DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Mechanical Characterization of High-Temperature Carbon Fiber-Polyphenylene Sulfide Composites for Large Area Extrusion Deposition Additive Manufacturing

Abstract

Additive manufacturing (AM) is evolving from rapid prototyping to production of structural components. The widespread application of AM demands a high level of mechanical performance from these components, and it is therefore essential to improve feedstock material in order to meet these mechanical expectations. However, compared to traditional manufacturing techniques, the mechanical properties of AM materials and their resulting components are not well understood. In this study, we investigated the processability, microstructure, and mechanical performance of twin-screw compounded short carbon fiber reinforced polyphenylene sulfide (PPS) pellets as a feedstock material for big area AM (BAAM). The performance of the AM components was compared to that of traditional processing methods, namely injection molding (IM) and extrusion-compression molding (ECM). It was found that the AM composites exhibited 118% lower tensile strength and 55% lower tensile modulus when compared to traditional injection molding composite specimens; however, AM composites exhibited comparable properties to ECM composites. This response was attributed to highly aligned fibers in IM and AM samples. However, the AM composites contained porosity (15.5% volume), which reduced their mechanical properties in comparison to ECM composites. Finally, the IM process showed the maximum amount of fiber attrition with minimum porosity (0.007% volume), while themore » ECM process exhibited the least fiber attrition with 4.3% volume porosity.« less

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2];  [3];  [1]
  1. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Institute for Advanced Composites Manufacturing Innovation (IACMI)-The Composites Institute, Knoxville, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Techmer PM, Clinton, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1817595
Alternate Identifier(s):
OSTI ID: 1694305
Grant/Contract Number:  
AC05-00OR22725; EE0006926
Resource Type:
Accepted Manuscript
Journal Name:
Additive Manufacturing
Additional Journal Information:
Journal Volume: 34; Journal ID: ISSN 2214-8604
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; extrusion deposition modeling; additive manufacturing; extrusion compression molding; injection molding; mechanical characterization

Citation Formats

Yeole, Pritesh, Hassen, Ahmed Arabi, Kim, Seokpum, Lindahl, John, Kunc, Vlastimil, Franc, Alan S., and Vaidya, Uday. Mechanical Characterization of High-Temperature Carbon Fiber-Polyphenylene Sulfide Composites for Large Area Extrusion Deposition Additive Manufacturing. United States: N. p., 2020. Web. doi:10.1016/j.addma.2020.101255.
Yeole, Pritesh, Hassen, Ahmed Arabi, Kim, Seokpum, Lindahl, John, Kunc, Vlastimil, Franc, Alan S., & Vaidya, Uday. Mechanical Characterization of High-Temperature Carbon Fiber-Polyphenylene Sulfide Composites for Large Area Extrusion Deposition Additive Manufacturing. United States. https://doi.org/10.1016/j.addma.2020.101255
Yeole, Pritesh, Hassen, Ahmed Arabi, Kim, Seokpum, Lindahl, John, Kunc, Vlastimil, Franc, Alan S., and Vaidya, Uday. Fri . "Mechanical Characterization of High-Temperature Carbon Fiber-Polyphenylene Sulfide Composites for Large Area Extrusion Deposition Additive Manufacturing". United States. https://doi.org/10.1016/j.addma.2020.101255. https://www.osti.gov/servlets/purl/1817595.
@article{osti_1817595,
title = {Mechanical Characterization of High-Temperature Carbon Fiber-Polyphenylene Sulfide Composites for Large Area Extrusion Deposition Additive Manufacturing},
author = {Yeole, Pritesh and Hassen, Ahmed Arabi and Kim, Seokpum and Lindahl, John and Kunc, Vlastimil and Franc, Alan S. and Vaidya, Uday},
abstractNote = {Additive manufacturing (AM) is evolving from rapid prototyping to production of structural components. The widespread application of AM demands a high level of mechanical performance from these components, and it is therefore essential to improve feedstock material in order to meet these mechanical expectations. However, compared to traditional manufacturing techniques, the mechanical properties of AM materials and their resulting components are not well understood. In this study, we investigated the processability, microstructure, and mechanical performance of twin-screw compounded short carbon fiber reinforced polyphenylene sulfide (PPS) pellets as a feedstock material for big area AM (BAAM). The performance of the AM components was compared to that of traditional processing methods, namely injection molding (IM) and extrusion-compression molding (ECM). It was found that the AM composites exhibited 118% lower tensile strength and 55% lower tensile modulus when compared to traditional injection molding composite specimens; however, AM composites exhibited comparable properties to ECM composites. This response was attributed to highly aligned fibers in IM and AM samples. However, the AM composites contained porosity (15.5% volume), which reduced their mechanical properties in comparison to ECM composites. Finally, the IM process showed the maximum amount of fiber attrition with minimum porosity (0.007% volume), while the ECM process exhibited the least fiber attrition with 4.3% volume porosity.},
doi = {10.1016/j.addma.2020.101255},
journal = {Additive Manufacturing},
number = ,
volume = 34,
place = {United States},
year = {Fri Apr 24 00:00:00 EDT 2020},
month = {Fri Apr 24 00:00:00 EDT 2020}
}

