Metallic 1T Phase, 3d1 Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride

Wong, Ping Kwan Johnny; Zhang, Wen; Zhou, Jun; Bussolotti, Fabio; Yin, Xinmao; Zhang, Lei; N’Diaye, Alpha T.; Morton, Simon A.; Chen, Wei; Goh, Johnson; de Jong, Michel P.; Feng, Yuan Ping; Wee, Andrew T.  S.

doi:10.1021/acsnano.9b05349

Title: Metallic 1T Phase, 3d¹ Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride

Abstract

We present a combined experimental and theoretical study of monolayer vanadium ditelluride, VTe2, grown on highly oriented pyrolytic graphite by molecular-beam epitaxy. Using various in situ microscopic and spectroscopic techniques, including scanning tunneling microscopy/spectroscopy, synchrotron X-ray and angle-resolved photoemission, and X-ray absorption, together with theoretical analysis by density functional theory calculations, we demonstrate direct evidence of the metallic 1T phase and 3d1 electronic configuration in monolayer VTe2 that also features a (4 × 4) charge density wave order at low temperatures. In contrast to previous theoretical predictions, our element-specific characterization by X-ray magnetic circular dichroism rules out a ferromagnetic order intrinsic to the monolayer. Our findings provide essential knowledge necessary for understanding this interesting yet less explored metallic monolayer in the emerging family of van der Waals magnets.

Authors:

^[1];

^[1]; Bussolotti, Fabio ^[2];

^[1];

^[1]; N’Diaye, Alpha T. ^[3]; Morton, Simon A. ^[3]; Chen, Wei ^[1]; Goh, Johnson ^[4];

^[5];

^[1];

^[1]

National Univ. of Singapore (Singapore)
Agency for Science, Technology, and Research (A*Star), Innovis, (Singapore)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
National Univ. of Singapore (Singapore); Agency for Science, Technology, and Research (A*Star), Innovis, (Singapore)
Univ. of Twente, Enschede (Netherlands)

Publication Date:: Wed Nov 06 00:00:00 EST 2019

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Singapore Ministry of Education

OSTI Identifier:: 1619138

Grant/Contract Number:: AC02-05CH11231; MOE2016-T2-2-110; R-143-000-652-112; 1527000016

Resource Type:: Accepted Manuscript

Journal Name:: ACS Nano

Additional Journal Information:: Journal Volume: 13; Journal Issue: 11; Journal ID: ISSN 1936-0851

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; two-dimensional materials; transition-metal dichalcogenides; vanadium ditelluride; molecular beam epitaxy; magnetism

Citation Formats


                    Wong, Ping Kwan Johnny, Zhang, Wen, Zhou, Jun, Bussolotti, Fabio, Yin, Xinmao, Zhang, Lei, N’Diaye, Alpha T., Morton, Simon A., Chen, Wei, Goh, Johnson, de Jong, Michel P., Feng, Yuan Ping, and Wee, Andrew T.  S. Metallic 1T Phase, 3d1 Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride.  United States: N. p., 2019. 
Web.  doi:10.1021/acsnano.9b05349.

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                    Wong, Ping Kwan Johnny, Zhang, Wen, Zhou, Jun, Bussolotti, Fabio, Yin, Xinmao, Zhang, Lei, N’Diaye, Alpha T., Morton, Simon A., Chen, Wei, Goh, Johnson, de Jong, Michel P., Feng, Yuan Ping, & Wee, Andrew T.  S. Metallic 1T Phase, 3d1 Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride.  United States.  https://doi.org/10.1021/acsnano.9b05349

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                    Wong, Ping Kwan Johnny, Zhang, Wen, Zhou, Jun, Bussolotti, Fabio, Yin, Xinmao, Zhang, Lei, N’Diaye, Alpha T., Morton, Simon A., Chen, Wei, Goh, Johnson, de Jong, Michel P., Feng, Yuan Ping, and Wee, Andrew T.  S. Wed .  
"Metallic 1T Phase, 3d1 Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride".  United States.  https://doi.org/10.1021/acsnano.9b05349.  https://www.osti.gov/servlets/purl/1619138.

