Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency
Abstract
The selenium substitution strategy was applied to develop two new A′-DAD-A′-type small molecular acceptors. The resulting selenium-incorporated molecules exhibit red-shifted absorption and an enhanced photon response, leading to high device efficiencies of over 16%.
- Authors:
-
- Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology, Kowloon, Hong Kong
- Department of Physics, Organic and Carbon Electronics Laboratories (ORaCEL), North Carolina State University, Raleigh, USA
- The Institute for Advanced Studies, Wuhan University, Wuhan 430072, China
- Hong Kong University of Science and Technology, Shenzhen Research Institute, Shenzhen 518057, China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1708954
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 45; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Yu, Han, Qi, Zhenyu, Zhang, Jianquan, Wang, Zhen, Sun, Rui, Chang, Yuan, Sun, Huiliang, Zhou, Wentao, Min, Jie, Ade, Harald, and Yan, He. Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency. United Kingdom: N. p., 2020.
Web. doi:10.1039/D0TA06658C.
Yu, Han, Qi, Zhenyu, Zhang, Jianquan, Wang, Zhen, Sun, Rui, Chang, Yuan, Sun, Huiliang, Zhou, Wentao, Min, Jie, Ade, Harald, & Yan, He. Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency. United Kingdom. https://doi.org/10.1039/D0TA06658C
Yu, Han, Qi, Zhenyu, Zhang, Jianquan, Wang, Zhen, Sun, Rui, Chang, Yuan, Sun, Huiliang, Zhou, Wentao, Min, Jie, Ade, Harald, and Yan, He. Tue .
"Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency". United Kingdom. https://doi.org/10.1039/D0TA06658C.
@article{osti_1708954,
title = {Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency},
author = {Yu, Han and Qi, Zhenyu and Zhang, Jianquan and Wang, Zhen and Sun, Rui and Chang, Yuan and Sun, Huiliang and Zhou, Wentao and Min, Jie and Ade, Harald and Yan, He},
abstractNote = {The selenium substitution strategy was applied to develop two new A′-DAD-A′-type small molecular acceptors. The resulting selenium-incorporated molecules exhibit red-shifted absorption and an enhanced photon response, leading to high device efficiencies of over 16%.},
doi = {10.1039/D0TA06658C},
journal = {Journal of Materials Chemistry. A},
number = 45,
volume = 8,
place = {United Kingdom},
year = {Tue Nov 24 00:00:00 EST 2020},
month = {Tue Nov 24 00:00:00 EST 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0TA06658C
https://doi.org/10.1039/D0TA06658C
Other availability
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Naphthalene Diimide-Based Terpolymers with Controlled Crystalline Properties for Producing High Electron Mobility and Optimal Blend Morphology in All-Polymer Solar Cells
journal, March 2020
- Lee, Jin-Woo; Sung, Min Jae; Kim, Donguk
- Chemistry of Materials, Vol. 32, Issue 6
Understanding the High Performance of over 15% Efficiency in Single‐Junction Bulk Heterojunction Organic Solar Cells
journal, October 2019
- Karki, Akchheta; Vollbrecht, Joachim; Dixon, Alana L.
