An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes

Liu, Sufu; Ji, Xiao; Piao, Nan; Chen, Ji; Eidson, Nico; Xu, Jijian; Wang, Pengfei; Chen, Long; Zhang, Jiaxun; Deng, Tao; Hou, Singyuk; Jin, Ting; Wan, Hongli; Li, Jingru; Tu, Jiangping; Wang, Chunsheng

doi:10.1002/ange.202012005

Title: An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes

Abstract

Abstract In carbonate electrolytes, the organic–inorganic solid electrolyte interphase (SEI) formed on the Li‐metal anode surface is strongly bonded to Li and experiences the same volume change as Li, thus it undergoes continuous cracking/reformation during plating/stripping cycles. Here, an inorganic‐rich SEI is designed on a Li‐metal surface to reduce its bonding energy with Li metal by dissolving 4 m concentrated LiNO ₃ in dimethyl sulfoxide (DMSO) as an additive for a fluoroethylene‐carbonate (FEC)‐based electrolyte. Due to the aggregate structure of NO ₃ ⁻ ions and their participation in the primary Li ⁺ solvation sheath, abundant Li ₂ O, Li ₃ N, and LiN _x O _y grains are formed in the resulting SEI, in addition to the uniform LiF distribution from the reduction of PF ₆ ⁻ ions. The weak bonding of the SEI (high interface energy) to Li can effectively promote Li diffusion along the SEI/Li interface and prevent Li dendrite penetration into the SEI. As a result, our designed carbonate electrolyte enables a Li anode to achieve a high Li plating/stripping Coulombic efficiency of 99.55 % (1 mA cm ⁻² , 1.0 mAh cm ⁻² ) and the electrolyte also enables a Li||LiNi _0.8 Co _0.1 Mn _0.1 O ₂more »« less

Authors:

Liu, Sufu ^[1]; Ji, Xiao ^[1]; Piao, Nan ^[1]; Chen, Ji ^[1]; Eidson, Nico ^[1]; Xu, Jijian ^[1]; Wang, Pengfei ^[1]; Chen, Long ^[1]; Zhang, Jiaxun ^[1]; Deng, Tao ^[1]; Hou, Singyuk ^[1]; Jin, Ting ^[1]; Wan, Hongli ^[1]; Li, Jingru ^[2]; Tu, Jiangping ^[2];

^[1]

Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20740 USA
State Key Laboratory of Silicon Materials Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province School of Materials Science&, Engineering Zhejiang University Hangzhou 310027 China

Publication Date:: Wed Dec 16 00:00:00 EST 2020

Sponsoring Org.:: USDOE

OSTI Identifier:: 1786223

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 133 Journal Issue: 7; Journal ID: ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Liu, Sufu, Ji, Xiao, Piao, Nan, Chen, Ji, Eidson, Nico, Xu, Jijian, Wang, Pengfei, Chen, Long, Zhang, Jiaxun, Deng, Tao, Hou, Singyuk, Jin, Ting, Wan, Hongli, Li, Jingru, Tu, Jiangping, and Wang, Chunsheng. An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes.  Germany: N. p., 2020. 
Web.  doi:10.1002/ange.202012005.

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                    Liu, Sufu, Ji, Xiao, Piao, Nan, Chen, Ji, Eidson, Nico, Xu, Jijian, Wang, Pengfei, Chen, Long, Zhang, Jiaxun, Deng, Tao, Hou, Singyuk, Jin, Ting, Wan, Hongli, Li, Jingru, Tu, Jiangping, & Wang, Chunsheng. An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes.  Germany.  https://doi.org/10.1002/ange.202012005

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                    Liu, Sufu, Ji, Xiao, Piao, Nan, Chen, Ji, Eidson, Nico, Xu, Jijian, Wang, Pengfei, Chen, Long, Zhang, Jiaxun, Deng, Tao, Hou, Singyuk, Jin, Ting, Wan, Hongli, Li, Jingru, Tu, Jiangping, and Wang, Chunsheng. Wed .  
"An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes".  Germany.  https://doi.org/10.1002/ange.202012005.