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@article{osti_1619138,

  title        = {Metallic 1T Phase, 3d1 Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride},

  author       = {Wong, Ping Kwan Johnny and Zhang, Wen and Zhou, Jun and Bussolotti, Fabio and Yin, Xinmao and Zhang, Lei and N’Diaye, Alpha T. and Morton, Simon A. and Chen, Wei and Goh, Johnson and de Jong, Michel P. and Feng, Yuan Ping and Wee, Andrew T.  S.},

  abstractNote = {We present a combined experimental and theoretical study of monolayer vanadium ditelluride, VTe2, grown on highly oriented pyrolytic graphite by molecular-beam epitaxy. Using various in situ microscopic and spectroscopic techniques, including scanning tunneling microscopy/spectroscopy, synchrotron X-ray and angle-resolved photoemission, and X-ray absorption, together with theoretical analysis by density functional theory calculations, we demonstrate direct evidence of the metallic 1T phase and 3d1 electronic configuration in monolayer VTe2 that also features a (4 × 4) charge density wave order at low temperatures. In contrast to previous theoretical predictions, our element-specific characterization by X-ray magnetic circular dichroism rules out a ferromagnetic order intrinsic to the monolayer. Our findings provide essential knowledge necessary for understanding this interesting yet less explored metallic monolayer in the emerging family of van der Waals magnets.},

  doi          = {10.1021/acsnano.9b05349},

  journal      = {ACS Nano},

  number       = 11,

  volume       = 13,

  place        = {United States},

  year         = {Wed Nov 06 00:00:00 EST 2019},

  month        = {Wed Nov 06 00:00:00 EST 2019}

}

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Works referenced in this record:

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012

Wang, Qing Hua; Kalantar-Zadeh, Kourosh; Kis, Andras
Nature Nanotechnology, Vol. 7, Issue 11, p. 699-712
DOI: 10.1038/nnano.2012.193

The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
journal, April 2013

Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki
Nature Chemistry, Vol. 5, Issue 4, p. 263-275
DOI: 10.1038/nchem.1589

Two-Dimensional Crystals: Beyond Graphene
journal, March 2011

Neto, A. H. Castro; Novoselov, K.
Materials Express, Vol. 1, Issue 1
DOI: 10.1166/mex.2011.1002

Magnetism in two-dimensional van der Waals materials
journal, October 2018

Burch, Kenneth S.; Mandrus, David; Park, Je-Geun
Nature, Vol. 563, Issue 7729
DOI: 10.1038/s41586-018-0631-z

Two-dimensional magnetic crystals and emergent heterostructure devices
journal, February 2019

Gong, Cheng; Zhang, Xiang
Science, Vol. 363, Issue 6428
DOI: 10.1126/science.aav4450

2D materials and van der Waals heterostructures
journal, July 2016

Novoselov, K. S.; Mishchenko, A.; Carvalho, A.
Science, Vol. 353, Issue 6298
DOI: 10.1126/science.aac9439

Recent development in 2D materials beyond graphene
journal, August 2015

Gupta, Ankur; Sakthivel, Tamilselvan; Seal, Sudipta
Progress in Materials Science, Vol. 73
DOI: 10.1016/j.pmatsci.2015.02.002

Materials for Flexible, Stretchable Electronics: Graphene and 2D Materials
journal, July 2015

Kim, Sang Jin; Choi, Kyoungjun; Lee, Bora
Annual Review of Materials Research, Vol. 45, Issue 1
DOI: 10.1146/annurev-matsci-070214-020901

Hybrid spintronic materials: Growth, structure and properties
journal, January 2019

Liu, Wenqing; Wong, Ping Kwan Johnny; Xu, Yongbing
Progress in Materials Science, Vol. 99
DOI: 10.1016/j.pmatsci.2018.08.001

The crystal structure of vanadium ditelluride, V1+xTe2
journal, July 1984

Bronsema, K. D.; Bus, G. W.; Wiegers, G. A.
Journal of Solid State Chemistry, Vol. 53, Issue 3
DOI: 10.1016/0022-4596(84)90120-8

Transition metal-chalcogen systems IX: The vanadium-tellurium system — phase diagram and magnetic properties
journal, May 1986

Terzieff, Peter; Ipser, Herbert; Wachtel, Ernst
Journal of the Less Common Metals, Vol. 119, Issue 1
DOI: 10.1016/0022-5088(86)90191-8

