High-Energy All-Solid-State Organic–Lithium Batteries Based on Ceramic Electrolytes

Hao, Fang; Liang, Yanliang; Zhang, Ye; Chen, Zhaoyang; Zhang, Jibo; Ai, Qing; Guo, Hua; Fan, Zheng; Lou, Jun; Yao, Yan

doi:10.1021/acsenergylett.0c02227

Title: High-Energy All-Solid-State Organic–Lithium Batteries Based on Ceramic Electrolytes

Journal Article · Thu Dec 17 04:00:00 UTC 2020 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.0c02227 · OSTI ID:1737467

^[1];

^[2]; Zhang, Ye ^[2]; Chen, Zhaoyang ^[2]; Zhang, Jibo ^[2]; Ai, Qing ^[3]; Guo, Hua ^[3]; Fan, Zheng ^[2];

^[3];

^[2]

Univ. of Houston, TX (United States); University of Houston
Univ. of Houston, TX (United States)
Rice Univ., Houston, TX (United States)

Recent studies have identified unique properties of organic battery electrode materials such as moderate redox potentials and mechanical softness which are uniquely beneficial for all-solid-state batteries based on ceramic electrolytes. Here, we further explore the promise of organic materials and demonstrate a sulfide electrolyte- based organic-lithium battery with a specific energy of 828 Wh kg^–1, rivaling the state-of- the-art of all-solid-state batteries. Two innovation steps are responsible for the accomplishment. First, the combination of lithium anode and the high-capacity cathode material pyrene-4,5,9,10-tetraone ensures a high theoretical specific energy. Second, the microstructure of the organic cathode is optimized with the introduction of cryomilling, a technique common to processing soft materials but not familiar to electrode fabrication. The cathode material utilization increases to 99.5% as a result, up from the 55–89% previously reported for ceramic electrolyte-based solid-state organic batteries. In conclusion, the improvement highlights the special requirements of solid-state organic electrodes for microstructural engineering while preserving the chemical integrity of components.

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Research Organization:: Univ. of Houston, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: EE0008234; EE0008864

OSTI ID:: 1737467

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Vol. 6; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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