Silicon Microwire Arrays for Solar Energy-Conversion Applications
Abstract
Highly structured silicon microwire (Si MW) arrays have been synthesized and characterized as absorbers for solar energy-conversion systems. These materials are of great interest for applications in solar energy conversion, including solar electricity and solar fuels production, due to their unique materials properties, form factors, ease of fabrication, and device processing attributes. The Si MW array geometry allows for efficient collection of photogenerated carriers from impure materials that have short minority-carrier diffusion lengths, while simultaneously allowing for high optical absorption and high external quantum yields for charge carrier collection. In addition, Si MW arrays exhibit unique mesoscale optical behavior and can be removed from the growth substrate to provide flexible, processable arrays of Si microwires ordered in a variety of organic polymers and ionomers. The unique photon management properties of Si MW arrays, combined with their high internal surface area and controlled morphology for catalyst placement and support, allow for the use of earth-abundant electrocatalysts to produce an integrated, functional photoelectrode. Furthermore, these materials therefore also provide an opportunity to explore the 3-dimensional photoelectrochemical behavior of fuel-forming microstructured electrodes.
- Authors:
-
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Publication Date:
- Research Org.:
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1634125
- Grant/Contract Number:
- SC0004993; FG02-03-ER15483
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 118; Journal Issue: 2; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 30 DIRECT ENERGY CONVERSION; catalysts; wires; silicon; absorption; materials
Citation Formats
Warren, Emily L., Atwater, Harry A., and Lewis, Nathan S. Silicon Microwire Arrays for Solar Energy-Conversion Applications. United States: N. p., 2013.
Web. doi:10.1021/jp406280x.
Warren, Emily L., Atwater, Harry A., & Lewis, Nathan S. Silicon Microwire Arrays for Solar Energy-Conversion Applications. United States. https://doi.org/10.1021/jp406280x
Warren, Emily L., Atwater, Harry A., and Lewis, Nathan S. Mon .
"Silicon Microwire Arrays for Solar Energy-Conversion Applications". United States. https://doi.org/10.1021/jp406280x. https://www.osti.gov/servlets/purl/1634125.
@article{osti_1634125,
title = {Silicon Microwire Arrays for Solar Energy-Conversion Applications},
author = {Warren, Emily L. and Atwater, Harry A. and Lewis, Nathan S.},
abstractNote = {Highly structured silicon microwire (Si MW) arrays have been synthesized and characterized as absorbers for solar energy-conversion systems. These materials are of great interest for applications in solar energy conversion, including solar electricity and solar fuels production, due to their unique materials properties, form factors, ease of fabrication, and device processing attributes. The Si MW array geometry allows for efficient collection of photogenerated carriers from impure materials that have short minority-carrier diffusion lengths, while simultaneously allowing for high optical absorption and high external quantum yields for charge carrier collection. In addition, Si MW arrays exhibit unique mesoscale optical behavior and can be removed from the growth substrate to provide flexible, processable arrays of Si microwires ordered in a variety of organic polymers and ionomers. The unique photon management properties of Si MW arrays, combined with their high internal surface area and controlled morphology for catalyst placement and support, allow for the use of earth-abundant electrocatalysts to produce an integrated, functional photoelectrode. Furthermore, these materials therefore also provide an opportunity to explore the 3-dimensional photoelectrochemical behavior of fuel-forming microstructured electrodes.},
doi = {10.1021/jp406280x},
journal = {Journal of Physical Chemistry. C},
number = 2,
volume = 118,
place = {United States},
year = {Mon Dec 09 00:00:00 EST 2013},
month = {Mon Dec 09 00:00:00 EST 2013}
}
Web of Science
Works referenced in this record:
High-resolution detection of Au catalyst atoms in Si nanowires
journal, February 2008
- Allen, Jonathan E.; Hemesath, Eric R.; Perea, Daniel E.