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@article{osti_1786223,

  title        = {An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes},

  author       = {Liu, Sufu and Ji, Xiao and Piao, Nan and Chen, Ji and Eidson, Nico and Xu, Jijian and Wang, Pengfei and Chen, Long and Zhang, Jiaxun and Deng, Tao and Hou, Singyuk and Jin, Ting and Wan, Hongli and Li, Jingru and Tu, Jiangping and Wang, Chunsheng},

  abstractNote = {Abstract In carbonate electrolytes, the organic–inorganic solid electrolyte interphase (SEI) formed on the Li‐metal anode surface is strongly bonded to Li and experiences the same volume change as Li, thus it undergoes continuous cracking/reformation during plating/stripping cycles. Here, an inorganic‐rich SEI is designed on a Li‐metal surface to reduce its bonding energy with Li metal by dissolving 4 m concentrated LiNO 3 in dimethyl sulfoxide (DMSO) as an additive for a fluoroethylene‐carbonate (FEC)‐based electrolyte. Due to the aggregate structure of NO 3 − ions and their participation in the primary Li + solvation sheath, abundant Li 2 O, Li 3 N, and LiN x O y grains are formed in the resulting SEI, in addition to the uniform LiF distribution from the reduction of PF 6 − ions. The weak bonding of the SEI (high interface energy) to Li can effectively promote Li diffusion along the SEI/Li interface and prevent Li dendrite penetration into the SEI. As a result, our designed carbonate electrolyte enables a Li anode to achieve a high Li plating/stripping Coulombic efficiency of 99.55 % (1 mA cm −2 , 1.0 mAh cm −2 ) and the electrolyte also enables a Li||LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NMC811) full cell (2.5 mAh cm −2 ) to retain 75 % of its initial capacity after 200 cycles with an outstanding CE of 99.83 %.},

  doi          = {10.1002/ange.202012005},

  journal      = {Angewandte Chemie},

  number       = 7,

  volume       = 133,

  place        = {Germany},

  year         = {Wed Dec 16 00:00:00 EST 2020},

  month        = {Wed Dec 16 00:00:00 EST 2020}

}

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Journal Article Chen, Ji ; Li, Qin ; Pollard, Travis P. ; ... - Materials Today

Li metal, with the lowest thermodynamically achievable negative electrochemical potential and the highest specific capacity (3860 mAh g^-1), is the ultimate anode choice for Li batteries. However, the highest reported Li plating/stripping Coulombic efficiency (CE) of 99.5% after extensive efforts is still too low for the Li metal-free (all the Li metal in cycling comes from cathode, without anode pre-lithiation) Li metal batteries. The low CE is attributed to both non-uniform Li plating/stripping on the lithiophobic Cu current collector and Li dendrite growth through lithiophilic organic–inorganic solid electrolyte interphase (SEI) formed in carbonate electrolytes. Here, we use a lithiophilic Bismuthmore »« less
https://doi.org/10.1016/j.mattod.2020.04.004

Full Text Available
High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries

Journal Article Liu, Sufu ; Ji, Xiao ; Yue, Jie ; ... - Journal of the American Chemical Society

We report engineering a stable solid electrolyte interphase (SEI) is critical for suppression of lithium dendrites. However, formation of desired SEI by formulating electrolyte composition is very difficult due to complex electrochemical reduction reactions. Here, instead of try-and-error of electrolyte composition, we design a Li-11 wt% Sr alloy anode to form SrF₂-rich SEI in fluorinated electrolytes. Density functional theory (DFT) calculation and experimental characterization demonstrate that SrF₂-rich SEI has a large interfacial energy with Li metal and a high mechanical strength, which can effectively suppress the Li dendrite growth by simultaneously promoting the lateral growth of deposited Li metal andmore »« less
https://doi.org/10.1021/jacs.9b11750

Full Text Available
F and N Rich Solid Electrolyte for Stable All-Solid-State Battery

Journal Article Wan, Hongli L. ; Zhang, Jiaxun X. ; Xia, Jiale L. ; ... - Advanced Functional Materials

Abstract The instability of sulfide solid electrolytes to Li anode and high‐voltage LiNi _0.8 Mn _0.1 Co _0.1 O ₂ (NMC811) cathodes limits the cyclic performance of all‐solid‐state lithium battery (ASSLB). Herein, the stability of Li ₆ PS ₅ Cl against Li anode is enhanced by mixing a small amount (0.32 wt%) of CuF ₂ ‐LiNO ₃ (CL) into Li ₆ PS ₅ Cl electrolyte layer to in‐situ form a mixed‐conductive‐lithiophobic and self‐healing LiF‐Li ₃ N‐Cu solid electrolyte interphase (SEI) at Li ₆ PS ₅ Cl‐CL/Li interface. The critical current density (CCD) of Li ₆ PS ₅ Cl‐CuF ₂ ‐LiNOmore »« less
https://doi.org/10.1002/adfm.202110876

