Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery
Abstract
Sodium metal batteries have potentially high energy densities, but severe sodium-dendrite growth and side reactions prevent their practical applications, especially at high temperatures. Herein, we design an inorganic ionic conductor/gel polymer electrolyte composite, where uniformly cross-linked beta alumina nanowires are compactly coated by a poly(vinylidene fluoride-co-hexafluoropropylene)-based gel polymer electrolyte through their strong molecular interactions. These beta alumina nanowires combined with the gel polymer layer create dense and homogeneous solid-liquid hybrid sodium-ion transportation channels through and along the nanowires, which promote uniform sodium deposition and formation of a stable and flat solid electrolyte interface on the sodium metal anode. Side reactions between the sodium metal and liquid electrolyte, as well as sodium dendrite formation, are successfully suppressed, especially at 60 °C. The sodium vanadium phosphate/sodium full cells with composite electrolyte exhibit 95.3% and 78.8% capacity retention after 1000 cycles at 1C at 25 °C and 60 °C, respectively.
- Authors:
-
[4];
[10];
[4];
- Shenzhen Geim Graphene Center, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, China; State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, China
- Shenzhen Geim Graphene Center, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, China
- Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences (CAS), University of Science and Technology of China, Hefei, Anhui, China
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Xiamen Institute of Rare Earth Materials, Haixi institutes, Chinese Academy of Sciences, Xiamen, China
- School of Chemical Engineering and Technology, Xi’an Jiaotong University, Xi’an, China
- Shenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua University, Shenzhen, China
- Hefei National Laboratory for Physical Sciences at the Microscale, Department of Materials Science and Engineering, Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences (CAS), University of Science and Technology of China, Hefei, Anhui, China; Dalian National Laboratory for Clean Energy (DNL), Chinese Academy of Sciences (CAS), Dalian, Liaoning, China
- Nanoyang Group, School of Chemical Engineering and Technology, Tianjin University, Tianjin, China
- State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
- Shenzhen Geim Graphene Center, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, China; Shenzhen Environmental Science and New Energy Technology Engineering Laboratory, Tsinghua-Berkeley Shenzhen Institute (TBSI), Tsinghua University, Shenzhen, China
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Key Research Program; National Natural Science Foundation of China (NSFC); Local Innovative Research Teams Project of Guangdong Pearl River Talents Program; Guangdong special support program; Guangdong Province Technical Plan Project; Shenzhen Technical Plan Project; DNL cooperation Fund, Chinese Academy of Sciences (CAS)
- OSTI Identifier:
- 1624189
- Grant/Contract Number:
- AC02-06CH11357; 2018YFB0905400; 51672156; 51622210; 51872277; 51802361; 2017BT01N111; 2015TQ01N401; 2017B010119001; 2017B090907005; JCYJ20170412170706047; JCYJ20170307153806471; JCYJ20170817161221958; DNL180310
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Science & Technology - Other Topics
Citation Formats
Lei, Danni, He, Yan-Bing, Huang, Huijuan, Yuan, Yifei, Zhong, Guiming, Zhao, Qiang, Hao, Xiaoge, Zhang, Danfeng, Lai, Chen, Zhang, Siwei, Ma, Jiabin, Wei, Yinping, Yu, Qipeng, Lv, Wei, Yu, Yan, Li, Baohua, Yang, Quan-Hong, Yang, Yong, Lu, Jun, and Kang, Feiyu. Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery. United States: N. p., 2019.
Web. doi:10.1038/s41467-019-11960-w.
