Perovskite-sensitized β-Ga2O3 nanorod arrays for highly selective and sensitive NO2 detection at high temperature
Abstract
Amongst various gaseous pollutants, NO2 is one of the major exhausts originating from fossil fuel and gas combustions in vehicle engines and power plants at high temperature. Under such a scenario, in situ and real-time gas detection and monitoring solutions are largely limited, which hinders the energy-efficient and resource-saving operations of these advanced energy systems. Herein, a new type of perovskite-sensitized β-Ga2O3 nanorod-array has been successfully fabricated to detect NOx at high temperature selectively and sensitively. The demonstrated gas sensors are highly sensitive to NO2 at 800 °C, with excellent reversible and reproducible response characteristics. Through the surface decoration of perovskite-type La0.8Sr0.2CoO3 (LSCO) nanoparticles, the sensitivity of β-Ga2O3 nanorod array gas sensors is enhanced by nearly an order of magnitude, along with much faster response dynamics. A remarkable selectivity toward oxidative gases was also demonstrated with the robust differentiation of NO2.
- Authors:
-
[2];
[1]
- Univ. of Connecticut, Storrs, CT (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1637486
- Alternate Identifier(s):
- OSTI ID: 1630167
- Report Number(s):
- BNL-216115-2020-JAAM
Journal ID: ISSN 2050-7488
- Grant/Contract Number:
- SC0012704; FE0026219; FE0000870; FE0011577; EE0008423
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 21; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Zhang, Bo, Lin, Hui-Jan, Gao, Haiyong, Lu, Xingxu, Nam, Chang-Yong, and Gao, Pu-Xian. Perovskite-sensitized β-Ga2O3 nanorod arrays for highly selective and sensitive NO2 detection at high temperature. United States: N. p., 2020.
Web. doi:10.1039/d0ta02691c.
Zhang, Bo, Lin, Hui-Jan, Gao, Haiyong, Lu, Xingxu, Nam, Chang-Yong, & Gao, Pu-Xian. Perovskite-sensitized β-Ga2O3 nanorod arrays for highly selective and sensitive NO2 detection at high temperature. United States. https://doi.org/10.1039/d0ta02691c
Zhang, Bo, Lin, Hui-Jan, Gao, Haiyong, Lu, Xingxu, Nam, Chang-Yong, and Gao, Pu-Xian. Wed .
"Perovskite-sensitized β-Ga2O3 nanorod arrays for highly selective and sensitive NO2 detection at high temperature". United States. https://doi.org/10.1039/d0ta02691c. https://www.osti.gov/servlets/purl/1637486.
@article{osti_1637486,
title = {Perovskite-sensitized β-Ga2O3 nanorod arrays for highly selective and sensitive NO2 detection at high temperature},
author = {Zhang, Bo and Lin, Hui-Jan and Gao, Haiyong and Lu, Xingxu and Nam, Chang-Yong and Gao, Pu-Xian},
abstractNote = {Amongst various gaseous pollutants, NO2 is one of the major exhausts originating from fossil fuel and gas combustions in vehicle engines and power plants at high temperature. Under such a scenario, in situ and real-time gas detection and monitoring solutions are largely limited, which hinders the energy-efficient and resource-saving operations of these advanced energy systems. Herein, a new type of perovskite-sensitized β-Ga2O3 nanorod-array has been successfully fabricated to detect NOx at high temperature selectively and sensitively. The demonstrated gas sensors are highly sensitive to NO2 at 800 °C, with excellent reversible and reproducible response characteristics. Through the surface decoration of perovskite-type La0.8Sr0.2CoO3 (LSCO) nanoparticles, the sensitivity of β-Ga2O3 nanorod array gas sensors is enhanced by nearly an order of magnitude, along with much faster response dynamics. A remarkable selectivity toward oxidative gases was also demonstrated with the robust differentiation of NO2.},
doi = {10.1039/d0ta02691c},
journal = {Journal of Materials Chemistry. A},
number = 21,
volume = 8,
place = {United States},
