Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties

Park, Jaehyeung; Sharma, Jaswinder; Monaghan, Kyle W.; Meyer, III, Harry M.; Cullen, David A.; Rossy, Andres M.; Keum, Jong K.; Wood, III, David L.; Polizos, Georgios

doi:10.3390/nano10091682

Title: Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties

Abstract

The mechanical and thermal conductivity properties of two composite elastomers were studied. Styrene–butadiene rubber (SBR) filled with functionalized graphene oxide (GO) and silica nanofibers, and styrene–butadiene–styrene (SBS) block copolymers filled with graphene oxide. For the SBR composites, GO fillers with two different surface functionalities were synthesized (cysteamine and dodecylamine) and dispersed in the SBR using mechanical and liquid mixing techniques. The hydrophilic cysteamine-based GO fillers were dispersed in the SBR by mechanical mixing, whereas the hydrophobic dodecylamine-based GO fillers were dispersed in the SBR by liquid mixing. Silica nanofibers (SnFs) were fabricated by electrospinning a sol–gel precursor solution. The surface chemistry of the functionalized fillers was studied in detail. The properties of the composites and the synergistic improvements between the GO and SnFs are presented. For the SBS composites, GO fillers were dispersed in the SBS elastomer at several weight percent loadings using liquid mixing. Characterization of the filler material and the composite elastomers was performed using x-ray photoelectron spectroscopy, x-ray diffraction, transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis, dynamic mechanical analysis, tensile testing, nanoindentation, thermal conductivity and abrasion testing.

Authors:

; Sharma, Jaswinder; Monaghan, Kyle W.; Meyer, III, Harry M.; Cullen, David A.; Rossy, Andres M.;

;

Publication Date:: Thu Aug 27 00:00:00 EDT 2020

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; USDOE Office of Science (SC)

OSTI Identifier:: 1651162

Alternate Identifier(s):: OSTI ID: 1651306

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Published Article

Journal Name:: Nanomaterials

Additional Journal Information:: Journal Name: Nanomaterials Journal Volume: 10 Journal Issue: 9; Journal ID: ISSN 2079-4991

Publisher:: MDPI

Country of Publication:: Switzerland

Language:: English

Subject:: 36 MATERIALS SCIENCE; SBR composites; SBS composites; graphene oxide; silica nanofibers; mechanical properties; thermal conductivity

Citation Formats


                    Park, Jaehyeung, Sharma, Jaswinder, Monaghan, Kyle W., Meyer, III, Harry M., Cullen, David A., Rossy, Andres M., Keum, Jong K., Wood, III, David L., and Polizos, Georgios. Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties.  Switzerland: N. p., 2020. 
Web.  doi:10.3390/nano10091682.

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                    Park, Jaehyeung, Sharma, Jaswinder, Monaghan, Kyle W., Meyer, III, Harry M., Cullen, David A., Rossy, Andres M., Keum, Jong K., Wood, III, David L., & Polizos, Georgios. Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties.  Switzerland.  https://doi.org/10.3390/nano10091682

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                    Park, Jaehyeung, Sharma, Jaswinder, Monaghan, Kyle W., Meyer, III, Harry M., Cullen, David A., Rossy, Andres M., Keum, Jong K., Wood, III, David L., and Polizos, Georgios. Thu .  
"Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties".  Switzerland.  https://doi.org/10.3390/nano10091682.

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@article{osti_1651162,

  title        = {Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties},

  author       = {Park, Jaehyeung and Sharma, Jaswinder and Monaghan, Kyle W. and Meyer, III, Harry M. and Cullen, David A. and Rossy, Andres M. and Keum, Jong K. and Wood, III, David L. and Polizos, Georgios},

