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Title: Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency

Abstract

The selenium substitution strategy was applied to develop two new A′-DAD-A′-type small molecular acceptors. The resulting selenium-incorporated molecules exhibit red-shifted absorption and an enhanced photon response, leading to high device efficiencies of over 16%.

Authors:
 [1];  [1];  [1];  [2];  [3];  [1];  [4];  [1]; ORCiD logo [3];  [2]; ORCiD logo [1]
  1. Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Hong Kong University of Science and Technology, Kowloon, Hong Kong
  2. Department of Physics, Organic and Carbon Electronics Laboratories (ORaCEL), North Carolina State University, Raleigh, USA
  3. The Institute for Advanced Studies, Wuhan University, Wuhan 430072, China
  4. Hong Kong University of Science and Technology, Shenzhen Research Institute, Shenzhen 518057, China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1708954
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 45; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Yu, Han, Qi, Zhenyu, Zhang, Jianquan, Wang, Zhen, Sun, Rui, Chang, Yuan, Sun, Huiliang, Zhou, Wentao, Min, Jie, Ade, Harald, and Yan, He. Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency. United Kingdom: N. p., 2020. Web. https://doi.org/10.1039/D0TA06658C.
Yu, Han, Qi, Zhenyu, Zhang, Jianquan, Wang, Zhen, Sun, Rui, Chang, Yuan, Sun, Huiliang, Zhou, Wentao, Min, Jie, Ade, Harald, & Yan, He. Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency. United Kingdom. https://doi.org/10.1039/D0TA06658C
Yu, Han, Qi, Zhenyu, Zhang, Jianquan, Wang, Zhen, Sun, Rui, Chang, Yuan, Sun, Huiliang, Zhou, Wentao, Min, Jie, Ade, Harald, and Yan, He. Tue . "Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency". United Kingdom. https://doi.org/10.1039/D0TA06658C.
@article{osti_1708954,
title = {Tailoring non-fullerene acceptors using selenium-incorporated heterocycles for organic solar cells with over 16% efficiency},
author = {Yu, Han and Qi, Zhenyu and Zhang, Jianquan and Wang, Zhen and Sun, Rui and Chang, Yuan and Sun, Huiliang and Zhou, Wentao and Min, Jie and Ade, Harald and Yan, He},
abstractNote = {The selenium substitution strategy was applied to develop two new A′-DAD-A′-type small molecular acceptors. The resulting selenium-incorporated molecules exhibit red-shifted absorption and an enhanced photon response, leading to high device efficiencies of over 16%.},
doi = {10.1039/D0TA06658C},
journal = {Journal of Materials Chemistry. A},
number = 45,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0TA06658C

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Works referenced in this record:

Understanding the High Performance of over 15% Efficiency in Single‐Junction Bulk Heterojunction Organic Solar Cells
journal, October 2019

  • Karki, Akchheta; Vollbrecht, Joachim; Dixon, Alana L.
  • Advanced Materials, Vol. 31, Issue 48
  • DOI: 10.1002/adma.201903868

Phthalimide Polymer Donor Guests Enable over 17% Efficient Organic Solar Cells via Parallel‐Like Ternary and Quaternary Strategies
journal, July 2020

  • Zhang, Weichao; Huang, Jianhua; Xu, Jianqiu
  • Advanced Energy Materials, Vol. 10, Issue 32
  • DOI: 10.1002/aenm.202001436

Over 14.5% efficiency and 71.6% fill factor of ternary organic solar cells with 300 nm thick active layers
journal, January 2020

  • Gao, Jinhua; Gao, Wei; Ma, Xiaoling
  • Energy & Environmental Science, Vol. 13, Issue 3
  • DOI: 10.1039/C9EE04020J

Ternary Organic Solar Cells with Efficiency >16.5% Based on Two Compatible Nonfullerene Acceptors
journal, November 2019


Non-fullerene polymer solar cells based on a selenophene-containing fused-ring acceptor with photovoltaic performance of 8.6%
journal, January 2016

  • Li, Yongxi; Zhong, Lian; Wu, Fu-Peng
  • Energy & Environmental Science, Vol. 9, Issue 11
  • DOI: 10.1039/C6EE00315J

