Energetic decomposition yields efficient bimetallic Cu MOF-derived catalysts
Abstract
Metal–organic frameworks (MOFs) have recently emerged as efficient self-sacrificial templates to fabricate porous carbon-supported metal nanoparticles (NPs). Due to observed increased activity, catalysts containing bimetallic NPs represent an active frontier for heterogeneous catalyst development. A strategy to synthesize active catalysts with highly dispersed bimetallic metal/metal oxides within a porous carbon matrix via rapid MOF decomposition using dopants is presented in this paper. A 2,4,6-trinitrotoluene (TNT) additive enhances the rapid thermolysis of the metal-doped Cu-based MOFs to minimize particle aggregation. Catalyst characterization reveals that a secondary metal increases dispersion of both metals over the carbon composite support. The catalyst preparation method influences both the metal particle size and oxidation state. Catalytic performance shows increased rates for 4-nitrophenol reduction even with <1 wt% of added secondary metal. Among the synthesized catalysts, the Ni–CuO@C bimetallic catalyst exhibits outstanding activity. This synthetic strategy is useful for creating highly efficient, robust, non-noble metal catalysts for development of sustainable chemical processes.
- Authors:
-
[3];
[1]
- Brigham Young Univ., Provo, UT (United States)
- Sichuan Univ., Chengdu (China)
- Univ. of Michigan, Ann Arbor, MI (United States)
- Publication Date:
- Research Org.:
- Univ. of Michigan, Ann Arbor, MI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1800560
- Alternate Identifier(s):
- OSTI ID: 1640251
- Grant/Contract Number:
- FG02-08ER15997; FG02-08ER 15997
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 30; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry; Energy & Fuels; Materials Science
Citation Formats
Nguyen Sorenson, Anh H. T., Wu, Yu, Orcutt, Emma K., Kent, Rosalyn V., Anderson, Hans C., Matzger, Adam J., and Stowers, Kara J. Energetic decomposition yields efficient bimetallic Cu MOF-derived catalysts. United States: N. p., 2020.
Web. doi:10.1039/d0ta04765a.
Nguyen Sorenson, Anh H. T., Wu, Yu, Orcutt, Emma K., Kent, Rosalyn V., Anderson, Hans C., Matzger, Adam J., & Stowers, Kara J. Energetic decomposition yields efficient bimetallic Cu MOF-derived catalysts. United States. https://doi.org/10.1039/d0ta04765a
Nguyen Sorenson, Anh H. T., Wu, Yu, Orcutt, Emma K., Kent, Rosalyn V., Anderson, Hans C., Matzger, Adam J., and Stowers, Kara J. Fri .
"Energetic decomposition yields efficient bimetallic Cu MOF-derived catalysts". United States. https://doi.org/10.1039/d0ta04765a. https://www.osti.gov/servlets/purl/1800560.
@article{osti_1800560,
title = {Energetic decomposition yields efficient bimetallic Cu MOF-derived catalysts},
author = {Nguyen Sorenson, Anh H. T. and Wu, Yu and Orcutt, Emma K. and Kent, Rosalyn V. and Anderson, Hans C. and Matzger, Adam J. and Stowers, Kara J.},
abstractNote = {Metal–organic frameworks (MOFs) have recently emerged as efficient self-sacrificial templates to fabricate porous carbon-supported metal nanoparticles (NPs). Due to observed increased activity, catalysts containing bimetallic NPs represent an active frontier for heterogeneous catalyst development. A strategy to synthesize active catalysts with highly dispersed bimetallic metal/metal oxides within a porous carbon matrix via rapid MOF decomposition using dopants is presented in this paper. A 2,4,6-trinitrotoluene (TNT) additive enhances the rapid thermolysis of the metal-doped Cu-based MOFs to minimize particle aggregation. Catalyst characterization reveals that a secondary metal increases dispersion of both metals over the carbon composite support. The catalyst preparation method influences both the metal particle size and oxidation state. Catalytic performance shows increased rates for 4-nitrophenol reduction even with <1 wt% of added secondary metal. Among the synthesized catalysts, the Ni–CuO@C bimetallic catalyst exhibits outstanding activity. This synthetic strategy is useful for creating highly efficient, robust, non-noble metal catalysts for development of sustainable chemical processes.},
doi = {10.1039/d0ta04765a},
journal = {Journal of Materials Chemistry. A},
number = 30,
volume = 8,
place = {United States},
year = {Fri Jul 17 00:00:00 EDT 2020},
month = {Fri Jul 17 00:00:00 EDT 2020}
}
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Works referenced in this record:
From Metal–Organic Framework to Nanoporous Carbon: Toward a Very High Surface Area and Hydrogen Uptake
journal, August 2011
- Jiang, Hai-Long; Liu, Bo; Lan, Ya-Qian
- Journal of the American Chemical Society, Vol. 133, Issue 31
Gas storage in porous metal–organic frameworks for clean energy applications
journal, January 2010
- Ma, Shengqian; Zhou, Hong-Cai
- Chem. Commun., Vol. 46, Issue 1
Biosynthesis of Highly Retrievable Magnetic Palladium Nanoparticles Stabilized on Bio-composite for Production of Various Biaryl Compounds and Catalytic Reduction of 4-Nitrophenol
journal, March 2019
- Baran, Talat
- Catalysis Letters, Vol. 149, Issue 6
Three-dimensional graphene-based aerogels prepared by a self-assembly process and its excellent catalytic and absorbing performance
journal, January 2013
- Wu, Tao; Chen, Mingxi; Zhang, Lei
- Journal of Materials Chemistry A, Vol. 1, Issue 26
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn
journal, November 2010
- Biesinger, Mark C.; Lau, Leo W. M.; Gerson, Andrea R.
