Lead halide perovskites for photocatalytic organic synthesis
Abstract
Abstract Nature is capable of storing solar energy in chemical bonds via photosynthesis through a series of C–C, C–O and C–N bond-forming reactions starting from CO 2 and light. Direct capture of solar energy for organic synthesis is a promising approach. Lead (Pb)-halide perovskite solar cells reach 24.2% power conversion efficiency, rendering perovskite a unique type material for solar energy capture. We argue that photophysical properties of perovskites already proved for photovoltaics, also should be of interest in photoredox organic synthesis. Because the key aspects of these two applications are both relying on charge separation and transfer. Here we demonstrated that perovskites nanocrystals are exceptional candidates as photocatalysts for fundamental organic reactions, for example C–C, C–N and C–O bond-formations. Stability of CsPbBr 3 in organic solvents and ease-of-tuning their bandedges garner perovskite a wider scope of organic substrate activations. Our low-cost, easy-to-process, highly-efficient, air-tolerant and bandedge-tunable perovskites may bring new breakthrough in organic chemistry.
- Authors:
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Hybrid Organic-Inorganic Semiconductors for Energy (CHOISE); San Diego State Univ., CA (United States)
- Sponsoring Org.:
- USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1619528
- Alternate Identifier(s):
- OSTI ID: 1624161
- Grant/Contract Number:
- EFRC-CHOISE; FG02-00ER41132
- Resource Type:
- Published Article
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Name: Nature Communications Journal Volume: 10 Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Science & Technology - Other Topics
Citation Formats
Zhu, Xiaolin, Lin, Yixiong, San Martin, Jovan, Sun, Yue, Zhu, Dian, and Yan, Yong. Lead halide perovskites for photocatalytic organic synthesis. United Kingdom: N. p., 2019.
Web. doi:10.1038/s41467-019-10634-x.
Zhu, Xiaolin, Lin, Yixiong, San Martin, Jovan, Sun, Yue, Zhu, Dian, & Yan, Yong. Lead halide perovskites for photocatalytic organic synthesis. United Kingdom. https://doi.org/10.1038/s41467-019-10634-x
Zhu, Xiaolin, Lin, Yixiong, San Martin, Jovan, Sun, Yue, Zhu, Dian, and Yan, Yong. Fri .
"Lead halide perovskites for photocatalytic organic synthesis". United Kingdom. https://doi.org/10.1038/s41467-019-10634-x.
@article{osti_1619528,
title = {Lead halide perovskites for photocatalytic organic synthesis},
author = {Zhu, Xiaolin and Lin, Yixiong and San Martin, Jovan and Sun, Yue and Zhu, Dian and Yan, Yong},
abstractNote = {Abstract Nature is capable of storing solar energy in chemical bonds via photosynthesis through a series of C–C, C–O and C–N bond-forming reactions starting from CO 2 and light. Direct capture of solar energy for organic synthesis is a promising approach. Lead (Pb)-halide perovskite solar cells reach 24.2% power conversion efficiency, rendering perovskite a unique type material for solar energy capture. We argue that photophysical properties of perovskites already proved for photovoltaics, also should be of interest in photoredox organic synthesis. Because the key aspects of these two applications are both relying on charge separation and transfer. Here we demonstrated that perovskites nanocrystals are exceptional candidates as photocatalysts for fundamental organic reactions, for example C–C, C–N and C–O bond-formations. Stability of CsPbBr 3 in organic solvents and ease-of-tuning their bandedges garner perovskite a wider scope of organic substrate activations. Our low-cost, easy-to-process, highly-efficient, air-tolerant and bandedge-tunable perovskites may bring new breakthrough in organic chemistry.},
doi = {10.1038/s41467-019-10634-x},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United Kingdom},
year = {Fri Jun 28 00:00:00 EDT 2019},
month = {Fri Jun 28 00:00:00 EDT 2019}
}
https://doi.org/10.1038/s41467-019-10634-x
Web of Science
Figures / Tables:
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