Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries

Flamary-Mespoulie, Florian; Boulineau, Adrien; Martinez, Hervé; Suchomel, Matthew R.; Delmas, Claude; Pecquenard, Brigitte; Le Cras, Frédéric

doi:10.1016/j.ensm.2019.12.033

Title: Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries

Authors:

Flamary-Mespoulie, Florian; Boulineau, Adrien; Martinez, Hervé;

; Delmas, Claude;

;

Publication Date:: Wed Apr 01 00:00:00 EDT 2020

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1781475

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Energy Storage Materials

Additional Journal Information:: Journal Name: Energy Storage Materials Journal Volume: 26 Journal Issue: C; Journal ID: ISSN 2405-8297

Publisher:: Elsevier

Country of Publication:: Netherlands

Language:: English

Citation Formats


                    Flamary-Mespoulie, Florian, Boulineau, Adrien, Martinez, Hervé, Suchomel, Matthew R., Delmas, Claude, Pecquenard, Brigitte, and Le Cras, Frédéric. Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries.  Netherlands: N. p., 2020. 
Web.  doi:10.1016/j.ensm.2019.12.033.

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                    Flamary-Mespoulie, Florian, Boulineau, Adrien, Martinez, Hervé, Suchomel, Matthew R., Delmas, Claude, Pecquenard, Brigitte, & Le Cras, Frédéric. Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries.  Netherlands.  https://doi.org/10.1016/j.ensm.2019.12.033

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                    Flamary-Mespoulie, Florian, Boulineau, Adrien, Martinez, Hervé, Suchomel, Matthew R., Delmas, Claude, Pecquenard, Brigitte, and Le Cras, Frédéric. Wed .  
"Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries".  Netherlands.  https://doi.org/10.1016/j.ensm.2019.12.033.

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@article{osti_1781475,

  title        = {Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries},

  author       = {Flamary-Mespoulie, Florian and Boulineau, Adrien and Martinez, Hervé and Suchomel, Matthew R. and Delmas, Claude and Pecquenard, Brigitte and Le Cras, Frédéric},

  abstractNote = {},

  doi          = {10.1016/j.ensm.2019.12.033},

  journal      = {Energy Storage Materials},

  number       = C,

  volume       = 26,

  place        = {Netherlands},

  year         = {Wed Apr 01 00:00:00 EDT 2020},

  month        = {Wed Apr 01 00:00:00 EDT 2020}

}

Copy to clipboard

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https://doi.org/10.1016/j.ensm.2019.12.033

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Cited by: 31 works

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Title: Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries

Citation Formats

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes journal, July 2013

Dual Cation- and Anion-Based Redox Process in Lithium Titanium Oxysulfide Thin Film Cathodes for All-Solid-State Lithium-Ion Batteries journal, January 2017

Electrochemical Na-Deintercalation from NaVO2 journal, January 2011

On “Really” Stoichiometric LiCoO[sub 2] journal, January 2008

A Search for Low-Irreversible Capacity and High-Reversible Capacity Positive Electrode Materials in the Li–Ni–Mn–Co Pseudoquaternary System journal, December 2015

Study of the nanosized Li2MnO3: Electrochemical behavior, structure, magnetic properties, and vibrational modes journal, May 2013

Occurrence and characterization of anionic bondings in transition metal dichalcogenides journal, February 1992

Fabrication and electrochemical properties of a LiCoO2 and Li10GeP2S12 composite electrode for use in all-solid-state batteries journal, February 2016

All-Solid-State Lithium-Ion Microbatteries Using Silicon Nanofilm Anodes: High Performance and Memory Effect journal, July 2015

Fast Lithium Ion Conduction in Li 2 SnS 3 : Synthesis, Physicochemical Characterization, and Electronic Structure journal, December 2014

Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 journal, June 2006

O′3–Na x VO 2 System: A Superstructure for Na 1/2 VO 2 journal, September 2012

The lithium intercalates of the transition metal dichalcogenides journal, May 1975

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials journal, May 2016

Rock-salt-type lithium metal sulphides as novel positive-electrode materials journal, May 2014

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

Reinvestigation of Li 2 MnO 3 Structure: Electron Diffraction and High Resolution TEM journal, September 2009

Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries journal, April 2018

Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries journal, January 2017

Future generations of cathode materials: an automotive industry perspective journal, January 2015

A lithium superionic conductor journal, July 2011

The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries journal, January 2016

Convenient preparation and physical properties of lithium intercalation compounds of Group 4B and 5B layered transition metal dichalcogenides journal, January 1976

Synthesis and crystal structure of alkali metal uranium sulfides, Li2US3 and Na2US3 journal, March 1999

High-power all-solid-state batteries using sulfide superionic conductors journal, March 2016

Origin of voltage decay in high-capacity layered oxide electrodes journal, December 2014

The 3R phase of LixTiS2 journal, May 1989

Na2ZrS3: Ein ternäres Sulfid des Zirconiums mit aufgefüllter AlCl3-Struktur journal, February 1999

XPS investigations of TiOySz amorphous thin films used as positive electrode in lithium microbatteries journal, May 2005

High Capacity Li-Rich Positive Electrode Materials with Reduced First-Cycle Irreversible Capacity Loss journal, January 2015

A Novel Surface Treatment Method and New Insight into Discharge Voltage Deterioration for High-Performance 0.4Li 2 MnO 3- 0.6LiNi 1/3 Co 1/3 Mn 1/3 O 2 Cathode Materials journal, June 2014