- Advanced Materials, Vol. 31, Issue 48
Phthalimide Polymer Donor Guests Enable over 17% Efficient Organic Solar Cells via Parallel‐Like Ternary and Quaternary Strategies
journal, July 2020
- Zhang, Weichao; Huang, Jianhua; Xu, Jianqiu
- Advanced Energy Materials, Vol. 10, Issue 32
Over 14.5% efficiency and 71.6% fill factor of ternary organic solar cells with 300 nm thick active layers
journal, January 2020
- Gao, Jinhua; Gao, Wei; Ma, Xiaoling
- Energy & Environmental Science, Vol. 13, Issue 3
Benzo[1,2- b :4,5- b ′]diselenophene-fused nonfullerene acceptors with alternative aromatic ring-based and monochlorinated end groups: a new synergistic strategy to simultaneously achieve highly efficient organic solar cells with the energy loss of 0.49 eV
journal, January 2019
- Wan, Shi-Sheng; Xu, Xiaopeng; Wang, Jin-Liang
- Journal of Materials Chemistry A, Vol. 7, Issue 19
Ternary Organic Solar Cells with Efficiency >16.5% Based on Two Compatible Nonfullerene Acceptors
journal, November 2019
- Song, Jiali; Li, Chao; Zhu, Lei
- Advanced Materials, Vol. 31, Issue 52
Non-fullerene polymer solar cells based on a selenophene-containing fused-ring acceptor with photovoltaic performance of 8.6%
journal, January 2016
- Li, Yongxi; Zhong, Lian; Wu, Fu-Peng
- Energy & Environmental Science, Vol. 9, Issue 11
Regio-Specific Selenium Substitution in Non-Fullerene Acceptors for Efficient Organic Solar Cells
journal, December 2018
- Lin, Francis; Zuo, Lijian; Gao, Ke
- Chemistry of Materials, Vol. 31, Issue 17
Bromination: An Alternative Strategy for Non‐Fullerene Small Molecule Acceptors
journal, February 2020
- Wang, Huan; Liu, Tao; Zhou, Jiadong
- Advanced Science, Vol. 7, Issue 9
The new era for organic solar cells: polymer acceptors
journal, September 2020
- Duan, Chunhui; Ding, Liming
- Science Bulletin, Vol. 65, Issue 18
Solution‐Processed Polymer Solar Cells with over 17% Efficiency Enabled by an Iridium Complexation Approach
journal, April 2020
- Wang, Tao; Sun, Rui; Shi, Mumin
- Advanced Energy Materials, Vol. 10, Issue 22
Asymmetric Acceptors with Fluorine and Chlorine Substitution for Organic Solar Cells toward 16.83% Efficiency
journal, April 2020
- Liu, Tao; Zhang, Youdi; Shao, Yiming
- Advanced Functional Materials, Vol. 30, Issue 24
High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor
journal, June 2016
- Holliday, Sarah; Ashraf, Raja Shahid; Wadsworth, Andrew
- Nature Communications, Vol. 7, Issue 1
Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis
journal, April 2012
- Gann, E.; Young, A. T.; Collins, B. A.
- Review of Scientific Instruments, Vol. 83, Issue 4
18% Efficiency organic solar cells
journal, February 2020
- Liu, Qishi; Jiang, Yufan; Jin, Ke
- Science Bulletin, Vol. 65, Issue 4
Enabling low voltage losses and high photocurrent in fullerene-free organic photovoltaics
journal, February 2019
- Yuan, Jun; Huang, Tianyi; Cheng, Pei
- Nature Communications, Vol. 10, Issue 1
Selenopheno[3,2- b ]thiophene-Based Narrow-Bandgap Nonfullerene Acceptor Enabling 13.3% Efficiency for Organic Solar Cells with Thickness-Insensitive Feature
journal, November 2018
- Wang, Jin-Liang; Liu, Kai-Kai; Hong, Ling
- ACS Energy Letters, Vol. 3, Issue 12
Dithienopicenocarbazole-Based Acceptors for Efficient Organic Solar Cells with Optoelectronic Response Over 1000 nm and an Extremely Low Energy Loss