Full Text Available
Enhanced Stability of Li Metal Anodes by Synergetic Control of Nucleation and the Solid Electrolyte Interphase

Journal Article Peng, Zhe ; Song, Junhua ; Huai, Liyuan ; ... - Advanced Energy Materials

Abstract Use of a protective coating on a lithium metal anode (LMA) is an effective approach to enhance its coulombic efficiency and cycling stability. Here, a facile approach to produce uniform silver nanoparticle‐decorated LMA for high‐performance Li metal batteries (LMBs) is reported. This effective treatment can lead to well‐controlled nucleation and the formation of a stable solid electrolyte interphase (SEI). Ag nanoparticles embedded in the surface of Li anodes induce uniform Li plating/stripping morphologies with reduced overpotential. More importantly, cross‐linked lithium fluoride‐rich interphase formed during Ag ⁺ reduction enables a highly stable SEI layer. Based on the Ag‐LiF decorated anodes,more »« less
Cited by 86
https://doi.org/10.1002/aenm.201901764

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Title: An Inorganic‐Rich Solid Electrolyte Interphase for Advanced Lithium‐Metal Batteries in Carbonate Electrolytes

Abstract

Citation Formats

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries journal, January 2018

Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries journal, June 2020

Volume Changes of Graphite Anodes Revisited: A Combined Operando X-ray Diffraction and In Situ Pressure Analysis Study journal, April 2018

High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries journal, January 2020

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery journal, December 2018

Dendrite-Free Lithium Deposition with Self-Aligned Columnar Structure in a Carbonate–Ether Mixed Electrolyte journal, May 2017

Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite journal, May 2019

The electrochemical behavior of selected polar aprotic systems journal, February 1989

Effect of donor number of solvent on the conductivity behaviour of nonaqueous proton-conducting polymer gel electrolytes journal, June 2003

Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives journal, October 2018

Cuprite-coated Cu foam skeleton host enabling lateral growth of lithium dendrites for advanced Li metal batteries journal, September 2019

A high-energy sulfur cathode in carbonate electrolyte by eliminating polysulfides via solid-phase lithium-sulfur transformation journal, October 2018

Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes journal, March 2018

Effects of Fluoroethylene Carbonate (FEC) on Anode and Cathode Interfaces at Elevated Temperatures journal, January 2015

Colossal Granular Lithium Deposits Enabled by the Grain‐Coarsening Effect for High‐Efficiency Lithium Metal Full Batteries journal, May 2020

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries journal, November 2015

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review journal, July 2017

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal, October 2004

Spontaneous and field-induced crystallographic reorientation of metal electrodeposits at battery anodes journal, June 2020

Structural and Functional Analysis of Surface Film on Li Anode in Vinylene Carbonate-Containing Electrolyte journal, January 2004

Lithium Metal Anodes: Toward an Improved Understanding of Coupled Morphological, Electrochemical, and Mechanical Behavior journal, February 2017

Electrolytes and Interphases in Li-Ion Batteries and Beyond journal, October 2014

Non-encapsulation approach for high-performance Li–S batteries through controlled nucleation and growth journal, September 2017

Li3N: A promising Li ionic conductor journal, September 1979

DFT+U Study of Polaronic Conduction in Li 2 O 2 and Li 2 CO 3 : Implications for Li–Air Batteries journal, March 2013

Lithium metal anodes for rechargeable batteries journal, January 2014

Electrolytic Characteristics of Fluoroethylene Carbonate for Electric Double-Layer Capacitors at High Concentrations of Electrolyte journal, January 2013

The Li-Ion Rechargeable Battery: A Perspective journal, January 2013

High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes journal, May 2018

Fluoroethylene Carbonate as an Important Component in Electrolyte Solutions for High-Voltage Lithium Batteries: Role of Surface Chemistry on the Cathode journal, June 2014

Elektrolytadditive für Lithiummetallanoden und wiederaufladbare Lithiummetallbatterien: Fortschritte und Perspektiven journal, October 2018

