DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Influence of polymeric binders on mechanical properties and microstructure evolution of silicon composite electrodes during electrochemical cycling

Authors:
ORCiD logo; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1636531
Grant/Contract Number:  
EE0007787
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Name: Journal of Power Sources Journal Volume: 425 Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
Netherlands
Language:
English

Citation Formats

Wang, Yikai, Dang, Dingying, Li, Dawei, Hu, Jiazhi, and Cheng, Yang-Tse. Influence of polymeric binders on mechanical properties and microstructure evolution of silicon composite electrodes during electrochemical cycling. Netherlands: N. p., 2019. Web. doi:10.1016/j.jpowsour.2019.04.006.
Wang, Yikai, Dang, Dingying, Li, Dawei, Hu, Jiazhi, & Cheng, Yang-Tse. Influence of polymeric binders on mechanical properties and microstructure evolution of silicon composite electrodes during electrochemical cycling. Netherlands. https://doi.org/10.1016/j.jpowsour.2019.04.006
Wang, Yikai, Dang, Dingying, Li, Dawei, Hu, Jiazhi, and Cheng, Yang-Tse. Sat . "Influence of polymeric binders on mechanical properties and microstructure evolution of silicon composite electrodes during electrochemical cycling". Netherlands. https://doi.org/10.1016/j.jpowsour.2019.04.006.
@article{osti_1636531,
title = {Influence of polymeric binders on mechanical properties and microstructure evolution of silicon composite electrodes during electrochemical cycling},
author = {Wang, Yikai and Dang, Dingying and Li, Dawei and Hu, Jiazhi and Cheng, Yang-Tse},
abstractNote = {},
doi = {10.1016/j.jpowsour.2019.04.006},
journal = {Journal of Power Sources},
number = C,
volume = 425,
place = {Netherlands},
year = {Sat Jun 01 00:00:00 EDT 2019},
month = {Sat Jun 01 00:00:00 EDT 2019}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.jpowsour.2019.04.006

Citation Metrics:
Cited by: 39 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency
journal, October 2016


Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices
journal, August 2018


The emerging era of supramolecular polymeric binders in silicon anodes
journal, January 2018

  • Kwon, Tae-woo; Choi, Jang Wook; Coskun, Ali
  • Chemical Society Reviews, Vol. 47, Issue 6
  • DOI: 10.1039/C7CS00858A

Microstructural degradation of silicon electrodes during lithiation observed via operando X-ray tomographic imaging
journal, February 2017


Investigation of cycling-induced microstructural degradation in silicon-based electrodes in lithium-ion batteries using X-ray nanotomography
journal, November 2017


Stress evolution in elastic-plastic electrodes during electrochemical processes: A numerical method and its applications
journal, July 2018


Electrode Side Reactions, Capacity Loss and Mechanical Degradation in Lithium-Ion Batteries
journal, January 2015

  • Xu, Jiagang; Deshpande, Rutooj D.; Pan, Jie
  • Journal of The Electrochemical Society, Vol. 162, Issue 10
  • DOI: 10.1149/2.0291510jes

Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation
journal, August 2011

  • Liu, Xiao Hua; Zheng, He; Zhong, Li
  • Nano Letters, Vol. 11, Issue 8, p. 3312-3318
  • DOI: 10.1021/nl201684d

Unveiling the Critical Role of Polymeric Binders for Silicon Negative Electrodes in Lithium-Ion Full Cells
journal, January 2017

  • Xu, Jiagang; Zhang, Long; Wang, Yikai
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 4
  • DOI: 10.1021/acsami.6b11121

Size-Dependent Fracture of Silicon Nanoparticles During Lithiation
journal, January 2012

  • Liu, Xiao Hua; Zhong, Li; Huang, Shan
  • ACS Nano, Vol. 6, Issue 2
  • DOI: 10.1021/nn204476h

Engineering Empty Space between Si Nanoparticles for Lithium-Ion Battery Anodes
journal, January 2012

  • Wu, Hui; Zheng, Guangyuan; Liu, Nian
  • Nano Letters, Vol. 12, Issue 2
  • DOI: 10.1021/nl203967r

The influence of surface mechanics on diffusion induced stresses within spherical nanoparticles
journal, October 2008

  • Cheng, Yang-Tse; Verbrugge, Mark W.
  • Journal of Applied Physics, Vol. 104, Issue 8
  • DOI: 10.1063/1.3000442

Crossed carbon skeleton enhances the electrochemical performance of porous silicon nanowires for lithium ion battery anode
journal, August 2018


Modeling diffusion-induced stress in nanowire electrode structures
journal, August 2010


Chemically stable artificial SEI for Li-ion battery electrodes
journal, March 2017

  • Zhang, Qinglin; Han, Lei; Pan, Jie
  • Applied Physics Letters, Vol. 110, Issue 13
  • DOI: 10.1063/1.4979108

Systematic Investigation of the Alucone-Coating Enhancement on Silicon Anodes
journal, November 2017

  • Son, Seoung-Bum; Wang, Yikai; Xu, Jiagang
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 46
  • DOI: 10.1021/acsami.7b08960

Molecular Layer Deposition for Surface Modification of Lithium-Ion Battery Electrodes
journal, October 2016


Reversible High-Capacity Si Nanocomposite Anodes for Lithium-ion Batteries Enabled by Molecular Layer Deposition
journal, December 2013

  • Piper, Daniela Molina; Travis, Jonathan J.; Young, Matthias
  • Advanced Materials, Vol. 26, Issue 10
  • DOI: 10.1002/adma.201304714

Effect of Binder Architecture on the Performance of Silicon/Graphite Composite Anodes for Lithium Ion Batteries
journal, January 2018