Phase relationships and properties in the VTe system
journal, October 1984

Ohtani, T.; Onoue, S.; Nakahira, M.
Materials Research Bulletin, Vol. 19, Issue 10
DOI: 10.1016/0025-5408(84)90202-2

Importance of short interlayer Te···Te contacts for the structural distortions and physical properties of CdI2-type layered transition-metal ditellurides
journal, July 1992

Canadell, Enric; Jobic, Ste´phane; Brec, Raymond
Journal of Solid State Chemistry, Vol. 99, Issue 1
DOI: 10.1016/0022-4596(92)90304-E

Analogies between the concepts of molecular chemistry and solid-state physics concerning structural instabilities. Electronic origin of the structural modulations in layered transition metal dichalcogenides
journal, November 1992

Whangbo, Myung Hwan; Canadell, Enric
Journal of the American Chemical Society, Vol. 114, Issue 24
DOI: 10.1021/ja00050a044

Lithium and sodium intercalation into VTe ₂
journal, January 1993

Guzmán, Rafael; Morales, Julián; Tirado, José L.
J. Mater. Chem., Vol. 3, Issue 12
DOI: 10.1039/JM9930301271

Structural, Thermodynamic, and Kinetic Properties of Alkali-Metal Intercalation into Group 5 Metal Ditellurides
journal, June 1995

Guzman, R.; Morales, J.; Tirado, J. L.
Chemistry of Materials, Vol. 7, Issue 6
DOI: 10.1021/cm00054a016

Synthesis of Ultrathin Metallic MTe ₂ (M = V, Nb, Ta) Single-Crystalline Nanoplates
journal, July 2018

Li, Jia; Zhao, Bei; Chen, Peng
Advanced Materials, Vol. 30, Issue 36
DOI: 10.1002/adma.201801043

Charge Density Wave Phase Transitions in Large-Scale Few-Layer 1T-VTe ₂ Grown by Molecular Beam Epitaxy
journal, February 2019

Ma, Xingyuan; Dai, Tian; Dang, Shuai
ACS Applied Materials & Interfaces, Vol. 11, Issue 11
DOI: 10.1021/acsami.8b21442

Newtype single-layer magnetic semiconductor in transition-metal dichalcogenides VX2 (X = S, Se and Te)
journal, September 2016

Fuh, Huei-Ru; Chang, Ching-Ray; Wang, Yin-Kuo
Scientific Reports, Vol. 6, Issue 1
DOI: 10.1038/srep32625

Evidence of the Existence of Magnetism in Pristine VX ₂ Monolayers (X = S, Se) and Their Strain-Induced Tunable Magnetic Properties
journal, January 2012

Ma, Yandong; Dai, Ying; Guo, Meng
ACS Nano, Vol. 6, Issue 2
DOI: 10.1021/nn204667z

Electronic and Magnetic Properties of Vanadium Dichalcogenides Monolayers Tuned by Hydrogenation
journal, June 2014

Pan, Hui
The Journal of Physical Chemistry C, Vol. 118, Issue 24
DOI: 10.1021/jp503030b

Evidence of Spin Frustration in a Vanadium Diselenide Monolayer Magnet
journal, April 2019

Wong, Ping Kwan Johnny; Zhang, Wen; Bussolotti, Fabio
Advanced Materials, Vol. 31, Issue 23
DOI: 10.1002/adma.201901185

Absence of nesting in the charge-density-wave system $1 {T-VS}_{2}$ as seen by photoelectron spectroscopy
journal, August 2010

Mulazzi, M.; Chainani, A.; Katayama, N.
Physical Review B, Vol. 82, Issue 7
DOI: 10.1103/PhysRevB.82.075130

Trace element content and magnetic properties of commercial HOPG samples studied by ion beam microscopy and SQUID magnetometry
journal, October 2014

Spemann, D.; Esquinazi, P.; Setzer, A.
AIP Advances, Vol. 4, Issue 10
DOI: 10.1063/1.4900613

Combinatorial synthesis and characterization of magnetic FexAl1−xNyO1−y thin films
journal, July 2008

Guan, Yingfeng; Wang, Xingwu; Liu, Yuandan
Thin Solid Films, Vol. 516, Issue 18
DOI: 10.1016/j.tsf.2007.10.122

