Colloidal Synthesis of Bulk-Bandgap Lead Selenide Nanocrystals

Abeywickrama, Thulitha M.; Hassan, Asra; Snee, Preston T.

doi:10.3389/fchem.2018.00562

Title: Colloidal Synthesis of Bulk-Bandgap Lead Selenide Nanocrystals

Journal Article · 22 November 2018 · Frontiers in Chemistry

DOI: https://doi.org/10.3389/fchem.2018.00562 · OSTI ID:1628028

Abeywickrama, Thulitha M. ^[1]; Hassan, Asra ^[2]; Snee, Preston T. ^[2]

Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry; DOE/OSTI
Univ. of Illinois, Chicago, IL (United States). Dept. of Chemistry

Lead selenide quantum dots (QDs) are low-bandgap IV-VI semiconducting nanomaterials that have been studied for a variety of applications. Their preparation using colloidal methods can create small spherical to larger cubic nanocrystals, with an upper limit of ~17 nm reported to date. Here we describe methods for preparing cubic PbSe nanocrystals over a 20–40 nm size range using a twostep procedure. Specifically, ~10 nm PbSe QDs are generated using the rapid injection method, the products from which are overcoated with additional lead and selenium precursors. The use of two lead reagents were studied; lead oleate resulted in a maximum of 20 nm cubes, while more reactive lead hexyldecanoate resulted in much larger nanomaterials with bulk bandgaps. However, PbSe samples prepared with lead hexyldecanoate also contained agglomerates. Special care must be taken when characterizing larger strained nanomaterials with X-ray powder diffraction, for which the Scherrer equation is inadequate. A more rigorous approach using the Williamson–Hall method provides characterizations that are consistent with electron microscopy analysis.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1628028

Journal Information:: Frontiers in Chemistry, Journal Name: Frontiers in Chemistry Vol. 6; ISSN 2296-2646

Publisher:: Frontiers Research FoundationCopyright Statement

Country of Publication:: United States

Language:: English

References (51)

