Discovery of Anion Insertion Electrochemistry in Layered Hydroxide Nanomaterials

Young, Matthias J.; Kiryutina, Tatyana; Bedford, Nicholas M.; Woehl, Taylor J.; Segre, Carlo U.

doi:10.1038/s41598-019-39052-1

Title: Discovery of Anion Insertion Electrochemistry in Layered Hydroxide Nanomaterials

Journal Article · 21 February 2019 · Scientific Reports

DOI: https://doi.org/10.1038/s41598-019-39052-1 · OSTI ID:1624455

^[1]; Kiryutina, Tatyana ^[2]; Bedford, Nicholas M. ^[3]; Woehl, Taylor J. ^[4];

^[5]

Argonne National Lab. (ANL), Argonne, IL (United States). Applied Materials Division; National Institute of Standards and Technology (NIST), Boulder, Colorado, 80305, (United States). Applied Chemicals and Materials Division; University of Missouri, Columbia, MO, 65211, (United States). Department of Biomedical, Biological, and Chemical Engineering; Department of Chemistry; DOE/OSTI
National Institute of Standards and Technology (NIST), Boulder, Colorado, 80305, (United States). Applied Chemicals and Materials Division
National Institute of Standards and Technology (NIST), Boulder, Colorado, 80305, (United States). Applied Chemicals and Materials Division; University of New South Wales, Sydney, NSW, 2052, (Australia). School of Chemical Engineering
National Institute of Standards and Technology (NIST), Boulder, Colorado, 80305 (United States). Applied Chemicals and Materials Division; University of Maryland, College Park, Maryland, 20742 (United States), Department of Chemical and Biomolecular Engineering
Illinois Institute of Technology, Chicago, IL (United States). Department of Physics

Electrode materials which undergo anion insertion are a void in the materials innovation landscape and a missing link to energy efficient electrochemical desalination. In recent years layered hydroxides (LHs) have been studied for a range of electrochemical applications, but to date have not been considered as electrode materials for anion insertion electrochemistry. Here, we show reversible anion insertion in a LH for the first time using Co and Co-V layer hydroxides. By pairing in situ synchrotron and quartz crystal microbalance measurements with a computational unified electrochemical band-diagram description, we reveal a previously undescribed anion-insertion mechanism occurring in Co and Co-V LHs. This proof of concept study demonstrates reversible electrochemical anion insertion in LHs without significant material optimization. These results coupled with our foundational understanding of anion insertion electrochemistry establishes LHs as a materials platform for anion insertion electrochemistry with the potential for future application to electrochemical desalination.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Joint Center for Energy Storage Research (JCESR); National Institute of Standards and Technology (NIST); USDOE Office of Science (SC), Basic Energy Sciences (BES); University of Maryland; University of Missouri

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1624455

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 9; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (101)

Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
Nickel-Cobalt Layered Double Hydroxide Nanosheets for High-performance Supercapacitor Electrode Materials Chen, Hao; Hu, Linfeng; Chen, Min Advanced Functional Materials, Vol. 24, Issue 7 https://doi.org/10.1002/adfm.201301747	journal	September 2013
Band Diagram and Rate Analysis of Thin Film Spinel LiMn ₂ O ₄ Formed by Electrochemical Conversion of ALD-Grown MnO Young, Matthias J.; Schnabel, Hans-Dieter; Holder, Aaron M. Advanced Functional Materials, Vol. 26, Issue 43 https://doi.org/10.1002/adfm.201602773	journal	September 2016
The Unified Electrochemical Band Diagram Framework: Understanding the Driving Forces of Materials Electrochemistry Young, Matthias J.; Holder, Aaron M.; Musgrave, Charles B. Advanced Functional Materials, Vol. 28, Issue 41 https://doi.org/10.1002/adfm.201803439	journal	August 2018
Modification of Wide-Band-Gap Oxide Semiconductors with Cobalt Hydroxide Nanoclusters for Visible-Light Water Oxidation Maeda, Kazuhiko; Ishimaki, Koki; Tokunaga, Yuki Angewandte Chemie International Edition, Vol. 55, Issue 29 https://doi.org/10.1002/anie.201602764	journal	May 2016
Electrochemical surface properties of Co3O4 electrodes Boggio, R.; Carugati, A.; Trasatti, S. Journal of Applied Electrochemistry, Vol. 17, Issue 4 https://doi.org/10.1007/bf01007821	journal	July 1987
Reversible electrochemical insertion of anions in poly-p-phenylene from aqueous electrolytes Beck, Fritz; Pruß, Arno Electrochimica Acta, Vol. 28, Issue 12 https://doi.org/10.1016/0013-4686(83)87025-x	journal	December 1983
The synthesis of a hybrid graphene–nickel/manganese mixed oxide and its performance in lithium-ion batteries Latorre-Sanchez, Marcos; Atienzar, Pedro; Abellán, Gonzalo Carbon, Vol. 50, Issue 2 https://doi.org/10.1016/j.carbon.2011.09.007	journal	February 2012
Energy consumption in membrane capacitive deionization for different water recoveries and flow rates, and comparison with reverse osmosis Zhao, R.; Porada, S.; Biesheuvel, P. M. Desalination, Vol. 330 https://doi.org/10.1016/j.desal.2013.08.017	journal	December 2013
Ultrahigh energy density and stable supercapacitor with 2D NiCoAl Layered double hydroxide Xiao, Yuanhua; Su, Dangcheng; Wang, Xuezhao Electrochimica Acta, Vol. 253 https://doi.org/10.1016/j.electacta.2017.09.033	journal	November 2017
Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water Porada, Slawomir; Shrivastava, Aniruddh; Bukowska, Pamela Electrochimica Acta, Vol. 255 https://doi.org/10.1016/j.electacta.2017.09.137	journal	November 2017
Silver nanoparticles: Behaviour and effects in the aquatic environment Fabrega, Julia; Luoma, Samuel N.; Tyler, Charles R. Environment International, Vol. 37, Issue 2 https://doi.org/10.1016/j.envint.2010.10.012	journal	February 2011
Water Desalination with Energy Storage Electrode Materials Suss, Matthew E.; Presser, Volker Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.12.010	journal	January 2018
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Rechargeable magnesium battery: Current status and key challenges for the future Saha, Partha; Datta, Moni Kanchan; Velikokhatnyi, Oleg I. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.04.001	journal	October 2014
Low Energy Desalination Using Battery Electrode Deionization Kim, Taeyoung; Gorski, Christopher A.; Logan, Bruce E. Environmental Science & Technology Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acs.estlett.7b00392	journal	September 2017
Calcined MgAl-Layered Double Hydroxide/Graphene Hybrids for Capacitive Deionization Ren, Qidi; Wang, Gang; Wu, Tingting Industrial & Engineering Chemistry Research, Vol. 57, Issue 18 https://doi.org/10.1021/acs.iecr.7b04983	journal	March 2018
Rocking Chair Desalination Battery Based on Prussian Blue Electrodes Lee, Jaehan; Kim, Seonghwan; Yoon, Jeyong ACS Omega, Vol. 2, Issue 4 https://doi.org/10.1021/acsomega.6b00526	journal	April 2017
