Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials

Zachman, Michael; Hachtel, Jordan; Idrobo Tapia, Juan; Chi, Miaofang

doi:10.1002/anie.201902993

Title: Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials

Journal Article · 13 May 2019 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201902993 · OSTI ID:1651402

^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Abstract Interfaces play a fundamental role in many areas of chemistry. However, their localized nature requires characterization techniques with high spatial resolution in order to fully understand their structure and properties. State‐of‐the‐art atomic resolution or in situ scanning transmission electron microscopy and electron energy‐loss spectroscopy are indispensable tools for characterizing the local structure and chemistry of materials with single‐atom resolution, but they are not able to measure many properties that dictate function, such as vibrational modes or charge transfer, and are limited to room‐temperature samples containing no liquids. Here, we outline emerging electron microscopy techniques that are allowing these limitations to be overcome and highlight several recent studies that were enabled by these techniques. We then provide a vision for how these techniques can be paired with each other and with in situ methods to deliver new insights into the static and dynamic behavior of functional interfaces.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1651402

Alternate ID(s):: OSTI ID: 1570538

Journal Information:: Angewandte Chemie (International Edition), Vol. 59, Issue 4; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (166)

Exploring the capabilities of monochromated electron energy loss spectroscopy in the infrared regime Hachtel, Jordan A.; Lupini, Andrew R.; Idrobo, Juan Carlos Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-23805-5	journal	April 2018
In situ and operando transmission electron microscopy of catalytic materials Crozier, Peter A.; Hansen, Thomas W. MRS Bulletin, Vol. 40, Issue 1 https://doi.org/10.1557/mrs.2014.304	journal	January 2015
The potential for Bayesian compressive sensing to significantly reduce electron dose in high-resolution STEM images Stevens, Andrew; Yang, Hao; Carin, Lawrence Microscopy, Vol. 63, Issue 1 https://doi.org/10.1093/jmicro/dft042	journal	October 2013
Progress in ultrahigh energy resolution EELS Krivanek, O. L.; Dellby, N.; Hachtel, J. A. Ultramicroscopy, Vol. 203 https://doi.org/10.1016/j.ultramic.2018.12.006	journal	August 2019
A focused ion beam milling and lift-out approach for site-specific preparation of frozen-hydrated lamellas from multicellular organisms Mahamid, Julia; Schampers, Ruud; Persoon, Hans Journal of Structural Biology, Vol. 192, Issue 2 https://doi.org/10.1016/j.jsb.2015.07.012	journal	November 2015
Identification of site-specific isotopic labels by vibrational spectroscopy in the electron microscope Hachtel, Jordan A.; Huang, Jingsong; Popovs, Ilja Science, Vol. 363, Issue 6426 https://doi.org/10.1126/science.aav5845	journal	January 2019
Theory and practice of electron diffraction from single atoms and extended objects using an EMPAD Cao, Michael C.; Han, Yimo; Chen, Zhen Microscopy, Vol. 67, Issue suppl_1 https://doi.org/10.1093/jmicro/dfx123	journal	December 2017
Jointed magnetic skyrmion lattices at a small-angle grain boundary directly visualized by advanced electron microscopy Matsumoto, Takao; So, Yeong-Gi; Kohno, Yuji Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep35880	journal	October 2016
Crystallization Pathways in Biomineralization Weiner, Steve; Addadi, Lia Annual Review of Materials Research, Vol. 41, Issue 1 https://doi.org/10.1146/annurev-matsci-062910-095803	journal	August 2011
Das Aufl�sungsverm�gen des elektrostatisch-magnetischen Energieanalysators f�r schnelle Elektronen Boersch, H.; Geiger, J.; Stickel, W. Zeitschrift f�r Physik, Vol. 180, Issue 4 https://doi.org/10.1007/BF01380526	journal	August 1964
Image registration of low signal-to-noise cryo-STEM data Savitzky, Benjamin H.; El Baggari, Ismail; Clement, Colin B. Ultramicroscopy, Vol. 191 https://doi.org/10.1016/j.ultramic.2018.04.008	journal	August 2018
Dynamics of annular bright field imaging in scanning transmission electron microscopy Findlay, S. D.; Shibata, N.; Sawada, H. Ultramicroscopy, Vol. 110, Issue 7 https://doi.org/10.1016/j.ultramic.2010.04.004	journal	June 2010
Atomic-Scale Imaging in Real and Energy Space Developed in Ultrafast Electron Microscopy Park, Hyun Soon; Baskin, J. Spencer; Kwon, Oh-Hoon Nano Letters, Vol. 7, Issue 9 https://doi.org/10.1021/nl071369q	journal	September 2007
Non-spectroscopic composition measurements of SrTiO ₃ -La _0.7 Sr _0.3 MnO ₃ multilayers using scanning convergent beam electron diffraction Ophus, Colin; Ercius, Peter; Huijben, Mark Applied Physics Letters, Vol. 110, Issue 6 https://doi.org/10.1063/1.4975932	journal	February 2017