Works referenced in this record:

Nanofiber-reinforced polymers prepared by fused deposition modeling: Nanofiber-Reinforced Polymers
journal, June 2003

  • Shofner, M. L.; Lozano, K.; Rodríguez-Macías, F. J.
  • Journal of Applied Polymer Science, Vol. 89, Issue 11
  • DOI: 10.1002/app.12496

Oxidation of carbon and metal coated carbon fibers
journal, April 1970


Effects of fiber length and orientation distribution on the elastic modulus of short fiber reinforced thermoplastics
journal, February 1988

  • Chin, Wei-Kuo; Liu, Hsin-Tzu; Lee, Yu-Der
  • Polymer Composites, Vol. 9, Issue 1
  • DOI: 10.1002/pc.750090105

The oxidation behaviour of carbon fibres
journal, April 1994

  • Yin, Y.; Binner, J. G. P.; Cross, T. E.
  • Journal of Materials Science, Vol. 29, Issue 8
  • DOI: 10.1007/BF01154706

Fused deposition modeling with polypropylene
journal, October 2015


Polyphenylene sulfide (PPS) composites reinforced with recycled carbon fiber
journal, July 2013


Development and validation of extrusion deposition additive manufacturing process simulations
journal, January 2019


XPS analysis of the interface between AA2024-T3/CF-PPS friction spot joints: XPS analysis of the AA2024-T3/CF-PPS friction spot joints interface
journal, September 2015

  • Goushegir, Seyed Mohammad; Scharnagl, Nico; dos Santos, Jorge F.
  • Surface and Interface Analysis, Vol. 48, Issue 8
  • DOI: 10.1002/sia.5816

A study on extruded filament bonding in fused filament fabrication
journal, April 2019

  • Costa, Ana Elisa; Ferreira da Silva, Alexandre; Sousa Carneiro, Olga
  • Rapid Prototyping Journal, Vol. 25, Issue 3
  • DOI: 10.1108/RPJ-03-2018-0062

The importance of carbon fiber to polymer additive manufacturing
journal, September 2014

  • Love, Lonnie J.; Kunc, Vlastamil; Rios, Orlando
  • Journal of Materials Research, Vol. 29, Issue 17
  • DOI: 10.1557/jmr.2014.212

Polyamide 6?long glass fiber injection moldings
journal, October 1995


Thermal and rheological properties of poly(phenylene sulfide) and poly(ether etherketone) resins and composites
journal, August 1987

  • Ma, Chen-chi M.; Hsia, Hung-chung; Liu, Wen-liang
  • Polymer Composites, Vol. 8, Issue 4
  • DOI: 10.1002/pc.750080408

Using XPS to Investigate Fiber/Matrix Chemical Interactions in Carbon-fiber-reinforced Composites
journal, February 1997


Tensile properties of short-glass-fiber- and short-carbon-fiber-reinforced polypropylene composites
journal, October 2000


Tensile properties of injection molded long fiber thermoplastic composites
journal, October 1989

  • Denault, J.; Vu-Khanh, T.; Foster, B.
  • Polymer Composites, Vol. 10, Issue 5
  • DOI: 10.1002/pc.750100507

Rheology, crystal structure, and nanomechanical properties in large-scale additive manufacturing of polyphenylene sulfide/carbon fiber composites
journal, November 2018


Crystallization kinetics of poly(phenylene sulfide) (PPS) and PPS/carbon fiber composites
journal, April 1991

  • Kenny, J. M.; Maffezzoli, A.
  • Polymer Engineering and Science, Vol. 31, Issue 8
  • DOI: 10.1002/pen.760310812

Properties, environmental stability, and molding characteristics of polyphenylene sulfide
journal, December 1976

  • Hill, H. Wayne; Brady, D. G.
  • Polymer Engineering and Science, Vol. 16, Issue 12
  • DOI: 10.1002/pen.760161211

Structure and mechanical behavior of Big Area Additive Manufacturing (BAAM) materials
journal, January 2017

  • Duty, Chad E.; Kunc, Vlastimil; Compton, Brett
  • Rapid Prototyping Journal, Vol. 23, Issue 1
  • DOI: 10.1108/RPJ-12-2015-0183

The Effect of Flocculent, Dispersants, and Binder on Wet–laid Process for Recycled Glass Fiber/PA6 Composite
journal, March 2018

  • Yeole, Pritesh; Ning, Haibin; Hassen, Ahmed Arabi
  • Polymers and Polymer Composites, Vol. 26, Issue 3
  • DOI: 10.1177/096739111802600306

Additive manufacturing of carbon fiber reinforced thermoplastic composites using fused deposition modeling
journal, October 2015


Highly oriented carbon fiber–polymer composites via additive manufacturing
journal, December 2014


Short fiber reinforced composites for fused deposition modeling
journal, March 2001


Influence of processing on the fiber length degradation in fiber reinforced plastic parts
conference, January 2016

  • Willems, F.; Bonten, C.
  • PROCEEDINGS OF THE REGIONAL CONFERENCE GRAZ 2015 – POLYMER PROCESSING SOCIETY PPS: Conference Papers, AIP Conference Proceedings
  • DOI: 10.1063/1.4965454