  • Cao, Peng-Fei; Naguib, Michael; Du, Zhijia
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 4
  • DOI: 10.1021/acsami.7b13205

High-capacity Si–graphite composite electrodes with a self-formed porous structure by a partially neutralized polyacrylate for Li-ion batteries
journal, January 2012

  • Han, Zhen-Ji; Yabuuchi, Naoaki; Shimomura, Keiji
  • Energy & Environmental Science, Vol. 5, Issue 10
  • DOI: 10.1039/c2ee22292b

Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid
journal, October 2010

  • Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 11
  • DOI: 10.1021/am100871y

Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries
journal, July 2017


Effects of adhesion and cohesion on the electrochemical performance and durability of silicon composite electrodes
journal, September 2018


Mussel-Inspired Adhesive Binders for High-Performance Silicon Nanoparticle Anodes in Lithium-Ion Batteries
journal, December 2012

  • Ryou, Myung-Hyun; Kim, Jangbae; Lee, Inhwa
  • Advanced Materials, Vol. 25, Issue 11
  • DOI: 10.1002/adma.201203981

Sodium Carboxymethyl Cellulose
journal, January 2007

  • Li, Jing; Lewis, R. B.; Dahn, J. R.
  • Electrochemical and Solid-State Letters, Vol. 10, Issue 2
  • DOI: 10.1149/1.2398725

Study of styrene butadiene rubber and sodium methyl cellulose as binder for negative electrodes in lithium-ion batteries
journal, October 2006


Understanding Polyacrylic Acid and Lithium Polyacrylate Binder Behavior in Silicon Based Electrodes for Li-Ion Batteries
journal, January 2017

  • Porcher, W.; Chazelle, S.; Boulineau, A.
  • Journal of The Electrochemical Society, Vol. 164, Issue 14
  • DOI: 10.1149/2.0821714jes

Natural karaya gum as an excellent binder for silicon-based anodes in high-performance lithium-ion batteries
journal, January 2017

  • Bie, Yitian; Yang, Jun; Nuli, Yanna
  • Journal of Materials Chemistry A, Vol. 5, Issue 5
  • DOI: 10.1039/C6TA09522D

High Capacity Silicon Electrodes with Nafion as Binders for Lithium-Ion Batteries
journal, December 2015

  • Xu, Jiagang; Zhang, Qinglin; Cheng, Yang-Tse
  • Journal of The Electrochemical Society, Vol. 163, Issue 3
  • DOI: 10.1149/2.0261603jes

A Facile and Very Effective Method to Enhance the Mechanical Strength and the Cyclability of Si-Based Electrodes for Li-Ion Batteries
journal, October 2017

  • Hernandez, Cuauhtémoc Reale; Etiemble, Aurélien; Douillard, Thierry
  • Advanced Energy Materials, Vol. 8, Issue 6
  • DOI: 10.1002/aenm.201701787

A review on modeling of electro-chemo-mechanics in lithium-ion batteries
journal, February 2019


Constitutive behavior and progressive mechanical failure of electrodes in lithium-ion batteries
journal, July 2017


Ex-situ depth-sensing indentation measurements of electrochemically produced Si–Li alloy films
journal, August 2011


Elastic softening of amorphous and crystalline Li–Si Phases with increasing Li concentration: A first-principles study
journal, October 2010


Operando Nanoindentation: A New Platform to Measure the Mechanical Properties of Electrodes during Electrochemical Reactions
journal, January 2017

  • de Vasconcelos, Luize Scalco; Xu, Rong; Zhao, Kejie
  • Journal of The Electrochemical Society, Vol. 164, Issue 14
  • DOI: 10.1149/2.1411714jes

Structure and Properties of Li−Si Alloys: A First-Principles Study
journal, December 2010

  • Kim, Hyunwoo; Chou, Chia-Yun; Ekerdt, John G.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 5
  • DOI: 10.1021/jp1083899

Examining Solid Electrolyte Interphase Formation on Crystalline Silicon Electrodes: Influence of Electrochemical Preparation and Ambient Exposure Conditions
journal, September 2012

  • Schroder, Kjell W.; Celio, Hugo; Webb, Lauren J.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp307372m

Effect of impurities and moisture on lithium bisoxalatoborate (LiBOB) electrolyte performance in lithium-ion cells
journal, March 2010


Electronic Origin for the Phase Transition from Amorphous Li x Si to Crystalline Li 15 Si 4
journal, June 2013

  • Gu, Meng; Wang, Zhiguo; Connell, Justin G.
  • ACS Nano, Vol. 7, Issue 7
  • DOI: 10.1021/nn402349j

Mechanical Property Evolution of Silicon Composite Electrodes Studied by Environmental Nanoindentation
journal, January 2018

  • Wang, Yikai; Zhang, Qinglin; Li, Dawei
  • Advanced Energy Materials, Vol. 8, Issue 10
  • DOI: 10.1002/aenm.201702578

A nanoindentation study of the viscoplastic behavior of pure lithium
journal, March 2017


An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

  • Oliver, W. C.; Pharr, G. M.
  • Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583
  • DOI: 10.1557/JMR.1992.1564

Stress-Strain Curves of Nafion Membranes in Acid and Salt Forms
journal, January 2002


Imaging of 3D morphological evolution of nanoporous silicon anode in lithium ion battery by X-ray nano-tomography
journal, October 2018


Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model
journal, January 2014

  • Radvanyi, Etienne; Porcher, Willy; De Vito, Eric
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 32
  • DOI: 10.1039/C4CP02324B

The failure mechanism of nano-sized Si-based negative electrodes for lithium ion batteries
journal, January 2011

  • Oumellal, Y.; Delpuech, N.; Mazouzi, D.
  • Journal of Materials Chemistry, Vol. 21, Issue 17
  • DOI: 10.1039/c1jm10213c