Core/Shell PbSe/PbS QDs TiO ₂ Heterojunction Solar Cell Etgar, Lioz; Yanover, Diana; Čapek, Richard Karel Advanced Functional Materials, Vol. 23, Issue 21 https://doi.org/10.1002/adfm.201202322	journal	December 2012
X-ray line broadening from filed aluminium and wolfram Williamson, G. K.; Hall, W. H. Acta Metallurgica, Vol. 1, Issue 1 https://doi.org/10.1016/0001-6160(53)90006-6	journal	January 1953
Tuning Optical Activity of IV–VI Colloidal Quantum Dots in the Short-Wave Infrared (SWIR) Spectral Regime Shapiro, Arthur; Jang, Youngjin; Rubin-Brusilovski, Anna Chemistry of Materials, Vol. 28, Issue 17 https://doi.org/10.1021/acs.chemmater.6b02917	journal	August 2016
Entropic Ligands for Nanocrystals: From Unexpected Solution Properties to Outstanding Processability Yang, Yu; Qin, Haiyan; Jiang, Maowei Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.6b00730	journal	March 2016
Small-Sized PbSe/PbS Core/Shell Colloidal Quantum Dots Yanover, Diana; Čapek, Richard K.; Rubin-Brusilovski, Anna Chemistry of Materials, Vol. 24, Issue 22 https://doi.org/10.1021/cm302793k	journal	November 2012
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V. Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900137k	journal	January 2010
Pushing the Band Gap Envelope: Mid-Infrared Emitting Colloidal PbSe Quantum Dots Pietryga, Jeffrey M.; Schaller, Richard D.; Werder, Donald Journal of the American Chemical Society, Vol. 126, Issue 38 https://doi.org/10.1021/ja047659f	journal	September 2004
A Ratiometric CdSe/ZnS Nanocrystal pH Sensor Snee, Preston T.; Somers, Rebecca C.; Nair, Gautham Journal of the American Chemical Society, Vol. 128, Issue 41 https://doi.org/10.1021/ja0618999	journal	October 2006
Size-Dependent Charge Collection in Junctions Containing Single-Size and Multi-Size Arrays of Colloidal CdSe Quantum Dots Weiss, Emily A.; Chiechi, Ryan C.; Geyer, Scott M. Journal of the American Chemical Society, Vol. 130, Issue 1 https://doi.org/10.1021/ja076438h	journal	January 2008
Mysteries of TOPSe Revealed: Insights into Quantum Dot Nucleation Evans, Christopher M.; Evans, Meagan E.; Krauss, Todd D. Journal of the American Chemical Society, Vol. 132, Issue 32, p. 10973-10975 https://doi.org/10.1021/ja103805s	journal	August 2010
One-Dimensional Carrier Confinement in “Giant” CdS/CdSe Excitonic Nanoshells Razgoniaeva, Natalia; Moroz, Pavel; Yang, Mingrui Journal of the American Chemical Society, Vol. 139, Issue 23 https://doi.org/10.1021/jacs.7b02054	journal	June 2017
Ideal CdSe/CdS Core/Shell Nanocrystals Enabled by Entropic Ligands and Their Core Size-, Shell Thickness-, and Ligand-Dependent Photoluminescence Properties Zhou, Jianhai; Zhu, Meiyi; Meng, Renyang Journal of the American Chemical Society, Vol. 139, Issue 46 https://doi.org/10.1021/jacs.7b07434	journal	November 2017
On-Surface Reactions in the Growth of High-Quality CdSe Nanocrystals in Nonpolar Solutions Lai, Runchen; Pu, Chaodan; Peng, Xiaogang Journal of the American Chemical Society, Vol. 140, Issue 29 https://doi.org/10.1021/jacs.8b04743	journal	June 2018
Imaging Schottky Barriers and Ohmic Contacts in PbS Quantum Dot Devices Strasfeld, David B.; Dorn, August; Wanger, Darcy D. Nano Letters, Vol. 12, Issue 2 https://doi.org/10.1021/nl204116b	journal	January 2012
Ultrabright PbSe Magic-sized Clusters Evans, Christopher M.; Guo, Li; Peterson, Jeffrey J. Nano Letters, Vol. 8, Issue 9 https://doi.org/10.1021/nl801685a	journal	September 2008
Shape-Controlled Colloidal Synthesis of Rock-Salt Lead Selenide Nanocrystals Jawaid, Ali M.; Asunskis, Daniel J.; Snee, Preston T. ACS Nano, Vol. 5, Issue 8 https://doi.org/10.1021/nn2016716	journal	July 2011
The use of nanocrystals in biological detection Alivisatos, Paul Nature Biotechnology, Vol. 22, Issue 1, p. 47-52 https://doi.org/10.1038/nbt927	journal	January 2003
Colloidal-quantum-dot photovoltaics using atomic-ligand passivation Tang, Jiang; Kemp, Kyle W.; Hoogland, Sjoerd Nature Materials, Vol. 10, Issue 10 https://doi.org/10.1038/nmat3118	journal	September 2011
