Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites

Percival, Stephen J.; Melia, Michael Anthony; Alexander, Christopher L.; Nelson, Derek W.; Schindelholz, Eric J.; Spoerke, Erik David

doi:10.1016/j.surfcoat.2019.125228

Title: Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites

Abstract

In this paper, we describe the immersion corrosion resistance of multilayer polymer-clay nanocomposite (PCN) barrier thin films coated on low carbon steel. Deposited using a Layer-by-Layer (LbL) self-assembly process and only a few hundred nanometers thick, the thin film polymer clay nanocomposites (PCN) exhibited excellent corrosion barrier properties, comparable to coatings that are orders of magnitude thicker. PCN barrier thin films comprising up to 60 “bilayers” of polyethyleneimine and exfoliated montmorillonite were coated onto steel coupons and immersed in high salinity water for up to 7 days to evaluate barrier film corrosion resistance. PCN film performance is shown to be influenced by the number of coated bilayers and, critically, a post-coating crosslinking treatment. Covalently crosslinking the polyethyleneimine components of the films resulted in a significant improvement in corrosion resistance. PCN films that were not crosslinked showed nearly identical electrochemical impedance compared to bare steel, failing rapidly and leading to large areas of visible corrosion. Impedance behavior of the corroding samples was analyzed with a precise model, which allowed the determination of the PCN film properties separate from the substrate and solution. The resistivity through the PCN thin films was very high, even after 7 days of immersion. Though increasing PCNmore »« less

Authors:

Percival, Stephen J. ^[1]; Melia, Michael Anthony ^[1]; Alexander, Christopher L. ^[1]; Nelson, Derek W. ^[1]; Schindelholz, Eric J. ^[1];

^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Publication Date:: Thu Dec 05 00:00:00 EST 2019

Research Org.:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program

OSTI Identifier:: 1670771

Alternate Identifier(s):: OSTI ID: 1702635

Report Number(s):: SAND-2020-10520J
Journal ID: ISSN 0257-8972; 691055

Grant/Contract Number:: AC04-94AL85000; NA0003525

Resource Type:: Accepted Manuscript

Journal Name:: Surface and Coatings Technology

Additional Journal Information:: Journal Volume: 383; Journal ID: ISSN 0257-8972

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Layer-by-layer; Anticorrosion; Coatings; Immersion; Steel

Citation Formats


                    Percival, Stephen J., Melia, Michael Anthony, Alexander, Christopher L., Nelson, Derek W., Schindelholz, Eric J., and Spoerke, Erik David. Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites.  United States: N. p., 2019. 
Web.  doi:10.1016/j.surfcoat.2019.125228.

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                    Percival, Stephen J., Melia, Michael Anthony, Alexander, Christopher L., Nelson, Derek W., Schindelholz, Eric J., & Spoerke, Erik David. Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites.  United States.  https://doi.org/10.1016/j.surfcoat.2019.125228

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                    Percival, Stephen J., Melia, Michael Anthony, Alexander, Christopher L., Nelson, Derek W., Schindelholz, Eric J., and Spoerke, Erik David. Thu .  
"Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites".  United States.  https://doi.org/10.1016/j.surfcoat.2019.125228.  https://www.osti.gov/servlets/purl/1670771.

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@article{osti_1670771,

  title        = {Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites},

  author       = {Percival, Stephen J. and Melia, Michael Anthony and Alexander, Christopher L. and Nelson, Derek W. and Schindelholz, Eric J. and Spoerke, Erik David},