Lei, Danni, He, Yan-Bing, Huang, Huijuan, Yuan, Yifei, Zhong, Guiming, Zhao, Qiang, Hao, Xiaoge, Zhang, Danfeng, Lai, Chen, Zhang, Siwei, Ma, Jiabin, Wei, Yinping, Yu, Qipeng, Lv, Wei, Yu, Yan, Li, Baohua, Yang, Quan-Hong, Yang, Yong, Lu, Jun, & Kang, Feiyu. Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery. United States. https://doi.org/10.1038/s41467-019-11960-w
Lei, Danni, He, Yan-Bing, Huang, Huijuan, Yuan, Yifei, Zhong, Guiming, Zhao, Qiang, Hao, Xiaoge, Zhang, Danfeng, Lai, Chen, Zhang, Siwei, Ma, Jiabin, Wei, Yinping, Yu, Qipeng, Lv, Wei, Yu, Yan, Li, Baohua, Yang, Quan-Hong, Yang, Yong, Lu, Jun, and Kang, Feiyu. Wed .
"Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery". United States. https://doi.org/10.1038/s41467-019-11960-w. https://www.osti.gov/servlets/purl/1624189.
@article{osti_1624189,
title = {Cross-linked beta alumina nanowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery},
author = {Lei, Danni and He, Yan-Bing and Huang, Huijuan and Yuan, Yifei and Zhong, Guiming and Zhao, Qiang and Hao, Xiaoge and Zhang, Danfeng and Lai, Chen and Zhang, Siwei and Ma, Jiabin and Wei, Yinping and Yu, Qipeng and Lv, Wei and Yu, Yan and Li, Baohua and Yang, Quan-Hong and Yang, Yong and Lu, Jun and Kang, Feiyu},
abstractNote = {Sodium metal batteries have potentially high energy densities, but severe sodium-dendrite growth and side reactions prevent their practical applications, especially at high temperatures. Herein, we design an inorganic ionic conductor/gel polymer electrolyte composite, where uniformly cross-linked beta alumina nanowires are compactly coated by a poly(vinylidene fluoride-co-hexafluoropropylene)-based gel polymer electrolyte through their strong molecular interactions. These beta alumina nanowires combined with the gel polymer layer create dense and homogeneous solid-liquid hybrid sodium-ion transportation channels through and along the nanowires, which promote uniform sodium deposition and formation of a stable and flat solid electrolyte interface on the sodium metal anode. Side reactions between the sodium metal and liquid electrolyte, as well as sodium dendrite formation, are successfully suppressed, especially at 60 °C. The sodium vanadium phosphate/sodium full cells with composite electrolyte exhibit 95.3% and 78.8% capacity retention after 1000 cycles at 1C at 25 °C and 60 °C, respectively.},
doi = {10.1038/s41467-019-11960-w},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United States},
year = {Wed Sep 18 00:00:00 EDT 2019},
month = {Wed Sep 18 00:00:00 EDT 2019}
}
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Ambient-Temperature Sodium-Sulfur Batteries with a Sodiated Nafion Membrane and a Carbon Nanofiber-Activated Carbon Composite Electrode
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A Sodium-Ion Battery with a Low-Cost Cross-Linked Gel-Polymer Electrolyte
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3D Flexible Carbon Felt Host for Highly Stable Sodium Metal Anodes
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- Chi, Shang-Sen; Qi, Xing-Guo; Hu, Yong-Sheng
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Ionic Liquids and Organic Ionic Plastic Crystals: Advanced Electrolytes for Safer High Performance Sodium Energy Storage Technologies
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- Basile, Andrew; Hilder, Matthias; Makhlooghiazad, Faezeh
- Advanced Energy Materials, Vol. 8, Issue 17
Highly Reversible Na Storage in Na 3 V 2 (PO 4 ) 3 by Optimizing Nanostructure and Rational Surface Engineering
journal, March 2018
- Jiang, Yu; Zhou, Xuefeng; Li, Dongjun
- Advanced Energy Materials, Vol. 8, Issue 16
High-Performance Sodium Metal Anodes Enabled by a Bifunctional Potassium Salt
journal, May 2018
- Shi, Qiuwei; Zhong, Yiren; Wu, Min
- Angewandte Chemie, Vol. 130, Issue 29
Ion–Solvent Complexes Promote Gas Evolution from Electrolytes on a Sodium Metal Anode
journal, January 2018
- Chen, Xiang; Shen, Xin; Li, Bo
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Facile Stabilization of the Sodium Metal Anode with Additives: Unexpected Key Role of Sodium Polysulfide and Adverse Effect of Sodium Nitrate
journal, May 2018
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The relative stability of spray-frozen/freeze-dried β″-Al2O3 powders
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Novel ternary composites reduced-graphene oxide/zine oxide/poly(p-phenylenediamine) for supercapacitor: Synthesis and properties
journal, June 2017
- Li, Jie; Sun, Ying; Li, Dan
- Journal of Alloys and Compounds, Vol. 708
Electrolyte and Interface Engineering for Solid-State Sodium Batteries
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- Lu, Yong; Li, Lin; Zhang, Qiu
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Ion transport and ion–filler-polymer interaction in poly(methyl methacrylate)-based, sodium ion conducting, gel polymer electrolytes dispersed with silica nanoparticles
journal, August 2010
- Kumar, Deepak; Hashmi, S. A.
