Melt-extracted Gd73.5Si13B13.5/GdB6 ferromagnetic/antiferromagnetic microwires with excellent magnetocaloric properties

Duc, N. T.M.; Shen, H. X.; Thiabgoh, O.; Huong, N. T.; Sun, J. F.; Phan, M. H.

doi:10.1016/j.jallcom.2019.153333

Title: Melt-extracted Gd_73.5Si₁₃B_13.5/GdB₆ ferromagnetic/antiferromagnetic microwires with excellent magnetocaloric properties

Journal Article · 09 December 2019 · Journal of Alloys and Compounds

DOI: https://doi.org/10.1016/j.jallcom.2019.153333 · OSTI ID:1800498

Duc, N. T.M. ^[1]; Shen, H. X. ^[2]; Thiabgoh, O. ^[3]; Huong, N. T. ^[4]; Sun, J. F. ^[5]; Phan, M. H. ^[6]

Univ. of South Florida, Tampa, FL (United States); VNU Univ. of Science, Hanoi (Vietnam); Univ. of Danang (Vietnam); OSTI
Univ. of South Florida, Tampa, FL (United States); Harbin Institute of Technology (China)
Ubon Ratchathani Univ. (Thailand)
VNU Univ. of Science, Hanoi (Vietnam)
Harbin Institute of Technology (China)
Univ. of South Florida, Tampa, FL (United States)

A novel class of magnetocaloric microwires composed of antiferromagnetic GdB₆ nanocrystals embedded in an amorphous ferromagnetic Gd_73.5Si₁₃B_13.5 matrix is reported. These composite microwires were created directly from a melt-extraction process. XRD, TEM, HRTEM and SAED confirm the formation of GdB₆ nanocrystals (~10 nm) in the amorphous Gd_73.5Si₁₃B_13.5 matrix. As a second-order magnetic material, the Gd_73.5Si₁₃B_13.5/GdB₆ microwires exhibit an excellent magnetocaloric response, with a large magnetic entropy change ΔS_M ~6.4 J kg^-1 K^-1 at ~120 K, a large temperature interval δT_FWHM ~130 K, and the large refrigerant capacity RC ~890 J kg^-1 for a field change of 5 T. Such microwires are a promising candidate for active magnetic refrigeration in the temperature range of 10–200 K.

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Research Organization:: Univ. of South Florida, Tampa, FL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER46438

OSTI ID:: 1800498

Journal Information:: Journal of Alloys and Compounds, Journal Name: Journal of Alloys and Compounds Vol. 818; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Melt-extracted Gd73.5Si13B13.5/GdB6 ferromagnetic/antiferromagnetic microwires with excellent magnetocaloric properties

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Title: Melt-extracted Gd_73.5Si₁₃B_13.5/GdB₆ ferromagnetic/antiferromagnetic microwires with excellent magnetocaloric properties