DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Impact of Laboratory-Accelerated Aging Methods to Study Alkali–Silica Reaction and Reinforcement Corrosion on the Properties of Concrete

Abstract

This study focuses on two separate investigations of the main aging mechanisms: alkali–silica reactivity (ASR) and the corrosion of reinforcing steel (rebar) concrete, both of which may result in a premature failure to meet the serviceability or strength requirements of a concrete structure. However, these processes occur very slowly, spanning decades. The impact of direct chemical additives to fresh concrete to accelerate ASR and the corrosion of reinforcing steel on the fresh and hardened properties of the ensuing material are investigated to inform the potential use of chemicals in large-scale studies. The deterioration of reinforced concrete (RC) is determined by means of expansion, cracking, bulk diffusivity and surface resistivity measurements, and compressive, split tensile and flexural strength tests. The results indicate that the addition of sodium hydroxide and calcium chloride can effectively accelerate the crack formation and propagation in concrete due to ASR and the corrosion of rebar, respectively. The ASR-induced cracks maintained a constant crack width from 0.05 mm to 0.1 mm over the measurement period regardless of the intensity of aging acceleration. Adding 4% chloride by weight of cement for accelerating rebar corrosion resulted in an average crack that was 82% larger than in the case of ASRmore » accelerated with the addition of sodium hydroxide. The addition of alkali resulted in an increase in early-age (7-day) strength. At a total alkali loading of 2.98 kg/m3, 3.84 kg/m3 and 5.57 kg/m3, the 28-day compressive strength of concrete decreased by 3%, 10% and 24%, respectively. Similarly, a higher early-age strength and a lower later-age strength was observed for the concrete in the presence of corrosive calcium chloride. The results from this research are expected to inform future studies on the long-term performance of RC structures under accelerated ASR and corrosion.« less

Authors:
 [1]; ORCiD logo [2];  [2];  [3]
  1. Mueser Rutledge Consulting Engineers, New York, NY (United States). Structural Engineering III
  2. Univ. of Southern California, Los Angeles, CA (United States). Sonny Astani Department of Civil and Environmental Engineering
  3. Univ. of Massachusetts, Lowell, MA (United States). Dept. of Civil and Environmental Engineering
Publication Date:
Research Org.:
Univ. of Houston, TX (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1801222
Grant/Contract Number:  
NE0008438
Resource Type:
Accepted Manuscript
Journal Name:
Materials
Additional Journal Information:
Journal Volume: 13; Journal Issue: 15; Journal ID: ISSN 1996-1944
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 42 ENGINEERING; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics

Citation Formats

Attar, Arezou, Gencturk, Bora, Aryan, Hadi, and Wei, Jianqiang. Impact of Laboratory-Accelerated Aging Methods to Study Alkali–Silica Reaction and Reinforcement Corrosion on the Properties of Concrete. United States: N. p., 2020. Web. doi:10.3390/ma13153273.
Attar, Arezou, Gencturk, Bora, Aryan, Hadi, & Wei, Jianqiang. Impact of Laboratory-Accelerated Aging Methods to Study Alkali–Silica Reaction and Reinforcement Corrosion on the Properties of Concrete. United States. https://doi.org/10.3390/ma13153273
Attar, Arezou, Gencturk, Bora, Aryan, Hadi, and Wei, Jianqiang. Thu . "Impact of Laboratory-Accelerated Aging Methods to Study Alkali–Silica Reaction and Reinforcement Corrosion on the Properties of Concrete". United States. https://doi.org/10.3390/ma13153273. https://www.osti.gov/servlets/purl/1801222.
@article{osti_1801222,
title = {Impact of Laboratory-Accelerated Aging Methods to Study Alkali–Silica Reaction and Reinforcement Corrosion on the Properties of Concrete},
author = {Attar, Arezou and Gencturk, Bora and Aryan, Hadi and Wei, Jianqiang},
abstractNote = {This study focuses on two separate investigations of the main aging mechanisms: alkali–silica reactivity (ASR) and the corrosion of reinforcing steel (rebar) concrete, both of which may result in a premature failure to meet the serviceability or strength requirements of a concrete structure. However, these processes occur very slowly, spanning decades. The impact of direct chemical additives to fresh concrete to accelerate ASR and the corrosion of reinforcing steel on the fresh and hardened properties of the ensuing material are investigated to inform the potential use of chemicals in large-scale studies. The deterioration of reinforced concrete (RC) is determined by means of expansion, cracking, bulk diffusivity and surface resistivity measurements, and compressive, split tensile and flexural strength tests. The results indicate that the addition of sodium hydroxide and calcium chloride can effectively accelerate the crack formation and propagation in concrete due to ASR and the corrosion of rebar, respectively. The ASR-induced cracks maintained a constant crack width from 0.05 mm to 0.1 mm over the measurement period regardless of the intensity of aging acceleration. Adding 4% chloride by weight of cement for accelerating rebar corrosion resulted in an average crack that was 82% larger than in the case of ASR accelerated with the addition of sodium hydroxide. The addition of alkali resulted in an increase in early-age (7-day) strength. At a total alkali loading of 2.98 kg/m3, 3.84 kg/m3 and 5.57 kg/m3, the 28-day compressive strength of concrete decreased by 3%, 10% and 24%, respectively. Similarly, a higher early-age strength and a lower later-age strength was observed for the concrete in the presence of corrosive calcium chloride. The results from this research are expected to inform future studies on the long-term performance of RC structures under accelerated ASR and corrosion.},
doi = {10.3390/ma13153273},
journal = {Materials},
number = 15,
volume = 13,
place = {United States},
year = {Thu Jul 23 00:00:00 EDT 2020},
month = {Thu Jul 23 00:00:00 EDT 2020}
}

