Trends in the thermal stability of two-dimensional covalent organic frameworks

Evans, Austin M.; Ryder, Matthew R.; Ji, Woojung; Strauss, Michael J.; Corcos, Amanda R.; Vitaku, Edon; Flanders, Nathan C.; Bisbey, Ryan P.; Dichtel, William R.

doi:10.1039/D0FD00054J

Title: Trends in the thermal stability of two-dimensional covalent organic frameworks

Abstract

Here, we study the thermal stability of ten 2D covalent organic frameworks using a combination of variable-temperature X-ray diffraction, thermogravimetric analysis, diffuse reflectance infrared spectroscopy, and density-functional theory.

Authors:

^[1];

^[2];

^[1];

^[1]

Northwestern University, Department of Chemistry, Evanston, USA
Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, USA

Publication Date:: Thu Feb 04 00:00:00 EST 2021

Sponsoring Org.:: USDOE

OSTI Identifier:: 1716545

Grant/Contract Number:: AC02-05CH11231; AC0206CH11357

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Faraday Discussions

Additional Journal Information:: Journal Name: Faraday Discussions Journal Volume: 225; Journal ID: ISSN 1359-6640

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Evans, Austin M., Ryder, Matthew R., Ji, Woojung, Strauss, Michael J., Corcos, Amanda R., Vitaku, Edon, Flanders, Nathan C., Bisbey, Ryan P., and Dichtel, William R. Trends in the thermal stability of two-dimensional covalent organic frameworks.  United Kingdom: N. p., 2021. 
Web.  doi:10.1039/D0FD00054J.

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                    Evans, Austin M., Ryder, Matthew R., Ji, Woojung, Strauss, Michael J., Corcos, Amanda R., Vitaku, Edon, Flanders, Nathan C., Bisbey, Ryan P., & Dichtel, William R. Trends in the thermal stability of two-dimensional covalent organic frameworks.  United Kingdom.  https://doi.org/10.1039/D0FD00054J

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                    Evans, Austin M., Ryder, Matthew R., Ji, Woojung, Strauss, Michael J., Corcos, Amanda R., Vitaku, Edon, Flanders, Nathan C., Bisbey, Ryan P., and Dichtel, William R. Thu .  
"Trends in the thermal stability of two-dimensional covalent organic frameworks".  United Kingdom.  https://doi.org/10.1039/D0FD00054J.

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@article{osti_1716545,

  title        = {Trends in the thermal stability of two-dimensional covalent organic frameworks},

  author       = {Evans, Austin M. and Ryder, Matthew R. and Ji, Woojung and Strauss, Michael J. and Corcos, Amanda R. and Vitaku, Edon and Flanders, Nathan C. and Bisbey, Ryan P. and Dichtel, William R.},

  abstractNote = {Here, we study the thermal stability of ten 2D covalent organic frameworks using a combination of variable-temperature X-ray diffraction, thermogravimetric analysis, diffuse reflectance infrared spectroscopy, and density-functional theory.},

  doi          = {10.1039/D0FD00054J},

  journal      = {Faraday Discussions},

  number       = ,

  volume       = 225,

  place        = {United Kingdom},

  year         = {Thu Feb 04 00:00:00 EST 2021},

  month        = {Thu Feb 04 00:00:00 EST 2021}

}

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Title: Trends in the thermal stability of two-dimensional covalent organic frameworks

Abstract

Citation Formats

Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis journal, September 2016

Comprehensive Handbook of Chemical Bond Energies book, March 2007

Generalized Gradient Approximation Made Simple journal, October 1996

Synthesis of 2D Imine-Linked Covalent Organic Frameworks through Formal Transimination Reactions journal, September 2017

Imine-based covalent triazine framework: Synthesis, characterization, and evaluation its adsorption journal, March 2020

Two-Dimensional Covalent Organic Frameworks for Optoelectronics and Energy Storage journal, May 2017

Quasi‐Harmonic Lattice Dynamics of a Prototypical Metal–Organic Framework journal, July 2019

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework journal, April 2009

Improved synthesis of β-ketoenamine-linked covalent organic frameworks via monomer exchange reactions journal, January 2019

Polarization properties of ZnO and BeO: An ab initio study through the Berry phase and Wannier functions approaches journal, December 2001

Covalent organic frameworks for membrane separation journal, January 2019

Removal of GenX and Perfluorinated Alkyl Substances from Water by Amine-Functionalized Covalent Organic Frameworks journal, September 2018

Designed Synthesis of 3D Covalent Organic Frameworks journal, April 2007

Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework journal, June 2017

Humidity Sensing through Reversible Isomerization of a Covalent Organic Framework journal, December 2019