Charge Storage in Cation Incorporated α-MnO ₂ Young, Matthias J.; Holder, Aaron M.; George, Steven M. Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm503544e	journal	February 2015
Recent Advances in the Synthesis and Application of Layered Double Hydroxide (LDH) Nanosheets Wang, Qiang; O’Hare, Dermot Chemical Reviews, Vol. 112, Issue 7 https://doi.org/10.1021/cr200434v	journal	March 2012
Selective and Controlled Synthesis of α- and β-Cobalt Hydroxides in Highly Developed Hexagonal Platelets Liu, Zhaoping; Ma, Renzhi; Osada, Minoru Journal of the American Chemical Society, Vol. 127, Issue 40 https://doi.org/10.1021/ja0523338	journal	October 2005
Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ Bloor, Leanne G.; Molina, Pedro I.; Symes, Mark D. Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja5003197	journal	February 2014
Structural modelling of glasses using reverse Monte Carlo simulation Keen, D. A.; McGreevy, R. L. Nature, Vol. 344, Issue 6265 https://doi.org/10.1038/344423a0	journal	March 1990
Charge self-regulation upon changing the oxidation state of transition metals in insulators Raebiger, Hannes; Lany, Stephan; Zunger, Alex Nature, Vol. 453, Issue 7196 https://doi.org/10.1038/nature07009	journal	June 2008
Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes Mefford, J. Tyler; Hardin, William G.; Dai, Sheng Nature Materials, Vol. 13, Issue 7 https://doi.org/10.1038/nmat4000	journal	June 2014
Layered double hydroxide films: synthesis, properties and applications Guo, Xiaoxiao; Zhang, Fazhi; Evans, David G. Chemical Communications, Vol. 46, Issue 29 https://doi.org/10.1039/c0cc00313a	journal	January 2010
Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties Islam, M. Saiful; Fisher, Craig A. J. Chem. Soc. Rev., Vol. 43, Issue 1 https://doi.org/10.1039/c3cs60199d	journal	January 2014
Ultrafast high-capacity NiZn battery with NiAlCo-layered double hydroxide Gong, Ming; Li, Yanguang; Zhang, Hongbo Energy & Environmental Science, Vol. 7, Issue 6 https://doi.org/10.1039/c4ee00317a	journal	January 2014
Sodium-ion batteries: present and future Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook Chemical Society Reviews, Vol. 46, Issue 12 https://doi.org/10.1039/c6cs00776g	journal	January 2017
Electrochemistry of the viologens Bird, C. L.; Kuhn, A. T. Chemical Society Reviews, Vol. 10, Issue 1 https://doi.org/10.1039/cs9811000049	journal	January 1981
In situ electrochemical high-energy X-ray diffraction using a capillary working electrode cell geometry Young, Matthias J.; Bedford, Nicholas M.; Jiang, Naisheng Journal of Synchrotron Radiation, Vol. 24, Issue 4 https://doi.org/10.1107/s1600577517006282	journal	May 2017
Characterization of Sol-Gel-Derived Cobalt Oxide Xerogels as Electrochemical Capacitors Lin, Chuan Journal of The Electrochemical Society, Vol. 145, Issue 12 https://doi.org/10.1149/1.1838920	journal	January 1998
Efficient Capacitive Deionization Using Thin Film Sodium Manganese Oxide Wallas, Jasmine M.; Young, Matthias J.; Sun, Huaxing Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.0751810jes	journal	January 2018
Strategies for Developing New Anion Exchange Membranes and Electrode Ionomers Hickner, Michael A. The Electrochemical Society Interface, Vol. 26, Issue 1 https://doi.org/10.1149/2.f08171if	journal	January 2017
Mixed magnesium-aluminiun hydroxides. I. Preparation and characterization of compounds formed in dialysed systems Gastuche, M. C.; Brown, G.; Mortland, M. M. Clay Minerals, Vol. 7, Issue 2 https://doi.org/10.1180/claymin.1967.007.2.05	journal	December 1967
Mixed magnesium-aluminium hydroxides. II. Structure and structural chemistry of synthetic hydroxycarbonates and related minerals and compounds Brown, G.; Gastuche, M. C. Clay Minerals, Vol. 7, Issue 2 https://doi.org/10.1180/claymin.1967.007.2.06	journal	December 1967