journal, February 2018
- Yao, Zhaoyang; Liao, Xunfan; Gao, Ke
- Journal of the American Chemical Society, Vol. 140, Issue 6
A Narrow‐Bandgap n‐Type Polymer with an Acceptor–Acceptor Backbone Enabling Efficient All‐Polymer Solar Cells
journal, September 2020
- Sun, Huiliang; Yu, Han; Shi, Yongqiang
- Advanced Materials, Vol. 32, Issue 43
An Electron Acceptor Challenging Fullerenes for Efficient Polymer Solar Cells
journal, January 2015
- Lin, Yuze; Wang, Jiayu; Zhang, Zhi-Guo
- Advanced Materials, Vol. 27, Issue 7
Subtle Molecular Tailoring Induces Significant Morphology Optimization Enabling over 16% Efficiency Organic Solar Cells with Efficient Charge Generation
journal, December 2019
- Zhou, Zichun; Liu, Wenrui; Zhou, Guanqing
- Advanced Materials, Vol. 32, Issue 4
Highly Efficient Organic Solar Cells Based on S,N-Heteroacene Non-Fullerene Acceptors
journal, July 2018
- Huang, Chuyi; Liao, Xunfan; Gao, Ke
- Chemistry of Materials, Vol. 30, Issue 15
Fused Tris(thienothiophene)-Based Electron Acceptor with Strong Near-Infrared Absorption for High-Performance As-Cast Solar Cells
journal, January 2018
- Li, Tengfei; Dai, Shuixing; Ke, Zhifan
- Advanced Materials, Vol. 30, Issue 10
Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
journal, January 2014
- Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei
- Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440
Material insights and challenges for non-fullerene organic solar cells based on small molecular acceptors
journal, July 2018
- Zhang, Jianquan; Tan, Huei Shuan; Guo, Xugang
- Nature Energy, Vol. 3, Issue 9
8.78% Efficient All‐Polymer Solar Cells Enabled by Polymer Acceptors Based on a B←N Embedded Electron‐Deficient Unit
journal, September 2019
- Li, Yongchun; Meng, Huifeng; Liu, Tao
- Advanced Materials, Vol. 31, Issue 44
Over 16.7% efficiency of ternary organic photovoltaics by employing extra PC71BM as morphology regulator
journal, November 2019
- Gao, Jinhua; Wang, Jian; An, Qiaoshi
- Science China Chemistry, Vol. 63, Issue 1
Modulating Energy Level on an A‐D‐A′‐D‐A‐Type Unfused Acceptor by a Benzothiadiazole Core Enables Organic Solar Cells with Simple Procedure and High Performance
journal, August 2020
- Yu, Han; Qi, Zhenyu; Li, Xingye
- Solar RRL, Vol. 4, Issue 11
Achieving high-performance non-halogenated nonfullerene acceptor-based organic solar cells with 13.7% efficiency via a synergistic strategy of an indacenodithieno[3,2- b ]selenophene core unit and non-halogenated thiophene-based terminal group
journal, January 2019
- Liu, Kai-Kai; Xu, Xiaopeng; Wang, Jin-Liang
- Journal of Materials Chemistry A, Vol. 7, Issue 42
Quantitative relations between interaction parameter, miscibility and function in organic solar cells
journal, February 2018
- Ye, Long; Hu, Huawei; Ghasemi, Masoud
- Nature Materials, Vol. 17, Issue 3
26 mA cm−2 Jsc from organic solar cells with a low-bandgap nonfullerene acceptor
journal, November 2017
- Xiao, Zuo; Jia, Xue; Li, Dan
- Science Bulletin, Vol. 62, Issue 22
Constructing a Strongly Absorbing Low-Bandgap Polymer Acceptor for High-Performance All-Polymer Solar Cells
journal, September 2017
- Zhang, Zhi-Guo; Yang, Yankang; Yao, Jia
- Angewandte Chemie International Edition, Vol. 56, Issue 43
Dithieno[3,2- b :2′,3′- d ]pyrrol Fused Nonfullerene Acceptors Enabling Over 13% Efficiency for Organic Solar Cells