Regio-Specific Selenium Substitution in Non-Fullerene Acceptors for Efficient Organic Solar Cells
journal, December 2018


Bromination: An Alternative Strategy for Non‐Fullerene Small Molecule Acceptors
journal, February 2020


The new era for organic solar cells: polymer acceptors
journal, September 2020


Solution‐Processed Polymer Solar Cells with over 17% Efficiency Enabled by an Iridium Complexation Approach
journal, April 2020


Asymmetric Acceptors with Fluorine and Chlorine Substitution for Organic Solar Cells toward 16.83% Efficiency
journal, April 2020

  • Liu, Tao; Zhang, Youdi; Shao, Yiming
  • Advanced Functional Materials, Vol. 30, Issue 24
  • DOI: 10.1002/adfm.202000456

High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor
journal, June 2016

  • Holliday, Sarah; Ashraf, Raja Shahid; Wadsworth, Andrew
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11585

Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis
journal, April 2012

  • Gann, E.; Young, A. T.; Collins, B. A.
  • Review of Scientific Instruments, Vol. 83, Issue 4
  • DOI: 10.1063/1.3701831

18% Efficiency organic solar cells
journal, February 2020


Enabling low voltage losses and high photocurrent in fullerene-free organic photovoltaics
journal, February 2019


Dithienopicenocarbazole-Based Acceptors for Efficient Organic Solar Cells with Optoelectronic Response Over 1000 nm and an Extremely Low Energy Loss
journal, February 2018

  • Yao, Zhaoyang; Liao, Xunfan; Gao, Ke
  • Journal of the American Chemical Society, Vol. 140, Issue 6
  • DOI: 10.1021/jacs.7b13239

A Narrow‐Bandgap n‐Type Polymer with an Acceptor–Acceptor Backbone Enabling Efficient All‐Polymer Solar Cells
journal, September 2020


An Electron Acceptor Challenging Fullerenes for Efficient Polymer Solar Cells
journal, January 2015


Highly Efficient Organic Solar Cells Based on S,N-Heteroacene Non-Fullerene Acceptors
journal, July 2018


Fused Tris(thienothiophene)-Based Electron Acceptor with Strong Near-Infrared Absorption for High-Performance As-Cast Solar Cells
journal, January 2018


Ammonia Capture in Porous Organic Polymers Densely Functionalized with Brønsted Acid Groups
journal, January 2014

  • Van Humbeck, Jeffrey F.; McDonald, Thomas M.; Jing, Xiaofei
  • Journal of the American Chemical Society, Vol. 136, Issue 6, p. 2432-2440
  • DOI: 10.1021/ja4105478

Material insights and challenges for non-fullerene organic solar cells based on small molecular acceptors
journal, July 2018


8.78% Efficient All‐Polymer Solar Cells Enabled by Polymer Acceptors Based on a B←N Embedded Electron‐Deficient Unit
journal, September 2019


Over 16.7% efficiency of ternary organic photovoltaics by employing extra PC71BM as morphology regulator
journal, November 2019


Quantitative relations between interaction parameter, miscibility and function in organic solar cells
journal, February 2018


26 mA cm−2 Jsc from organic solar cells with a low-bandgap nonfullerene acceptor
journal, November 2017


Constructing a Strongly Absorbing Low-Bandgap Polymer Acceptor for High-Performance All-Polymer Solar Cells
journal, September 2017

  • Zhang, Zhi-Guo; Yang, Yankang; Yao, Jia
  • Angewandte Chemie International Edition, Vol. 56, Issue 43
  • DOI: 10.1002/anie.201707678

Dithieno[3,2- b :2′,3′- d ]pyrrol Fused Nonfullerene Acceptors Enabling Over 13% Efficiency for Organic Solar Cells
journal, March 2018


Asymmetric selenophene-based non-fullerene acceptors for high-performance organic solar cells
journal, January 2019

  • Li, Chao; Xia, Tian; Song, Jiali
  • Journal of Materials Chemistry A, Vol. 7, Issue 4
  • DOI: 10.1039/C8TA11197A