  abstractNote = {The mechanical and thermal conductivity properties of two composite elastomers were studied. Styrene–butadiene rubber (SBR) filled with functionalized graphene oxide (GO) and silica nanofibers, and styrene–butadiene–styrene (SBS) block copolymers filled with graphene oxide. For the SBR composites, GO fillers with two different surface functionalities were synthesized (cysteamine and dodecylamine) and dispersed in the SBR using mechanical and liquid mixing techniques. The hydrophilic cysteamine-based GO fillers were dispersed in the SBR by mechanical mixing, whereas the hydrophobic dodecylamine-based GO fillers were dispersed in the SBR by liquid mixing. Silica nanofibers (SnFs) were fabricated by electrospinning a sol–gel precursor solution. The surface chemistry of the functionalized fillers was studied in detail. The properties of the composites and the synergistic improvements between the GO and SnFs are presented. For the SBS composites, GO fillers were dispersed in the SBS elastomer at several weight percent loadings using liquid mixing. Characterization of the filler material and the composite elastomers was performed using x-ray photoelectron spectroscopy, x-ray diffraction, transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis, dynamic mechanical analysis, tensile testing, nanoindentation, thermal conductivity and abrasion testing.},

  doi          = {10.3390/nano10091682},

  journal      = {Nanomaterials},

  number       = 9,

  volume       = 10,

  place        = {Switzerland},

  year         = {Thu Aug 27 00:00:00 EDT 2020},

  month        = {Thu Aug 27 00:00:00 EDT 2020}

}

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Title: Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties

Abstract

Citation Formats

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Stiffness predictions for unidirectional short-fiber composites: Review and evaluation journal, April 1999

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Multifunctional Binding Chemistry on Modified Graphene Composite for Selective and Highly Efficient Adsorption of Mercury journal, December 2018

Graphene-induced tuning of the d -spacing of graphene oxide composite nanofiltration membranes for frictionless capillary action-induced enhancement of water permeability journal, January 2018

Click chemistry modified graphene oxide/styrene-butadiene rubber composites and molecular simulation study journal, April 2020

Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids journal, April 2014

Properties of a nanodielectric cryogenic resin journal, April 2010

High-concentration organic solutions of poly(styrene-co-butadiene-co-styrene)-modified graphene sheets exfoliated from graphite journal, September 2011

Fabrication of conductive elastic nanocomposites via framing intact interconnected graphene networks journal, August 2014

Rubber–filler interactions and rheological properties in filled compounds journal, May 2002

High Performance Graphene Oxide Based Rubber Composites journal, August 2013

Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices journal, August 2018

Studies of Reduced Graphene Oxide and Graphite Oxide in the Aspect of Their Possible Application in Gas Sensors journal, January 2016

Highly Sensitive Piezoresistive Graphene-Based Stretchable Composites for Sensing Applications journal, November 2019

Molecular pillar supported graphene oxide framework: conformational heterogeneity and tunable d-spacing journal, January 2015

Microstructural analysis and cis–trans isomerization of BR and SBR vulcanizates reinforced with silica and carbon black using NMR and IR journal, January 2014

Structural Evolution of Hydrothermally Derived Reduced Graphene Oxide journal, May 2018

An Elastic, Conductive, Electroactive Nanocomposite Binder for Flexible Sulfur Cathodes in Lithium-Sulfur Batteries
journal, September 2016

Liquid Exfoliation of Layered Materials
journal, June 2013

Stiffness predictions for unidirectional short-fiber composites: Review and evaluation
journal, April 1999

Simultaneous reduction and surface functionalization of graphene oxide by cystamine dihydrochloride for rubber composites
journal, July 2019

Graphene–Multilayer Graphene Nanocomposites as Highly Efficient Thermal Interface Materials
journal, January 2012

Tailoring the Oxygen Content of Graphite and Reduced Graphene Oxide for Specific Applications
journal, February 2016

Dielectric study of Poly(styrene- co -butadiene) Composites with Carbon Black, Silica, and Nanoclay
journal, August 2011

Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites
journal, August 2006

Graphite Nanoplatelet−Epoxy Composite Thermal Interface Materials
journal, May 2007

Functionalization and Reduction of Graphene Oxide with p -Phenylene Diamine for Electrically Conductive and Thermally Stable Polystyrene Composites
journal, March 2012

Micromechanics of short-fiber composites
journal, January 1992

Processing–Morphology–Property Relationships and Composite Theory Analysis of Reduced Graphene Oxide/Natural Rubber Nanocomposites
journal, July 2012

Graphene oxide induced crosslinking and reinforcement of elastomers
journal, May 2017

Effect of polymer–nanoparticle interactions on the glass transition dynamics and the conductivity mechanism in polyurethane titanium dioxide nanocomposites
journal, January 2012