journal, March 2018
- Sun, Jia; Ma, Xiaoling; Zhang, Zhuohan
- Advanced Materials, Vol. 30, Issue 16
Fine-Tuning Energy Levels via Asymmetric End Groups Enables Polymer Solar Cells with Efficiencies over 17%
journal, June 2020
- Luo, Zhenghui; Ma, Ruijie; Liu, Tao
- Joule, Vol. 4, Issue 6
Asymmetric selenophene-based non-fullerene acceptors for high-performance organic solar cells
journal, January 2019
- Li, Chao; Xia, Tian; Song, Jiali
- Journal of Materials Chemistry A, Vol. 7, Issue 4
New Phase for Organic Solar Cell Research: Emergence of Y-Series Electron Acceptors and Their Perspectives
journal, April 2020
- Li, Shuixing; Li, Chang-Zhi; Shi, Minmin
- ACS Energy Letters, Vol. 5, Issue 5
Highly efficient near-infrared and semitransparent polymer solar cells based on an ultra-narrow bandgap nonfullerene acceptor
journal, January 2019
- Chen, Juan; Li, Guangda; Zhu, Qinglian
- Journal of Materials Chemistry A, Vol. 7, Issue 8
Graphdiyne Derivative as Multifunctional Solid Additive in Binary Organic Solar Cells with 17.3% Efficiency and High Reproductivity
journal, February 2020
- Liu, Le; Kan, Yuanyuan; Gao, Ke
- Advanced Materials, Vol. 32, Issue 11
Non-fullerene acceptors for organic solar cells
journal, February 2018
- Yan, Cenqi; Barlow, Stephen; Wang, Zhaohui
- Nature Reviews Materials, Vol. 3, Issue 3
Simultaneous enhanced efficiency and thermal stability in organic solar cells from a polymer acceptor additive
journal, March 2020
- Yang, Wenyan; Luo, Zhenghui; Sun, Rui
- Nature Communications, Vol. 11, Issue 1
Rational Tuning of Molecular Interaction and Energy Level Alignment Enables High‐Performance Organic Photovoltaics
journal, September 2019
- Wang, Rui; Yuan, Jun; Wang, Rui
- Advanced Materials, Vol. 31, Issue 43
A 16.4% efficiency organic photovoltaic cell enabled using two donor polymers with their side-chains oriented differently by a ternary strategy
journal, January 2020
- Chang, Yuan; Lau, Tsz-Ki; Chow, Philip C. Y.
- Journal of Materials Chemistry A, Vol. 8, Issue 7
Noncovalently fused-ring electron acceptors with near-infrared absorption for high-performance organic solar cells
journal, July 2019
- Huang, Hao; Guo, Qingxin; Feng, Shiyu
- Nature Communications, Vol. 10, Issue 1
Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells
journal, May 2017
- Zhao, Wenchao; Li, Sunsun; Yao, Huifeng
- Journal of the American Chemical Society, Vol. 139, Issue 21
Design rules for minimizing voltage losses in high-efficiency organic solar cells
journal, July 2018
- Qian, Deping; Zheng, Zilong; Yao, Huifeng
- Nature Materials, Vol. 17, Issue 8
High Efficiency Near-Infrared and Semitransparent Non-Fullerene Acceptor Organic Photovoltaic Cells
journal, November 2017
- Li, Yongxi; Lin, Jiu-Dong; Che, Xiaozhou
- Journal of the American Chemical Society, Vol. 139, Issue 47
High Efficiency Polymer Solar Cells with Efficient Hole Transfer at Zero Highest Occupied Molecular Orbital Offset between Methylated Polymer Donor and Brominated Acceptor
journal, January 2020
- Sun, Chenkai; Qin, Shucheng; Wang, Rui
- Journal of the American Chemical Society, Vol. 142, Issue 3
Capacitance Spectroscopy for Quantifying Recombination Losses in Nonfullerene Small-Molecule Bulk Heterojunction Solar Cells
journal, March 2016
- Brus, Viktor V.; Proctor, Christopher M.; Ran, Niva A.