New Phase for Organic Solar Cell Research: Emergence of Y-Series Electron Acceptors and Their Perspectives
journal, April 2020


Highly efficient near-infrared and semitransparent polymer solar cells based on an ultra-narrow bandgap nonfullerene acceptor
journal, January 2019

  • Chen, Juan; Li, Guangda; Zhu, Qinglian
  • Journal of Materials Chemistry A, Vol. 7, Issue 8
  • DOI: 10.1039/C8TA11484F

Graphdiyne Derivative as Multifunctional Solid Additive in Binary Organic Solar Cells with 17.3% Efficiency and High Reproductivity
journal, February 2020


Non-fullerene acceptors for organic solar cells
journal, February 2018


Simultaneous enhanced efficiency and thermal stability in organic solar cells from a polymer acceptor additive
journal, March 2020


Rational Tuning of Molecular Interaction and Energy Level Alignment Enables High‐Performance Organic Photovoltaics
journal, September 2019


A 16.4% efficiency organic photovoltaic cell enabled using two donor polymers with their side-chains oriented differently by a ternary strategy
journal, January 2020

  • Chang, Yuan; Lau, Tsz-Ki; Chow, Philip C. Y.
  • Journal of Materials Chemistry A, Vol. 8, Issue 7
  • DOI: 10.1039/C9TA13293G

Noncovalently fused-ring electron acceptors with near-infrared absorption for high-performance organic solar cells
journal, July 2019


Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells
journal, May 2017

  • Zhao, Wenchao; Li, Sunsun; Yao, Huifeng
  • Journal of the American Chemical Society, Vol. 139, Issue 21
  • DOI: 10.1021/jacs.7b02677

Design rules for minimizing voltage losses in high-efficiency organic solar cells
journal, July 2018


High Efficiency Near-Infrared and Semitransparent Non-Fullerene Acceptor Organic Photovoltaic Cells
journal, November 2017

  • Li, Yongxi; Lin, Jiu-Dong; Che, Xiaozhou
  • Journal of the American Chemical Society, Vol. 139, Issue 47
  • DOI: 10.1021/jacs.7b11278

High Efficiency Polymer Solar Cells with Efficient Hole Transfer at Zero Highest Occupied Molecular Orbital Offset between Methylated Polymer Donor and Brominated Acceptor
journal, January 2020

  • Sun, Chenkai; Qin, Shucheng; Wang, Rui
  • Journal of the American Chemical Society, Vol. 142, Issue 3
  • DOI: 10.1021/jacs.9b09939

Capacitance Spectroscopy for Quantifying Recombination Losses in Nonfullerene Small-Molecule Bulk Heterojunction Solar Cells
journal, March 2016

  • Brus, Viktor V.; Proctor, Christopher M.; Ran, Niva A.
  • Advanced Energy Materials, Vol. 6, Issue 11
  • DOI: 10.1002/aenm.201502250

Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core
journal, April 2019


Critical review of the molecular design progress in non-fullerene electron acceptors towards commercially viable organic solar cells
journal, January 2019

  • Wadsworth, Andrew; Moser, Maximilian; Marks, Adam
  • Chemical Society Reviews, Vol. 48, Issue 6
  • DOI: 10.1039/C7CS00892A

Organic solar cells based on non-fullerene acceptors
journal, January 2018

  • Hou, Jianhui; Inganäs, Olle; Friend, Richard H.
  • Nature Materials, Vol. 17, Issue 2
  • DOI: 10.1038/nmat5063

Effect of Replacing Thiophene by Selenophene on the Photovoltaic Performance of Wide Bandgap Copolymer Donors
journal, June 2019


A Selenophene Analogue of PCDTBT: Selective Fine-Tuning of LUMO to Lower of the Bandgap for Efficient Polymer Solar Cells
journal, October 2012

  • Kim, Boram; Yeom, Hye Rim; Yun, Myoung Hee
  • Macromolecules, Vol. 45, Issue 21
  • DOI: 10.1021/ma302133h

Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in PTB7:PC 71 BM Solar Cells
journal, October 2012

  • Collins, Brian A.; Li, Zhe; Tumbleston, John R.
  • Advanced Energy Materials, Vol. 3, Issue 1
  • DOI: 10.1002/aenm.201200377