year = {Wed May 06 00:00:00 EDT 2020},
month = {Wed May 06 00:00:00 EDT 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 17 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Cr-doped TiO2 gas sensor for exhaust NO2 monitoring
journal, August 2003
- Ruiz, Ana M.; Sakai, Go; Cornet, Albert
- Sensors and Actuators B: Chemical, Vol. 93, Issue 1-3
Fabrication of SnO 2 –SnO nanocomposites with p–n heterojunctions for the low-temperature sensing of NO 2 gas
journal, January 2015
- Li, Lei; Zhang, Chunmei; Chen, Wei
- Nanoscale, Vol. 7, Issue 28
Ultraselective and sensitive detection of xylene and toluene for monitoring indoor air pollution using Cr-doped NiO hierarchical nanostructures
journal, January 2013
- Kim, Hyo-Joong; Yoon, Ji-Wook; Choi, Kwon-Il
- Nanoscale, Vol. 5, Issue 15
Monolithically Integrated Enhancement-Mode and Depletion-Mode β-Ga 2 O 3 MESFETs with Graphene-Gate Architectures and Their Logic Applications
journal, January 2020
- Kim, Janghyuk; Kim, Jihyun
- ACS Applied Materials & Interfaces, Vol. 12, Issue 6
Nanoscale metal oxide-based heterojunctions for gas sensing: A review
journal, December 2014
- Miller, Derek R.; Akbar, Sheikh A.; Morris, Patricia A.
- Sensors and Actuators B: Chemical, Vol. 204
High temperature Ga2O3-gas sensors and SnO2-gas sensors: a comparison
journal, August 2001
- Hoefer, Ulrich; Frank, Joachim; Fleischer, Maximilian
- Sensors and Actuators B: Chemical, Vol. 78, Issue 1-3
O2 and CO sensing of Ga2O3 multiple nanowire gas sensors
journal, February 2008
- Liu, Zhifu; Yamazaki, Toshinari; Shen, Yanbai
- Sensors and Actuators B: Chemical, Vol. 129, Issue 2
Shape Transformation and Surface Melting of Cubic and Tetrahedral Platinum Nanocrystals
journal, August 1998
- Wang, Zhong L.; Petroski, Janet M.; Green, Travis C.
- The Journal of Physical Chemistry B, Vol. 102, Issue 32
Porous CuO–ZnO nanocomposite for sensing electrode of high-temperature CO solid-state electrochemical sensor
journal, October 2005
- Wu, Nianqiang; Zhao, Minhua; Zheng, Jian-Guo
- Nanotechnology, Vol. 16, Issue 12
Wearable Gallium Oxide Solar-Blind Photodetectors on Muscovite Mica Having Ultrahigh Photoresponsivity and Detectivity with Added High-Temperature Functionalities
journal, October 2019
- Tak, Bhera Ram; Gupta, Vinay; Kapoor, Ashok Kumar
- ACS Applied Electronic Materials, Vol. 1, Issue 11
Ultrasensitive and low operating temperature NO2 gas sensor using nanosheets assembled hierarchical WO3 hollow microspheres
journal, October 2012
- You, L.; He, X.; Wang, D.
- Sensors and Actuators B: Chemical, Vol. 173
Metal Oxide Gas Sensors: Sensitivity and Influencing Factors
journal, March 2010
- Wang, Chengxiang; Yin, Longwei; Zhang, Luyuan
- Sensors, Vol. 10, Issue 3
High-temperature sensors for NO and NO2 based on stabilized zirconiaand spinel-type oxide electrodes
journal, January 1997
- Lu, Geyu; Miura, Norio; Yamazoe, Noboru
- Journal of Materials Chemistry, Vol. 7, Issue 8
Structure and magnetic properties of three-dimensional (La,Sr)MnO3 nanofilms on ZnO nanorod arrays
journal, March 2011
- Gao, Haiyong; Staruch, M.; Jain, Menka
- Applied Physics Letters, Vol. 98, Issue 12
High-temperature NO 2 sensor based on aluminum/indium co-doped lanthanum silicate oxyapatite electrolyte and cobalt-free perovskite oxide sensing electrode
journal, October 2017
- Dai, Lei; Shi, Ming; Han, Wen
- Sensors and Actuators B: Chemical, Vol. 250
Enhanced response characteristics of SnO2 thin film based NO2 gas sensor integrated with nanoscaled metal oxide clusters
journal, May 2013
- Sharma, Anjali; Tomar, Monika; Gupta, Vinay
- Sensors and Actuators B: Chemical, Vol. 181
FT-IR and TPD Investigation of the NO x Storage Properties of BaO/Al 2 O 3 and Pt−BaO/Al 2 O 3 Catalysts
journal, December 2001
- Prinetto, F.; Ghiotti, G.; Nova, I.