Experimental Assessment of the Practical Oxidative Stability of Lithium Thiophosphate Solid Electrolytes journal, September 2019

The Role of Ternary Phases in Cathode Reactions journal, January 1976

Anion–Cation Redox Competition and the Formation of New Compounds in Highly Covalent Systems journal, September 1996

Quantification of Oxygen Loss from Li[sub 1+x](Ni[sub 1/3]Mn[sub 1/3]Co[sub 1/3])[sub 1−x]O[sub 2] at High Potentials by Differential Electrochemical Mass Spectrometry journal, January 2009

Lithium-Ion Battery Supply Chain Considerations: Analysis of Potential Bottlenecks in Critical Metals journal, October 2017

Interface Stability in Solid-State Batteries journal, December 2015

Temperature effects on Li 4 Ti 5 O 12 electrode/electrolyte interfaces at the first cycle: A X-ray Photoelectron Spectroscopy and Scanning Auger Microscopy study journal, June 2016

Intermediate phases in the systems niobium-selenium, niobium-tellurium, tantalum-selenium, and tantalum-tellurium journal, July 1966

New Insight into the Atomic-Scale Bulk and Surface Structure Evolution of Li 4 Ti 5 O 12 Anode journal, January 2015

Operating through oxygen journal, June 2016

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013

Dual Cation- and Anion-Based Redox Process in Lithium Titanium Oxysulfide Thin Film Cathodes for All-Solid-State Lithium-Ion Batteries
journal, January 2017

Electrochemical Na-Deintercalation from NaVO2
journal, January 2011

On “Really” Stoichiometric LiCoO[sub 2]
journal, January 2008

A Search for Low-Irreversible Capacity and High-Reversible Capacity Positive Electrode Materials in the Li–Ni–Mn–Co Pseudoquaternary System
journal, December 2015

Study of the nanosized Li2MnO3: Electrochemical behavior, structure, magnetic properties, and vibrational modes
journal, May 2013

Occurrence and characterization of anionic bondings in transition metal dichalcogenides
journal, February 1992

Fabrication and electrochemical properties of a LiCoO2 and Li10GeP2S12 composite electrode for use in all-solid-state batteries
journal, February 2016

All-Solid-State Lithium-Ion Microbatteries Using Silicon Nanofilm Anodes: High Performance and Memory Effect
journal, July 2015

Fast Lithium Ion Conduction in Li ₂ SnS ₃ : Synthesis, Physicochemical Characterization, and Electronic Structure
journal, December 2014

Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni_0.2Li_0.2Mn_0.6]O₂
journal, June 2006

O′3–Na _x VO ₂ System: A Superstructure for Na _1/2 VO ₂
journal, September 2012

The lithium intercalates of the transition metal dichalcogenides
journal, May 1975

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials
journal, May 2016

Rock-salt-type lithium metal sulphides as novel positive-electrode materials
journal, May 2014

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Reinvestigation of Li ₂ MnO ₃ Structure: Electron Diffraction and High Resolution TEM
journal, September 2009

Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries
journal, April 2018

Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries
journal, January 2017

Future generations of cathode materials: an automotive industry perspective
journal, January 2015

A lithium superionic conductor
journal, July 2011

The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries
journal, January 2016

Convenient preparation and physical properties of lithium intercalation compounds of Group 4B and 5B layered transition metal dichalcogenides
journal, January 1976

Synthesis and crystal structure of alkali metal uranium sulfides, Li2US3 and Na2US3
journal, March 1999

High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016

Origin of voltage decay in high-capacity layered oxide electrodes
journal, December 2014

The 3R phase of LixTiS2
journal, May 1989

Na2ZrS3: Ein ternäres Sulfid des Zirconiums mit aufgefüllter AlCl3-Struktur
journal, February 1999

XPS investigations of TiOySz amorphous thin films used as positive electrode in lithium microbatteries
journal, May 2005

High Capacity Li-Rich Positive Electrode Materials with Reduced First-Cycle Irreversible Capacity Loss
journal, January 2015

A Novel Surface Treatment Method and New Insight into Discharge Voltage Deterioration for High-Performance 0.4Li ₂ MnO _3- 0.6LiNi _1/3 Co _1/3 Mn _1/3 O ₂ Cathode Materials
journal, June 2014

Experimental Assessment of the Practical Oxidative Stability of Lithium Thiophosphate Solid Electrolytes
journal, September 2019

The Role of Ternary Phases in Cathode Reactions
journal, January 1976

Anion–Cation Redox Competition and the Formation of New Compounds in Highly Covalent Systems
journal, September 1996

Quantification of Oxygen Loss from Li[sub 1+x](Ni[sub 1/3]Mn[sub 1/3]Co[sub 1/3])[sub 1−x]O[sub 2] at High Potentials by Differential Electrochemical Mass Spectrometry
journal, January 2009

Lithium-Ion Battery Supply Chain Considerations: Analysis of Potential Bottlenecks in Critical Metals
journal, October 2017

Interface Stability in Solid-State Batteries
journal, December 2015

Temperature effects on Li 4 Ti 5 O 12 electrode/electrolyte interfaces at the first cycle: A X-ray Photoelectron Spectroscopy and Scanning Auger Microscopy study
journal, June 2016

Intermediate phases in the systems niobium-selenium, niobium-tellurium, tantalum-selenium, and tantalum-tellurium
journal, July 1966

New Insight into the Atomic-Scale Bulk and Surface Structure Evolution of Li ₄ Ti ₅ O ₁₂ Anode
journal, January 2015

Operating through oxygen
journal, June 2016