The Syntheses of Hydrotalcite-Like Compounds and Their Structures and Physico-Chemical Properties I: The Systems Mg2+-Al3+-NO3−, Mg2+-Al3+-Cl−, Mg2+-Al3+-ClO4−, Ni2+-Al3+-Cl− and Zn2+-Al3+-Cl− Miyata, Shigeo Clays and Clay Minerals, Vol. 23, Issue 5 https://doi.org/10.1346/ccmn.1975.0230508	journal	January 1975
Inorganic Layered Double Hydroxides as Nonviral Vectors Choy, Jin-Ho; Kwak, Seo-Young; Jeong, Yong-Joo Angewandte Chemie, Vol. 112, Issue 22 https://doi.org/10.1002/1521-3757(20001117)112:22<4207::aid-ange4207>3.0.co;2-h	journal	November 2000
Inorganic Layered Double Hydroxides as Nonviral Vectors Choy, Jin-Ho; Kwak, Seo-Young; Jeong, Yong-Joo Angewandte Chemie, Vol. 39, Issue 22 https://doi.org/10.1002/1521-3773(20001117)39:22<4041::AID-ANIE4041>3.0.CO;2-C	journal	November 2000
Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
Nickel-Cobalt Layered Double Hydroxide Nanosheets for High-performance Supercapacitor Electrode Materials Chen, Hao; Hu, Linfeng; Chen, Min Advanced Functional Materials, Vol. 24, Issue 7 https://doi.org/10.1002/adfm.201301747	journal	September 2013
High-Performing Monometallic Cobalt Layered Double Hydroxide Supercapacitor with Defined Local Structure Vialat, Pierre; Mousty, Christine; Taviot-Gueho, Christine Advanced Functional Materials, Vol. 24, Issue 30 https://doi.org/10.1002/adfm.201400310	journal	May 2014
Band Diagram and Rate Analysis of Thin Film Spinel LiMn ₂ O ₄ Formed by Electrochemical Conversion of ALD-Grown MnO Young, Matthias J.; Schnabel, Hans-Dieter; Holder, Aaron M. Advanced Functional Materials, Vol. 26, Issue 43 https://doi.org/10.1002/adfm.201602773	journal	September 2016
The Unified Electrochemical Band Diagram Framework: Understanding the Driving Forces of Materials Electrochemistry Young, Matthias J.; Holder, Aaron M.; Musgrave, Charles B. Advanced Functional Materials, Vol. 28, Issue 41 https://doi.org/10.1002/adfm.201803439	journal	August 2018
Sodium-Ion Batteries Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201800880	journal	June 2018
Modification of Wide-Band-Gap Oxide Semiconductors with Cobalt Hydroxide Nanoclusters for Visible-Light Water Oxidation Maeda, Kazuhiko; Ishimaki, Koki; Tokunaga, Yuki Angewandte Chemie, Vol. 128, Issue 29 https://doi.org/10.1002/ange.201602764	journal	May 2016
Modification of Wide-Band-Gap Oxide Semiconductors with Cobalt Hydroxide Nanoclusters for Visible-Light Water Oxidation Maeda, Kazuhiko; Ishimaki, Koki; Tokunaga, Yuki Angewandte Chemie International Edition, Vol. 55, Issue 29 https://doi.org/10.1002/anie.201602764	journal	May 2016
Intercalation Chemistry of Layered Double Hydroxides: Recent Developments and Applications Khan, Aamir I.; O'Hare, Dermot ChemInform, Vol. 34, Issue 20 https://doi.org/10.1002/chin.200320250	journal	May 2003
Beyond Crystallography: The Study of Disorder, Nanocrystallinity and Crystallographically Challenged Materials with Pair Distribution Functions Billinge, Simon J. L.; Kanatzidis, M. G. ChemInform, Vol. 35, Issue 25 https://doi.org/10.1002/chin.200425250	journal	June 2004
Electrochemical Equilibria Pourbaix, Marcel; Staehle, Roger W.; Pourbaix, Marcel Lectures on Electrochemical Corrosion, p 83-183 https://doi.org/10.1007/978-1-4684-1806-4_4	book	January 1973
Electrochemical surface properties of Co3O4 electrodes Boggio, R.; Carugati, A.; Trasatti, S. Journal of Applied Electrochemistry, Vol. 17, Issue 4 https://doi.org/10.1007/BF01007821	journal	July 1987
Reversible electrochemical insertion of anions in poly-p-phenylene from aqueous electrolytes Beck, Fritz; Pruß, Arno Electrochimica Acta, Vol. 28, Issue 12 https://doi.org/10.1016/0013-4686(83)87025-x	journal	December 1983
Electrosynthesis of poly(p-phenylene) films and their application to the electrodes of rechargeable batteries Morita, Masayuki; Komaguchi, Kenji; Tsutsumi, Hiromori Electrochimica Acta, Vol. 37, Issue 6 https://doi.org/10.1016/0013-4686(92)85227-C	journal	May 1992
