DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Heated Tobacco Products: Volatile Emissions and Their Predicted Impact on Indoor Air Quality

Journal Article · · Environmental Science and Technology
 [1]; ORCiD logo [2];  [3];  [3];  [4];  [5];  [3]; ORCiD logo [3]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); National Commission of Atomic Energy (CNEA)-CONICET, Buenos Aires (Argentina)
  2. Univ. Clermont Auvergne (France)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  4. National Commission of Atomic Energy (CNEA)-CONICET, Buenos Aires (Argentina); Centro Tecnologías Químicas, FRBA-UTN, Caba (Argentina)
  5. National Commission of Atomic Energy (CNEA)-CONICET, Buenos Aires (Argentina); Univ. de General San Martin, Buenos Aires (Argentina)

This study characterized emissions from IQOS, a heated tobacco product promoted as a less harmful alternative to cigarettes. Consumable tobacco plugs were analyzed by headspace GC/MS to assess the influence of heating temperature on the emission profile. Yields of major chemical constituents increased from 4.1 mg per unit at 180 °C to 6.2 mg at 200 °C, and 10.5 mg at 220 °C. The Health Canada Intense smoking regime was used to operate IQOS in an environmental chamber, quantifying 33 volatile organic compounds in mainstream and sidestream emissions. Aldehydes, nitrogenated species, and aromatic species were found, along with other harmful and potentially harmful compounds. Compared with combustion cigarettes, IQOS yields were in most cases 1-2 orders of magnitude lower. However, yields were closer to, and sometimes higher than electronic cigarettes. Predicted users' daily average intake of benzene, formaldehyde, acetaldehyde and acrolein were 39 μg, 32 μg, 2.2 mg and 71 μg, respectively. Indoor air concentrations were estimated for commonly encountered scenarios, with acrolein levels of concern (over 0.35 μg m-3) derived from IQOS used in homes and public spaces. Heated tobacco products are shown to be a weaker indoor pollution source than conventional cigarettes, but their impacts are neither negligible nor yet fully understood.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC); University of California Tobacco-Related Disease Research Program (TRDRP); Agencia Nacional de Promocioń Cientifíca y Tecnoloǵica (ANPCyT)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1637293
Journal Information:
Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 13 Vol. 53; ISSN 0013-936X
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (44)

Heat-Not-Burn Tobacco Cigarettes: Smoke by Any Other Name journal July 2017
Determination of toxic carbonyl compounds in cigarette smoke journal January 2006
Levels of selected analytes in the emissions of “heat not burn” tobacco products that are relevant to assess human health risks journal May 2018
Self-titration by experienced e-cigarette users: blood nicotine delivery and subjective effects journal May 2016
The chemical composition of environmental tobacco smoke III. Identification of conservative tracers of environmental tobacco smoke journal January 1989
Smoker Awareness of and Beliefs About Supposedly Less-Harmful Tobacco Products journal August 2005
Reaction kinetics and pathways for phytol in high-temperature water journal May 2012
A review of the impacts of tobacco heating system on indoor air quality versus conventional pollution sources journal September 2018
Impacts of exhaled aerosol from the usage of the tobacco heating system to indoor air quality: A chamber study journal May 2019
Second-hand smoke generated by combustion and electronic smoking devices used in real scenarios: Ultrafine particle pollution and age-related dose assessment journal October 2017
Characterization of airborne particles emitted by an electrically heated tobacco smoking system journal September 2018
Comparison of the impact of the Tobacco Heating System 2.2 and a cigarette on indoor air quality journal October 2016
Evaluation of the Tobacco Heating System 2.2. Part 1: Description of the system and the scientific assessment program journal November 2016
Evaluation of the Tobacco Heating System 2.2. Part 2: Chemical composition, genotoxicity, cytotoxicity, and physical properties of the aerosol journal November 2016
Comparative assessment of HPHC yields in the Tobacco Heating System THS2.2 and commercial cigarettes journal November 2017
Simple Determination of Gaseous and Particulate Compounds Generated from Heated Tobacco Products journal June 2018
Emissions from Electronic Cigarettes: Key Parameters Affecting the Release of Harmful Chemicals journal July 2016
Emissions from Electronic Cigarettes: Assessing Vapers’ Intake of Toxic Compounds, Secondhand Exposures, and the Associated Health Impacts journal July 2017
Chemical composition of environmental tobacco smoke. 2. Particulate-phase compounds journal June 1989
Inhalable Constituents of Thirdhand Tobacco Smoke: Chemical Characterization and Health Impact Considerations journal October 2014
An evaluation of the indoor air quality in bars before and after a smoking ban in Austin, Texas journal June 2006
Solvent Chemistry in the Electronic Cigarette Reaction Vessel journal February 2017
Gas Chromatographic Determination of Neophytadiene as a Measure of the Terpenoid Contribution to Experimental Tobacco Smoke Carcinogenesis journal January 1975
Environmental pollution and emission factors of electronic cigarettes, heat-not-burn tobacco products, and conventional cigarettes journal March 2017
A New Method for Estimating the Retention of Selected Smoke Constituents in the Respiratory Tract of Smokers During Cigarette Smoking journal January 2007
A quantitative study of the influence of inhaled compounds on their concentrations in exhaled breath journal February 2013
Secondhand Exposure to Vapors From Electronic Cigarettes journal December 2013
Compensatory Puffing With Lower Nicotine Concentration E-liquids Increases Carbonyl Exposure in E-cigarette Aerosols journal July 2017
Chemical Analysis and Simulated Pyrolysis of Tobacco Heating System 2.2 Compared to Conventional Cigarettes journal January 2018
Free-Base and Total Nicotine, Reactive Oxygen Species, and Carbonyl Emissions From IQOS, a Heated Tobacco Product journal November 2018
Carbonyl emissions from a novel heated tobacco product (IQOS): comparison with an e-cigarette and a tobacco cigarette: Carbonyl emissions in heated tobacco product journal July 2018
Residential air exchange rates in three major US metropolitan areas: results from the Relationship Among Indoor, Outdoor, and Personal Air Study 1999–2001 journal February 2010
Thirdhand smoke uptake to aerosol particles in the indoor environment journal May 2018
Relationship between chemical structure and the occupational asthma hazard of low molecular weight organic compounds journal April 2005
Levels of selected carcinogens and toxicants in vapour from electronic cigarettes journal March 2013
iQOS: evidence of pyrolysis and release of a toxicant from plastic journal March 2018
IQOS: examination of Philip Morris International’s claim of reduced exposure journal August 2018
Heat-not-burn tobacco products: a systematic literature review journal September 2018
Thirdhand Tobacco Smoke: Emerging Evidence and Arguments for a Multidisciplinary Research Agenda journal September 2011
Puffing Topography and Nicotine Intake of Electronic Cigarette Users journal February 2015
Self-titration by experienced e-cigarette users: blood nicotine delivery and subjective effects dataset January 2018
Determination of Carbonyl Compounds in Exhaled Cigarette Smoke journal June 2007
Methodologies for the quantitative estimation of toxicant dose to cigarette smokers using physical, chemical and bioanalytical data journal June 2013
Comparison of Chemicals in Mainstream Smoke in Heat-not-burn Tobacco and Combustion Cigarettes [加熱式タバコと燃焼式タバコの主流煙中に含まれる有害成分の比較] journal January 2017

Cited By (2)

Heated Tobacco Products: A Review of Current Knowledge and Initial Assessments journal October 2019
Heated Tobacco Products: A Review of Current Knowledge and Initial Assessments journal October 2019