Construction and characterization of the fringe field monochromator for a field emission gun Mook, H. W.; Kruit, P. Ultramicroscopy, Vol. 81, Issue 3-4 https://doi.org/10.1016/S0304-3991(99)00193-X	journal	April 2000
Simultaneous First-Order Valence and Oxygen Vacancy Order/Disorder Transitions in (Pr _0.85 Y _0.15 ) _0.7 Ca _0.3 CoO _3−δ via Analytical Transmission Electron Microscopy Gulec, Ahmet; Phelan, Daniel; Leighton, Chris ACS Nano, Vol. 10, Issue 1 https://doi.org/10.1021/acsnano.5b06067	journal	December 2015
Scattering delocalization and radiation damage in STEM-EELS Egerton, R. F. Ultramicroscopy, Vol. 180 https://doi.org/10.1016/j.ultramic.2017.02.007	journal	September 2017
Nanoscale Probing of Local Hydrogen Heterogeneity in Disordered Carbon Nitrides with Vibrational Electron Energy-Loss Spectroscopy Haiber, Diane M.; Crozier, Peter A. ACS Nano, Vol. 12, Issue 6 https://doi.org/10.1021/acsnano.8b00884	journal	May 2018
Implementing an accurate and rapid sparse sampling approach for low-dose atomic resolution STEM imaging Kovarik, L.; Stevens, A.; Liyu, A. Applied Physics Letters, Vol. 109, Issue 16 https://doi.org/10.1063/1.4965720	journal	October 2016
On the correlation between self-diffusion and the low-frequency LA ⅔⟨111⟩ phonon mode in b.c.c. metals Köhler, Ulrich; Herzig, Christian Philosophical Magazine A, Vol. 58, Issue 5 https://doi.org/10.1080/01418618808209952	journal	November 1988
Suppression of Octahedral Tilts and Associated Changes in Electronic Properties at Epitaxial Oxide Heterostructure Interfaces Borisevich, A. Y.; Chang, H. J.; Huijben, M. Physical Review Letters, Vol. 105, Issue 8 https://doi.org/10.1103/PhysRevLett.105.087204	journal	August 2010
Electron microscopy image enhanced Haider, Maximilian; Uhlemann, Stephan; Schwan, Eugen Nature, Vol. 392, Issue 6678 https://doi.org/10.1038/33823	journal	April 1998
Fast ion transport at solid–solid interfaces in hybrid battery anodes Tu, Zhengyuan; Choudhury, Snehashis; Zachman, Michael J. Nature Energy, Vol. 3, Issue 4 https://doi.org/10.1038/s41560-018-0096-1	journal	March 2018
Interfacial Challenges in Solid-State Li Ion Batteries Luntz, Alan C.; Voss, Johannes; Reuter, Karsten The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b02352	journal	October 2015
Direct observation of ferroelectric field effect and vacancy-controlled screening at the BiFeO3/LaxSr1−xMnO3 interface Kim, Young-Min; Morozovska, Anna; Eliseev, Eugene Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4058	journal	August 2014
Tailoring of surface plasmon resonances in TiN/(Al0.72Sc0.28)N multilayers by dielectric layer thickness variation Garbrecht, Magnus; Hultman, Lars; Fawey, Mohammed H. Journal of Materials Science, Vol. 53, Issue 6 https://doi.org/10.1007/s10853-017-1837-4	journal	November 2017
Development of high-resolution cathodoluminescence system for STEM and application to plasmonic nanostructures Yamamoto, Naoki Microscopy, Vol. 65, Issue 4 https://doi.org/10.1093/jmicro/dfw025	journal	July 2016
Advances in Ultra-High Energy Resolution STEM-EELS Lovejoy, T. C.; Corbin, G. C.; Dellby, N. Microscopy and Microanalysis, Vol. 24, Issue S1 https://doi.org/10.1017/S1431927618002726	journal	August 2018
Low-dose cryo electron ptychography via non-convex Bayesian optimization Pelz, Philipp Michael; Qiu, Wen Xuan; Bücker, Robert Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-07488-y	journal	August 2017
Controlling Structural Anisotropy of Anisotropic 2D Layers in Pseudo-1D/2D Material Heterojunctions Chen, Bin; Wu, Kedi; Suslu, Aslihan Advanced Materials, Vol. 29, Issue 34 https://doi.org/10.1002/adma.201701201	journal	July 2017
Designing Artificial Solid-Electrolyte Interphases for Single-Ion and High-Efficiency Transport in Batteries Tu, Zhengyuan; Choudhury, Snehashis; Zachman, Michael J. Joule, Vol. 1, Issue 2 https://doi.org/10.1016/j.joule.2017.06.002	journal	October 2017
Energy and fuels from electrochemical interfaces Stamenkovic, Vojislav R.; Strmcnik, Dusan; Lopes, Pietro P. Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4738	journal	December 2016
Optimization of monochromated TEM for ultimate resolution imaging and ultrahigh resolution electron energy loss spectroscopy Lopatin, Sergei; Cheng, Bin; Liu, Wei-Ting Ultramicroscopy, Vol. 184 https://doi.org/10.1016/j.ultramic.2017.08.016	journal	January 2018
Electron microscopy of frozen hydrated sections of vitreous ice and vitrified biological samples McDowall, A. W.; Chang, J. -J.; Freeman, R. Journal of Microscopy, Vol. 131, Issue 1 https://doi.org/10.1111/j.1365-2818.1983.tb04225.x	journal	July 1983
Direct imaging of hydrogen-atom columns in a crystal by annular bright-field electron microscopy Ishikawa, Ryo; Okunishi, Eiji; Sawada, Hidetaka Nature Materials, Vol. 10, Issue 4 https://doi.org/10.1038/nmat2957	journal	February 2011
In Situ TEM Characterization of Shear-Stress-Induced Interlayer Sliding in the Cross Section View of Molybdenum Disulfide Oviedo, Juan Pablo; Kc, Santosh; Lu, Ning ACS Nano, Vol. 9, Issue 2 https://doi.org/10.1021/nn506052d	journal	December 2014