- Nature Nanotechnology, Vol. 3, Issue 3
Epitaxial growth of silicon nanowires using an aluminium catalyst
journal, November 2006
- Wang, Yewu; Schmidt, Volker; Senz, Stephan
- Nature Nanotechnology, Vol. 1, Issue 3, p. 186-189
An Approach to Ideal Semiconductor Electrodes for Efficient Photoelectrochemical Reduction of Carbon Dioxide by Modification with Small Metal Particles
journal, February 1998
- Hinogami, R.; Nakamura, Y.; Yae, S.
- The Journal of Physical Chemistry B, Vol. 102, Issue 6
Hydrogen-evolution characteristics of Ni–Mo-coated, radial junction, n+p-silicon microwire array photocathodes
journal, January 2012
- Warren, Emily L.; McKone, James R.; Atwater, Harry A.
- Energy & Environmental Science, Vol. 5, Issue 11
Vapor-liquid-solid mechanism of single crystal growth
journal, March 1964
- Wagner, R. S.; Ellis, W. C.
- Applied Physics Letters, Vol. 4, Issue 5, p. 89-90
10 μm minority-carrier diffusion lengths in Si wires synthesized by Cu-catalyzed vapor-liquid-solid growth
journal, October 2009
- Putnam, Morgan C.; Turner-Evans, Daniel B.; Kelzenberg, Michael D.
- Applied Physics Letters, Vol. 95, Issue 16, 163116
A 14% efficient nonaqueous semiconductor/liquid junction solar cell
journal, November 1984
- Gibbons, James F.; Cogan, George W.; Gronet, Chris M.
- Applied Physics Letters, Vol. 45, Issue 10, p. 1095-1097
Physics of Copper in Silicon
journal, January 2002
- Istratov, Andrei A.; Weber, Eicke R.
- Journal of The Electrochemical Society, Vol. 149, Issue 1
Controlling Silicon Nanowire Growth Direction via Surface Chemistry
journal, May 2012
- Shin, Naechul; Filler, Michael A.
- Nano Letters, Vol. 12, Issue 6
Electrical and Photoelectrochemical Properties of WO 3 /Si Tandem Photoelectrodes
journal, March 2013
- Coridan, Robert H.; Shaner, Matthew; Wiggenhorn, Craig
- The Journal of Physical Chemistry C, Vol. 117, Issue 14
A Comparison of the Behavior of Single Crystalline and Nanowire Array ZnO Photoanodes
journal, January 2013
- Fitch, Anthony; Strandwitz, Nicholas C.; Brunschwig, Bruce S.
- The Journal of Physical Chemistry C, Vol. 117, Issue 5
Photoelectrochemical characterization of Si microwire array solar cells
conference, June 2012
- Warren, Emily L.; Turner-Evans, Daniel B.; Grimm, Ronald L.
- 2012 IEEE 38th Photovoltaic Specialists Conference (PVSC), 2012 38th IEEE Photovoltaic Specialists Conference
Analysis of Optical Absorption in Silicon Nanowire Arrays for Photovoltaic Applications
journal, October 2007
- Hu, Lu; Chen, Gang
- Nano Letters, Vol. 7, Issue 11, p. 3249-3252
Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications
journal, February 2010
- Kelzenberg, Michael D.; Boettcher, Shannon W.; Petykiewicz, Jan A.
- Nature Materials, Vol. 9, Issue 3, p. 239-244
Orientation habits of metal whiskers
journal, October 1957
- Treuting, R. G.; Arnold, S. M.
- Acta Metallurgica, Vol. 5, Issue 10
Energy-Conversion Properties of Vapor-Liquid-Solid-Grown Silicon Wire-Array Photocathodes
journal, January 2010
- Boettcher, S. W.; Spurgeon, J. M.; Putnam, M. C.
- Science, Vol. 327, Issue 5962, p. 185-187
High-performance Si microwire photovoltaics
journal, January 2011
- Kelzenberg, Michael D.; Turner-Evans, Daniel B.; Putnam, Morgan C.