- Advanced Energy Materials, Vol. 6, Issue 11
Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core
journal, April 2019
- Yuan, Jun; Zhang, Yunqiang; Zhou, Liuyang
- Joule, Vol. 3, Issue 4
Critical review of the molecular design progress in non-fullerene electron acceptors towards commercially viable organic solar cells
journal, January 2019
- Wadsworth, Andrew; Moser, Maximilian; Marks, Adam
- Chemical Society Reviews, Vol. 48, Issue 6
Organic solar cells based on non-fullerene acceptors
journal, January 2018
- Hou, Jianhui; Inganäs, Olle; Friend, Richard H.
- Nature Materials, Vol. 17, Issue 2
Effect of Replacing Thiophene by Selenophene on the Photovoltaic Performance of Wide Bandgap Copolymer Donors
journal, June 2019
- Zhong, Lian; Bin, Haijun; Angunawela, Indunil
- Macromolecules, Vol. 52, Issue 12
A Selenophene Analogue of PCDTBT: Selective Fine-Tuning of LUMO to Lower of the Bandgap for Efficient Polymer Solar Cells
journal, October 2012
- Kim, Boram; Yeom, Hye Rim; Yun, Myoung Hee
- Macromolecules, Vol. 45, Issue 21
Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in PTB7:PC 71 BM Solar Cells
journal, October 2012
- Collins, Brian A.; Li, Zhe; Tumbleston, John R.
- Advanced Energy Materials, Vol. 3, Issue 1
Achieving 17.4% Efficiency of Ternary Organic Photovoltaics with Two Well‐Compatible Nonfullerene Acceptors for Minimizing Energy Loss
journal, June 2020
- Ma, Xiaoling; Wang, Jian; Gao, Jinhua
- Advanced Energy Materials
Nonfullerene Acceptor Molecules for Bulk Heterojunction Organic Solar Cells
journal, February 2018
- Zhang, Guangye; Zhao, Jingbo; Chow, Philip C. Y.
- Chemical Reviews, Vol. 118, Issue 7
Subtle Polymer Donor and Molecular Acceptor Design Enable Efficient Polymer Solar Cells with a Very Small Energy Loss
journal, December 2019
- Xu, Xiaopeng; Feng, Kui; Lee, Young Woong
- Advanced Functional Materials, Vol. 30, Issue 9
Exploiting Ternary Blends for Improved Photostability in High-Efficiency Organic Solar Cells
journal, March 2020
- Gasparini, Nicola; Paleti, Sri Harish Kumar; Bertrandie, Jules
- ACS Energy Letters, Vol. 5, Issue 5
Trifluoromethylation Enables a 3D Interpenetrated Low-Band-Gap Acceptor for Efficient Organic Solar Cells
journal, March 2020
- Lai, Hanjian; Zhao, Qiaoqiao; Chen, Ziyi
- Joule, Vol. 4, Issue 3
All‐Polymer Solar Cells with over 12% Efficiency and a Small Voltage Loss Enabled by a Polymer Acceptor Based on an Extended Fused Ring Core
journal, July 2020
- Yao, Huatong; Ma, Lik‐Kuen; Yu, Han
- Advanced Energy Materials, Vol. 10, Issue 35
Concurrent improvement in J SC and V OC in high-efficiency ternary organic solar cells enabled by a red-absorbing small-molecule acceptor with a high LUMO level
journal, January 2020
- Liu, Tao; Ma, Ruijie; Luo, Zhenghui
- Energy & Environmental Science, Vol. 13, Issue 7
Near-infrared absorbing non-fullerene acceptors with selenophene as π bridges for efficient organic solar cells
journal, January 2018
- Liang, Ziqi; Li, Miaomiao; Zhang, Xiaomei
- Journal of Materials Chemistry A, Vol. 6, Issue 17
Improved organic solar cell efficiency based on the regulation of an alkyl chain on chlorinated non-fullerene acceptors
journal, January 2020
- Yu, Han; Ma, Ruijie; Xiao, Yiqun