Nonfullerene Acceptor Molecules for Bulk Heterojunction Organic Solar Cells
journal, February 2018


Subtle Polymer Donor and Molecular Acceptor Design Enable Efficient Polymer Solar Cells with a Very Small Energy Loss
journal, December 2019

  • Xu, Xiaopeng; Feng, Kui; Lee, Young Woong
  • Advanced Functional Materials, Vol. 30, Issue 9
  • DOI: 10.1002/adfm.201907570

Exploiting Ternary Blends for Improved Photostability in High-Efficiency Organic Solar Cells
journal, March 2020


Trifluoromethylation Enables a 3D Interpenetrated Low-Band-Gap Acceptor for Efficient Organic Solar Cells
journal, March 2020


All‐Polymer Solar Cells with over 12% Efficiency and a Small Voltage Loss Enabled by a Polymer Acceptor Based on an Extended Fused Ring Core
journal, July 2020

  • Yao, Huatong; Ma, Lik‐Kuen; Yu, Han
  • Advanced Energy Materials, Vol. 10, Issue 35
  • DOI: 10.1002/aenm.202001408

Near-infrared absorbing non-fullerene acceptors with selenophene as π bridges for efficient organic solar cells
journal, January 2018

  • Liang, Ziqi; Li, Miaomiao; Zhang, Xiaomei
  • Journal of Materials Chemistry A, Vol. 6, Issue 17
  • DOI: 10.1039/C8TA00783G

Improved organic solar cell efficiency based on the regulation of an alkyl chain on chlorinated non-fullerene acceptors
journal, January 2020

  • Yu, Han; Ma, Ruijie; Xiao, Yiqun
  • Materials Chemistry Frontiers, Vol. 4, Issue 8
  • DOI: 10.1039/D0QM00151A

Over 17% efficiency ternary organic solar cells enabled by two non-fullerene acceptors working in an alloy-like model
journal, January 2020

  • Zhan, Lingling; Li, Shuixing; Lau, Tsz-Ki
  • Energy & Environmental Science, Vol. 13, Issue 2
  • DOI: 10.1039/C9EE03710A

Semitransparent polymer solar cells with 12.37% efficiency and 18.6% average visible transmittance
journal, January 2020


Next-generation organic photovoltaics based on non-fullerene acceptors
journal, February 2018


Synthesis of a 4,9-Didodecyl Angular-Shaped Naphthodiselenophene Building Block To Achieve High-Mobility Transistors
journal, July 2016


Small-Molecule Acceptor Based on the Heptacyclic Benzodi(cyclopentadithiophene) Unit for Highly Efficient Nonfullerene Organic Solar Cells
journal, March 2017

  • Kan, Bin; Feng, Huanran; Wan, Xiangjian
  • Journal of the American Chemical Society, Vol. 139, Issue 13
  • DOI: 10.1021/jacs.7b01170

Mixed selenium-sulfur fused ring systems as building blocks for novel polymers used in field effect transistors
journal, January 2011

  • Mishra, Sarada P.; Javier, Anna E.; Zhang, Rui
  • J. Mater. Chem., Vol. 21, Issue 5
  • DOI: 10.1039/C0JM00602E

Progress of the key materials for organic solar cells
journal, April 2020


Mechanically Robust All-Polymer Solar Cells from Narrow Band Gap Acceptors with Hetero-Bridging Atoms
journal, March 2020


Transannularly conjugated tetrameric perylene diimide acceptors containing [2.2]paracyclophane for non-fullerene organic solar cells
journal, January 2020

  • Yu, Han; Arunagiri, Lingeswaran; Zhang, Lin
  • Journal of Materials Chemistry A, Vol. 8, Issue 14
  • DOI: 10.1039/D0TA00047G

Asymmetric Electron Acceptors for High‐Efficiency and Low‐Energy‐Loss Organic Photovoltaics
journal, May 2020

  • Li, Shuixing; Zhan, Lingling; Jin, Yingzhi
  • Advanced Materials, Vol. 32, Issue 24
  • DOI: 10.1002/adma.202001160