	journal	April 2006
Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications Ghosh Chaudhuri, Rajib; Paria, Santanu Chemical Reviews, Vol. 112, Issue 4 https://doi.org/10.1021/cr100449n	journal	December 2011
A Nanoscale Optical Biosensor: Sensitivity and Selectivity of an Approach Based on the Localized Surface Plasmon Resonance Spectroscopy of Triangular Silver Nanoparticles Haes, Amanda J.; Van Duyne, Richard P. Journal of the American Chemical Society, Vol. 124, Issue 35, p. 10596-10604 https://doi.org/10.1021/ja020393x	journal	September 2002
Correlating Second Harmonic Optical Responses of Single Ag Nanoparticles with Morphology Jin, Rongchao; Jureller, Justin E.; Kim, Hee Y. Journal of the American Chemical Society, Vol. 127, Issue 36 https://doi.org/10.1021/ja0537169	journal	September 2005
Cancer Cell Imaging and Photothermal Therapy in the Near-Infrared Region by Using Gold Nanorods Huang, Xiaohua; El-Sayed, Ivan H.; Qian, Wei Journal of the American Chemical Society, Vol. 128, Issue 6, p. 2115-2120 https://doi.org/10.1021/ja057254a	journal	February 2006
Tailoring DNA Structure To Increase Target Hybridization Kinetics on Surfaces Prigodich, Andrew E.; Lee, One-Sun; Daniel, Weston L. Journal of the American Chemical Society, Vol. 132, Issue 31 https://doi.org/10.1021/ja104859j	journal	August 2010
Synthesis and Surface Modification of Highly Monodispersed, Spherical Gold Nanoparticles of 50−200 nm Perrault, Steven D.; Chan, Warren C. W. Journal of the American Chemical Society, Vol. 132, Issue 33 https://doi.org/10.1021/ja105675q	journal	August 2010
Tailoring DNA Structure To Increase Target Hybridization Kinetics on Surfaces Prigodich, Andrew E.; Lee, One-Sun; Daniel, Weston L. Journal of the American Chemical Society, Vol. 132, Issue 45 https://doi.org/10.1021/ja1087419	journal	October 2010
Synthesis and Surface Modification of Highly Monodispersed, Spherical Gold Nanoparticles of 50−200 nm Perrault, Steven D.; Chan, Warren C. W. Journal of the American Chemical Society, Vol. 131, Issue 47 https://doi.org/10.1021/ja907069u	journal	December 2009
Real-Time Imaging of the Formation of Au–Ag Core–Shell Nanoparticles Tan, Shu Fen; Chee, See Wee; Lin, Guanhua Journal of the American Chemical Society, Vol. 138, Issue 16 https://doi.org/10.1021/jacs.6b00594	journal	January 2016
Meeting the Clean Energy Demand: Nanostructure Architectures for Solar Energy Conversion Kamat, Prashant V. The Journal of Physical Chemistry C, Vol. 111, Issue 7 https://doi.org/10.1021/jp066952u	journal	January 2007
Multipolar Contributions of the Second Harmonic Generation from Silver and Gold Nanoparticles Russier-Antoine, I.; Benichou, E.; Bachelier, G. The Journal of Physical Chemistry C, Vol. 111, Issue 26 https://doi.org/10.1021/jp0675025	journal	July 2007
Molecular Adsorption and Resonance Coupling at the Colloidal Gold Nanoparticle Interface Karam, Tony E.; Haber, Louis H. The Journal of Physical Chemistry C, Vol. 118, Issue 1 https://doi.org/10.1021/jp410128v	journal	December 2013
Second Harmonic Studies of Ions Crossing Liposome Membranes in Real Time Liu, Jian; Subir, Mahamud; Nguyen, Kim The Journal of Physical Chemistry B, Vol. 112, Issue 48 https://doi.org/10.1021/jp806690z	journal	December 2008
Sonochemical Synthesis of Au−Ag Core−Shell Bimetallic Nanoparticles Anandan, Sambandam; Grieser, Franz; Ashokkumar, Muthupandian The Journal of Physical Chemistry C, Vol. 112, Issue 39 https://doi.org/10.1021/jp806960r	journal	September 2008
The Effect of Particle Size in Second Harmonic Generation from the Surface of Spherical Colloidal Particles. I: Experimental Observations ^† Jen, Shih-Hui; Gonella, Grazia; Dai, Hai-Lung The Journal of Physical Chemistry A, Vol. 113, Issue 16 https://doi.org/10.1021/jp9009959	journal	April 2009
Photochemical Strategies for the Facile Synthesis of Gold−Silver Alloy and Core−Shell Bimetallic Nanoparticles Gonzalez, Carlos Miguel; Liu, Yun; Scaiano, J. C. The Journal of Physical Chemistry C, Vol. 113, Issue 27 https://doi.org/10.1021/jp902061v	journal	May 2009
