The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb2O5 and Pt/TiO2
Abstract
The hydrodeoxygenation (HDO) of m-cresol was studied on Pt/Nb2O5/MgAl2O4 and Pt/TiO2/MgAl2O4 catalysts to understand the effects of Strong Metal Support Interactions (SMSI). The Nb2O5 and TiO2 supports were prepared as 0.7-nm films on MgAl2O4 by Atomic Layer Deposition (ALD) to ensure that the structures of the catalyst were the same. When reduced at 773 K to place Pt in the encapsulated state, Pt/Nb2O5/MgAl2O4 was much less active than Pt/MgAl2O4 at 573 K but much more active at 623 K. While Pt/MgAl2O4 deactivated rapidly due to coking, Pt/Nb2O5/MgAl2O4 showed significantly better coke tolerance and was almost 100% selective towards toluene production. Pt/Nb2O5/MgAl2O4 reduced at lower temperatures exhibited intermediate catalytic properties. The effect of reduction temperature on Pt/TiO2/MgAl2O4 was much less and this catalyst was more similar to Pt/MgAl2O4 than its Nb2O5 counterpart. Lastly, the implications of these results for understanding the nature of oxide promoters on HDO of m-cresol are discussed.
- Authors:
-
- Univ. of Pennsylvania, Philadelphia, PA (United States); Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Publication Date:
- Research Org.:
- Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1779103
- Alternate Identifier(s):
- OSTI ID: 1781868
- Grant/Contract Number:
- SC0001004; NNCI-1542153
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Catalysis
- Additional Journal Information:
- Journal Volume: 398; Journal ID: ISSN 0021-9517
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; Cresol; Hydrodeoxygenation; Support effects; Platinum; Niobium oxide; Titanium oxide; Atomic Layer Deposition (ALD).
Citation Formats
Huang, Renjing, Kwon, Ohhun, Lin, Chao, and Gorte, Raymond J. The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb2O5 and Pt/TiO2. United States: N. p., 2021.
Web. doi:10.1016/j.jcat.2021.04.012.
Huang, Renjing, Kwon, Ohhun, Lin, Chao, & Gorte, Raymond J. The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb2O5 and Pt/TiO2. United States. https://doi.org/10.1016/j.jcat.2021.04.012
Huang, Renjing, Kwon, Ohhun, Lin, Chao, and Gorte, Raymond J. Wed .
"The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb2O5 and Pt/TiO2". United States. https://doi.org/10.1016/j.jcat.2021.04.012. https://www.osti.gov/servlets/purl/1779103.
@article{osti_1779103,
title = {The effects of SMSI on m-Cresol Hydrodeoxygenation over Pt/Nb2O5 and Pt/TiO2},
author = {Huang, Renjing and Kwon, Ohhun and Lin, Chao and Gorte, Raymond J.},
abstractNote = {The hydrodeoxygenation (HDO) of m-cresol was studied on Pt/Nb2O5/MgAl2O4 and Pt/TiO2/MgAl2O4 catalysts to understand the effects of Strong Metal Support Interactions (SMSI). The Nb2O5 and TiO2 supports were prepared as 0.7-nm films on MgAl2O4 by Atomic Layer Deposition (ALD) to ensure that the structures of the catalyst were the same. When reduced at 773 K to place Pt in the encapsulated state, Pt/Nb2O5/MgAl2O4 was much less active than Pt/MgAl2O4 at 573 K but much more active at 623 K. While Pt/MgAl2O4 deactivated rapidly due to coking, Pt/Nb2O5/MgAl2O4 showed significantly better coke tolerance and was almost 100% selective towards toluene production. Pt/Nb2O5/MgAl2O4 reduced at lower temperatures exhibited intermediate catalytic properties. The effect of reduction temperature on Pt/TiO2/MgAl2O4 was much less and this catalyst was more similar to Pt/MgAl2O4 than its Nb2O5 counterpart. Lastly, the implications of these results for understanding the nature of oxide promoters on HDO of m-cresol are discussed.},
doi = {10.1016/j.jcat.2021.04.012},
journal = {Journal of Catalysis},
number = ,
volume = 398,
place = {United States},
year = {Wed Apr 21 00:00:00 EDT 2021},
month = {Wed Apr 21 00:00:00 EDT 2021}
}
Works referenced in this record:
Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014
- Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
- Science, Vol. 344, Issue 6185, p. 1246843-1246843
Hydrogenation of o-cresol on platinum catalyst: Catalytic experiments and first-principles calculations
journal, January 2017
- Li, Yaping; Liu, Zhimin; Xue, Wenhua
- Applied Surface Science, Vol. 393
Insights into the catalytic activity and surface modification of MoO 3 during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures
journal, January 2014
- Prasomsri, Teerawit; Shetty, Manish; Murugappan, Karthick
- Energy Environ. Sci., Vol. 7, Issue 8
Hydrodeoxygenation of m-Cresol over Ru based catalysts: Influence of catalyst support on m-Cresol conversion and methylcyclohexane selectivity
journal, May 2020
- Kumar, Adarsh; Kumar, Avnish; Biswas, Bijoy
- Renewable Energy, Vol. 151
Role of the metal-support interface in the hydrodeoxygenation reaction of phenol
journal, November 2020
- Teles, Camila A.; Rabelo-Neto, Raimundo C.; Duong, Nhung
- Applied Catalysis B: Environmental, Vol. 277
Characterization of oxide impurities on Pt and their effect on the adsorption of CO and H2
journal, June 1985
- Ko, C. S.; Gorte, R. J.