Differential phase-contrast microscopy at atomic resolution Shibata, Naoya; Findlay, Scott D.; Kohno, Yuji Nature Physics, Vol. 8, Issue 8 https://doi.org/10.1038/nphys2337	journal	June 2012
Atomic lattice disorder in charge-density-wave phases of exfoliated dichalcogenides (1T-TaS ₂ ) Hovden, Robert; Tsen, Adam W.; Liu, Pengzi Proceedings of the National Academy of Sciences, Vol. 113, Issue 41 https://doi.org/10.1073/pnas.1606044113	journal	September 2016
Tuning mobility and stability of lithium ion conductors based on lattice dynamics Muy, Sokseiha; Bachman, John C.; Giordano, Livia Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/C7EE03364H	journal	January 2018
Quantitative measurements of internal electric fields with differential phase contrast microscopy on InGaN/GaN quantum well structures: Measurements of internal electric fields Lohr, Matthias; Schregle, Ralph; Jetter, Michael physica status solidi (b), Vol. 253, Issue 1 https://doi.org/10.1002/pssb.201552288	journal	October 2015
Spatially and spectrally resolved orbital angular momentum interactions in plasmonic vortex generators Hachtel, Jordan A.; Cho, Sang-Yeon; Davidson, Roderick B. Light: Science & Applications, Vol. 8, Issue 1 https://doi.org/10.1038/s41377-019-0136-z	journal	March 2019
Production and application of electron vortex beams Verbeeck, J.; Tian, H.; Schattschneider, P. Nature, Vol. 467, Issue 7313 https://doi.org/10.1038/nature09366	journal	September 2010
In Situ TEM Analysis of Organic–Inorganic Metal-Halide Perovskite Solar Cells under Electrical Bias Jeangros, Quentin; Duchamp, Martial; Werner, Jérémie Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03158	journal	October 2016
Prospects of spatial resolution in vibrational electron energy loss spectroscopy: Implications of dipolar scattering Dwyer, Christian Physical Review B, Vol. 96, Issue 22 https://doi.org/10.1103/PhysRevB.96.224102	journal	December 2017
Direct observation of Σ7 domain boundary core structure in magnetic skyrmion lattice Matsumoto, Takao; So, Yeong-Gi; Kohno, Yuji Science Advances, Vol. 2, Issue 2 https://doi.org/10.1126/sciadv.1501280	journal	February 2016
Electron-Beam Mapping of Vibrational Modes with Nanometer Spatial Resolution Dwyer, C.; Aoki, T.; Rez, P. Physical Review Letters, Vol. 117, Issue 25 https://doi.org/10.1103/PhysRevLett.117.256101	journal	December 2016
Site-Specific Preparation of Intact Solid–Liquid Interfaces by Label-Free In Situ Localization and Cryo-Focused Ion Beam Lift-Out Zachman, Michael J.; Asenath-Smith, Emily; Estroff, Lara A. Microscopy and Microanalysis, Vol. 22, Issue 6 https://doi.org/10.1017/S1431927616011892	journal	November 2016
Integrated Circuits Comprising Patterned Functional Liquids Prasad, Bhagwati; Pfanzelt, Georg; Fillis-Tsirakis, Evangelos Advanced Materials, Vol. 30, Issue 35 https://doi.org/10.1002/adma.201802598	journal	July 2018
Atomic-scale origin of the large grain-boundary resistance in perovskite Li-ion-conducting solid electrolytes Ma, Cheng; Chen, Kai; Liang, Chengdu Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c4ee00382a	journal	January 2014
Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries Zachman, Michael J.; Tu, Zhengyuan; Choudhury, Snehashis Nature, Vol. 560, Issue 7718 https://doi.org/10.1038/s41586-018-0397-3	journal	August 2018
Direct observation of chemical reactions on single gold nanocrystals using surface plasmon spectroscopy Novo, Carolina; Funston, Alison M.; Mulvaney, Paul Nature Nanotechnology, Vol. 3, Issue 10 https://doi.org/10.1038/nnano.2008.246	journal	September 2008
Direct Detection Electron Energy-Loss Spectroscopy: A Method to Push the Limits of Resolution and Sensitivity Hart, James L.; Lang, Andrew C.; Leff, Asher C. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-07709-4	journal	August 2017
Controllable Perovskite Crystallization at a Gas–Solid Interface for Hole Conductor-Free Solar Cells with Steady Power Conversion Efficiency over 10% Hao, Feng; Stoumpos, Constantinos C.; Liu, Zhao Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja509245x	journal	November 2014
Carbon-based materials as supercapacitor electrodes Zhang, Li Li; Zhao, X. S. Chemical Society Reviews, Vol. 38, Issue 9 https://doi.org/10.1039/b813846j	journal	January 2009
Resonant Coupling between Molecular Vibrations and Localized Surface Plasmon Resonance of Faceted Metal Oxide Nanocrystals Agrawal, Ankit; Singh, Ajay; Yazdi, Sadegh Nano Letters, Vol. 17, Issue 4 https://doi.org/10.1021/acs.nanolett.7b00404	journal	March 2017
Performance of low-voltage STEM/TEM with delta corrector and cold field emission gun Sasaki, T.; Sawada, H.; Hosokawa, F. Journal of Electron Microscopy, Vol. 59, Issue S1 https://doi.org/10.1093/jmicro/dfq027	journal	June 2010
Nanoscale optical tomography with cathodoluminescence spectroscopy Atre, Ashwin C.; Brenny, Benjamin J. M.; Coenen, Toon Nature Nanotechnology, Vol. 10, Issue 5 https://doi.org/10.1038/nnano.2015.39	journal	April 2015