- Applied Surface Science, Vol. 257, Issue 3
Enhanced Drug Delivery by Dissolution of Amorphous Drug Encapsulated in a Water Unstable Metal–Organic Framework (MOF)
journal, November 2019
- Suresh, Kuthuru; Matzger, Adam J.
- Angewandte Chemie International Edition, Vol. 58, Issue 47
Facile solid-state synthesis of highly dispersed Cu nanospheres anchored on coal-based activated carbons as an efficient heterogeneous catalyst for the reduction of 4-nitrophenol
journal, April 2018
- Wang, Shan; Gao, Shasha; Tang, Yakun
- Journal of Solid State Chemistry, Vol. 260
In situ growth of hollow CuNi alloy nanoparticles on reduced graphene oxide nanosheets and their magnetic and catalytic properties
journal, October 2014
- Yang, Jinglei; Shen, Xiaoping; Ji, Zhenyuan
- Applied Surface Science, Vol. 316
Graphene-based nanocomposites for energy storage and conversion in lithium batteries, supercapacitors and fuel cells
journal, January 2014
- Mahmood, Nasir; Zhang, Chenzhen; Yin, Han
- J. Mater. Chem. A, Vol. 2, Issue 1
Microporous Brookite-Phase Titania Made by Replication of a Metal–Organic Framework
journal, October 2013
- Hall, Anthony Shoji; Kondo, Atsushi; Maeda, Kazuyuki
- Journal of the American Chemical Society, Vol. 135, Issue 44
Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000
- Ferrari, A. C.; Robertson, J.
- Physical Review B, Vol. 61, Issue 20, p. 14095-14107
Copper Oxide Nanocrystals
journal, July 2005
- Yin, Ming; Wu, Chun-Kwei; Lou, Yongbing
- Journal of the American Chemical Society, Vol. 127, Issue 26
CuNi@C catalysts with high activity derived from metal–organic frameworks precursor for conversion of furfural to cyclopentanone
journal, September 2016
- Wang, Yuan; Sang, Shengya; Zhu, Wei
- Chemical Engineering Journal, Vol. 299
Catalytic Activity of Faceted Gold Nanoparticles Studied by a Model Reaction: Evidence for Substrate-Induced Surface Restructuring
journal, June 2011
- Wunder, Stefanie; Lu, Yan; Albrecht, Martin
- ACS Catalysis, Vol. 1, Issue 8
Development of Efficient Copper-Based MOF-Derived Catalysts for the Reduction of Aromatic Nitro Compounds: Development of Efficient Copper-Based MOF-Derived Catalysts for the Reduction of Aromatic Nitro Compounds
journal, March 2018
- Karahan, Özlem; Biçer, Emre; Taşdemir, Adnan
- European Journal of Inorganic Chemistry, Vol. 2018, Issue 9
Role of Metal–Support Interactions, Particle Size, and Metal–Metal Synergy in CuNi Nanocatalysts for H 2 Generation
journal, August 2015
- Yen, Hoang; Seo, Yongbeom; Kaliaguine, Serge
- ACS Catalysis, Vol. 5, Issue 9
Potential applications of metal-organic frameworks
journal, December 2009
- Kuppler, Ryan J.; Timmons, Daren J.; Fang, Qian-Rong
- Coordination Chemistry Reviews, Vol. 253, Issue 23-24
Chemoselective Hydrogenation of Nitro Compounds with Supported Gold Catalysts
journal, July 2006
- Corma, Avelino; Serna, Pedro
- Science, Vol. 313, Issue 5785, p. 332-334
Characterization of amorphous and nanocrystalline carbon films
journal, April 2006
- Chu, Paul K.; Li, Liuhe
- Materials Chemistry and Physics, Vol. 96, Issue 2-3
Hierarchical plasmonic-metal/semiconductor micro/nanostructures: green synthesis and application in catalytic reduction of p-nitrophenol
journal, February 2012
- Gao, Shuyan; Jia, Xiaoxia; Li, Zhengdao
- Journal of Nanoparticle Research, Vol. 14, Issue 3
Vapor-phase dehydrogenation of ethylbenzene to styrene over a V 2 O 5 /TiO 2 –Al 2 O 3 catalyst with CO 2
journal, January 2017
- Kainthla, Itika; Ramesh Babu, Gurram Venkata; Bhanushali, Jayesh T.
