Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition
Abstract
Focused electron beam induced deposition (FEBID) is a versatile tool for the direct-write fabrication of nanostructures on surfaces. However, FEBID nanostructures are usually highly contaminated by carbon originating from the precursor used in the process. Recently, it was shown that platinum nanostructures produced by FEBID can be efficiently purified by electron irradiation in the presence of water. If such processes can be transferred to FEBID deposits produced from other carbon-containing precursors, a new general approach to the generation of pure metallic nanostructures could be implemented. Therefore this study aims to understand the chemical reactions that are fundamental to the water-assisted purification of platinum FEBID deposits generated from trimethyl(methylcyclopentadienyl)platinum(IV) (MeCpPtMe3). The experiments performed under ultrahigh vacuum conditions apply a combination of different desorption experiments coupled with mass spectrometry to analyse reaction products. Electron-stimulated desorption monitors species that leave the surface during electron exposure while post-irradiation thermal desorption spectrometry reveals products that evolve during subsequent thermal treatment. In addition, desorption of volatile products was also observed when a deposit produced by electron exposure was subsequently brought into contact with water. The results distinguish between contributions of thermal chemistry, direct chemistry between water and the deposit, and electron-induced reactions that all contribute tomore »
- Authors:
-
[1];
[1]
- Univ. of Bremen (Germany). Inst. of Applied and Physical Chemistry
- Univ. of Bremen (Germany). Inst. of Applied and Physical Chemistry; Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Science Division
- Siedlce Univ. (Poland). Faculty of Sciences
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1628620
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Beilstein Journal of Nanotechnology
- Additional Journal Information:
- Journal Volume: 9; Journal ID: ISSN 2190-4286
- Publisher:
- Beilstein Institute
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; science & technology - other topics; materials science; physics; carbon contamination; electron induced reactions; focused electron beam induced deposition; nanostructure purification; platinum precursor
Citation Formats
Warneke, Ziyan, Rohdenburg, Markus, Warneke, Jonas, Kopyra, Janina, and Swiderek, Petra. Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition. United States: N. p., 2018.
Web. doi:10.3762/bjnano.9.10.
Warneke, Ziyan, Rohdenburg, Markus, Warneke, Jonas, Kopyra, Janina, & Swiderek, Petra. Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition. United States. https://doi.org/10.3762/bjnano.9.10
Warneke, Ziyan, Rohdenburg, Markus, Warneke, Jonas, Kopyra, Janina, and Swiderek, Petra. Mon .
"Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition". United States. https://doi.org/10.3762/bjnano.9.10. https://www.osti.gov/servlets/purl/1628620.
@article{osti_1628620,
title = {Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition},
author = {Warneke, Ziyan and Rohdenburg, Markus and Warneke, Jonas and Kopyra, Janina and Swiderek, Petra},
abstractNote = {Focused electron beam induced deposition (FEBID) is a versatile tool for the direct-write fabrication of nanostructures on surfaces. However, FEBID nanostructures are usually highly contaminated by carbon originating from the precursor used in the process. Recently, it was shown that platinum nanostructures produced by FEBID can be efficiently purified by electron irradiation in the presence of water. If such processes can be transferred to FEBID deposits produced from other carbon-containing precursors, a new general approach to the generation of pure metallic nanostructures could be implemented. Therefore this study aims to understand the chemical reactions that are fundamental to the water-assisted purification of platinum FEBID deposits generated from trimethyl(methylcyclopentadienyl)platinum(IV) (MeCpPtMe3). The experiments performed under ultrahigh vacuum conditions apply a combination of different desorption experiments coupled with mass spectrometry to analyse reaction products. Electron-stimulated desorption monitors species that leave the surface during electron exposure while post-irradiation thermal desorption spectrometry reveals products that evolve during subsequent thermal treatment. In addition, desorption of volatile products was also observed when a deposit produced by electron exposure was subsequently brought into contact with water. The results distinguish between contributions of thermal chemistry, direct chemistry between water and the deposit, and electron-induced reactions that all contribute to the purification process. We discuss reaction kinetics for the main volatile products CO and CH4to obtain mechanistic information. The results provide novel insights into the chemistry that occurs during purification of FEBID nanostructures with implications also for the stability of the carbonaceous matrix of nanogranular FEBID materials under humid conditions.},
doi = {10.3762/bjnano.9.10},
journal = {Beilstein Journal of Nanotechnology},
number = ,
volume = 9,
place = {United States},
year = {Mon Jan 08 00:00:00 EST 2018},
month = {Mon Jan 08 00:00:00 EST 2018}
}
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Low-Energy Electron-Induced Decomposition and Reactions of Adsorbed Tetrakis(trifluorophosphine)platinum [Pt(PF 3 ) 4 ]
journal, August 2011
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Rapid and Highly Compact Purification for Focused Electron Beam Induced Deposits: A Low Temperature Approach Using Electron Stimulated H 2 O Reactions
journal, June 2014
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Electron-Induced Reactions of MeCpPtMe 3 Investigated by HREELS
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A new sequential EBID process for the creation of pure Pt structures from MeCpPtMe 3
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- Nanotechnology, Vol. 24, Issue 14
Embedded purification for electron beam induced Pt deposition using MeCpPtMe 3
journal, February 2015
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- Nanotechnology, Vol. 26, Issue 9
Tuning shape, composition and magnetization of 3D cobalt nanowires grown by focused electron beam induced deposition (FEBID)
journal, April 2017
- Pablo-Navarro, Javier; Sanz-Hernández, Dédalo; Magén, César
- Journal of Physics D: Applied Physics, Vol. 50, Issue 18
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journal, September 1978
- Shaver, Alan
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Focused electron beam induced deposition: A perspective
journal, January 2012
- Huth, Michael; Porrati, Fabrizio; Schwalb, Christian
- Beilstein Journal of Nanotechnology, Vol. 3
The role of low-energy electrons in focused electron beam induced deposition: four case studies of representative precursors
journal, January 2015
- Thorman, Rachel M.; Kumar T. P., Ragesh; Fairbrother, D. Howard
- Beilstein Journal of Nanotechnology, Vol. 6
Works referencing / citing this record:
Chemistry for electron-induced nanofabrication
journal, January 2018
- Swiderek, Petra; Marbach, Hubertus; Hagen, Cornelis W.
- Beilstein Journal of Nanotechnology, Vol. 9