Visualizing the interfacial evolution from charge compensation to metallic screening across the manganite metal–insulator transition Mundy, Julia A.; Hikita, Yasuyuki; Hidaka, Takeaki Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4464	journal	March 2014
Vibrational Spectroscopy of Water with High Spatial Resolution Jokisaari, Jacob R.; Hachtel, Jordan A.; Hu, Xuan Advanced Materials, Vol. 30, Issue 36 https://doi.org/10.1002/adma.201802702	journal	July 2018
Phase contrast STEM for thin samples: Integrated differential phase contrast Lazić, Ivan; Bosch, Eric G. T.; Lazar, Sorin Ultramicroscopy, Vol. 160 https://doi.org/10.1016/j.ultramic.2015.10.011	journal	January 2016
Resolution beyond the 'information limit' in transmission electron microscopy Nellist, P. D.; McCallum, B. C.; Rodenburg, J. M. Nature, Vol. 374, Issue 6523 https://doi.org/10.1038/374630a0	journal	April 1995
Development of a high energy resolution electron energy-loss spectroscopy microscope: HIGH ENERGY RESOLUTION EELS MICROSCOPE Journal of Microscopy, Vol. 194, Issue 1 https://doi.org/10.1046/j.1365-2818.1999.00450.x	journal	April 1999
In Situ Electron Energy-Loss Spectroscopy in Liquids Holtz, Megan E.; Yu, Yingchao; Gao, Jie Microscopy and Microanalysis, Vol. 19, Issue 4 https://doi.org/10.1017/S1431927613001505	journal	May 2013
Vibrational and valence aloof beam EELS: A potential tool for nondestructive characterization of nanoparticle surfaces Crozier, Peter A. Ultramicroscopy, Vol. 180 https://doi.org/10.1016/j.ultramic.2017.03.011	journal	September 2017
In Situ TEM Imaging of Defect Dynamics under Electrical Bias in Resistive Switching Rutile-TiO ₂ Kamaladasa, Ranga J.; Sharma, Abhishek A.; Lai, Yu-Ting Microscopy and Microanalysis, Vol. 21, Issue 1 https://doi.org/10.1017/S1431927614013555	journal	December 2014
Sample tilt effects on atom column position determination in ABF–STEM imaging Zhou, Dan; Müller-Caspary, Knut; Sigle, Wilfried Ultramicroscopy, Vol. 160 https://doi.org/10.1016/j.ultramic.2015.10.008	journal	January 2016
Energy resolution of an Omega-type monochromator and imaging properties of the MANDOLINE filter Essers, Erik; Benner, Gerd; Mandler, Thilo Ultramicroscopy, Vol. 110, Issue 8 https://doi.org/10.1016/j.ultramic.2010.02.009	journal	July 2010
Optical properties and biomedical applications of plasmonic nanoparticles Khlebtsov, Nikolai G.; Dykman, Lev A. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 111, Issue 1 https://doi.org/10.1016/j.jqsrt.2009.07.012	journal	January 2010
High-κ gate dielectrics: Current status and materials properties considerations Wilk, G. D.; Wallace, R. M.; Anthony, J. M. Journal of Applied Physics, Vol. 89, Issue 10 https://doi.org/10.1063/1.1361065	journal	May 2001
Nanoporous Hybrid Electrolytes for High-Energy Batteries Based on Reactive Metal Anodes Tu, Zhengyuan; Zachman, Michael J.; Choudhury, Snehashis Advanced Energy Materials, Vol. 7, Issue 8 https://doi.org/10.1002/aenm.201602367	journal	January 2017
Development of a TEM to study in situ structural and chemical changes at an atomic level during gas-solid interactions at elevated temperatures Sharma, Renu; Weiss, Karl Microscopy Research and Technique, Vol. 42, Issue 4 https://doi.org/10.1002/(SICI)1097-0029(19980915)42:4<270::AID-JEMT6>3.0.CO;2-U	journal	September 1998
A pnCCD-based, fast direct single electron imaging camera for TEM and STEM Ryll, H.; Simson, M.; Hartmann, R. Journal of Instrumentation, Vol. 11, Issue 04 https://doi.org/10.1088/1748-0221/11/04/P04006	journal	April 2016
Plasmon-enhanced optical sensors: a review Li, Ming; Cushing, Scott K.; Wu, Nianqiang The Analyst, Vol. 140, Issue 2 https://doi.org/10.1039/C4AN01079E	journal	January 2015
Electron Vortex Beams with High Quanta of Orbital Angular Momentum McMorran, B. J.; Agrawal, A.; Anderson, I. M. Science, Vol. 331, Issue 6014, p. 192-195 https://doi.org/10.1126/science.1198804	journal	January 2011
Mapping vibrational surface and bulk modes in a single nanocube Lagos, Maureen J.; Trügler, Andreas; Hohenester, Ulrich Nature, Vol. 543, Issue 7646 https://doi.org/10.1038/nature21699	journal	March 2017
Damage-free vibrational spectroscopy of biological materials in the electron microscope Rez, Peter; Aoki, Toshihiro; March, Katia Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10945	journal	March 2016
Lithium battery chemistries enabled by solid-state electrolytes Manthiram, Arumugam; Yu, Xingwen; Wang, Shaofei Nature Reviews Materials, Vol. 2, Issue 4 https://doi.org/10.1038/natrevmats.2016.103	journal	February 2017
Improvement of windowed type environmental-cell transmission electron microscope for in situ observation of gas-solid interactions Kawasaki, Tadahiro; Ueda, Kouta; Ichihashi, Mikio Review of Scientific Instruments, Vol. 80, Issue 11 https://doi.org/10.1063/1.3250862	journal	November 2009
Cathodoluminescence in the scanning transmission electron microscope Kociak, M.; Zagonel, L. F. Ultramicroscopy, Vol. 176 https://doi.org/10.1016/j.ultramic.2017.03.014	journal	May 2017