Switching on and off Interlayer Correlations and Porosity in 2D Covalent Organic Frameworks journal, June 2019

Chemical, thermal and mechanical stabilities of metal–organic frameworks journal, February 2016

Covalent organic frameworks journal, January 2012

Buckling of Two-Dimensional Covalent Organic Frameworks under Thermal Stress journal, May 2019

Nanoscrolls Formed from Two-Dimensional Covalent Organic Frameworks journal, April 2019

Microtubular Self-Assembly of Covalent Organic Frameworks journal, December 2017

A 2D Mesoporous Imine-Linked Covalent Organic Framework for High Pressure Gas Storage Applications journal, February 2013

2D sp2 Carbon-Conjugated Covalent Organic Frameworks for Photocatalytic Hydrogen Production from Water journal, June 2019

Porous, Crystalline, Covalent Organic Frameworks journal, November 2005

Real-time optical and electronic sensing with a β-amino enone linked, triazine-containing 2D covalent organic framework journal, July 2019

Emissive Single-Crystalline Boroxine-Linked Colloidal Covalent Organic Frameworks journal, November 2019

Bulk Synthesis of Exfoliated Two-Dimensional Polymers Using Hydrazone-Linked Covalent Organic Frameworks journal, September 2013

Two-dimensional polymers: concepts and perspectives journal, January 2016

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β-Ketoenamine-Linked Covalent Organic Frameworks Capable of Pseudocapacitive Energy Storage journal, October 2013

Acid Exfoliation of Imine‐linked Covalent Organic Frameworks Enables Solution Processing into Crystalline Thin Films journal, March 2020

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal, April 2010

Exceptional ammonia uptake by a covalent organic framework journal, February 2010

Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting journal, December 2017

Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis
journal, September 2016

Comprehensive Handbook of Chemical Bond Energies
book, March 2007

Generalized Gradient Approximation Made Simple
journal, October 1996

Synthesis of 2D Imine-Linked Covalent Organic Frameworks through Formal Transimination Reactions
journal, September 2017

Imine-based covalent triazine framework: Synthesis, characterization, and evaluation its adsorption
journal, March 2020

Two-Dimensional Covalent Organic Frameworks for Optoelectronics and Energy Storage
journal, May 2017

Quasi‐Harmonic Lattice Dynamics of a Prototypical Metal–Organic Framework
journal, July 2019

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009

Improved synthesis of β-ketoenamine-linked covalent organic frameworks via monomer exchange reactions
journal, January 2019

Polarization properties of ZnO and BeO: An ab initio study through the Berry phase and Wannier functions approaches
journal, December 2001

Covalent organic frameworks for membrane separation
journal, January 2019

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journal, September 2018

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007

Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework
journal, June 2017

Humidity Sensing through Reversible Isomerization of a Covalent Organic Framework
journal, December 2019

Switching on and off Interlayer Correlations and Porosity in 2D Covalent Organic Frameworks
journal, June 2019

Chemical, thermal and mechanical stabilities of metal–organic frameworks
journal, February 2016

Covalent organic frameworks
journal, January 2012

Buckling of Two-Dimensional Covalent Organic Frameworks under Thermal Stress
journal, May 2019

Nanoscrolls Formed from Two-Dimensional Covalent Organic Frameworks
journal, April 2019

Microtubular Self-Assembly of Covalent Organic Frameworks
journal, December 2017

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journal, February 2013

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journal, November 2005

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journal, July 2019

Emissive Single-Crystalline Boroxine-Linked Colloidal Covalent Organic Frameworks
journal, November 2019

Bulk Synthesis of Exfoliated Two-Dimensional Polymers Using Hydrazone-Linked Covalent Organic Frameworks
journal, September 2013

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journal, January 2016

Covalent Organic Framework–Covalent Organic Framework Bilayer Membranes for Highly Selective Gas Separation
journal, July 2018

Reducing the Pore Size of Covalent Organic Frameworks in Thin-Film Composite Membranes Enhances Solute Rejection
journal, August 2019

A new look at the collapse of two-dimensional polymers
journal, September 2015

Pore surface engineering in covalent organic frameworks
journal, September 2011

Enhanced Structural Organization in Covalent Organic Frameworks Through Fluorination
journal, March 2017

Chiral BINOL-Based Covalent Organic Frameworks for Enantioselective Sensing
journal, April 2019

β-Ketoenamine-Linked Covalent Organic Frameworks Capable of Pseudocapacitive Energy Storage
journal, October 2013

Acid Exfoliation of Imine‐linked Covalent Organic Frameworks Enables Solution Processing into Crystalline Thin Films
journal, March 2020

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

Exceptional ammonia uptake by a covalent organic framework
journal, February 2010

Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting
journal, December 2017