- The Journal of Physical Chemistry B, Vol. 105, Issue 51
The Role of Surface Oxygen Vacancies in the NO 2 Sensing Properties of SnO 2 Nanocrystals
journal, November 2008
- Epifani, Mauro; Prades, Joan Daniel; Comini, Elisabetta
- The Journal of Physical Chemistry C, Vol. 112, Issue 49
Nanotubular Cr-doped TiO 2 for use as high-temperature NO 2 gas sensor
journal, October 2015
- Gönüllü, Yakup; Haidry, Azhar Ali; Saruhan, Bilge
- Sensors and Actuators B: Chemical, Vol. 217
Perovskite Nanoparticle-Sensitized Ga 2 O 3 Nanorod Arrays for CO Detection at High Temperature
journal, April 2016
- Lin, Hui-Jan; Baltrus, John P.; Gao, Haiyong
- ACS Applied Materials & Interfaces, Vol. 8, Issue 14
Environmental Monitoring Systems: A Review
journal, April 2013
- Kumar, Anuj; Kim, Hiesik; Hancke, Gerhard P.
- IEEE Sensors Journal, Vol. 13, Issue 4
NOx sensors based on semiconducting metal oxide nanostructures: Progress and perspectives
journal, August 2012
- Afzal, Adeel; Cioffi, Nicola; Sabbatini, Luigia
- Sensors and Actuators B: Chemical, Vol. 171-172
?-Gallium Oxide as Oxygen Gas Sensors at a High Temperature
journal, September 2007
- Bartic, Marilena; Baban, Cristian-Ioan; Suzuki, Hisao
- Journal of the American Ceramic Society, Vol. 90, Issue 9
Flexible β-Ga 2 O 3 Nanomembrane Schottky Barrier Diodes
journal, January 2019
- Swinnich, Edward; Hasan, Md Nazmul; Zeng, Ke
- Advanced Electronic Materials, Vol. 5, Issue 3
Heterovalent ions incorporated pyrochlore Sm2Zr2O7 ceramic for enhanced NO2 sensing
journal, August 2020
- Zheng, Yong; Duan, Pei; Li, Zhiyu
- Journal of the European Ceramic Society, Vol. 40, Issue 9
High-temperature NO2 gas sensor based on stabilized zirconia and CoTa2O6 sensing electrode
journal, March 2017
- Liu, Fangmeng; Wang, Bin; Yang, Xue
- Sensors and Actuators B: Chemical, Vol. 240
Solid electrolyte based sensors for the measurement of CO and hydrocarbon gases
journal, March 2007
- Fergus, Jeffrey W.
- Sensors and Actuators B: Chemical, Vol. 122, Issue 2
SnO 2 Nanoslab as NO 2 Sensor: Identification of the NO 2 Sensing Mechanism on a SnO 2 Surface
journal, December 2013
- Maeng, Sunglyul; Kim, Sang-Woo; Lee, Deuk-Hee
- ACS Applied Materials & Interfaces, Vol. 6, Issue 1
Superconducting Double Perovskite Bismuth Oxide Prepared by a Low-Temperature Hydrothermal Reaction
journal, February 2014
- Rubel, Mirza H. K.; Miura, Akira; Takei, Takahiro
- Angewandte Chemie International Edition, Vol. 53, Issue 14
High sensitivity and selectivity of mixed potential sensor based on Pt/YSZ/SmFeO3 to NO2 gas
journal, July 2013
- Giang, Ho Truong; Duy, Ha Thai; Ngan, Pham Quang
- Sensors and Actuators B: Chemical, Vol. 183
Single-crystalline Sb-doped SnO2 nanowires: synthesis and gas sensor application
journal, January 2005
- Wan, Q.; Wang, T. H.