Direct imaging of lithium atoms in LiV2O4 by spherical aberration-corrected electron microscopy Oshima, Yoshifumi; Sawada, Hidetaka; Hosokawa, Fumio Microscopy, Vol. 59, Issue 6 https://doi.org/10.1093/jmicro/dfq017	journal	April 2010
Probing the light harvesting and charge rectification of bismuth nanoparticles behind the promoted photoreactivity onto Bi/BiOCl catalyst by (in-situ) electron microscopy Chang, Xiaofeng; Xie, Lin; Sha, Wei E. I. Applied Catalysis B: Environmental, Vol. 201 https://doi.org/10.1016/j.apcatb.2016.08.049	journal	February 2017
Cryogenic Focused Ion Beam Characterization of Lithium Metal Anodes Lee, Jungwoo Z.; Wynn, Thomas A.; Schroeder, Marshall A. ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.8b02381	journal	January 2019
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Nanoscale momentum-resolved vibrational spectroscopy Hage, Fredrik S.; Nicholls, Rebecca J.; Yates, Jonathan R. Science Advances, Vol. 4, Issue 6 https://doi.org/10.1126/sciadv.aar7495	journal	June 2018
A site-specific focused-ion-beam lift-out method for cryo Transmission Electron Microscopy Rubino, Stefano; Akhtar, Sultan; Melin, Petter Journal of Structural Biology, Vol. 180, Issue 3 https://doi.org/10.1016/j.jsb.2012.08.012	journal	December 2012
Enhancement of resolution in core-loss and low-loss spectroscopy in a monochromated microscope Lazar, S.; Botton, G. A.; Zandbergen, H. W. Ultramicroscopy, Vol. 106, Issue 11-12 https://doi.org/10.1016/j.ultramic.2006.04.024	journal	October 2006
Towards sub-Å electron beams Krivanek, O. L.; Dellby, N.; Lupini, A. R. Ultramicroscopy, Vol. 78, Issue 1-4 https://doi.org/10.1016/S0304-3991(99)00013-3	journal	June 1999
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Direct Visualization of Local Electromagnetic Field Structures by Scanning Transmission Electron Microscopy Shibata, Naoya; Findlay, Scott D.; Matsumoto, Takao Accounts of Chemical Research, Vol. 50, Issue 7 https://doi.org/10.1021/acs.accounts.7b00123	journal	July 2017
Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl404577c	journal	February 2014
Stabilizing Protic and Aprotic Liquid Electrolytes at High-Bandgap Oxide Interphases Tu, Zhengyuan; Zachman, Michael J.; Choudhury, Snehashis Chemistry of Materials, Vol. 30, Issue 16 https://doi.org/10.1021/acs.chemmater.8b01996	journal	July 2018
Probing low-energy hyperbolic polaritons in van der Waals crystals with an electron microscope Govyadinov, Alexander A.; Konečná, Andrea; Chuvilin, Andrey Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00056-y	journal	July 2017
Nature and evolution of incommensurate charge order in manganites visualized with cryogenic scanning transmission electron microscopy El Baggari, Ismail; Savitzky, Benjamin H.; Admasu, Alemayehu S. Proceedings of the National Academy of Sciences, Vol. 115, Issue 7 https://doi.org/10.1073/pnas.1714901115	journal	January 2018
Pixelated detectors and improved efficiency for magnetic imaging in STEM differential phase contrast Krajnak, Matus; McGrouther, Damien; Maneuski, Dzmitry Ultramicroscopy, Vol. 165 https://doi.org/10.1016/j.ultramic.2016.03.006	journal	June 2016
Investigation of the Interaction between Nafion Ionomer and Surface Functionalized Carbon Black Using Both Ultrasmall Angle X-ray Scattering and Cryo-TEM Yang, Fan; Xin, Le; Uzunoglu, Aytekin ACS Applied Materials & Interfaces, Vol. 9, Issue 7 https://doi.org/10.1021/acsami.6b12949	journal	February 2017
Prospects for analyzing the electronic properties in nanoscale systems by VEELS Erni, Rolf; Lazar, Sorin; Browning, Nigel D. Ultramicroscopy, Vol. 108, Issue 3 https://doi.org/10.1016/j.ultramic.2007.07.008	journal	February 2008
Electrochemical aspects of the generation of ramified metallic electrodeposits Chazalviel, J. -N. Physical Review A, Vol. 42, Issue 12 https://doi.org/10.1103/PhysRevA.42.7355	journal	December 1990
Direct Electron Detection for Atomic Resolution in situ EELS Goodge, Berit H.; Baek, David J.; Kourkoutis, Lena F. Microscopy and Microanalysis, Vol. 24, Issue S1 https://doi.org/10.1017/S1431927618009704	journal	August 2018
Aberration-Corrected STEM/EELS at Cryogenic Temperatures Kourkoutis, Lena F.; El Baggari, Ismail; Savitzky, Benjamin H. Microscopy and Microanalysis, Vol. 23, Issue S1 https://doi.org/10.1017/S1431927617002823	journal	July 2017
Nanoscale Imaging of Fundamental Li Battery Chemistry: Solid-Electrolyte Interphase Formation and Preferential Growth of Lithium Metal Nanoclusters Sacci, Robert L.; Black, Jennifer M.; Balke, Nina Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl5048626	journal	February 2015
Hot Electron Generation and Cathodoluminescence Nanoscopy of Chiral Split Ring Resonators Fang, Yurui; Verre, Ruggero; Shao, Lei Nano Letters, Vol. 16, Issue 8 https://doi.org/10.1021/acs.nanolett.6b02154	journal	July 2016
Strain mapping at nanometer resolution using advanced nano-beam electron diffraction Ozdol, V. B.; Gammer, C.; Jin, X. G. Applied Physics Letters, Vol. 106, Issue 25 https://doi.org/10.1063/1.4922994	journal	June 2015