Multifunctional properties of graphene/rubber nanocomposites fabricated by a modified latex compounding method
journal, July 2014

Simultaneous Reduction and Surface Functionalization of Graphene Oxide by Mussel-Inspired Chemistry
journal, November 2010

Novel low-cost hybrid composites from asphaltene/SBS tri-block copolymer with improved thermal and mechanical properties
journal, November 2015

Hybrid hollow silica particles: synthesis and comparison of properties with pristine particles
journal, January 2020

Targeted thiolation of graphene oxide and its utilization as precursor for graphene/silver nanoparticles composites
journal, September 2013

Graphene-Based Hybrid Composites for Efficient Thermal Management of Electronic Devices
journal, October 2015

Solution-derived monolithic thin films with low adhesion surface
journal, March 2020

Shape controlled spherical (0D) and rod-like (1D) silica nanoparticles in silica/styrene butadiene rubber nanocomposites: Role of the particle morphology on the filler reinforcing effect
journal, March 2014

Graphene-reinforced elastomeric nanocomposites: A review
journal, July 2018

Magadiite/styrene-butadiene rubber composites for tire tread applications: Effects of varying layer spacing and alternate inorganic fillers
journal, January 2017

Anti-soiling and highly transparent coatings with multi-scale features
journal, December 2018

Physical properties of epoxy resin/titanium dioxide nanocomposites
journal, August 2010

Resonance vibration of amorphous SiO2 nanowires driven by mechanical or electrical field excitation
journal, January 2003

Electrospinning silica/polyvinylpyrrolidone composite nanofibers
journal, May 2014

Rational Design of Graphene Surface Chemistry for High-Performance Rubber/Graphene Composites
journal, December 2014

Scalable superhydrophobic coatings based on fluorinated diatomaceous earth: Abrasion resistance versus particle geometry
journal, February 2014

Tear Strength of Styrene−Butadiene−Styrene Block Copolymers
journal, December 2001

Enhanced gas barrier properties of graphene oxide/rubber composites with strong interfaces constructed by graphene oxide and sulfur
journal, March 2020

Solution-Phase Synthesis of Silica Fibers and Their Use in Making Transparent High-Strength Silica-Polymer Composites
journal, December 2018

Cross-Linking with Diamine Monomers To Prepare Composite Graphene Oxide-Framework Membranes with Varying d -Spacing
journal, April 2014

The elasticity and strength of paper and other fibrous materials
journal, March 1952

Poly(2-hydroxyethyl acrylate) hydrogel confined in a hydrophobous porous matrix
journal, October 2004

Conductivity and mechanical properties of composites based on MWCNTs and styrene-butadiene-styrene block™ copolymers
journal, June 2009

Multifunctional Binding Chemistry on Modified Graphene Composite for Selective and Highly Efficient Adsorption of Mercury
journal, December 2018

Graphene-induced tuning of the d -spacing of graphene oxide composite nanofiltration membranes for frictionless capillary action-induced enhancement of water permeability
journal, January 2018

Click chemistry modified graphene oxide/styrene-butadiene rubber composites and molecular simulation study
journal, April 2020

Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids
journal, April 2014

Properties of a nanodielectric cryogenic resin
journal, April 2010

High-concentration organic solutions of poly(styrene-co-butadiene-co-styrene)-modified graphene sheets exfoliated from graphite
journal, September 2011

Fabrication of conductive elastic nanocomposites via framing intact interconnected graphene networks
journal, August 2014

Rubber–filler interactions and rheological properties in filled compounds
journal, May 2002

High Performance Graphene Oxide Based Rubber Composites
journal, August 2013

Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices
journal, August 2018

Studies of Reduced Graphene Oxide and Graphite Oxide in the Aspect of Their Possible Application in Gas Sensors
journal, January 2016

Highly Sensitive Piezoresistive Graphene-Based Stretchable Composites for Sensing Applications
journal, November 2019

Molecular pillar supported graphene oxide framework: conformational heterogeneity and tunable d-spacing
journal, January 2015

Microstructural analysis and cis–trans isomerization of BR and SBR vulcanizates reinforced with silica and carbon black using NMR and IR
journal, January 2014

Structural Evolution of Hydrothermally Derived Reduced Graphene Oxide
journal, May 2018