- Energy & Environmental Science, Vol. 4, Issue 3
Evaluation and optimization of mass transport of redox species in silicon microwire-array photoelectrodes
journal, August 2012
- Xiang, C.; Meng, A. C.; Lewis, N. S.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
Improvement of photoelectrochemical hydrogen generation by surface modification of p-type silicon semiconductor photocathodes
journal, January 1982
- Dominey, Raymond N.; Lewis, Nathan S.; Bruce, James A.
- Journal of the American Chemical Society, Vol. 104, Issue 2
Solar Water Splitting Cells
journal, November 2010
- Walter, Michael G.; Warren, Emily L.; McKone, James R.
- Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
Impurity effects in silicon for high efficiency solar cells
journal, May 1986
- Hopkins, R. H.; Rohatgi, A.
- Journal of Crystal Growth, Vol. 75, Issue 1, p. 67-79
Magnetic Field Alignment of Randomly Oriented, High Aspect Ratio Silicon Microwires into Vertically Oriented Arrays
journal, October 2012
- Beardslee, Joseph A.; Sadtler, Bryce; Lewis, Nathan S.
- ACS Nano, Vol. 6, Issue 11
Modeling, simulation, and design criteria for photoelectrochemical water-splitting systems
journal, January 2012
- Haussener, Sophia; Xiang, Chengxiang; Spurgeon, Joshua M.
- Energy & Environmental Science, Vol. 5, Issue 12
Light Trapping in Silicon Nanowire Solar Cells
journal, January 2010
- Garnett, Erik; Yang, Peidong
- Nano Letters, Vol. 10, Issue 3, p. 1082-1087
Comparison of the device physics principles of planar and radial p-n junction nanorod solar cells
journal, June 2005
- Kayes, Brendan M.; Atwater, Harry A.; Lewis, Nathan S.
- Journal of Applied Physics, Vol. 97, Issue 11, Article No. 114302
Electrochemistry of porous and crystalline silicon electrodes in methylviologen solutions
journal, April 1996
- Kooij, E. S.; Despo, R. W.; Mulders, F. P. J.
- Journal of Electroanalytical Chemistry, Vol. 406, Issue 1-2
Three-Dimensional Nanoscale Composition Mapping of Semiconductor Nanowires
journal, February 2006
- Perea, Daniel E.; Allen, Jonathan E.; May, Steven J.
- Nano Letters, Vol. 6, Issue 2
Flexible Polymer-Embedded Si Wire Arrays
journal, January 2009
- Plass, Katherine E.; Filler, Michael A.; Spurgeon, Joshua M.
- Advanced Materials, Vol. 21, Issue 3, p. 325-328
A quantitative assessment of the competition between water and anion oxidation at WO3 photoanodes in acidic aqueous electrolytes
journal, January 2012
- Mi, Qixi; Zhanaidarova, Almagul; Brunschwig, Bruce S.
- Energy & Environmental Science, Vol. 5, Issue 2
Secondary Ion Mass Spectrometry of Vapor−Liquid−Solid Grown, Au-Catalyzed, Si Wires
journal, September 2008
- Putnam, Morgan C.; Filler, Michael A.; Kayes, Brendan M.
- Nano Letters, Vol. 8, Issue 10, p. 3109-3113
Optimized light absorption in Si wire array solar cells
journal, January 2012
- Alaeian, Hadiseh; Atre, Ashwin C.; Dionne, Jennifer A.
- Journal of Optics, Vol. 14, Issue 2
Wafer-Scale Growth of Silicon Microwire Arrays for Photovoltaics and Solar Fuel Generation
journal, July 2012
- Tamboli, Adele C.; Chen, Christopher T.; Warren, Emily L.
- IEEE Journal of Photovoltaics, Vol. 2, Issue 3
Si microwire-array solar cells
journal, January 2010
- Putnam, Morgan C.; Boettcher, Shannon W.; Kelzenberg, Michael D.