Works referenced in this record:

The role of lithium compounds in mitigating alkali-gravel aggregate reaction
journal, July 2016


Effect of sample conditioning on the water absorption of concrete
journal, September 2011


Effect of reinforcement corrosion on bond strength
journal, March 1996

  • Almusallam, Abdullah A.; Al-Gahtani, Ahmad S.; Aziz, Abdur Rauf
  • Construction and Building Materials, Vol. 10, Issue 2
  • DOI: 10.1016/0950-0618(95)00077-1

The management of aging in nuclear power plant concrete structures
journal, July 2009


Modeling alkali–silica reaction in non-isothermal, partially saturated cement based materials
journal, June 2012

  • Pesavento, Francesco; Gawin, Dariusz; Wyrzykowski, Mateusz
  • Computer Methods in Applied Mechanics and Engineering, Vol. 225-228
  • DOI: 10.1016/j.cma.2012.02.019

Effectiveness of nondestructive testing for the evaluation of alkali–silica reaction in concrete
journal, August 2010


Experimental study on fatigue behavior of Steel Reinforced Concrete (SRC) beams
journal, September 2016


Microstructural Studies of Alkali-Silica Reaction in Fly Ash Concrete Immersed in Alkaline Solutions
journal, March 1998


Effect of calcium chloride on the hydration characteristics of ground clay bricks cement pastes
journal, March 2013

  • Kishar, Essam A.; Ahmed, Doaa A.; Mohammed, Maha R.
  • Beni-Suef University Journal of Basic and Applied Sciences, Vol. 2, Issue 1
  • DOI: 10.1016/j.bjbas.2013.09.003

The combined effect of chlorides and sulphates present in water and aggregates on properties of concrete
journal, November 1988

  • Al-Kadhimi, Talib K.; Ikzer, Baha'a G.; Al-Takarli, Sawsan F.
  • Materials and Structures, Vol. 21, Issue 6
  • DOI: 10.1007/BF02472324

The corrosion potential of stainless steel rebars in concrete: Temperature effect
journal, December 2012


A combined synchrotron radiation micro computed tomography and micro X-ray diffraction study on deleterious alkali-silica reaction
journal, September 2015

  • Marinoni, Nicoletta; Voltolini, Marco; Broekmans, Maarten A. T. M.
  • Journal of Materials Science, Vol. 50, Issue 24
  • DOI: 10.1007/s10853-015-9364-7

Numerical Investigation on Lateral Confinement Effects on Concrete Cracking Induced by Rebar Corrosion
journal, March 2020

  • Choe, Gyeongcheol; Shinohara, Yasuji; Kim, Gyuyong
  • Materials, Vol. 13, Issue 5
  • DOI: 10.3390/ma13051156

Permeability of concrete containing large amounts of fly ash
journal, January 1994


Influences of location of reinforcement corrosion on seismic performance of corroded reinforced concrete beams
journal, November 2016


On the thermal spalling mechanism of reactive powder concrete exposed to high temperature: Numerical and experimental studies
journal, July 2016


Alkali–silica reaction (ASR) expansion: Pessimum effect versus scale effect
journal, February 2013


Mathematical model for kinetics of alkali–silica reaction in concrete
journal, March 2000


Carbonation-Induced and Chloride-Induced Corrosion in Reinforced Concrete Structures
journal, September 2015


Influence of alkalis on porosity percolation in hydrating cement pastes
journal, May 2006


Chloride-induced corrosion products of steel in cracked-concrete subjected to different loading conditions
journal, February 2009


Chloride threshold level for corrosion of steel in concrete
journal, November 2007


Cracking and failure of patch repairs in RC members subjected to bar corrosion
journal, March 2016


Interaction between drying, shrinkage, creep and cracking phenomena in concrete
journal, January 2005


Review of Thaumasite Sulfate Attack on Cement Mortar and Concrete
journal, December 2012


Influence of the Alkali-Silica Reaction on the Mechanical Degradation of Concrete
journal, June 2016


Alkali-silica reaction products and their development
journal, July 1988


Crack shape and rust distribution in corrosion-induced cracking concrete
journal, February 2012


Thermal analysis of reinforced concrete beams and frames
journal, April 2017


Impact of Alkali Silica Reaction on Fly Ash-Based Geopolymer Concrete
journal, January 2013


Corrosion resistance and mechanism of steel rebar coated with three types of enamel
journal, June 2012


Resistance of concrete and mortar against combined attack of chloride and sodium sulphate
journal, October 2014


Effects of alkali addition on the mechanical properties and durability of concrete
journal, February 2005


Fatigue life prediction for aging RC beams considering corrosive environments
journal, November 2014


Relation of ASR-induced expansion and compressive strength of concrete
journal, November 2014


Alkali Release from Aggregates in Long-Service Concrete Structures: Laboratory Test Evaluation and ASR Prediction
journal, August 2018

  • Berra, Mario; Mangialardi, Teresa; Paolini, Antonio
  • Materials, Vol. 11, Issue 8
  • DOI: 10.3390/ma11081393

Effect of CaCl2 and NaCl additions on concrete corrosivity
journal, July 2004


Effect of calcium chloride on portland cements and concretes
journal, April 1935

  • Rapp, P.
  • Journal of Research of the National Bureau of Standards, Vol. 14, Issue 4
  • DOI: 10.6028/jres.014.026