Iodosodalite synthesis with hot isostatic pressing of precursors produced from aqueous and hydrothermal processes
Abstract
Iodosodalite powders were synthesized using aqueous and hydrothermal methods, with or without sodium borosilicate glass binders, and then hot isostatically pressed (HIP) at 900 ? and 175 MPa for 3 h to convert into waste forms. After HIPing, the structures, compositions, morphologies, porosities, and leach rates of the aqueous and hydrothermally produced iodosodalite samples were compared. X-ray diffraction patterns of HIPed samples showed that iodosodalite remained as the dominant phase. However, the fraction of the iodosodalite phase decreased after HIPing, indicating decomposition of the iodosodalite structure during the HIP process. Scanning electron microscopy and chemical imaging on the cross sections of HIPed samples showed homogeneous elemental distribution for aqueous-grown iodosodalite, whereas hydrothermally grown iodosodalite samples had more heterogeneity and porosity. The densities of HIPed samples with more glass binder were generally higher than sampled HIPed without binder. The leach tests on samples containing 20 mass% glass binder showed that the iodine dissolution rate of HIPed hydrothermally grown iodosodalite was about 4 times higher than iodosodalite by aqueous method. This study provides alternative techniques for immobilizing iodine-streams in iodosodalite waste forms.
- Authors:
-
[1];
[2];
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State Univ., Pullman, WA (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Washington State Univ., Pullman, WA (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE)
- OSTI Identifier:
- 1638742
- Alternate Identifier(s):
- OSTI ID: 1702446
- Report Number(s):
- PNNL-SA-149138
Journal ID: ISSN 0022-3115; TRN: US2201814
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Nuclear Materials
- Additional Journal Information:
- Journal Volume: 538; Journal ID: ISSN 0022-3115
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; sodalite, iodosodalite, immobilization, hydothermal synthesis, aqueous synthesis
Citation Formats
Chong, Saehwa, Riley, Brian J., Asmussen, Robert M., Lawter, Amanda R., Bruffey, Stephanie, Nam, Junghune, McCloy, John S., and Crum, Jarrod V. Iodosodalite synthesis with hot isostatic pressing of precursors produced from aqueous and hydrothermal processes. United States: N. p., 2020.
Web. doi:10.1016/j.jnucmat.2020.152222.
Chong, Saehwa, Riley, Brian J., Asmussen, Robert M., Lawter, Amanda R., Bruffey, Stephanie, Nam, Junghune, McCloy, John S., & Crum, Jarrod V. Iodosodalite synthesis with hot isostatic pressing of precursors produced from aqueous and hydrothermal processes. United States. https://doi.org/10.1016/j.jnucmat.2020.152222
Chong, Saehwa, Riley, Brian J., Asmussen, Robert M., Lawter, Amanda R., Bruffey, Stephanie, Nam, Junghune, McCloy, John S., and Crum, Jarrod V. Tue .
"Iodosodalite synthesis with hot isostatic pressing of precursors produced from aqueous and hydrothermal processes". United States. https://doi.org/10.1016/j.jnucmat.2020.152222. https://www.osti.gov/servlets/purl/1638742.
@article{osti_1638742,
title = {Iodosodalite synthesis with hot isostatic pressing of precursors produced from aqueous and hydrothermal processes},
author = {Chong, Saehwa and Riley, Brian J. and Asmussen, Robert M. and Lawter, Amanda R. and Bruffey, Stephanie and Nam, Junghune and McCloy, John S. and Crum, Jarrod V.},
abstractNote = {Iodosodalite powders were synthesized using aqueous and hydrothermal methods, with or without sodium borosilicate glass binders, and then hot isostatically pressed (HIP) at 900 ? and 175 MPa for 3 h to convert into waste forms. After HIPing, the structures, compositions, morphologies, porosities, and leach rates of the aqueous and hydrothermally produced iodosodalite samples were compared. X-ray diffraction patterns of HIPed samples showed that iodosodalite remained as the dominant phase. However, the fraction of the iodosodalite phase decreased after HIPing, indicating decomposition of the iodosodalite structure during the HIP process. Scanning electron microscopy and chemical imaging on the cross sections of HIPed samples showed homogeneous elemental distribution for aqueous-grown iodosodalite, whereas hydrothermally grown iodosodalite samples had more heterogeneity and porosity. The densities of HIPed samples with more glass binder were generally higher than sampled HIPed without binder. The leach tests on samples containing 20 mass% glass binder showed that the iodine dissolution rate of HIPed hydrothermally grown iodosodalite was about 4 times higher than iodosodalite by aqueous method. This study provides alternative techniques for immobilizing iodine-streams in iodosodalite waste forms.},
doi = {10.1016/j.jnucmat.2020.152222},
journal = {Journal of Nuclear Materials},
number = ,
volume = 538,
place = {United States},
year = {Tue May 19 00:00:00 EDT 2020},
month = {Tue May 19 00:00:00 EDT 2020}
}
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