- New Journal of Chemistry, Vol. 41, Issue 10
Preparation of para -Aminophenol from Nitrobenzene through Bamberger Rearrangement Using a Mixture of Heterogeneous and Homogeneous Acid Catalysts
journal, February 2018
- Joncour, Roxan; Ferreira, Amadéo; Duguet, Nicolas
- Organic Process Research & Development, Vol. 22, Issue 3
Formation of Mixed Metal Cu 3– x Zn x (btc) 2 Frameworks with Different Zinc Contents: Incorporation of Zn 2+ into the Metal–Organic Framework Structure as Studied by Solid-State NMR
journal, September 2012
- Gul-E-Noor, Farhana; Jee, Bettina; Mendt, Matthias
- The Journal of Physical Chemistry C, Vol. 116, Issue 39
Copper on carbon materials: stabilization by nitrogen doping
journal, January 2017
- Bulushev, Dmitri A.; Chuvilin, Andrey L.; Sobolev, Vladimir I.
- Journal of Materials Chemistry A, Vol. 5, Issue 21
Metal and metal oxidenanoparticle synthesis from metal organic frameworks (MOFs): finding the border of metal and metal oxides
journal, January 2012
- Das, Raja; Pachfule, Pradip; Banerjee, Rahul
- Nanoscale, Vol. 4, Issue 2
High efficiency degradation of 4-nitrophenol by microwave-enhanced catalytic method
journal, January 2011
- Lai, Teh-Long; Yong, Kim-Fui; Yu, Jen-Wei
- Journal of Hazardous Materials, Vol. 185, Issue 1
Ag-Cu bimetallic nanocatalysts for p-nitrophenol reduction using a green hydrogen source
journal, December 2017
- Verma, A. D.; Pal, Shaili; Verma, Pratibha
- Journal of Environmental Chemical Engineering, Vol. 5, Issue 6
Functional materials derived from open framework templates/precursors: synthesis and applications
journal, January 2014
- Sun, Jian-Ke; Xu, Qiang
- Energy & Environmental Science, Vol. 7, Issue 7
Bactericidal and catalytic performance of green nanocomposite based-on chitosan/carbon black fiber supported monometallic and bimetallic nanoparticles
journal, December 2017
- Ali, Fayaz; Khan, Sher Bahadar; Kamal, Tahseen
- Chemosphere, Vol. 188
The impact of size effects on the electrochemical behaviour of Cu2O-coated Cu nanopillars for advanced Li-ion microbatteries
journal, January 2014
- Valvo, Mario; Rehnlund, David; Lafont, Ugo
- Journal of Materials Chemistry A, Vol. 2, Issue 25
NiFe nanoalloys in-situ immobilized on coal based activated carbons through one-step pyrolysis as magnetically recoverable catalysts for reduction of 4-nitrophenol
journal, April 2017
- Gao, Shasha; Tang, Yakun; Wang, Lei
- Journal of Alloys and Compounds, Vol. 702
A graphene oxide-based electrochemical sensor for sensitive determination of 4-nitrophenol
journal, January 2012
- Li, Junhua; Kuang, Daizhi; Feng, Yonglan
- Journal of Hazardous Materials, Vol. 201-202
Highly active copper catalyst obtained through rapid MOF decomposition
journal, January 2019
- Nguyen-Sorenson, Anh H. T.; Anderson, Clifton M.; Balijepalli, Santosh K.