Rechargeable lithiated silicon–sulfur (SLS) battery prototypes journal, January 2012

Quantifying inactive lithium in lithium metal batteries journal, August 2019

Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes journal, March 2018

Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization journal, September 2019

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries journal, January 2009

Formation and Growth Mechanisms of Solid-Electrolyte Interphase Layers in Rechargeable Batteries journal, November 2015

Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries journal, March 2018

Critical Parameters for Evaluating Coin Cells and Pouch Cells of Rechargeable Li-Metal Batteries journal, April 2019

The Failure of Solid Electrolyte Interphase on Li Metal Anode: Structural Uniformity or Mechanical Strength? journal, March 2020

Countersolvent Electrolytes for Lithium‐Metal Batteries journal, March 2020

Wettable carbon felt framework for high loading Li-metal composite anode journal, June 2019

Enhanced cycling performance of a Li metal anode in a dimethylsulfoxide-based electrolyte using highly concentrated lithium salt for a lithium−oxygen battery journal, March 2016

Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte journal, January 2020

Unraveling and Mitigating the Storage Instability of Fluoroethylene Carbonate-Containing LiPF 6 Electrolytes To Stabilize Lithium Metal Anodes for High-Temperature Rechargeable Batteries journal, June 2019

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries journal, September 2018

Investigation of Fluoroethylene Carbonate Effects on Tin-based Lithium-Ion Battery Electrodes journal, March 2015

Defect Thermodynamics and Diffusion Mechanisms in Li 2 CO 3 and Implications for the Solid Electrolyte Interphase in Li-Ion Batteries journal, March 2013

A new direction for the performance improvement of rechargeable lithium/sulfur batteries journal, February 2012

Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries journal, June 2020

All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents journal, October 2019

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries journal, July 2018

Functional Electrolyte of Fluorinated Ether and Ester for Stabilizing Both 4.5 V LiCoO 2 Cathode and Lithium Metal Anode journal, January 2020

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries journal, October 2017

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes journal, October 2016

Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode journal, September 2018

Design principles for electrolytes and interfaces for stable lithium-metal batteries journal, September 2016

The critical role of lithium nitrate in the gas evolution of lithium–sulfur batteries journal, January 2016

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries journal, January 2017

Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF 6 and Cyclic Carbonate Additives journal, November 2017

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution journal, May 2017

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries journal, February 2013

Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation journal, November 2016

Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte journal, January 2020

Electronic and Ionic Channels in Working Interfaces of Lithium Metal Anodes journal, June 2018

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries journal, September 2018

Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability journal, August 2017

Review—SEI: Past, Present and Future journal, January 2017

Electrolyte design for Li metal-free Li batteries journal, April 2020

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal, January 1979

Polyethylene oxide film coating enhances lithium cycling efficiency of an anode-free lithium-metal battery journal, January 2018

Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li–O 2 battery capacity journal, July 2015

High rate and stable cycling of lithium metal anode journal, February 2015

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries
journal, January 2018

Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries
journal, June 2020

Volume Changes of Graphite Anodes Revisited: A Combined Operando X-ray Diffraction and In Situ Pressure Analysis Study
journal, April 2018

High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries
journal, January 2020

Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery
journal, December 2018

Dendrite-Free Lithium Deposition with Self-Aligned Columnar Structure in a Carbonate–Ether Mixed Electrolyte
journal, May 2017

Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite
journal, May 2019

The electrochemical behavior of selected polar aprotic systems
journal, February 1989

Effect of donor number of solvent on the conductivity behaviour of nonaqueous proton-conducting polymer gel electrolytes
journal, June 2003

Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives
journal, October 2018

Cuprite-coated Cu foam skeleton host enabling lateral growth of lithium dendrites for advanced Li metal batteries
journal, September 2019

A high-energy sulfur cathode in carbonate electrolyte by eliminating polysulfides via solid-phase lithium-sulfur transformation
journal, October 2018

Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes
journal, March 2018

Effects of Fluoroethylene Carbonate (FEC) on Anode and Cathode Interfaces at Elevated Temperatures
journal, January 2015

Colossal Granular Lithium Deposits Enabled by the Grain‐Coarsening Effect for High‐Efficiency Lithium Metal Full Batteries
journal, May 2020

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Spontaneous and field-induced crystallographic reorientation of metal electrodeposits at battery anodes
journal, June 2020