Reversible electrochemical insertion of anions in poly-p-phenylene from aqueous electrolytes Pruss, Arno; Beck, Fritz Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 172, Issue 1-2 https://doi.org/10.1016/0022-0728(84)80192-8	journal	August 1984
Electrochemical formation and reduction of silver oxides in alkaline media Droog, John M. M.; Huisman, Fred Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 115, Issue 2 https://doi.org/10.1016/S0022-0728(80)80326-3	journal	December 1980
Nanostructure by high-energy X-ray diffraction Petkov, Valeri Materials Today, Vol. 11, Issue 11 https://doi.org/10.1016/S1369-7021(08)70236-0	journal	November 2008
The synthesis of a hybrid graphene–nickel/manganese mixed oxide and its performance in lithium-ion batteries Latorre-Sanchez, Marcos; Atienzar, Pedro; Abellán, Gonzalo Carbon, Vol. 50, Issue 2 https://doi.org/10.1016/j.carbon.2011.09.007	journal	February 2012
Energy consumption in membrane capacitive deionization for different water recoveries and flow rates, and comparison with reverse osmosis Zhao, R.; Porada, S.; Biesheuvel, P. M. Desalination, Vol. 330 https://doi.org/10.1016/j.desal.2013.08.017	journal	December 2013
Electrochemical behavior of LiCoO₂ as aqueous lithium-ion battery electrodes Ruffo, Riccardo; Wessells, Colin; Huggins, Robert A. Electrochemistry Communications, Vol. 11, Issue 2, p. 247-249 https://doi.org/10.1016/j.elecom.2008.11.015	journal	February 2009
Ultrahigh energy density and stable supercapacitor with 2D NiCoAl Layered double hydroxide Xiao, Yuanhua; Su, Dangcheng; Wang, Xuezhao Electrochimica Acta, Vol. 253 https://doi.org/10.1016/j.electacta.2017.09.033	journal	November 2017
Nickel Hexacyanoferrate Electrodes for Continuous Cation Intercalation Desalination of Brackish Water Porada, Slawomir; Shrivastava, Aniruddh; Bukowska, Pamela Electrochimica Acta, Vol. 255 https://doi.org/10.1016/j.electacta.2017.09.137	journal	November 2017
Silver nanoparticles: Behaviour and effects in the aquatic environment Fabrega, Julia; Luoma, Samuel N.; Tyler, Charles R. Environment International, Vol. 37, Issue 2 https://doi.org/10.1016/j.envint.2010.10.012	journal	February 2011
Water Desalination with Energy Storage Electrode Materials Suss, Matthew E.; Presser, Volker Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.12.010	journal	January 2018
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Rechargeable magnesium battery: Current status and key challenges for the future Saha, Partha; Datta, Moni Kanchan; Velikokhatnyi, Oleg I. Progress in Materials Science, Vol. 66 https://doi.org/10.1016/j.pmatsci.2014.04.001	journal	October 2014
Low Energy Desalination Using Battery Electrode Deionization Kim, Taeyoung; Gorski, Christopher A.; Logan, Bruce E. Environmental Science & Technology Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acs.estlett.7b00392	journal	September 2017
Calcined MgAl-Layered Double Hydroxide/Graphene Hybrids for Capacitive Deionization Ren, Qidi; Wang, Gang; Wu, Tingting Industrial & Engineering Chemistry Research, Vol. 57, Issue 18 https://doi.org/10.1021/acs.iecr.7b04983	journal	March 2018
Rocking Chair Desalination Battery Based on Prussian Blue Electrodes Lee, Jaehan; Kim, Seonghwan; Yoon, Jeyong ACS Omega, Vol. 2, Issue 4 https://doi.org/10.1021/acsomega.6b00526	journal	April 2017
Charge Storage in Cation Incorporated α-MnO ₂ Young, Matthias J.; Holder, Aaron M.; George, Steven M. Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm503544e	journal	February 2015
Recent Advances in the Synthesis and Application of Layered Double Hydroxide (LDH) Nanosheets Wang, Qiang; O’Hare, Dermot Chemical Reviews, Vol. 112, Issue 7 https://doi.org/10.1021/cr200434v	journal	March 2012