Importance of Paramagnetic Background Subtraction for Determining the Magnetic Moment in Epitaxially Grown Ultrathin van der Waals Magnets
journal, January 2018

O'Hara, Dante Jamal; Zhu, Tiancong; Kawakami, Roland Kenji
IEEE Magnetics Letters, Vol. 9
DOI: 10.1109/LMAG.2018.2867339

Limitations of measuring small magnetic signals of samples deposited on a diamagnetic substrate
journal, December 2008

Ney, A.; Kammermeier, T.; Ney, V.
Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 23
DOI: 10.1016/j.jmmm.2008.07.008

Magnetic Transition in Monolayer VSe ₂ via Interface Hybridization
journal, July 2019

Zhang, Wen; Zhang, Lei; Wong, Ping Kwan Johnny
ACS Nano, Vol. 13, Issue 8
DOI: 10.1021/acsnano.9b02996

Charge Density Wave State Suppresses Ferromagnetic Ordering in VSe ₂ Monolayers
journal, May 2019

Coelho, Paula Mariel; Nguyen Cong, Kien; Bonilla, Manuel
The Journal of Physical Chemistry C, Vol. 123, Issue 22
DOI: 10.1021/acs.jpcc.9b04281

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

Kresse, G.; Furthmüller, J.
Computational Materials Science, Vol. 6, Issue 1, p. 15-50
DOI: 10.1016/0927-0256(96)00008-0

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Van der Waals Density Functional for General Geometries
journal, June 2004

Dion, M.; Rydberg, H.; Schröder, E.
Physical Review Letters, Vol. 92, Issue 24
DOI: 10.1103/PhysRevLett.92.246401

Efficient Implementation of a van der Waals Density Functional: Application to Double-Wall Carbon Nanotubes
journal, August 2009

Román-Pérez, Guillermo; Soler, José M.
Physical Review Letters, Vol. 103, Issue 9
DOI: 10.1103/PhysRevLett.103.096102

Chemical accuracy for the van der Waals density functional
journal, December 2009

Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
Journal of Physics: Condensed Matter, Vol. 22, Issue 2
DOI: 10.1088/0953-8984/22/2/022201

Van der Waals density functionals applied to solids
journal, May 2011

Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
Physical Review B, Vol. 83, Issue 19
DOI: 10.1103/PhysRevB.83.195131

Works referencing / citing this record:

Real-space investigation of the charge density wave in ${VTe}_{2}$ monolayer with broken rotational and mirror symmetries
journal, January 2020

Miao, Guangyao; Xue, Siwei; Li, Bo
Physical Review B, Vol. 101, Issue 3
DOI: 10.1103/physrevb.101.035407

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Title: Metallic 1T Phase, 3d1 Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride

Abstract

Citation Formats

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides journal, November 2012

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Two-Dimensional Crystals: Beyond Graphene journal, March 2011

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The crystal structure of vanadium ditelluride, V1+xTe2 journal, July 1984

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Phase relationships and properties in the VTe system journal, October 1984

Importance of short interlayer Te···Te contacts for the structural distortions and physical properties of CdI2-type layered transition-metal ditellurides journal, July 1992

Analogies between the concepts of molecular chemistry and solid-state physics concerning structural instabilities. Electronic origin of the structural modulations in layered transition metal dichalcogenides journal, November 1992

Lithium and sodium intercalation into VTe 2 journal, January 1993

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Title: Metallic 1T Phase, 3d¹ Electronic Configuration and Charge Density Wave Order in Molecular Beam Epitaxy Grown Monolayer Vanadium Ditelluride

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
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The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
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Two-Dimensional Crystals: Beyond Graphene
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Magnetism in two-dimensional van der Waals materials
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Transition metal-chalcogen systems IX: The vanadium-tellurium system — phase diagram and magnetic properties
journal, May 1986

Phase relationships and properties in the VTe system
journal, October 1984

Importance of short interlayer Te···Te contacts for the structural distortions and physical properties of CdI2-type layered transition-metal ditellurides
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Analogies between the concepts of molecular chemistry and solid-state physics concerning structural instabilities. Electronic origin of the structural modulations in layered transition metal dichalcogenides
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Evidence of the Existence of Magnetism in Pristine VX ₂ Monolayers (X = S, Se) and Their Strain-Induced Tunable Magnetic Properties
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