Air-stable n-type colloidal quantum dot solids Ning, Zhijun; Voznyy, Oleksandr; Pan, Jun Nature Materials, Vol. 13, Issue 8 https://doi.org/10.1038/nmat4007	journal	June 2014
Size control by rate control in colloidal PbSe quantum dot synthesis Čapek, Richard Karel; Yanover, Dianna; Lifshitz, Efrat Nanoscale, Vol. 7, Issue 12 https://doi.org/10.1039/c5nr00028a	journal	January 2015
Coulomb Blockade and Hopping Conduction in PbSe Quantum Dots Romero, Hugo E.; Drndic, Marija Physical Review Letters, Vol. 95, Issue 15 https://doi.org/10.1103/physrevlett.95.156801	journal	October 2005
PbSe Nanocrystal Solids for n- and p-Channel Thin Film Field-Effect Transistors Talapin, D. V. Science, Vol. 310, Issue 5745, p. 86-89 https://doi.org/10.1126/science.1116703	journal	October 2005
Core/Shell PbSe/PbS QDs TiO ₂ Heterojunction Solar Cell Etgar, Lioz; Yanover, Diana; Čapek, Richard Karel Advanced Functional Materials, Vol. 23, Issue 21 https://doi.org/10.1002/adfm.201202322	journal	December 2012
X-ray line broadening from filed aluminium and wolfram Williamson, G. K.; Hall, W. H. Acta Metallurgica, Vol. 1, Issue 1 https://doi.org/10.1016/0001-6160(53)90006-6	journal	January 1953
Purification of oleic acid and linoleic acid Arudi, R. L.; Sutherland, M. W.; Bielski, B. H. Journal of Lipid Research, Vol. 24, Issue 4 https://doi.org/10.1016/S0022-2275(20)37990-6	journal	April 1983
Tuning Optical Activity of IV–VI Colloidal Quantum Dots in the Short-Wave Infrared (SWIR) Spectral Regime Shapiro, Arthur; Jang, Youngjin; Rubin-Brusilovski, Anna Chemistry of Materials, Vol. 28, Issue 17 https://doi.org/10.1021/acs.chemmater.6b02917	journal	August 2016
Just Add Ligands: Self-Sustained Size Focusing of Colloidal Semiconductor Nanocrystals Razgoniaeva, Natalia; Yang, Mingrui; Garrett, Paul Chemistry of Materials, Vol. 30, Issue 4 https://doi.org/10.1021/acs.chemmater.7b05165	journal	February 2018
Entropic Ligands for Nanocrystals: From Unexpected Solution Properties to Outstanding Processability Yang, Yu; Qin, Haiyan; Jiang, Maowei Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.6b00730	journal	March 2016
Small-Sized PbSe/PbS Core/Shell Colloidal Quantum Dots Yanover, Diana; Čapek, Richard K.; Rubin-Brusilovski, Anna Chemistry of Materials, Vol. 24, Issue 22 https://doi.org/10.1021/cm302793k	journal	November 2012
Prospects of Colloidal Nanocrystals for Electronic and Optoelectronic Applications Talapin, Dmitri V.; Lee, Jong-Soo; Kovalenko, Maksym V. Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900137k	journal	January 2010
Pushing the Band Gap Envelope: Mid-Infrared Emitting Colloidal PbSe Quantum Dots Pietryga, Jeffrey M.; Schaller, Richard D.; Werder, Donald Journal of the American Chemical Society, Vol. 126, Issue 38 https://doi.org/10.1021/ja047659f	journal	September 2004
A Ratiometric CdSe/ZnS Nanocrystal pH Sensor Snee, Preston T.; Somers, Rebecca C.; Nair, Gautham Journal of the American Chemical Society, Vol. 128, Issue 41 https://doi.org/10.1021/ja0618999	journal	October 2006
Size-Dependent Charge Collection in Junctions Containing Single-Size and Multi-Size Arrays of Colloidal CdSe Quantum Dots Weiss, Emily A.; Chiechi, Ryan C.; Geyer, Scott M. Journal of the American Chemical Society, Vol. 130, Issue 1 https://doi.org/10.1021/ja076438h	journal	January 2008
Mysteries of TOPSe Revealed: Insights into Quantum Dot Nucleation Evans, Christopher M.; Evans, Meagan E.; Krauss, Todd D. Journal of the American Chemical Society, Vol. 132, Issue 32, p. 10973-10975 https://doi.org/10.1021/ja103805s	journal	August 2010
One-Dimensional Carrier Confinement in “Giant” CdS/CdSe Excitonic Nanoshells Razgoniaeva, Natalia; Moroz, Pavel; Yang, Mingrui Journal of the American Chemical Society, Vol. 139, Issue 23 https://doi.org/10.1021/jacs.7b02054	journal	June 2017
Ideal CdSe/CdS Core/Shell Nanocrystals Enabled by Entropic Ligands and Their Core Size-, Shell Thickness-, and Ligand-Dependent Photoluminescence Properties Zhou, Jianhai; Zhu, Meiyi; Meng, Renyang Journal of the American Chemical Society, Vol. 139, Issue 46 https://doi.org/10.1021/jacs.7b07434	journal	November 2017