Generation of electron beams carrying orbital angular momentum Uchida, Masaya; Tonomura, Akira Nature, Vol. 464, Issue 7289 https://doi.org/10.1038/nature08904	journal	April 2010
The influence of surfaces and interfaces on high spatial resolution vibrational EELS from SiO2 Venkatraman, Kartik; Rez, Peter; March, Katia Microscopy, Vol. 67, Issue suppl_1 https://doi.org/10.1093/jmicro/dfy003	journal	February 2018
High Dynamic Range Pixel Array Detector for Scanning Transmission Electron Microscopy Tate, Mark W.; Purohit, Prafull; Chamberlain, Darol Microscopy and Microanalysis, Vol. 22, Issue 1 https://doi.org/10.1017/S1431927615015664	journal	January 2016
Photocatalytic degradation of volatile organic compounds at the gas–solid interface of a TiO2 photocatalyst Kim, Sang Bum; Hwang, Hyun Tae; Hong, Sung Chang Chemosphere, Vol. 48, Issue 4 https://doi.org/10.1016/S0045-6535(02)00101-7	journal	July 2002
Surface-Enhanced Molecular Electron Energy Loss Spectroscopy Konečná, Andrea; Neuman, Tomáš; Aizpurua, Javier ACS Nano, Vol. 12, Issue 5 https://doi.org/10.1021/acsnano.8b01481	journal	April 2018
Ionic conduction in space charge regions Maier, Joachim Progress in Solid State Chemistry, Vol. 23, Issue 3 https://doi.org/10.1016/0079-6786(95)00004-E	journal	January 1995
Microscopic origins for stabilizing room-temperature ferromagnetism in ultrathin manganite layers Kourkoutis, L. F.; Song, J. H.; Hwang, H. Y. Proceedings of the National Academy of Sciences, Vol. 107, Issue 26 https://doi.org/10.1073/pnas.1005693107	journal	June 2010
In Situ TEM Near-Field Optical Probing of Nanoscale Silicon Crystallization Xiang, Bin; Hwang, David J.; In, Jung Bin Nano Letters, Vol. 12, Issue 5 https://doi.org/10.1021/nl3007352	journal	April 2012
Atomic electric fields revealed by a quantum mechanical approach to electron picodiffraction Müller, Knut; Krause, Florian F.; Béché, Armand Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6653	journal	December 2014
Atomic-Resolution STEM Imaging of Graphene at Low Voltage of 30 kV with Resolution Enhancement by Using Large Convergence Angle Sawada, H.; Sasaki, T.; Hosokawa, F. Physical Review Letters, Vol. 114, Issue 16 https://doi.org/10.1103/PhysRevLett.114.166102	journal	April 2015
Low-Dose Aberration-Free Imaging of Li-Rich Cathode Materials at Various States of Charge Using Electron Ptychography Lozano, Juan G.; Martinez, Gerardo T.; Jin, Liyu Nano Letters, Vol. 18, Issue 11 https://doi.org/10.1021/acs.nanolett.8b02718	journal	September 2018
Direct Electron Detection for Atomic-Resolution EELS Mapping at Cryogenic Temperature Baek, David J.; Zachman, Michael J.; Goodge, Berit H. Microscopy and Microanalysis, Vol. 24, Issue S1 https://doi.org/10.1017/S1431927618002763	journal	August 2018
Molecular recognition at the gas–solid interface: a powerful tool for chemical sensing Pirondini, Laura; Dalcanale, Enrico Chem. Soc. Rev., Vol. 36, Issue 5 https://doi.org/10.1039/B516256B	journal	January 2007
Phonon Spectroscopy at Atomic Resolution Hage, F. S.; Kepaptsoglou, D. M.; Ramasse, Q. M. Physical Review Letters, Vol. 122, Issue 1 https://doi.org/10.1103/PhysRevLett.122.016103	journal	January 2019
Selective breakdown of phonon quasiparticles across superionic transition in CuCrSe2 Niedziela, Jennifer L.; Bansal, Dipanshu; May, Andrew F. Nature Physics, Vol. 15, Issue 1 https://doi.org/10.1038/s41567-018-0298-2	journal	October 2018
4D Scanning Transmission Ultrafast Electron Microscopy: Single-Particle Imaging and Spectroscopy Ortalan, Volkan; Zewail, Ahmed H. Journal of the American Chemical Society, Vol. 133, Issue 28 https://doi.org/10.1021/ja203821y	journal	July 2011
Development of a monochromator for aberration-corrected scanning transmission electron microscopy Mukai, Masaki; Okunishi, Eiji; Ashino, Masanori Microscopy, Vol. 64, Issue 3 https://doi.org/10.1093/jmicro/dfv001	journal	February 2015
Sub-Ångstrom electric field measurements on a universal detector in a scanning transmission electron microscope Hachtel, Jordan A.; Idrobo, Juan Carlos; Chi, Miaofang Advanced Structural and Chemical Imaging, Vol. 4, Issue 1 https://doi.org/10.1186/s40679-018-0059-4	journal	August 2018
Vitrification of pure Water for Electron Microscopy Dubochet, J.; McDowall, A. W. Journal of Microscopy, Vol. 124, Issue 3 https://doi.org/10.1111/j.1365-2818.1981.tb02483.x	journal	December 1981
Plasmonics for improved photovoltaic devices Atwater, Harry A.; Polman, Albert Nature Materials, Vol. 9, Issue 3, p. 205-213 https://doi.org/10.1038/nmat2629	journal	February 2010
In situ TEM sintering of nano-sized ZrO2 particles Rankin, J.; Sheldon, B. W. Materials Science and Engineering: A, Vol. 204, Issue 1-2 https://doi.org/10.1016/0921-5093(95)09936-0	journal	December 1995
Role of Akaganeite (β-FeOOH) in the Growth of Hematite (α-Fe ₂ O ₃ ) in an Inorganic Silica Hydrogel Asenath-Smith, Emily; Estroff, Lara A. Crystal Growth & Design, Vol. 15, Issue 7 https://doi.org/10.1021/acs.cgd.5b00475	journal	June 2015