- Energy & Environmental Science, Vol. 3, Issue 8
High Aspect Ratio Silicon Wire Array Photoelectrochemical Cells
journal, October 2007
- Maiolo, James R.; Kayes, Brendan M.; Filler, Michael A.
- Journal of the American Chemical Society, Vol. 129, Issue 41, p. 12346-12347
Radial junction silicon wire array solar cells fabricated by gold-catalyzed vapor-liquid-solid growth
journal, October 2010
- Kendrick, Chito E.; Yoon, Heayong P.; Yuwen, Yu A.
- Applied Physics Letters, Vol. 97, Issue 14
In Situ Nanomechanical Measurements of Interfacial Strength in Membrane-Embedded Chemically Functionalized Si Microwires for Flexible Solar Cells
journal, May 2012
- Cho, Clara J.; O’Leary, Leslie; Lewis, Nathan S.
- Nano Letters, Vol. 12, Issue 6
Electrical Characterization of Si Microwires and of Si Microwire/Conducting Polymer Composite Junctions
journal, February 2011
- Yahyaie, Iman; McEleney, Kevin; Walter, Michael
- The Journal of Physical Chemistry Letters, Vol. 2, Issue 6
Growth of vertically aligned Si wire arrays over large areas (>1cm2) with Au and Cu catalysts
journal, September 2007
- Kayes, Brendan M.; Filler, Michael A.; Putnam, Morgan C.
- Applied Physics Letters, Vol. 91, Issue 10, 103110
Photoanodic behavior of vapor-liquid-solid–grown, lightly doped, crystalline Si microwire arrays
journal, January 2012
- Santori, Elizabeth A.; Maiolo III, James R.; Bierman, Matthew J.
- Energy & Environmental Science, Vol. 5, Issue 5
Ray optical light trapping in silicon microwires: exceeding the 2n2 intensity limit
journal, January 2011
- Kosten, Emily D.; Warren, Emily L.; Atwater, Harry A.
- Optics Express, Vol. 19, Issue 4
Photoelectrochemistry of core–shell tandem junction n–p + -Si/n-WO 3 microwire array photoelectrodes
journal, January 2014
- Shaner, Matthew R.; Fountaine, Katherine T.; Ardo, Shane
- Energy Environ. Sci., Vol. 7, Issue 2
A Comparison Between the Behavior of Nanorod Array and Planar Cd(Se, Te) Photoelectrodes
journal, April 2008
- Spurgeon, Joshua M.; Atwater, Harry A.; Lewis, Nathan S.
- The Journal of Physical Chemistry C, Vol. 112, Issue 15
Functional Nanoscale Electronic Devices Assembled Using Silicon Nanowire Building Blocks
journal, February 2001
- Cui, Yi; Lieber, Charles M.
- Science, Vol. 291, Issue 5505, p. 851-853
Control of the Stability, Electron-Transfer Kinetics, and pH-Dependent Energetics of Si/H 2 O Interfaces through Methyl Termination of Si(111) Surfaces
journal, November 2006
- Hamann, Thomas W.; Lewis, Nathan S.
- The Journal of Physical Chemistry B, Vol. 110, Issue 45
Electrical conductivity, ionic conductivity, optical absorption, and gas separation properties of ionically conductive polymer membranes embedded with Si microwire arrays
journal, January 2011
- Spurgeon, Joshua M.; Walter, Michael G.; Zhou, Junfeng
- Energy & Environmental Science, Vol. 4, Issue 5, p. 1772-1780
Solid Solubilities of Impurity Elements in Germanium and Silicon*
journal, January 1960
- Trumbore, F. A.
- Bell System Technical Journal, Vol. 39, Issue 1
Novel parallel multijunction solar cell
journal, December 1994
- Green, Martin A.; Wenham, Stuart R.
- Applied Physics Letters, Vol. 65, Issue 23
Conformal GaP layers on Si wire arrays for solar energy applications
journal, November 2010
- Tamboli, Adele C.; Malhotra, Manav; Kimball, Gregory M.