- Chemical Communications, Issue 30
Ultrahigh-Responsivity, Rapid-Recovery, Solar-Blind Photodetector Based on Highly Nonstoichiometric Amorphous Gallium Oxide
journal, August 2017
- Qian, Ling-Xuan; Wu, Ze-Han; Zhang, Yi-Yu
- ACS Photonics, Vol. 4, Issue 9
Gas sensor network for air-pollution monitoring
journal, October 2005
- Tsujita, Wataru; Yoshino, Akihito; Ishida, Hiroshi
- Sensors and Actuators B: Chemical, Vol. 110, Issue 2
Oxygen sensing properties at high temperatures of β-Ga2O3 thin films deposited by the chemical solution deposition method
journal, July 2007
- Bartic, Marilena; Ogita, Masami; Isai, Masaaki
- Journal of Applied Physics, Vol. 102, Issue 2
Suspended GaN nanowires as NO2 sensor for high temperature applications
journal, January 2013
- Sim, Jaesam; Kim, Kwanoh; Song, Soonho
- The Analyst, Vol. 138, Issue 8
Perovskite oxides for semiconductor-based gas sensors
journal, May 2007
- Fergus, Jeffrey W.
- Sensors and Actuators B: Chemical, Vol. 123, Issue 2
Surface Morphology-Dependent Room-Temperature LaFeO 3 Nanostructure Thin Films as Selective NO 2 Gas Sensor Prepared by Radio Frequency Magnetron Sputtering
journal, July 2014
- Thirumalairajan, S.; Girija, K.; Mastelaro, Valmor R.
- ACS Applied Materials & Interfaces, Vol. 6, Issue 16
The role of gold catalyst on the sensing behavior of ZnO nanorods for CO and NO2 gases
journal, April 2012
- Rai, Prabhakar; Kim, Yun-Su; Song, Hyeon-Min
- Sensors and Actuators B: Chemical, Vol. 165, Issue 1
A large-energy-gap oxide topological insulator based on the superconductor BaBiO3
journal, September 2013
- Yan, Binghai; Jansen, Martin; Felser, Claudia
- Nature Physics, Vol. 9, Issue 11
β -Ga 2 O 3 for wide-bandgap electronics and optoelectronics
journal, October 2018
- Galazka, Zbigniew
- Semiconductor Science and Technology, Vol. 33, Issue 11
Oxyanions in perovskites: from superconductors to solid oxide fuel cells
journal, January 2015
- Hancock, C. A.; Porras-Vazquez, J. M.; Keenan, P. J.
- Dalton Transactions, Vol. 44, Issue 23
Solid-state gas sensors for high temperature applications – a review
journal, January 2014
- Liu, Yixin; Parisi, Joseph; Sun, Xiangcheng
- J. Mater. Chem. A, Vol. 2, Issue 26
Free-standing ZnO–CuO composite nanowire array films and their gas sensing properties
journal, July 2011
- Wang, J. X.; Sun, X. W.; Yang, Y.
- Nanotechnology, Vol. 22, Issue 32
Urban pollution and solar radiation impacts
journal, May 2016
- Khodakarami, Jamal; Ghobadi, Parisa
- Renewable and Sustainable Energy Reviews, Vol. 57
Needle-like Zn-doped SnO 2 nanorods with enhanced photocatalytic and gas sensing properties
journal, February 2012
- Huang, Hongtao; Tian, Shouqin; Xu, Jing
- Nanotechnology, Vol. 23, Issue 10
Impedancemetric gas sensor based on zirconia solid electrolyte and oxide sensing electrode for detecting total NOx at high temperature
journal, August 2003
- Miura, Norio; Nakatou, Mitsunobu; Zhuiykov, Serge
- Sensors and Actuators B: Chemical, Vol. 93, Issue 1-3, p. 221-228
Materials for high temperature electrochemical applications: Automotive sensors, catalysts and traps
journal, October 2013
- Tuller, Harry L.
