Highly Stretchable, Ultratough, and Multifunctional Poly(vinyl chloride)-Based Plastics via a Green, Star-Shaped Macromolecular Additive
Abstract
As one of the most prolifically produced plastics in the world, poly(vinyl chloride) (PVC) suffers from mechanical brittleness and low toughness. Compared with traditional phthalate-type plasticizers, poly(ε-caprolactone) (PCL)-based plasticizers are especially attractive due to their “green” nature and capabilities to achieve improved physical properties. Herein, a stretchable and ultratough PVC-based plastic was achieved by a star-shaped PCL copolymer with a rigid, amino-containing, branched polylactide (N-BPLA) core and a soft PCL shell, that is, RN-SPCLs. With an optimal feed ratio of the CL monomer and N-BPLA core, the RN-SPCL2 can efficiently lower the glass transition temperature (Tg) of PVC plastics, achieving the transition from the “glassy” to “rubbery” state at ambient temperature. The obtained RN-SPCL2/PVC not only shows high extensibility, that is, 453%, but also maintains close to 80% of tensile strength of neat PVC, that is, 30.1 MPa, which is much higher than the previously reported plasticized PVCs. Its overall toughness reaches 92.7 MJ/m3, being more than 50-fold higher than neat PVC and 2 to 3 times higher than linear PCL or dibutyl phthalate plasticized PVCs. The important role of star-shaped architecture with a rigid core and flexible PCL shell for RN-SPCL2 in achieving highly stretchable and ultratough PVC plasticsmore »
- Authors:
-
[2];
[3];
[2]
- Tianjin Univ., Tianjin (China). School of Science, Dept. of Chemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Tianjin Univ., Tianjin (China). School of Science, Dept. of Chemistry; Tianjin Chengjian Univ., Tianjin (China). School of Science, Tianjin Engineering Technology Center of Chemical Wastewater Source Reduction and Recycling
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC); Natural Science Foundation of Tianjin City
- OSTI Identifier:
- 1797637
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Macromolecules
- Additional Journal Information:
- Journal Volume: 54; Journal Issue: 7; Journal ID: ISSN 0024-9297
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; Oxides; Plastics; Tensile strength; elastomers; polymers
Citation Formats
Chen, Wei-Guang, Wei, Hai-Jie, Luo, Jiancheng, Chen, Yu, and Cao, Peng-Fei. Highly Stretchable, Ultratough, and Multifunctional Poly(vinyl chloride)-Based Plastics via a Green, Star-Shaped Macromolecular Additive. United States: N. p., 2021.
Web. doi:10.1021/acs.macromol.1c00029.
Chen, Wei-Guang, Wei, Hai-Jie, Luo, Jiancheng, Chen, Yu, & Cao, Peng-Fei. Highly Stretchable, Ultratough, and Multifunctional Poly(vinyl chloride)-Based Plastics via a Green, Star-Shaped Macromolecular Additive. United States. https://doi.org/10.1021/acs.macromol.1c00029
Chen, Wei-Guang, Wei, Hai-Jie, Luo, Jiancheng, Chen, Yu, and Cao, Peng-Fei. Fri .
"Highly Stretchable, Ultratough, and Multifunctional Poly(vinyl chloride)-Based Plastics via a Green, Star-Shaped Macromolecular Additive". United States. https://doi.org/10.1021/acs.macromol.1c00029. https://www.osti.gov/servlets/purl/1797637.
@article{osti_1797637,
title = {Highly Stretchable, Ultratough, and Multifunctional Poly(vinyl chloride)-Based Plastics via a Green, Star-Shaped Macromolecular Additive},
author = {Chen, Wei-Guang and Wei, Hai-Jie and Luo, Jiancheng and Chen, Yu and Cao, Peng-Fei},
abstractNote = {As one of the most prolifically produced plastics in the world, poly(vinyl chloride) (PVC) suffers from mechanical brittleness and low toughness. Compared with traditional phthalate-type plasticizers, poly(ε-caprolactone) (PCL)-based plasticizers are especially attractive due to their “green” nature and capabilities to achieve improved physical properties. Herein, a stretchable and ultratough PVC-based plastic was achieved by a star-shaped PCL copolymer with a rigid, amino-containing, branched polylactide (N-BPLA) core and a soft PCL shell, that is, RN-SPCLs. With an optimal feed ratio of the CL monomer and N-BPLA core, the RN-SPCL2 can efficiently lower the glass transition temperature (Tg) of PVC plastics, achieving the transition from the “glassy” to “rubbery” state at ambient temperature. The obtained RN-SPCL2/PVC not only shows high extensibility, that is, 453%, but also maintains close to 80% of tensile strength of neat PVC, that is, 30.1 MPa, which is much higher than the previously reported plasticized PVCs. Its overall toughness reaches 92.7 MJ/m3, being more than 50-fold higher than neat PVC and 2 to 3 times higher than linear PCL or dibutyl phthalate plasticized PVCs. The important role of star-shaped architecture with a rigid core and flexible PCL shell for RN-SPCL2 in achieving highly stretchable and ultratough PVC plastics is systematically investigated. More interestingly, the as-prepared RN-SPCLs also endow PVC plastics with photoluminescence property and allow homogeneous dispersion of nanosized TiO2 for significantly enhancing the anti-UV capability.},
doi = {10.1021/acs.macromol.1c00029},
journal = {Macromolecules},
number = 7,
volume = 54,
place = {United States},
year = {Fri Apr 02 00:00:00 EDT 2021},
month = {Fri Apr 02 00:00:00 EDT 2021}
}
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