Imaging of Transient Structures Using Nanosecond in Situ TEM Kim, Judy S.; LaGrange, Thomas; Reed, Bryan W. Science, Vol. 321, Issue 5895 https://doi.org/10.1126/science.1161517	journal	September 2008
Thermal Signatures of Plasmonic Fano Interferences: Toward the Achievement of Nanolocalized Temperature Manipulation Baldwin, Christopher L.; Bigelow, Nicholas W.; Masiello, David J. The Journal of Physical Chemistry Letters, Vol. 5, Issue 8 https://doi.org/10.1021/jz500421z	journal	March 2014
In situ observation of heat-induced degradation of perovskite solar cells Divitini, G.; Cacovich, S.; Matteocci, F. Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.12	journal	January 2016
Imaging of built-in electric field at a p-n junction by scanning transmission electron microscopy Shibata, Naoya; Findlay, Scott D.; Sasaki, Hirokazu Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep10040	journal	June 2015
Vibrational spectroscopy in the electron microscope Krivanek, Ondrej L.; Lovejoy, Tracy C.; Dellby, Niklas Nature, Vol. 514, Issue 7521 https://doi.org/10.1038/nature13870	journal	October 2014
Atomic-Scale Chemical Imaging of Composition and Bonding by Aberration-Corrected Microscopy Muller, D. A.; Kourkoutis, L. F.; Murfitt, M. Science, Vol. 319, Issue 5866 https://doi.org/10.1126/science.1148820	journal	February 2008
Quantitative comparison of bright field and annular bright field imaging modes for characterization of oxygen octahedral tilts Kim, Young-Min; Pennycook, Stephen J.; Borisevich, Albina Y. Ultramicroscopy, Vol. 181 https://doi.org/10.1016/j.ultramic.2017.04.020	journal	October 2017
Making the practically impossible “Merely difficult”-Cryogenic FIB lift-out for “Damage free” soft matter imaging: FAST AND EFFICIENT CRYO LIFT-OUT AND TRANSFER TO TEM Parmenter, Christopher D. J.; Fay, Michael W.; Hartfield, Cheryl Microscopy Research and Technique, Vol. 79, Issue 4 https://doi.org/10.1002/jemt.22630	journal	February 2016
Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy Ma, Cheng; Cheng, Yongqiang; Yin, Kuibo Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03223	journal	October 2016
4D Nanoscale Diffraction Observed by Convergent-Beam Ultrafast Electron Microscopy Yurtsever, A.; Zewail, A. H. Science, Vol. 326, Issue 5953 https://doi.org/10.1126/science.1179314	journal	October 2009
Monochromated STEM with a 30 meV-wide, atom-sized electron probe Krivanek, Ondrej L.; Lovejoy, Tracy C.; Dellby, Niklas Microscopy, Vol. 62, Issue 1 https://doi.org/10.1093/jmicro/dfs089	journal	January 2013
Direct visualization of initial SEI morphology and growth kinetics during lithium deposition by in situ electrochemical transmission electron microscopy Sacci, Robert L.; Dudney, Nancy J.; More, Karren L. Chemical Communications, Vol. 50, Issue 17 https://doi.org/10.1039/c3cc49029g	journal	January 2014
SESAM: Exploring the Frontiers of Electron Microscopy Koch, Christoph T.; Sigle, Wilfried; Höschen, Rainer Microscopy and Microanalysis, Vol. 12, Issue 6 https://doi.org/10.1017/S1431927606060624	journal	October 2006
Comparison of first moment STEM with conventional differential phase contrast and the dependence on electron dose Müller-Caspary, Knut; Krause, Florian F.; Winkler, Florian Ultramicroscopy, Vol. 203 https://doi.org/10.1016/j.ultramic.2018.12.018	journal	August 2019
Hybridization of Single Nanocrystals of Cs ₄ PbBr ₆ and CsPbBr ₃ de Weerd, Chris; Lin, Junhao; Gomez, Leyre The Journal of Physical Chemistry C, Vol. 121, Issue 35 https://doi.org/10.1021/acs.jpcc.7b05752	journal	August 2017
Origin of additional capacities in metal oxide lithium-ion battery electrodes Hu, Yan-Yan; Liu, Zigeng; Nam, Kyung-Wan Nature Materials, Vol. 12, Issue 12 https://doi.org/10.1038/nmat3784	journal	November 2013
Designer interphases for the lithium-oxygen electrochemical cell Choudhury, Snehashis; Wan, Charles Tai-Chieh; Al Sadat, Wajdi I. Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1602809	journal	April 2017
Direct Imaging of Hydrogen within a Crystalline Environment Findlay, Scott D.; Saito, Tomohiro; Shibata, Naoya Applied Physics Express, Vol. 3, Issue 11 https://doi.org/10.1143/APEX.3.116603	journal	November 2010
Electric field imaging of single atoms Shibata, Naoya; Seki, Takehito; Sánchez-Santolino, Gabriel Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15631	journal	May 2017
Roles of phonon amplitude and low-energy optical phonons on superionic conduction Wakamura, Kunio Physical Review B, Vol. 56, Issue 18 https://doi.org/10.1103/PhysRevB.56.11593	journal	November 1997
New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM Wang, Xuefeng; Zhang, Minghao; Alvarado, Judith Nano Letters, Vol. 17, Issue 12 https://doi.org/10.1021/acs.nanolett.7b03606	journal	November 2017
Electron ptychography of 2D materials to deep sub-ångström resolution Jiang, Yi; Chen, Zhen; Han, Yimo Nature, Vol. 559, Issue 7714 https://doi.org/10.1038/s41586-018-0298-5	journal	July 2018