- Applied Physics Letters, Vol. 97, Issue 22
The TI solar energy system development
conference, January 1981
- Johnson, E. L.
- 1981 International Electron Devices Meeting
Flexible, Polymer-Supported, Si Wire Array Photoelectrodes
journal, June 2010
- Spurgeon, Joshua M.; Boettcher, Shannon W.; Kelzenberg, Michael D.
- Advanced Materials, Vol. 22, Issue 30
Macroporous Silicon as a Model for Silicon Wire Array Solar Cells
journal, April 2008
- Maiolo, James R.; Atwater, Harry A.; Lewis, Nathan S.
- The Journal of Physical Chemistry C, Vol. 112, Issue 15, p. 6194-6201
Predicted efficiency of Si wire array solar cells
conference, June 2009
- Kelzenberg, M. D.; Putnam, M. C.; Turner-Evans, D. B.
- 2009 34th IEEE Photovoltaic Specialists Conference (PVSC)
The effect of pattern density and wire diameter on the growth rate of micron diameter silicon wires
journal, December 2011
- Kendrick, Chito E.; Redwing, Joan M.
- Journal of Crystal Growth, Vol. 337, Issue 1
pH-Independent, 520 mV Open-Circuit Voltages of Si/Methyl Viologen 2+/+ Contacts Through Use of Radial n + p-Si Junction Microwire Array Photoelectrodes
journal, December 2010
- Warren, Emily L.; Boettcher, Shannon W.; Walter, Michael G.
- The Journal of Physical Chemistry C, Vol. 115, Issue 2
Optical, electrical, and solar energy-conversion properties of gallium arsenide nanowire-array photoanodes
journal, January 2013
- Hu, Shu; Chi, Chun-Yung; Fountaine, Katherine T.
- Energy & Environmental Science, Vol. 6, Issue 6
Growth, Thermodynamics, and Electrical Properties of Silicon Nanowires †
journal, January 2010
- Schmidt, V.; Wittemann, J. V.; Gösele, U.
- Chemical Reviews, Vol. 110, Issue 1
Repeated epitaxial growth and transfer of arrays of patterned, vertically aligned, crystalline Si wires from a single Si(111) substrate
journal, July 2008
- Spurgeon, Joshua M.; Plass, Katherine E.; Kayes, Brendan M.
- Applied Physics Letters, Vol. 93, Issue 3, 032112
Photoelectrochemical Hydrogen Evolution Using Si Microwire Arrays
journal, January 2011
- Boettcher, Shannon W.; Warren, Emily L.; Putnam, Morgan C.
- Journal of the American Chemical Society, Vol. 133, Issue 5, p. 1216-1219
Flexible, Transparent Contacts for Inorganic Nanostructures and Thin Films
journal, June 2013
- Turner-Evans, Daniel B.; Emmer, Hal; Chen, Christopher T.
- Advanced Materials, Vol. 25, Issue 29
Silicon Nanowires: A Review on Aspects of their Growth and their Electrical Properties
journal, June 2009
- Schmidt, Volker; Wittemann, Joerg V.; Senz, Stephan
- Advanced Materials, Vol. 21, Issue 25-26
Evaluation of Pt, Ni, and Ni–Mo electrocatalysts for hydrogen evolution on crystalline Si electrodes
journal, January 2011
- McKone, James R.; Warren, Emily L.; Bierman, Matthew J.
- Energy & Environmental Science, Vol. 4, Issue 9
Solubility and Diffusivity of Gold, Iron, and Copper in Silicon
journal, December 1956
- Struthers, J. D.
- Journal of Applied Physics, Vol. 27, Issue 12, p. 1560-1560
InP Nanowire Array Solar Cells Achieving 13.8% Efficiency by Exceeding the Ray Optics Limit
journal, January 2013
- Wallentin, J.; Anttu, N.; Asoli, D.