  abstractNote = {In this paper, we describe the immersion corrosion resistance of multilayer polymer-clay nanocomposite (PCN) barrier thin films coated on low carbon steel. Deposited using a Layer-by-Layer (LbL) self-assembly process and only a few hundred nanometers thick, the thin film polymer clay nanocomposites (PCN) exhibited excellent corrosion barrier properties, comparable to coatings that are orders of magnitude thicker. PCN barrier thin films comprising up to 60 “bilayers” of polyethyleneimine and exfoliated montmorillonite were coated onto steel coupons and immersed in high salinity water for up to 7 days to evaluate barrier film corrosion resistance. PCN film performance is shown to be influenced by the number of coated bilayers and, critically, a post-coating crosslinking treatment. Covalently crosslinking the polyethyleneimine components of the films resulted in a significant improvement in corrosion resistance. PCN films that were not crosslinked showed nearly identical electrochemical impedance compared to bare steel, failing rapidly and leading to large areas of visible corrosion. Impedance behavior of the corroding samples was analyzed with a precise model, which allowed the determination of the PCN film properties separate from the substrate and solution. The resistivity through the PCN thin films was very high, even after 7 days of immersion. Though increasing PCN thickness led to increased charge transfer resistance, chemical crosslinking most significantly increased charge transfer resistance by several orders of magnitude. The combined influences of PCN film resistivity and very high charge transfer resistances led to the outstanding corrosion barrier properties. These PCN films show promise toward a new class of low-cost highly applicable anticorrosion coatings.},

  doi          = {10.1016/j.surfcoat.2019.125228},

  journal      = {Surface and Coatings Technology},

  number       = ,

  volume       = 383,

  place        = {United States},

  year         = {Thu Dec 05 00:00:00 EST 2019},

  month        = {Thu Dec 05 00:00:00 EST 2019}

}

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Title: Nanoscale thin film corrosion barriers enabled by multilayer polymer clay nanocomposites

Abstract

Citation Formats

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Marine Atmospheric Corrosion of Carbon Steel: A Review journal, April 2017

Electrochemical Behavior of Rust Formed on Carbon Steel in a Wet/Dry Environment Containing Chloride Ions journal, September 2000

Influence of Clay Concentration on the Gas Barrier of Clay–Polymer Nanobrick Wall Thin Film Assemblies journal, October 2011

Correlating the Compliance and Permeability of Photo-Cross-Linked Polyelectrolyte Multilayers journal, April 2011

Synthesis of Passivating, Nylon-Like Coatings through Cross-Linking of Ultrathin Polyelectrolyte Films journal, March 1999

Constant-phase-element behavior caused by inhomogeneous water uptake in anti-corrosion coatings journal, January 2013

Constant-Phase-Element Behavior Caused by Resistivity Distributions in Films journal, January 2010

Identification of Resistivity Distributions in Dielectric Layers by Measurement Model Analysis of Impedance Spectroscopy journal, November 2016

Evolution of dissolution processes at the interface of carbon steel corroding in a CO2 environment studied by EIS journal, February 2010

Corrosion study of carbon steel protected by a primer, by electrochemical impedance spectroscopy (EIS) in 3 %NaCl medium and in a soil simulating solution journal, February 1998

Electrochemical corrosion response of a low carbon heat treated steel in a NaCl solution: Electrochemical corrosion response of a low carbon heat treated steel journal, April 2009

Why Electrochemical Impedance Spectroscopy is the Ultimate Tool in Mechanistic Analysis journal, May 2009

Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings journal, May 2016

Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating journal, October 2009

Corrosion of Painted Metals—A Review
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Thin Nacre-Biomimetic Coating with Super-Anticorrosion Performance
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Interface-Engineered Parylene C Coating for Corrosion Protection of Cold-Rolled Steel
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Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites
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The Future of Layer-by-Layer Assembly: A Tribute to ACS Nano Associate Editor Helmuth Möhwald
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Innovation in Layer-by-Layer Assembly
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Technology-driven layer-by-layer assembly of nanofilms
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Mosaic tiling in molecular dimensions
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Nanostructured artificial nacre
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Thick Growing Multilayer Nanobrick Wall Thin Films: Super Gas Barrier with Very Few Layers
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Preparation of polymer–clay nanocomposites and their properties
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A review of flame retardant nanocoatings prepared using layer-by-layer assembly of polyelectrolytes
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Controlling Effective Aspect Ratio and Packing of Clay with pH for Improved Gas Barrier in Nanobrick Wall Thin Films
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High gas barrier imparted by similarly charged multilayers in nanobrick wall thin films
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Flexible Transparent Clay Films with Heat-Resistant and High Gas-Barrier Properties
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Extraordinary Corrosion Protection from Polymer–Clay Nanobrick Wall Thin Films
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Ultrathin Transparent Nanobrick Wall Anticorrosion Coatings
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Dramatic Enhancement of Graphene Oxide/Silk Nanocomposite Membranes: Increasing Toughness, Strength, and Young’s modulus via Annealing of Interfacial Structures
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Graphene-polymer nanocomposites for structural and functional applications
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Ultra-Robust Graphene Oxide-Silk Fibroin Nanocomposite Membranes
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Interaction of Polar and Nonpolar Polyfluorenes with Layers of Two-Dimensional Titanium Carbide (MXene): Intercalation and Pseudocapacitance
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Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene)
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Formation of Nanoparticle-Containing Multilayers in Nanochannels via Layer-by-Layer Assembly
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Catalytic Nanoparticles Formed by Reduction of Metal Ions in Multilayered Polyelectrolyte Films
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Selective Hydrogenation of Monosubstituted Alkenes by Pd Nanoparticles Embedded in Polyelectrolyte Films
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New electro-active self-assembled multilayer thin films based on alternately adsorbed layers of polyelectrolytes and functional dye molecules
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Biodegradable self-reporting nanocomposite films of poly(lactic acid) nanoparticles engineered by layer-by-layer assembly
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Flame retardant and hydrophobic coatings on cotton fabrics via sol-gel and self-assembly techniques
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Clay and DOPA Containing Polyelectrolyte Multilayer Film for Imparting Anticorrosion Properties to Galvanized Steel
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Corrosion Control Using Polyelectrolyte Multilayers
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Ultrathin, Layered Polyamide and Polyimide Coatings on Aluminum
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Layer-by-Layer Assembly of a Self-Healing Anticorrosion Coating on Magnesium Alloys
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Self-Healing Anticorrosion Coatings Based on pH-Sensitive Polyelectrolyte/Inhibitor Sandwichlike Nanostructures
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Active Anticorrosion Coatings with Halloysite Nanocontainers
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Self-Repairing Coatings Containing Active Nanoreservoirs
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Layer-by-Layer Assembled Nanocontainers for Self-Healing Corrosion Protection
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Marine Atmospheric Corrosion of Carbon Steel: A Review
journal, April 2017

Electrochemical Behavior of Rust Formed on Carbon Steel in a Wet/Dry Environment Containing Chloride Ions
journal, September 2000

Influence of Clay Concentration on the Gas Barrier of Clay–Polymer Nanobrick Wall Thin Film Assemblies
journal, October 2011

Correlating the Compliance and Permeability of Photo-Cross-Linked Polyelectrolyte Multilayers
journal, April 2011

Synthesis of Passivating, Nylon-Like Coatings through Cross-Linking of Ultrathin Polyelectrolyte Films
journal, March 1999

Constant-phase-element behavior caused by inhomogeneous water uptake in anti-corrosion coatings
journal, January 2013

Constant-Phase-Element Behavior Caused by Resistivity Distributions in Films
journal, January 2010

Identification of Resistivity Distributions in Dielectric Layers by Measurement Model Analysis of Impedance Spectroscopy
journal, November 2016

Evolution of dissolution processes at the interface of carbon steel corroding in a CO2 environment studied by EIS
journal, February 2010

Corrosion study of carbon steel protected by a primer, by electrochemical impedance spectroscopy (EIS) in 3 %NaCl medium and in a soil simulating solution
journal, February 1998

Electrochemical corrosion response of a low carbon heat treated steel in a NaCl solution: Electrochemical corrosion response of a low carbon heat treated steel
journal, April 2009

Why Electrochemical Impedance Spectroscopy is the Ultimate Tool in Mechanistic Analysis
journal, May 2009

Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings
journal, May 2016

Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating
journal, October 2009