Structural and Functional Analysis of Surface Film on Li Anode in Vinylene Carbonate-Containing Electrolyte
journal, January 2004

Lithium Metal Anodes: Toward an Improved Understanding of Coupled Morphological, Electrochemical, and Mechanical Behavior
journal, February 2017

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

Non-encapsulation approach for high-performance Li–S batteries through controlled nucleation and growth
journal, September 2017

Li3N: A promising Li ionic conductor
journal, September 1979

DFT+U Study of Polaronic Conduction in Li ₂ O ₂ and Li ₂ CO ₃ : Implications for Li–Air Batteries
journal, March 2013

Lithium metal anodes for rechargeable batteries
journal, January 2014

Electrolytic Characteristics of Fluoroethylene Carbonate for Electric Double-Layer Capacitors at High Concentrations of Electrolyte
journal, January 2013

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes
journal, May 2018

Fluoroethylene Carbonate as an Important Component in Electrolyte Solutions for High-Voltage Lithium Batteries: Role of Surface Chemistry on the Cathode
journal, June 2014

Elektrolytadditive für Lithiummetallanoden und wiederaufladbare Lithiummetallbatterien: Fortschritte und Perspektiven
journal, October 2018

Rechargeable lithiated silicon–sulfur (SLS) battery prototypes
journal, January 2012

Quantifying inactive lithium in lithium metal batteries
journal, August 2019

Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes
journal, March 2018

Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization
journal, September 2019

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries
journal, January 2009

Formation and Growth Mechanisms of Solid-Electrolyte Interphase Layers in Rechargeable Batteries
journal, November 2015

Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
journal, March 2018

Critical Parameters for Evaluating Coin Cells and Pouch Cells of Rechargeable Li-Metal Batteries
journal, April 2019

The Failure of Solid Electrolyte Interphase on Li Metal Anode: Structural Uniformity or Mechanical Strength?
journal, March 2020

Countersolvent Electrolytes for Lithium‐Metal Batteries
journal, March 2020

Wettable carbon felt framework for high loading Li-metal composite anode
journal, June 2019

Enhanced cycling performance of a Li metal anode in a dimethylsulfoxide-based electrolyte using highly concentrated lithium salt for a lithium−oxygen battery
journal, March 2016

Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte
journal, January 2020

Unraveling and Mitigating the Storage Instability of Fluoroethylene Carbonate-Containing LiPF ₆ Electrolytes To Stabilize Lithium Metal Anodes for High-Temperature Rechargeable Batteries
journal, June 2019

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries
journal, September 2018

Investigation of Fluoroethylene Carbonate Effects on Tin-based Lithium-Ion Battery Electrodes
journal, March 2015

Defect Thermodynamics and Diffusion Mechanisms in Li ₂ CO ₃ and Implications for the Solid Electrolyte Interphase in Li-Ion Batteries
journal, March 2013

A new direction for the performance improvement of rechargeable lithium/sulfur batteries
journal, February 2012

Synergistic Dual‐Additive Electrolyte Enables Practical Lithium‐Metal Batteries
journal, June 2020

All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents
journal, October 2019

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018

Functional Electrolyte of Fluorinated Ether and Ester for Stabilizing Both 4.5 V LiCoO ₂ Cathode and Lithium Metal Anode
journal, January 2020

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
journal, October 2017

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes
journal, October 2016

Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode
journal, September 2018

Design principles for electrolytes and interfaces for stable lithium-metal batteries
journal, September 2016

The critical role of lithium nitrate in the gas evolution of lithium–sulfur batteries
journal, January 2016

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF ₆ and Cyclic Carbonate Additives
journal, November 2017

Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution
journal, May 2017

A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013

Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation
journal, November 2016

Enabling High‐Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte
journal, January 2020

Electronic and Ionic Channels in Working Interfaces of Lithium Metal Anodes
journal, June 2018

Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries
journal, September 2018

Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability
journal, August 2017

Review—SEI: Past, Present and Future
journal, January 2017

Electrolyte design for Li metal-free Li batteries
journal, April 2020

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model
journal, January 1979

Polyethylene oxide film coating enhances lithium cycling efficiency of an anode-free lithium-metal battery
journal, January 2018

Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li–O ₂ battery capacity
journal, July 2015

High rate and stable cycling of lithium metal anode
journal, February 2015