Selective and Controlled Synthesis of α- and β-Cobalt Hydroxides in Highly Developed Hexagonal Platelets Liu, Zhaoping; Ma, Renzhi; Osada, Minoru Journal of the American Chemical Society, Vol. 127, Issue 40 https://doi.org/10.1021/ja0523338	journal	October 2005
An Advanced Ni–Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation Gong, Ming; Li, Yanguang; Wang, Hailiang Journal of the American Chemical Society, Vol. 135, Issue 23 https://doi.org/10.1021/ja4027715	journal	May 2013
Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ Bloor, Leanne G.; Molina, Pedro I.; Symes, Mark D. Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja5003197	journal	February 2014
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst Song, Fang; Hu, Xile Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja5096733	journal	November 2014
Dispersion and Size Control of Layered Double Hydroxide Nanoparticles in Aqueous Solutions Xu, Zhi Ping; Stevenson, Gregory; Lu, Chao-Qing The Journal of Physical Chemistry B, Vol. 110, Issue 34 https://doi.org/10.1021/jp062281o	journal	August 2006
A Desalination Battery Pasta, Mauro; Wessells, Colin D.; Cui, Yi Nano Letters, Vol. 12, Issue 2 https://doi.org/10.1021/nl203889e	journal	January 2012
Structural modelling of glasses using reverse Monte Carlo simulation Keen, D. A.; McGreevy, R. L. Nature, Vol. 344, Issue 6265 https://doi.org/10.1038/344423a0	journal	March 1990
Charge self-regulation upon changing the oxidation state of transition metals in insulators Raebiger, Hannes; Lany, Stephan; Zunger, Alex Nature, Vol. 453, Issue 7196 https://doi.org/10.1038/nature07009	journal	June 2008
Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes Mefford, J. Tyler; Hardin, William G.; Dai, Sheng Nature Materials, Vol. 13, Issue 7 https://doi.org/10.1038/nmat4000	journal	June 2014
Intercalation chemistry of layered double hydroxides: recent developments and applications Khan, Aamir I.; O’Hare, Dermot J. Mater. Chem., Vol. 12, Issue 11 https://doi.org/10.1039/B204076J	journal	January 2002
Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties Islam, M. Saiful; Fisher, Craig A. J. Chem. Soc. Rev., Vol. 43, Issue 1 https://doi.org/10.1039/C3CS60199D	journal	January 2014
Three-dimensional NiAl-mixed metal oxide film: preparation and capacitive deionization performances Lei, Xiaodong; Wang, Bo; Liu, Junfeng RSC Adv., Vol. 4, Issue 78 https://doi.org/10.1039/C4RA08415B	journal	January 2014
Sodium-ion batteries: present and future Hwang, Jang-Yeon; Myung, Seung-Taek; Sun, Yang-Kook Chemical Society Reviews, Vol. 46, Issue 12 https://doi.org/10.1039/C6CS00776G	journal	January 2017
Ultrahigh-rate-capability of a layered double hydroxide supercapacitor based on a self-generated electrolyte reservoir Liu, Xiaoxi; Zhou, Awu; Pan, Ting Journal of Materials Chemistry A, Vol. 4, Issue 21 https://doi.org/10.1039/C6TA02164F	journal	January 2016
Dual-ions electrochemical deionization: a desalination generator Chen, Fuming; Huang, Yinxi; Guo, Lu Energy & Environmental Science, Vol. 10, Issue 10 https://doi.org/10.1039/C7EE00855D	journal	January 2017
Beyond crystallography: the study of disorder, nanocrystallinity and crystallographically challenged materials with pair distribution functions Billinge, Simon J. L.; Kanatzidis, M. G. Chemical Communications, Issue 7 https://doi.org/10.1039/b309577k	journal	January 2004
Layered double hydroxide films: synthesis, properties and applications Guo, Xiaoxiao; Zhang, Fazhi; Evans, David G. Chemical Communications, Vol. 46, Issue 29 https://doi.org/10.1039/c0cc00313a	journal	January 2010
Ultrafast high-capacity NiZn battery with NiAlCo-layered double hydroxide Gong, Ming; Li, Yanguang; Zhang, Hongbo Energy & Environmental Science, Vol. 7, Issue 6 https://doi.org/10.1039/c4ee00317a	journal	January 2014
Electrochemistry of the viologens Bird, C. L.; Kuhn, A. T. Chemical Society Reviews, Vol. 10, Issue 1 https://doi.org/10.1039/cs9811000049	journal	January 1981