- Inorganic Chemistry Frontiers, Vol. 6, Issue 2
Catalysis by metallic nanoparticles in aqueous solution: model reactions
journal, January 2012
- Hervés, Pablo; Pérez-Lorenzo, Moisés; Liz-Marzán, Luis M.
- Chemical Society Reviews, Vol. 41, Issue 17, p. 5577-5587
Thermal decomposition pathways of nitro-functionalized metal–organic frameworks
journal, January 2017
- McDonald, Kyle A.; Ko, Nakeun; Noh, Kyungkyou
- Chemical Communications, Vol. 53, Issue 55
Photochemical Green Synthesis of Calcium-Alginate-Stabilized Ag and Au Nanoparticles and Their Catalytic Application to 4-Nitrophenol Reduction
journal, February 2010
- Saha, Sandip; Pal, Anjali; Kundu, Subrata
- Langmuir, Vol. 26, Issue 4
Nitroarene reduction: a trusted model reaction to test nanoparticle catalysts
journal, January 2015
- Aditya, Teresa; Pal, Anjali; Pal, Tarasankar
- Chemical Communications, Vol. 51, Issue 46, p. 9410-9431
Metal-Organic Frameworks for Energy Applications
journal, January 2017
- Wang, Hailong; Zhu, Qi-Long; Zou, Ruqiang
- Chem, Vol. 2, Issue 1
Graphene-based non-noble-metal Co/N/C catalyst for oxygen reduction reaction in alkaline solution
journal, December 2013
- Niu, Kexing; Yang, Baoping; Cui, Jinfeng
- Journal of Power Sources, Vol. 243
Chitosan nanocomposite fibers supported copper nanoparticles based perceptive sensor and active catalyst for nitrophenol in real water
journal, March 2019
- Khan, Sher Bahadar; Ali, Fayaz; Akhtar, Kalsoom
- Carbohydrate Polymers, Vol. 207
Luminescent metal–organic frameworks for chemical sensing and explosive detection
journal, January 2014
- Hu, Zhichao; Deibert, Benjamin J.; Li, Jing
- Chem. Soc. Rev., Vol. 43, Issue 16
Preparation of Copper Nanoparticles and Catalytic Properties for the Reduction of Aromatic Nitro Compounds
journal, December 2012
- Duan, Zhongyu; Ma, Guoli; Zhang, Wenjun
- Bulletin of the Korean Chemical Society, Vol. 33, Issue 12
Synthesis and applications of MOF-derived porous nanostructures
journal, July 2017
- Yap, Min Hui; Fow, Kam Loon; Chen, George Zheng
- Green Energy & Environment, Vol. 2, Issue 3
State of the Art and Prospects in Metal–Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis
journal, June 2019
- Wang, Qi; Astruc, Didier
- Chemical Reviews, Vol. 120, Issue 2
Oxidation studies on mono (Cu, Ni) and bimetallic (Cu–Ni) nanoparticles and its impact on catalytic activity
journal, March 2020
- Vivek, S.; Preethi, S.; Kumar, T. H. Vignesh
- Journal of Alloys and Compounds, Vol. 816
MOF derived Mesoporous Nitrogen doped Carbons with high Activity towards Oxygen Reduction
journal, October 2017
- Díaz-Duran, Ana Katherine; Roncaroli, Federico
- Electrochimica Acta, Vol. 251
Efficient and recyclable copper-based MOF-catalyzed N-arylation of N-containing heterocycles with aryliodides
journal, January 2016
- Li, Zihao; Meng, Fei; Zhang, Jie
- Organic & Biomolecular Chemistry, Vol. 14, Issue 46
Study on the influence of oxygen-containing groups on the performance of Ni/AC catalysts in methanol vapor-phase carbonylation
journal, June 2016
- Pang, Fei; Song, Faen; Zhang, Qingde
- Chemical Engineering Journal, Vol. 293
Metal-Organic Framework as a Template for Porous Carbon Synthesis
journal, April 2008
- Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki
- Journal of the American Chemical Society, Vol. 130, Issue 16
Green and convenient protocols for the efficient reduction of nitriles and nitro compounds to corresponding amines with NaBH4 in water catalyzed by magnetically retrievable CuFe2O4 nanoparticles
journal, March 2019
- Zeynizadeh, Behzad; Mohammad Aminzadeh, Farkhondeh; Mousavi, Hossein
- Research on Chemical Intermediates, Vol. 45, Issue 6
Facile fabrication of faceted copper nanocrystals with high catalytic activity for p-nitrophenol reduction
journal, January 2013
- Zhang, Pinhua; Sui, Yongming; Xiao, Guanjun
- J. Mater. Chem. A, Vol. 1, Issue 5
Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information
journal, July 2005
- Sadezky, A.; Muckenhuber, H.; Grothe, H.