- Journal of Power Sources, Vol. 195, Issue 15
A superior composite gel polymer electrolyte of Li7La3Zr2O12- poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) for rechargeable solid-state lithium ion batteries
journal, June 2018
- Liang, Y. F.; Deng, S. J.; Xia, Y.
- Materials Research Bulletin, Vol. 102
Li-ion battery materials: present and future
journal, June 2015
- Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
- Materials Today, Vol. 18, Issue 5
Encapsulation of Metallic Na in an Electrically Conductive Host with Porous Channels as a Highly Stable Na Metal Anode
journal, May 2017
- Luo, Wei; Zhang, Ying; Xu, Shaomao
- Nano Letters, Vol. 17, Issue 6
Inorganic–Organic Coating via Molecular Layer Deposition Enables Long Life Sodium Metal Anode
journal, August 2017
- Zhao, Yang; Goncharova, Lyudmila V.; Zhang, Qian
- Nano Letters, Vol. 17, Issue 9
Porous Al Current Collector for Dendrite-Free Na Metal Anodes
journal, August 2017
- Liu, Shan; Tang, Shan; Zhang, Xinyue
- Nano Letters, Vol. 17, Issue 9
Enhancing the Cycling Stability of Sodium Metal Electrodes by Building an Inorganic–Organic Composite Protective Layer
journal, February 2017
- Kim, Yun-Jung; Lee, Hongkyung; Noh, Hyungjun
- ACS Applied Materials & Interfaces, Vol. 9, Issue 7
A Highly Reversible Room-Temperature Sodium Metal Anode
journal, November 2015
- Seh, Zhi Wei; Sun, Jie; Sun, Yongming
- ACS Central Science, Vol. 1, Issue 8
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Lithium battery chemistries enabled by solid-state electrolytes
journal, February 2017
- Manthiram, Arumugam; Yu, Xingwen; Wang, Shaofei
- Nature Reviews Materials, Vol. 2, Issue 4
Advanced intermediate temperature sodium–nickel chloride batteries with ultra-high energy density
journal, February 2016
- Li, Guosheng; Lu, Xiaochuan; Kim, Jin Y.
- Nature Communications, Vol. 7, Issue 1
A stable room-temperature sodium–sulfur battery
journal, June 2016
- Wei, Shuya; Xu, Shaomao; Agrawral, Akanksha
- Nature Communications, Vol. 7, Issue 1
Enhancing ionic conductivity in composite polymer electrolytes with well-aligned ceramic nanowires
journal, April 2017
- Liu, Wei; Lee, Seok Woo; Lin, Dingchang
- Nature Energy, Vol. 2, Issue 5
A rechargeable room-temperature sodium superoxide (NaO2) battery
journal, December 2012
- Hartmann, Pascal; Bender, Conrad L.; Vračar, Miloš
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