- Surface Science, Vol. 155, Issue 1
Insight into the nature of Brönsted acidity of Pt-(WOx)n-H model catalysts in glycerol hydrogenolysis
journal, August 2020
- Zhou, Wei; Li, Ying; Wang, Xiaofei
- Journal of Catalysis, Vol. 388
Evidence for diffusion of a partially oxidized titanium species into bulk platinum
journal, November 1984
- Ko, C.
- Journal of Catalysis, Vol. 90, Issue 1
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006
- Huber, George W.; Iborra, Sara; Corma, Avelino
- Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098
Hydrodeoxygenation of phenol over niobia supported Pd catalyst
journal, March 2018
- Barrios, Adriana M.; Teles, Camila A.; de Souza, Priscilla M.
- Catalysis Today, Vol. 302
Mechanisms for High Selectivity in the Hydrodeoxygenation of 5-Hydroxymethylfurfural over PtCo Nanocrystals
journal, May 2016
- Luo, Jing; Yun, Hongseok; Mironenko, Alexander V.
- ACS Catalysis, Vol. 6, Issue 7
A review on thermal chemical reactions of lignin model compounds
journal, December 2017
- Yang, Le; Seshan, K.; Li, Yongdan
- Catalysis Today, Vol. 298
Hydrodeoxygenation of m-Cresol Over Pt-WOx/C Using H2 Generated In Situ by n-Hexane Dehydrogenation
journal, November 2019
- Wang, Cong; Wittreich, Gerhard R.; Lin, Chao
- Catalysis Letters
Strong metal-support interactions: Occurrence among the binary oxides of groups IIA?VB
journal, October 1978
- Tauster, S.
- Journal of Catalysis, Vol. 55, Issue 1
Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis
journal, January 2013
- Parsell, Trenton H.; Owen, Benjamin C.; Klein, Ian
- Chem. Sci., Vol. 4, Issue 2, p. 806-813
Activity and selectivity of a niobia (Nb2O5)-supported nickel catalyst in CO hydrogenation
journal, January 1983
- Ko, Edmond I.; Hupp, John M.; Wagner, Norman J.
- Journal of the Chemical Society, Chemical Communications, Issue 2
Direct Hydrodeoxygenation of m -Cresol to Toluene over Bifunctional NbO x –Pt
journal, June 2020
- Chen, Tianqi; Vohs, John M.
- The Journal of Physical Chemistry C, Vol. 124, Issue 26
Improved Coking Resistance of “Intelligent” Ni Catalysts Prepared by Atomic Layer Deposition
journal, July 2018
- Lin, Chao; Jang, Joon Baek; Zhang, Lihua
- ACS Catalysis, Vol. 8, Issue 8
Relationship between Atomic Scale Structure and Reactivity of Pt Catalysts: Hydrodeoxygenation of m -Cresol over Isolated Pt Cations and Clusters
journal, November 2019
- Resasco, Joaquin; Yang, Feifei; Mou, Tong
- ACS Catalysis, Vol. 10, Issue 1
Smart Pd Catalyst with Improved Thermal Stability Supported on High-Surface-Area LaFeO 3 Prepared by Atomic Layer Deposition
journal, January 2018
- Onn, Tzia Ming; Monai, Matteo; Dai, Sheng
- Journal of the American Chemical Society, Vol. 140, Issue 14
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
journal, January 1978
- Tauster, S. J.; Fung, S. C.; Garten, R. L.
- Journal of the American Chemical Society, Vol. 100, Issue 1
The Synergy of the Support Acid Function and the Metal Function in the Catalytic Hydrodeoxygenation of m-Cresol
journal, March 2012
- Foster, Andrew J.; Do, Phuong T. M.; Lobo, Raul F.
- Topics in Catalysis, Vol. 55, Issue 3-4
Active sites for the selective hydrodeoxygenation of m-cresol on WOx-modified Pt
journal, November 2019
- Chen, Tianqi; Vohs, John M.
- Surface Science, Vol. 689
Role of the Support and Reaction Conditions on the Vapor-Phase Deoxygenation of m -Cresol over Pt/C and Pt/TiO 2 Catalysts
journal, March 2016
- Griffin, Michael B.; Ferguson, Glen A.; Ruddy, Daniel A.
- ACS Catalysis, Vol. 6, Issue 4
Catalytic upgrading of biomass pyrolysis vapors and model compounds using niobia supported Pd catalyst
journal, December 2018
- Teles, Camila A.; de Souza, Priscilla M.; Rabelo-Neto, Raimundo C.
