The Use of Flow-Injection Analysis with Chemiluminescence Detection of Aqueous Ferrous Iron in Waters Containing High Concentrations of Organic Compounds

Borman, Christopher; Sullivan, B. Patrick; Eggleston, Carrick; Colberg, Patricia

doi:10.3390/s90604390

Title: The Use of Flow-Injection Analysis with Chemiluminescence Detection of Aqueous Ferrous Iron in Waters Containing High Concentrations of Organic Compounds

Journal Article · 31 May 2009 · Sensors

DOI: https://doi.org/10.3390/s90604390 · OSTI ID:1628571

Borman, Christopher ^[1]; Sullivan, B. Patrick ^[2]; Eggleston, Carrick ^[3]; Colberg, Patricia ^[4]

Univ. of Wyoming, Laramie, WY (United States). Dept. of Chemistry; DOE/OSTI
Univ. of Wyoming, Laramie, WY (United States). Dept. of Chemistry
Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics
Univ. of Wyoming, Laramie, WY (United States). Dept. of Civil and Architectural Engineering

An evaluation of flow-injection analysis with chemiluminescence detection (FIA-CL) to quantify Fe2+ (aq) in freshwaters was performed. Iron-coordinating and/or ironreducing compounds, dissolved organic matter (DOM), and samples from two natural water systems were used to amend standard solutions of Fe2+ (aq). Slopes of the response curves from ferrous iron standards (1 – 100 nM) were compared to the response curves of iron standards containing the amendments. Results suggest that FIA-CL is not suitable for systems containing ascorbate, hydroxylamine, cysteine or DOM. Little or no change in sensitivity occurred in solutions of oxalate and glycine or in natural waters with little organic matter.

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Research Organization:: Univ. of Wyoming, Laramie, WY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: FG02-06ER15823

OSTI ID:: 1628571

Journal Information:: Sensors, Journal Name: Sensors Journal Issue: 6 Vol. 9; ISSN SENSC9; ISSN 1424-8220

Publisher:: MDPI AGCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
42 ENGINEERING
Chemistry
Engineering
Felume
Instruments & Instrumentation
chemiluminescence
ferrous iron determination
flow-injection analysis
iron oxide dissolution
luminol

Title: The Use of Flow-Injection Analysis with Chemiluminescence Detection of Aqueous Ferrous Iron in Waters Containing High Concentrations of Organic Compounds

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