New Method for Determination of Surface Potential of Microscopic Particles by Second Harmonic Generation Yan, Elsa C. Y.; Liu, Yan; Eisenthal, Kenneth B. The Journal of Physical Chemistry B, Vol. 102, Issue 33 https://doi.org/10.1021/jp981335u	journal	August 1998
Enormous Hyper-Rayleigh Scattering from Nanocrystalline Gold Particle Suspensions Vance, Fredrick W.; Lemon, Buford I.; Hupp, Joseph T. The Journal of Physical Chemistry B, Vol. 102, Issue 50 https://doi.org/10.1021/jp984044u	journal	December 1998
Study of Interfacial Charge-Transfer Complex on TiO ₂ Particles in Aqueous Suspension by Second-Harmonic Generation Liu, Yan; Dadap, J. I.; Zimdars, David The Journal of Physical Chemistry B, Vol. 103, Issue 13 https://doi.org/10.1021/jp984288e	journal	April 1999
Seeding Bimetallic Nanostructures as a New Class of Plasmonic Colloids DeSantis, Christopher J.; Weiner, Rebecca G.; Radmilovic, Andjela The Journal of Physical Chemistry Letters, Vol. 4, Issue 18 https://doi.org/10.1021/jz4011866	journal	August 2013
Photochemical Strategies for the Seed-Mediated Growth of Gold and Gold–Silver Nanoparticles McGilvray, Katherine L.; Fasciani, Chiara; Bueno-Alejo, Carlos J. Langmuir, Vol. 28, Issue 46 https://doi.org/10.1021/la302814v	journal	November 2012
Size Tunable Au@Ag Core–Shell Nanoparticles: Synthesis and Surface-Enhanced Raman Scattering Properties Samal, Akshaya K.; Polavarapu, Lakshminarayana; Rodal-Cedeira, Sergio Langmuir, Vol. 29, Issue 48 https://doi.org/10.1021/la403707j	journal	November 2013
A Facile, Water-Based Synthesis of Highly Branched Nanostructures of Silver Wang, Yilong; Camargo, Pedro H. C.; Skrabalak, Sara E. Langmuir, Vol. 24, Issue 20 https://doi.org/10.1021/la8020904	journal	October 2008
Surface Plasmon Resonance Scattering and Absorption of anti-EGFR Antibody Conjugated Gold Nanoparticles in Cancer Diagnostics: Applications in Oral Cancer El-Sayed, Ivan H.; Huang, Xiaohua; El-Sayed, Mostafa A. Nano Letters, Vol. 5, Issue 5, p. 829-834 https://doi.org/10.1021/nl050074e	journal	May 2005
Formation Mechanism of Colloidal Silver Nanoparticles: Analogies and Differences to the Growth of Gold Nanoparticles Polte, Jörg; Tuaev, Xenia; Wuithschick, Maria ACS Nano, Vol. 6, Issue 7 https://doi.org/10.1021/nn301724z	journal	June 2012
Direct in Situ Determination of the Mechanisms Controlling Nanoparticle Nucleation and Growth Woehl, Taylor J.; Evans, James E.; Arslan, Ilke ACS Nano, Vol. 6, Issue 10 https://doi.org/10.1021/nn303371y	journal	September 2012
Shedding Light on the Growth of Gold Nanoshells Sauerbeck, Christian; Haderlein, Michael; Schürer, Benedikt ACS Nano, Vol. 8, Issue 3 https://doi.org/10.1021/nn500729r	journal	February 2014
Surface properties probed by second-harmonic and sum-frequency generation Shen, Y. R. Nature, Vol. 337, Issue 6207 https://doi.org/10.1038/337519a0	journal	February 1989
Phase-referenced nonlinear spectroscopy of the α-quartz/water interface Ohno, Paul E.; Saslow, Sarah A.; Wang, Hong-fei Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13587	journal	December 2016
Seed-mediated growth of large, monodisperse core–shell gold–silver nanoparticles with Ag-like optical properties Lu, Lehui; Wang, Haishui; Zhou, Yonghui Chemical Communications, Issue 2 https://doi.org/10.1039/b108473a	journal	January 2002
Biological applications of gold nanoparticles Sperling, Ralph A.; Rivera Gil, Pilar; Zhang, Feng Chemical Society Reviews, Vol. 37, Issue 9 https://doi.org/10.1039/b712170a	journal	January 2008
Time resolved growth of membrane stabilized silver NPs and their catalytic activity Patra, Sabyasachi; Sen, Debasis; Pandey, Ashok K. RSC Adv., Vol. 4, Issue 103 https://doi.org/10.1039/c4ra10400e	journal	January 2014