- Science, Vol. 339, Issue 6123
Controlled Growth of Si Nanowire Arrays for Device Integration
journal, March 2005
- Hochbaum, Allon I.; Fan, Rong; He, Rongrui
- Nano Letters, Vol. 5, Issue 3, p. 457-460
Photovoltaic Measurements in Single-Nanowire Silicon Solar Cells
journal, February 2008
- Kelzenberg, Michael D.; Turner-Evans, Daniel B.; Kayes, Brendan M.
- Nano Letters, Vol. 8, Issue 2, p. 710-714
Operation of lightly doped Si microwires under high-level injection conditions
journal, January 2014
- Santori, Elizabeth A.; Strandwitz, Nicholas C.; Grimm, Ronald L.
- Energy Environ. Sci., Vol. 7, Issue 7
Works referencing / citing this record:
Numerical Monte Carlo simulations of charge transport across the surface of dye and cocatalyst modified spherical nanoparticles under conditions of pulsed or continuous illumination
journal, January 2019
- Tkaczibson, Kevin; Ardo, Shane
- Sustainable Energy & Fuels, Vol. 3, Issue 6
The potential versus current state of water splitting with hematite
journal, January 2015
- Zandi, Omid; Hamann, Thomas W.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 35
Photo-electrochemical hydrogen production from neutral phosphate buffer and seawater using micro-structured p-Si photo-electrodes functionalized by solution-based methods
journal, January 2018
- Kawde, Anurag; Annamalai, Alagappan; Amidani, Lucia
- Sustainable Energy & Fuels, Vol. 2, Issue 10
Solar to fuels conversion technologies: a perspective
journal, January 2017
- Tuller, Harry L.
- Materials for Renewable and Sustainable Energy, Vol. 6, Issue 1
Microengineering laser plasma interactions at relativistic intensities
text, January 2015
- Jiang, S.; Ji, L. L.; Audesirk, H.
- arXiv
Modeling, Simulation, and Implementation of Solar-Driven Water-Splitting Devices
journal, October 2016
- Xiang, Chengxiang; Weber, Adam Z.; Ardo, Shane
- Angewandte Chemie International Edition, Vol. 55, Issue 42
Enhanced Stability and Thickness‐Independent Oxygen Evolution Electrocatalysis of Heterostructured Anodes with Buried Epitaxial Bilayers
journal, June 2019
- Baniecki, John D.; Yamaguchi, Hideshi; Harnagea, Catalin
- Advanced Energy Materials, Vol. 9, Issue 28
Photoelectrochemical Characterisation on Surface-Inverted Black Silicon Photocathodes by Using Platinum/Palladium Co-catalysts for Solar-to-Hydrogen Conversion
journal, June 2018
- Halima, Ahmed Farid; Zhang, Xinyi; MacFarlane, Douglas Robert
- ChemPlusChem, Vol. 83, Issue 7
Controlled Doping Methods for Radial p/n Junctions in Silicon
journal, November 2014
- Elbersen, Rick; Tiggelaar, Roald M.; Milbrat, Alexander
- Advanced Energy Materials, Vol. 5, Issue 6
Titania Nanotubes by Electrochemical Anodization for Solar Energy Conversion
journal, January 2014
- Tsui, Lok-kun; Zangari, Giovanni
- Journal of The Electrochemical Society, Vol. 161, Issue 7
A heteroelectrode structure for solar water splitting: integrated cobalt ditelluride across a TiO 2 -passivated silicon microwire array
journal, January 2017
- Bazri, Behrouz; Lin, Yu-Chen; Lu, Tzu-Hsiang
- Catalysis Science & Technology, Vol. 7, Issue 7
Solar to fuels conversion technologies: a perspective
journal, January 2017
- Tuller, Harry L.
- Materials for Renewable and Sustainable Energy, Vol. 6, Issue 1
Integration of Molybdenum-Doped, Hydrogen-Annealed BiVO4 with Silicon Microwires for Photoelectrochemical Applications
journal, February 2019
- Milbrat, Alexander; Vijselaar, Wouter; Guo, Yuxi
- ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 5