- Materials Chemistry Frontiers, Vol. 4, Issue 8
A bromine and chlorine concurrently functionalized end group for benzo[1,2- b :4,5- b ′]diselenophene-based non-fluorinated acceptors: a new hybrid strategy to balance the crystallinity and miscibility of blend films for enabling highly efficient polymer solar cells
journal, January 2020
- Wan, Shi-Sheng; Xu, Xiaopeng; Jiang, Zhao
- Journal of Materials Chemistry A, Vol. 8, Issue 9
Fused selenophene-thieno[3,2- b ]thiophene–selenophene (ST)-based narrow-bandgap electron acceptor for efficient organic solar cells with small voltage loss
journal, January 2019
- Liao, Xunfan; Shi, Xueliang; Zhang, Ming
- Chemical Communications, Vol. 55, Issue 57
Over 17% efficiency ternary organic solar cells enabled by two non-fullerene acceptors working in an alloy-like model
journal, January 2020
- Zhan, Lingling; Li, Shuixing; Lau, Tsz-Ki
- Energy & Environmental Science, Vol. 13, Issue 2
Semitransparent polymer solar cells with 12.37% efficiency and 18.6% average visible transmittance
journal, January 2020
- Hu, Zhenghao; Wang, Zhi; An, Qiaoshi
- Science Bulletin, Vol. 65, Issue 2
Next-generation organic photovoltaics based on non-fullerene acceptors
journal, February 2018
- Cheng, Pei; Li, Gang; Zhan, Xiaowei
- Nature Photonics, Vol. 12, Issue 3
Synthesis of a 4,9-Didodecyl Angular-Shaped Naphthodiselenophene Building Block To Achieve High-Mobility Transistors
journal, July 2016
- Tsai, Che-En; Yu, Ruo-Han; Lin, Fang-Ju
- Chemistry of Materials, Vol. 28, Issue 14
Small-Molecule Acceptor Based on the Heptacyclic Benzodi(cyclopentadithiophene) Unit for Highly Efficient Nonfullerene Organic Solar Cells
journal, March 2017
- Kan, Bin; Feng, Huanran; Wan, Xiangjian
- Journal of the American Chemical Society, Vol. 139, Issue 13
Mixed selenium-sulfur fused ring systems as building blocks for novel polymers used in field effect transistors
journal, January 2011
- Mishra, Sarada P.; Javier, Anna E.; Zhang, Rui
- J. Mater. Chem., Vol. 21, Issue 5
Progress of the key materials for organic solar cells
journal, April 2020
- Tong, Yang; Xiao, Zuo; Du, Xiaoyan
- Science China Chemistry, Vol. 63, Issue 6
Delayed Fluorescence Emitter Enables Near 17% Efficiency Ternary Organic Solar Cells with Enhanced Storage Stability and Reduced Recombination Energy Loss
journal, February 2020
- Du, Xiaoyang; Yuan, Yi; Zhou, Lei
- Advanced Functional Materials, Vol. 30, Issue 15
Mechanically Robust All-Polymer Solar Cells from Narrow Band Gap Acceptors with Hetero-Bridging Atoms
journal, March 2020
- Fan, Qunping; Su, Wenyan; Chen, Shanshan
- Joule, Vol. 4, Issue 3
14.4% efficiency all-polymer solar cell with broad absorption and low energy loss enabled by a novel polymer acceptor
journal, June 2020
- Jia, Tao; Zhang, Jiabin; Zhong, Wenkai
- Nano Energy, Vol. 72
Transannularly conjugated tetrameric perylene diimide acceptors containing [2.2]paracyclophane for non-fullerene organic solar cells
journal, January 2020
- Yu, Han; Arunagiri, Lingeswaran; Zhang, Lin
- Journal of Materials Chemistry A, Vol. 8, Issue 14
Asymmetric Electron Acceptors for High‐Efficiency and Low‐Energy‐Loss Organic Photovoltaics
journal, May 2020
- Li, Shuixing; Zhan, Lingling; Jin, Yingzhi
- Advanced Materials, Vol. 32, Issue 24