Insight into geometric preferences in uranium( vi ) mixed tris(imido) systems

Raghavan, Adharsh; Anderson, Nickolas H.; Tatebe, Caleb J.; Stanley, Dalton A.; Zeller, Matthias; Bart, Suzanne C.

doi:10.1039/D0CC03261A

Title: Insight into geometric preferences in uranium( vi ) mixed tris(imido) systems

Journal Article · Tue Sep 22 00:00:00 UTC 2020 · ChemComm

DOI: https://doi.org/10.1039/D0CC03261A · OSTI ID:1648382

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H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, USA

Uranium tris(imido) species have been synthesized using different imido groups in the axial and equatorial positions by treating [( ^Mes PDI ^Me )U(THF)] ₂ ( 1-THF ) – a uranium( iv ) dimer supported by ^Mes PDI ^Me tetraanions – with mixed organoazide solutions.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0008479

OSTI ID:: 1648382

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 75 Vol. 56; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (14)

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The Inverse Trans Influence in a Family of Pentavalent Uranium Complexes Lewis, Andrew J.; Mullane, Kimberly C.; Nakamaru-Ogiso, Eiko Inorganic Chemistry, Vol. 53, Issue 13 https://doi.org/10.1021/ic500833s	journal	June 2014
Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis Spencer, Liam P.; Yang, Ping; Scott, Brian L. Inorganic Chemistry, Vol. 48, Issue 6 https://doi.org/10.1021/ic802212m	journal	March 2009
Synthesis and Properties of High-Valent Organouranium Complexes Containing Terminal Organoimido and Oxo Functional Groups. A New Class of Organo-f-Element Complexes Arney, David S. J.; Burns, Carol J. Journal of the American Chemical Society, Vol. 117, Issue 37 https://doi.org/10.1021/ja00142a011	journal	September 1995
Synthesis and Reactivity of the Imido Analogues of the Uranyl Ion Hayton, Trevor W.; Boncella, James M.; Scott, Brian L. Journal of the American Chemical Society, Vol. 128, Issue 32 https://doi.org/10.1021/ja0629155	journal	August 2006
Exchange of an Imido Ligand in Bis(imido) Complexes of Uranium Hayton, Trevor W.; Boncella, James M.; Scott, Brian L. Journal of the American Chemical Society, Vol. 128, Issue 39 https://doi.org/10.1021/ja064400j	journal	October 2006
Synthesis and Characterization of an f-Block Terminal Parent Imido [U═NH] Complex: A Masked Uranium(IV) Nitride King, David M.; McMaster, Jonathan; Tuna, Floriana Journal of the American Chemical Society, Vol. 136, Issue 15 https://doi.org/10.1021/ja502405e	journal	April 2014
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Multi-electron reduction facilitated by a trianionic pyridine(diimine) ligand Cladis, Dennis P.; Kiernicki, John J.; Fanwick, Phillip E. Chem. Commun., Vol. 49, Issue 39 https://doi.org/10.1039/C2CC37193F	journal	January 2013
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