- Sensors and Actuators B: Chemical, Vol. 187
Gas sensing properties of p-type semiconducting Cr-doped TiO2 thin films
journal, March 2002
- Li, Yongxiang; Wlodarski, Wojtek; Galatsis, Kosmas
- Sensors and Actuators B: Chemical, Vol. 83, Issue 1-3
YSZ-based NO2 sensor utilizing hierarchical In2O3 electrode
journal, January 2016
- Liu, Fangmeng; Guan, Yehui; Sun, Hongbin
- Sensors and Actuators B: Chemical, Vol. 222
SnO2 thin film sensor with enhanced response for NO2 gas at lower temperatures
journal, August 2011
- Sharma, Anjali; Tomar, Monika; Gupta, Vinay
- Sensors and Actuators B: Chemical, Vol. 156, Issue 2
Highly sensitive NO 2 sensors based on local p-n heterojunctions composed of 0D CuO nanoparticles and 1D ZnO nanorods: Highly sensitive NO 2 sensors
journal, February 2013
- Hoa, Le Thuy; Hur, Seung Hyun
- physica status solidi (a), Vol. 210, Issue 6
Modulating Gas Sensing Properties of CuO Nanowires through Creation of Discrete Nanosized p–n Junctions on Their Surfaces
journal, July 2012
- Mashock, Mark; Yu, Kehan; Cui, Shumao
- ACS Applied Materials & Interfaces, Vol. 4, Issue 8
High temperature amperometric NO2 sensor based on nano-structured Gd0.2Sr0.8FeO3−δ prepared by impregnating method
journal, January 2014
- Wang, Ling; Wang, Yunfei; Dai, Lei
- Journal of Alloys and Compounds, Vol. 583
Low-Field Magnetoresistance in La0.67Sr0.33MnO3:ZnO Composite Film
journal, May 2012
- Staruch, Margo; Gao, Haiyong; Gao, Pu-Xian
- Advanced Functional Materials, Vol. 22, Issue 17
Enhanced Gas Sensing by Individual SnO 2 Nanowires and Nanobelts Functionalized with Pd Catalyst Particles
journal, April 2005
- Kolmakov, A.; Klenov, D. O.; Lilach, Y.
- Nano Letters, Vol. 5, Issue 4
Au@Cu 2 O core–shell nanoparticles as chemiresistors for gas sensor applications: effect of potential barrier modulation on the sensing performance
journal, January 2014
- Rai, Prabhakar; Khan, Rizwan; Raj, Sudarsan
- Nanoscale, Vol. 6, Issue 1
Materials for high temperature electrochemical NOx gas sensors
journal, February 2007
- Fergus, J.
- Sensors and Actuators B: Chemical, Vol. 121, Issue 2
Au-modified three-dimensional In 2 O 3 inverse opals: synthesis and improved performance for acetone sensing toward diagnosis of diabetes
journal, January 2015
- Xing, Ruiqing; Li, Qingling; Xia, Lei
- Nanoscale, Vol. 7, Issue 30
CO-Sensor for domestic use based on high temperature stable Ga2O3 thin films
journal, June 1998
- Schwebel, T.; Fleischer, M.; Meixner, H.
- Sensors and Actuators B: Chemical, Vol. 49, Issue 1-2
Automotive catalytic converters: current status and some perspectives
journal, January 2003
- Kašpar, Jan; Fornasiero, Paolo; Hickey, Neal
- Catalysis Today, Vol. 77, Issue 4
Effect of Growth Pressure on PLD‐Deposited Gallium Oxide Thin Films for Deep‐UV Photodetectors
journal, August 2019
- Blumenschein, Nicholas; Paskova, Tania; Muth, John F.
- physica status solidi (a), Vol. 216, Issue 20
Ultrasensitive multiple networked Ga2O3-core/ZnO-shell nanorod gas sensors
journal, January 2012
- Jin, Changhyun; Park, Sunghoon; Kim, Hyunsu
- Sensors and Actuators B: Chemical, Vol. 161, Issue 1
Oxygen sensors based on semiconducting metal oxides: an overview
journal, June 2000
- Xu, Yulong; Zhou, Xiaohua; Sorensen, O. Toft
- Sensors and Actuators B: Chemical, Vol. 65, Issue 1-3