In situ electrochemical high-energy X-ray diffraction using a capillary working electrode cell geometry Young, Matthias J.; Bedford, Nicholas M.; Jiang, Naisheng Journal of Synchrotron Radiation, Vol. 24, Issue 4 https://doi.org/10.1107/S1600577517006282	journal	May 2017
Structural and Spectroelectrochemical Investigations of Sol-Gel Derived Electrochromic Spinel Co[sub 3]O[sub 4] Films Švegl, F. Journal of The Electrochemical Society, Vol. 143, Issue 5 https://doi.org/10.1149/1.1836675	journal	January 1996
Characterization of Sol-Gel-Derived Cobalt Oxide Xerogels as Electrochemical Capacitors Lin, Chuan Journal of The Electrochemical Society, Vol. 145, Issue 12 https://doi.org/10.1149/1.1838920	journal	January 1998
Silver/Silver Chloride Electrodes: Surface Morphology on Charging and Discharging Katan, T.; Szpak, S.; Bennion, Douglas N. Journal of The Electrochemical Society, Vol. 121, Issue 6 https://doi.org/10.1149/1.2401904	journal	January 1974
A Co–Al Layered Double Hydroxides Nanosheets Thin-Film Electrode Wang, Yi; Yang, Wensheng; Yang, Junjiao Electrochemical and Solid-State Letters, Vol. 10, Issue 10 https://doi.org/10.1149/1.2768166	journal	January 2007
Efficient Capacitive Deionization Using Thin Film Sodium Manganese Oxide Wallas, Jasmine M.; Young, Matthias J.; Sun, Huaxing Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.0751810jes	journal	January 2018
Strategies for Developing New Anion Exchange Membranes and Electrode Ionomers Hickner, Michael A. The Electrochemical Society Interface, Vol. 26, Issue 1 https://doi.org/10.1149/2.F08171if	journal	January 2017
Mixed magnesium-aluminiun hydroxides. I. Preparation and characterization of compounds formed in dialysed systems Gastuche, M. C.; Brown, G.; Mortland, M. M. Clay Minerals, Vol. 7, Issue 2 https://doi.org/10.1180/claymin.1967.007.2.05	journal	December 1967
Mixed magnesium-aluminium hydroxides. II. Structure and structural chemistry of synthetic hydroxycarbonates and related minerals and compounds Brown, G.; Gastuche, M. C. Clay Minerals, Vol. 7, Issue 2 https://doi.org/10.1180/claymin.1967.007.2.06	journal	December 1967
The Syntheses of Hydrotalcite-Like Compounds and Their Structures and Physico-Chemical Properties I: The Systems Mg2+-Al3+-NO3−, Mg2+-Al3+-Cl−, Mg2+-Al3+-ClO4−, Ni2+-Al3+-Cl− and Zn2+-Al3+-Cl− Miyata, Shigeo Clays and Clay Minerals, Vol. 23, Issue 5 https://doi.org/10.1346/CCMN.1975.0230508	journal	January 1975
Anion-Exchange Properties of Hydrotalcite-Like Compounds Miyata, Shigeo Clays and Clay Minerals, Vol. 31, Issue 4 https://doi.org/10.1346/CCMN.1983.0310409	journal	January 1983
Water Desalination with Energy Storage Electrode Materials Suss, Matthew E.; Presser, Volker Universität des Saarlandes https://doi.org/10.22028/d291-28908	collection	January 2018

Cited By (1)

A Facile Microwave‐Assisted Method to Prepare Highly Electrosorptive Reduced Graphene Oxide/Activated Carbon Composite Electrode for Capacitive Deionization Lai, Yi‐Ting; Liu, Wei‐Ting; Chung, Li‐Ching Advanced Materials Technologies, Vol. 4, Issue 9 https://doi.org/10.1002/admt.201900213	journal	August 2019

Similar Records

Layered hydroxides as anion insertion materials

Patent · 2024 · OSTI ID:2541634

Young, Matthias J.; Elam, Jeffrey W.

Nanomaterials in electrochemistry. Technical report number 19

Technical Report · 1998 · OSTI ID:658711

Martin, C R

Lithium Insertion Mechanism in Iron‐Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis

Journal Article · 2015 · ChemistryOpen · OSTI ID:1222371

Dambournet, Damien; Chapman, Karena W.; Duttine, Mathieu; +3 more

Related Subjects

Science & Technology - Other Topics

Title: Discovery of Anion Insertion Electrochemistry in Layered Hydroxide Nanomaterials

Citation Formats

References (101)

Cited By (1)

Similar Records

Related Subjects