On-Surface Reactions in the Growth of High-Quality CdSe Nanocrystals in Nonpolar Solutions Lai, Runchen; Pu, Chaodan; Peng, Xiaogang Journal of the American Chemical Society, Vol. 140, Issue 29 https://doi.org/10.1021/jacs.8b04743	journal	June 2018
Dependence of Carrier Mobility on Nanocrystal Size and Ligand Length in PbSe Nanocrystal Solids Liu, Yao; Gibbs, Markelle; Puthussery, James Nano Letters, Vol. 10, Issue 5 https://doi.org/10.1021/nl101284k	journal	May 2010
Imaging Schottky Barriers and Ohmic Contacts in PbS Quantum Dot Devices Strasfeld, David B.; Dorn, August; Wanger, Darcy D. Nano Letters, Vol. 12, Issue 2 https://doi.org/10.1021/nl204116b	journal	January 2012
Ultrabright PbSe Magic-sized Clusters Evans, Christopher M.; Guo, Li; Peterson, Jeffrey J. Nano Letters, Vol. 8, Issue 9 https://doi.org/10.1021/nl801685a	journal	September 2008
Shape-Controlled Colloidal Synthesis of Rock-Salt Lead Selenide Nanocrystals Jawaid, Ali M.; Asunskis, Daniel J.; Snee, Preston T. ACS Nano, Vol. 5, Issue 8 https://doi.org/10.1021/nn2016716	journal	July 2011
Air-stable n-type colloidal quantum dot solids Ning, Zhijun; Voznyy, Oleksandr; Pan, Jun Nature Materials, Vol. 13, Issue 8 https://doi.org/10.1038/NMAT4007	journal	June 2014
The use of nanocrystals in biological detection Alivisatos, Paul Nature Biotechnology, Vol. 22, Issue 1, p. 47-52 https://doi.org/10.1038/nbt927	journal	January 2003
Colloidal-quantum-dot photovoltaics using atomic-ligand passivation Tang, Jiang; Kemp, Kyle W.; Hoogland, Sjoerd Nature Materials, Vol. 10, Issue 10 https://doi.org/10.1038/nmat3118	journal	September 2011
Size control by rate control in colloidal PbSe quantum dot synthesis Čapek, Richard Karel; Yanover, Dianna; Lifshitz, Efrat Nanoscale, Vol. 7, Issue 12 https://doi.org/10.1039/C5NR00028A	journal	January 2015
The Separation of Cold‐Work Distortion and Particle Size Broadening in X‐Ray Patterns Warren, B. E.; Averbach, B. L. Journal of Applied Physics, Vol. 23, Issue 4 https://doi.org/10.1063/1.1702234	journal	April 1952
Charge transport in PbSe nanocrystal arrays Mentzel, T. S.; Porter, V. J.; Geyer, S. Physical Review B, Vol. 77, Issue 7 https://doi.org/10.1103/PhysRevB.77.075316	journal	February 2008
Coulomb Blockade and Hopping Conduction in PbSe Quantum Dots Romero, Hugo E.; Drndic, Marija Physical Review Letters, Vol. 95, Issue 15 https://doi.org/10.1103/PhysRevLett.95.156801	journal	October 2005
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
PbSe Nanocrystal Solids for n- and p-Channel Thin Film Field-Effect Transistors Talapin, D. V. Science, Vol. 310, Issue 5745, p. 86-89 https://doi.org/10.1126/science.1116703	journal	October 2005
A tunable library of substituted thiourea precursors to metal sulfide nanocrystals Hendricks, M. P.; Campos, M. P.; Cleveland, G. T. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa2951	journal	June 2015

Similar Records

Simple synthesis of PbSe nanocrystals and their self-assembly into 2D ‘flakes’ and 1D ‘ribbons’ structures

Journal Article · 2016 · Materials Research Bulletin · OSTI ID:22581588

Ortega-López, M.; Matsumoto, Y.; Santoyo-Salazar, J.

Size Dependent Optical Properties and Structure of ZnS Nanocrystals Prepared from a Library of Thioureas

Journal Article · 2022 · Chemistry of Materials · OSTI ID:1842802

Bennett, Ellie; Greenberg, Matthew W.; Jordan, Abraham J.; +4 more

High Seebeck Coefficient from Screen-Printed Colloidal PbSe Nanocrystals Thin Film

Journal Article · 2022 · Materials · OSTI ID:2469935

Sousa, Viviana; Savelli, Guillaume; Lebedev, Oleg I.; +5 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
77 NANOSCIENCE AND NANOTECHNOLOGY
Chemistry
conductivity
lead selenide
nanomaterials
quantum dots
semiconductor

Title: Colloidal Synthesis of Bulk-Bandgap Lead Selenide Nanocrystals

Citation Formats

References (51)

Similar Records

Related Subjects