- Applied Catalysis B: Environmental, Vol. 238
The effect of niobia on the methanation activity of a Pt foil*1
journal, April 1986
- Demmin, R.
- Journal of Catalysis, Vol. 98, Issue 2
Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m -Cresol
journal, August 2014
- Hong, Yongchun; Zhang, He; Sun, Junming
- ACS Catalysis, Vol. 4, Issue 10
Atomic Layer Deposition on Porous Materials: Problems with Conventional Approaches to Catalyst and Fuel Cell Electrode Preparation
journal, March 2018
- Onn, Tzia; Küngas, Rainer; Fornasiero, Paolo
- Inorganics, Vol. 6, Issue 1
Effect of Strong Metal-Support Interaction of Pt/TiO 2 on Hydrodeoxygenation of m-Cresol
journal, October 2018
- Zhao, Xiangyu; Wu, Xiaoxia; Wang, Hua
- ChemistrySelect, Vol. 3, Issue 37
Preparation, reduction, and chemisorption behavior of niobia-supported nickel catalysts
journal, November 1983
- Ko, E.
- Journal of Catalysis, Vol. 84, Issue 1
Epitaxial and Strong Support Interactions between Pt and LaFeO 3 Films Stabilize Pt Dispersion
journal, May 2020
- Mao, Xinyu; Foucher, Alexandre C.; Montini, Tiziano
- Journal of the American Chemical Society, Vol. 142, Issue 23
Probing direct carbon-carbon acylation of furans and long-chain acids over H-ZSM-5
journal, May 2019
- Ji, Yichen; Pan, Jie; Dauenhauer, Paul
- Applied Catalysis A: General, Vol. 577
Geometric and electronic effects of bimetallic Ni–Re catalysts for selective deoxygenation of m-cresol to toluene
journal, May 2017
- Yang, Feifei; Liu, Dan; Wang, Hua
- Journal of Catalysis, Vol. 349
Enhanced Hydrodeoxygenation of m -Cresol over Bimetallic Pt–Mo Catalysts through an Oxophilic Metal-Induced Tautomerization Pathway
journal, June 2016
- Robinson, Allison; Ferguson, Glen Allen; Gallagher, James R.
- ACS Catalysis, Vol. 6, Issue 7
Efficient Conversion of m -Cresol to Aromatics on a Bifunctional Pt/HBeta Catalyst
journal, June 2014
- Zhu, Xinli; Nie, Lei; Lobban, Lance L.
- Energy & Fuels, Vol. 28, Issue 6
Selective hydrogenolysis of phenols and phenyl ethers to arenes through direct C–O cleavage over ruthenium–tungsten bifunctional catalysts
journal, January 2015
- Huang, Yao-Bing; Yan, Long; Chen, Meng-Yuan
- Green Chemistry, Vol. 17, Issue 5
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation
journal, January 2014
- Saidi, Majid; Samimi, Fereshteh; Karimipourfard, Dornaz
- Energy Environ. Sci., Vol. 7, Issue 1
Lignin Pyrolysis Components and Upgrading—Technology Review
journal, February 2013
- Mu, Wei; Ben, Haoxi; Ragauskas, Art
- BioEnergy Research, Vol. 6, Issue 4, p. 1183-1204
From Lignin to Chemicals: Hydrogenation of Lignin Models and Mechanistic Insights into Hydrodeoxygenation via Low-Temperature C–O Bond Cleavage
journal, January 2019
- Vriamont, Charles E. J. J.; Chen, Tianyi; Romain, Charles
- ACS Catalysis, Vol. 9, Issue 3
Hydrodeoxygenation of phenol over metal supported niobia catalysts
journal, April 2020
- Resende, K. A.; Noronha, F. B.; Hori, C. E.
- Renewable Energy, Vol. 149
Mechanistic Study of the Direct Hydrodeoxygenation of m -Cresol over WO x -Decorated Pt/C Catalysts
journal, July 2018
- Wang, Cong; Mironenko, Alexander V.; Raizada, Abhishek
- ACS Catalysis, Vol. 8, Issue 9
Effects of metal promoters in bimetallic catalysts in hydrogenolysis of lignin derivatives into value‐added chemicals
journal, September 2020
- Li, Tingting; Ji, Na; Jia, Zhichao
- ChemCatChem, Vol. 12, Issue 21
Selective conversion of m-cresol to toluene over bimetallic Ni–Fe catalysts
journal, July 2014
- Nie, Lei; de Souza, Priscilla M.; Noronha, Fabio B.
- Journal of Molecular Catalysis A: Chemical, Vol. 388-389
A Study of Support Effects for CH4 and CO Oxidation over Pd Catalysts on ALD-Modified Al2O3
journal, February 2019
- Mao, Xinyu; Foucher, Alexandre; Stach, Eric A.
- Catalysis Letters, Vol. 149, Issue 4