- Carbon, Vol. 43, Issue 8
Electrochemical approaches to the production of graphene flakes and their potential applications
journal, April 2013
- Low, C. T. J.; Walsh, F. C.; Chakrabarti, M. H.
- Carbon, Vol. 54
Heterogeneous catalytic reduction of anthropogenic pollutant, 4-nitrophenol by Au/AC nanocatalysts
journal, December 2019
- Kumar, Ashish; Belwal, Mamta; Maurya, Radha Raman
- Materials Science for Energy Technologies, Vol. 2, Issue 3
Reconciling the Discrepancies between Crystallographic Porosity and Guest Access As Exemplified by Zn-HKUST-1
journal, November 2011
- Feldblyum, Jeremy I.; Liu, Ming; Gidley, David W.
- Journal of the American Chemical Society, Vol. 133, Issue 45
Graphene Oxide Framework Materials: Theoretical Predictions and Experimental Results
journal, October 2010
- Burress, Jacob W.; Gadipelli, Srinivas; Ford, Jamie
- Angewandte Chemie International Edition, Vol. 49, Issue 47
In situ assembly of well-dispersed Ag nanoparticles (AgNPs) on electrospun carbon nanofibers (CNFs) for catalytic reduction of 4-nitrophenol
journal, January 2011
- Zhang, Peng; Shao, Changlu; Zhang, Zhenyi
- Nanoscale, Vol. 3, Issue 8
Magnetic Fe3O4@C/Cu and Fe3O4@CuO core–shell composites constructed from MOF-based materials and their photocatalytic properties under visible light
journal, January 2014
- Zhang, Yong-Fei; Qiu, Ling-Guang; Yuan, Yu-Peng
- Applied Catalysis B: Environmental, Vol. 144
Proton-conductive metal-organic frameworks: Recent advances and perspectives
journal, August 2017
- Li, Ai-Lin; Gao, Qiang; Xu, Jian
- Coordination Chemistry Reviews, Vol. 344
A review on contemporary Metal–Organic Framework materials
journal, May 2016
- Gangu, Kranthi Kumar; Maddila, Suresh; Mukkamala, Saratchandra Babu
- Inorganica Chimica Acta, Vol. 446
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Metal–organic framework-derived porous materials for catalysis
journal, May 2018
- Chen, Yu-Zhen; Zhang, Rui; Jiao, Long
- Coordination Chemistry Reviews, Vol. 362
Metal-organic frameworks derived bimetallic Cu-Co catalyst for efficient and selective hydrogenation of biomass-derived furfural to furfuryl alcohol
journal, July 2017
- Wang, Yuan; Miao, Yanan; Li, Shuai
- Molecular Catalysis, Vol. 436
Well-Dispersed and Size-Controlled Supported Metal Oxide Nanoparticles Derived from MOF Composites and Further Application in Catalysis
journal, March 2015
- Liu, Hong; Zhang, Suoying; Liu, Yayuan
- Small, Vol. 11, Issue 26
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Characterization of single-wall carbon nanotubes by N2 adsorption
journal, January 2004
- Li, Fanxing; Wang, Yao; Wang, Dezheng
- Carbon, Vol. 42, Issue 12-13
Catalytic Reduction of Aromatic Nitro Compounds by Coinage Metal Nanoparticles
journal, March 2001
- Pradhan, Narayan; Pal, Anjali; Pal, Tarasankar
- Langmuir, Vol. 17, Issue 5
A ternary Cu 2 O–Cu–CuO nanocomposite: a catalyst with intriguing activity
journal, January 2016
- Sasmal, Anup Kumar; Dutta, Soumen; Pal, Tarasankar
- Dalton Transactions, Vol. 45, Issue 7
Biodegradation and detoxification of -nitrophenol by Rhodococcus wratislaviensis
journal, March 2005
- Gemini, V. L.; Gallego, A.; de Oliveira, V. M.
- International Biodeterioration & Biodegradation, Vol. 55, Issue 2