Designing solid-liquid interphases for sodium batteries Choudhury, Snehashis; Wei, Shuya; Ozhabes, Yalcin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00742-x	journal	October 2017
In situ TEM observations of fast grain-boundary motion in stressed nanocrystalline aluminum films Legros, Marc; Gianola, Daniel S.; Hemker, Kevin J. Acta Materialia, Vol. 56, Issue 14 https://doi.org/10.1016/j.actamat.2008.03.032	journal	August 2008
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Low magnification differential phase contrast imaging of electric fields in crystals with fine electron probes Taplin, D. J.; Shibata, N.; Weyland, M. Ultramicroscopy, Vol. 169 https://doi.org/10.1016/j.ultramic.2016.07.010	journal	October 2016
Issues and challenges facing rechargeable lithium batteries Tarascon, J. -M.; Armand, M. Materials for Sustainable Energy https://doi.org/10.1142/9789814317665_0024	book	October 2010
Exciton Mapping at Subwavelength Scales in Two-Dimensional Materials Tizei, Luiz H. G.; Lin, Yung-Chang; Mukai, Masaki Physical Review Letters, Vol. 114, Issue 10 https://doi.org/10.1103/PhysRevLett.114.107601	journal	March 2015
On the origin of differential phase contrast at a locally charged and globally charge-compensated domain boundary in a polar-ordered material MacLaren, Ian; Wang, LiQiu; McGrouther, Damien Ultramicroscopy, Vol. 154 https://doi.org/10.1016/j.ultramic.2015.03.016	journal	July 2015
The direct determination of magnetic domain wall profiles by differential phase contrast electron microscopy Chapman, J. N.; Batson, P. E.; Waddell, E. M. Ultramicroscopy, Vol. 3 https://doi.org/10.1016/S0304-3991(78)80027-8	journal	January 1978
Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level Kim, Young-Min; He, Jun; Biegalski, Michael D. Nature Materials, Vol. 11, Issue 10 https://doi.org/10.1038/nmat3393	journal	August 2012
Quantitative measurement of mean inner potential and specimen thickness from high-resolution off-axis electron holograms of ultra-thin layered WSe 2 Winkler, Florian; Tavabi, Amir H.; Barthel, Juri Ultramicroscopy, Vol. 178 https://doi.org/10.1016/j.ultramic.2016.07.016	journal	July 2017
Inelastic Electron Scattering with Energy Losses in the meV-Region Geiger, J. Proceedings, annual meeting, Electron Microscopy Society of America, Vol. 39 https://doi.org/10.1017/S0424820100097545	journal	August 1981
Molecular Recognition at the Gas—Solid Interface: A Powerful Tool for Chemical Sensing Pirondini, Laura; Dalcanale, Enrico ChemInform, Vol. 38, Issue 31 https://doi.org/10.1002/chin.200731277	journal	July 2007
Atomic-Scale Chemical Imaging of Composition and Bonding by Aberration-Corrected Microscopy Muller, Da; Kourkoutis, Lf; Murfitt, M. Microscopy and Microanalysis, Vol. 14, Issue S2 https://doi.org/10.1017/s1431927608087448	journal	August 2008
Sample Tilt Effects on Atom Column Position Determination in ABF-STEM Imaging Zhou, Dan; Müller-Caspary, Knut; Sigle, Wilfried Microscopy and Microanalysis, Vol. 22, Issue S3 https://doi.org/10.1017/s1431927616005298	journal	July 2016
Plasmonics for improved photovoltaic devices Atwater, Harry A.; Polman, Albert Materials for Sustainable Energy https://doi.org/10.1142/9789814317665_0001	book	October 2010
Resonant Coupling between Molecular Vibrations and Localized Surface Plasmon Resonance of Faceted Metal Oxide Nanocrystals. Agrawal, Ankit; Singh, Ajay; Yazdi, Sadegh Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.30659	text	January 2017
On the origin of differential phase contrast at a locally charged and globally charge-compensated domain boundary in a polar-ordered material MacLaren, Ian; Wang, LiQiu; McGrouther, Damien RWTH Aachen University https://doi.org/10.18154/rwth-2015-06537	text	January 2015
In Situ Electron Energy-Loss Spectroscopy in Liquids Holtz, Megan E.; Yu, Yingchao; Gao, Jie arXiv https://doi.org/10.48550/arxiv.1212.1501	text	January 2012
Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte Holtz, Megan E.; Yu, Yingchao; Gunceler, Deniz arXiv https://doi.org/10.48550/arxiv.1311.6490	text	January 2013
Probing low-energy hyperbolic polaritons in van der Waals crystals with an electron microscope Govyadinov, Alexander A.; Konečná, Andrea; Chuvilin, Andrey arXiv https://doi.org/10.48550/arxiv.1611.05371	text	January 2016

Similar Records

Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials

Journal Article · 2019 · Angewandte Chemie · OSTI ID:1570539

Zachman, Michael J.; Hachtel, Jordan A.; Idrobo, Juan Carlos; +1 more

Emerging Electrochemical Techniques for Probing Site Behavior in Single-Atom Electrocatalysts

Journal Article · 2022 · Accounts of Chemical Research · OSTI ID:1865381

Jin, Zhaoyu; Li, Panpan; Fang, Zhiwei; +1 more

Identifying local structural states in atomic imaging by computer vision

Journal Article · 2016 · Advanced Structural and Chemical Imaging · OSTI ID:1330726

Laanait, Nouamane; Ziatdinov, Maxim; He, Qian; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials

Citation Formats

References (166)

Similar Records

Related Subjects