Multiscale Understanding and Architecture Design of High Energy/Power Lithium-Ion Battery Electrodes
Abstract
Among various commercially available energy storage devices, lithium-ion batteries (LIBs) stand out as the most compact and rapidly growing technology. This multicomponent system operates on coupled dynamics to reversibly store and release electricity. With the hierarchical electrode architectures inside LIBs, versatile functionality can be realized by design, while considerable difficulties remain to be solved to fully exploit the capability of each constituent. With the rapid electrification of the transportation sector and an urgent need to overhaul electric grids in the context of renewable energy penetration, demands for concomitant high energy and high power batteries are continuously increasing. Although building an ideal battery requires effort from multiple scientific and engineering aspects, it is imperative to gain insight into multiscale transport behaviors arising in both spatial and temporal dimensions, and enable their harmonic integration inside the whole battery system. In this progress report, recent research efforts on characterizing and understanding transport kinetics in LIBs are reviewed covering a broad range of electrode materials and length scales. Further, to demonstrate the crucial role of such information in revolutionary electrode design, examples of innovative high energy/power electrodes are provided with their unique hierarchical porous architectures highlighted. To conclude, perspectives on further approaches toward advancedmore »
- Authors:
-
[1]
- Univ. of Texas, Austin, TX (United States)
- Stony Brook Univ., NY (United States)
- Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); State Univ. of New York (SUNY), Albany, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1767779
- Alternate Identifier(s):
- OSTI ID: 1617400
- Grant/Contract Number:
- SC0012673
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 2; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; energy storage (including batteries and capacitors); charge transport; mesostructured materials
Citation Formats
Zhang, Xiao, Ju, Zhengyu, Zhu, Yue, Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., and Yu, Guihua. Multiscale Understanding and Architecture Design of High Energy/Power Lithium-Ion Battery Electrodes. United States: N. p., 2020.
Web. doi:10.1002/aenm.202000808.
Zhang, Xiao, Ju, Zhengyu, Zhu, Yue, Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., & Yu, Guihua. Multiscale Understanding and Architecture Design of High Energy/Power Lithium-Ion Battery Electrodes. United States. https://doi.org/10.1002/aenm.202000808
Zhang, Xiao, Ju, Zhengyu, Zhu, Yue, Takeuchi, Kenneth J., Takeuchi, Esther S., Marschilok, Amy C., and Yu, Guihua. Wed .
"Multiscale Understanding and Architecture Design of High Energy/Power Lithium-Ion Battery Electrodes". United States. https://doi.org/10.1002/aenm.202000808. https://www.osti.gov/servlets/purl/1767779.
@article{osti_1767779,
title = {Multiscale Understanding and Architecture Design of High Energy/Power Lithium-Ion Battery Electrodes},
author = {Zhang, Xiao and Ju, Zhengyu and Zhu, Yue and Takeuchi, Kenneth J. and Takeuchi, Esther S. and Marschilok, Amy C. and Yu, Guihua},
abstractNote = {Among various commercially available energy storage devices, lithium-ion batteries (LIBs) stand out as the most compact and rapidly growing technology. This multicomponent system operates on coupled dynamics to reversibly store and release electricity. With the hierarchical electrode architectures inside LIBs, versatile functionality can be realized by design, while considerable difficulties remain to be solved to fully exploit the capability of each constituent. With the rapid electrification of the transportation sector and an urgent need to overhaul electric grids in the context of renewable energy penetration, demands for concomitant high energy and high power batteries are continuously increasing. Although building an ideal battery requires effort from multiple scientific and engineering aspects, it is imperative to gain insight into multiscale transport behaviors arising in both spatial and temporal dimensions, and enable their harmonic integration inside the whole battery system. In this progress report, recent research efforts on characterizing and understanding transport kinetics in LIBs are reviewed covering a broad range of electrode materials and length scales. Further, to demonstrate the crucial role of such information in revolutionary electrode design, examples of innovative high energy/power electrodes are provided with their unique hierarchical porous architectures highlighted. To conclude, perspectives on further approaches toward advanced thick electrode designs with fast kinetics and tailored properties are discussed.},
doi = {10.1002/aenm.202000808},
journal = {Advanced Energy Materials},
number = 2,
volume = 11,
place = {United States},
year = {Wed May 06 00:00:00 EDT 2020},
month = {Wed May 06 00:00:00 EDT 2020}
}
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