Gold nanorod-seeded synthesis of Au@Ag/Au nanospheres with broad and intense near-infrared absorption for photothermal cancer therapy Ye, Xiaosheng; Shi, Hui; He, Xiaoxiao J. Mater. Chem. B, Vol. 2, Issue 23 https://doi.org/10.1039/c4tb00202d	journal	January 2014
Hyper-Rayleigh scattering from silver nanoparticles Hao, E. C.; Schatz, G. C.; Johnson, R. C. The Journal of Chemical Physics, Vol. 117, Issue 13 https://doi.org/10.1063/1.1510439	journal	October 2002
Pure surface plasmon resonance enhancement of the first hyperpolarizability of gold core–silver shell nanoparticles Abid, Jean-Pierre; Nappa, Jérôme; Girault, Hubert H. The Journal of Chemical Physics, Vol. 121, Issue 24 https://doi.org/10.1063/1.1826053	journal	January 2004
Multiscale Maxwell–Schrödinger modeling: A split field finite-difference time-domain approach to molecular nanopolaritonics Lopata, Kenneth; Neuhauser, Daniel The Journal of Chemical Physics, Vol. 130, Issue 10 https://doi.org/10.1063/1.3082245	journal	March 2009
Communication: Reactions and adsorption at the surface of silver nanoparticles probed by second harmonic generation Gan, Wei; Gonella, Grazia; Zhang, Min The Journal of Chemical Physics, Vol. 134, Issue 4 https://doi.org/10.1063/1.3548668	journal	January 2011
Near-field: A finite-difference time-dependent method for simulation of electrodynamics on small scales Coomar, Arunima; Arntsen, Christopher; Lopata, Kenneth A. The Journal of Chemical Physics, Vol. 135, Issue 8 https://doi.org/10.1063/1.3626549	journal	August 2011
Shape and size dependence of radiative, non-radiative and photothermal properties of gold nanocrystals Link, Stephan; El-Sayed, Mostafa A. International Reviews in Physical Chemistry, Vol. 19, Issue 3 https://doi.org/10.1080/01442350050034180	journal	July 2000
Origin of optical second-harmonic generation in spherical gold nanoparticles: Local surface and nonlocal bulk contributions Bachelier, G.; Butet, J.; Russier-Antoine, I. Physical Review B, Vol. 82, Issue 23 https://doi.org/10.1103/physrevb.82.235403	journal	December 2010
Second-Harmonic Rayleigh Scattering from a Sphere of Centrosymmetric Material Dadap, J. I.; Shan, J.; Eisenthal, K. B. Physical Review Letters, Vol. 83, Issue 20 https://doi.org/10.1103/physrevlett.83.4045	journal	November 1999
Nonlinear Light Scattering and Spectroscopy of Particles and Droplets in Liquids Roke, Sylvie; Gonella, Grazia Annual Review of Physical Chemistry, Vol. 63, Issue 1 https://doi.org/10.1146/annurev-physchem-032511-143748	journal	May 2012
Origin of optical second-harmonic generation in spherical gold nanoparticles: Local surface and nonlocal bulk contributions Bachelier, Guillaume; Butet, Jérémy; Russier-Antoine, Isabelle arXiv https://doi.org/10.48550/arxiv.1107.3708	text	January 2011
Phase-referenced Nonlinear Spectroscopy of the alpha-Quartz/Water Interface Ohno, Paul E.; Saslow, Sarah A.; Wang, Hong-fei arXiv https://doi.org/10.48550/arxiv.1606.09310	text	January 2016

Similar Records

Au_329–xAg_x(SR)₈₄ Nanomolecules: Plasmonic Alloy Faradaurate-329

Journal Article · 2015 · Journal of Physical Chemistry Letters · OSTI ID:1356950

Kumara, Chanaka; Zuo, Xiaobing; Cullen, David A.; +1 more

Femtosecond laser generated gold nanoparticles and their plasmonic properties

Journal Article · 2016 · AIP Conference Proceedings · OSTI ID:22606453

Das, Rupali; Navas, M. P.; Soni, R. K.

Formation of the alloy of Au and Ag nanoparticles upon laser irradiation of the mixture of their colloidal solutions

Journal Article · 2004 · Quantum Electronics (Woodbury, N.Y.) · OSTI ID:21470449

Izgaliev, Andrei T; Simakin, Aleksandr V; Shafeev, Georgii A

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Finite difference methods
Nanomaterials
Nanoparticles
Optical extinction spectroscopy
Plasmonics
Second harmonic generation

Title: Monitoring the growth dynamics of colloidal gold-silver core-shell nanoparticles using in situ second harmonic generation and extinction spectroscopy

Citation Formats

References (75)

Similar Records

Related Subjects