Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage
Abstract
The incorporation of supramolecular macrocycles into porous organic polymers may endow the material with enhanced uptake of specific guests through host–guest interactions. Here we report a solvent and catalyst-free mechanochemical synthesis of pillar[5]quinone (P5Q) derived multi-microporous organic polymers with hydrophenazine linkages (MHP-P5Q), which show a unique 3-step N2 adsorption isotherm. In comparison with analogous microporous hydrophenazine-linked organic polymers (MHPs) obtained using simple twofold benzoquinones, MHP-P5Q is demonstrated to have a superior performance in radioactive iodomethane (CH3I) capture and storage. Mechanistic studies show that the rigid pillar[5]arene cavity has additional binding sites though host–guest interactions as well as the halogen bond (-I···N = C-) and chemical adsorption in the multi-microporous MHP-P5Q mainly account for the rapid and high-capacity adsorption and long-term storage of CH3I.
- Authors:
-
[3];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Zheijiang Univ., Hangzhou (China)
- Univ. of California, Riverside, CA (United States)
- Univ. of Tennessee, Knoxville, TN (United States); Zheijiang Univ., Hangzhou (China)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
- OSTI Identifier:
- 1616810
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 1; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; polymer synthesis; polymers; solid-phase synthesis; supramolecular polymers
Citation Formats
Jie, Kecheng, Zhou, Yujuan, Sun, Qi, Li, Bo, Zhao, Run, Jiang, De-en, Guo, Wei, Chen, Hao, Yang, Zhenzhen, Huang, Feihe, and Dai, Sheng. Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage. United States: N. p., 2020.
Web. doi:10.1038/s41467-020-14892-y.
Jie, Kecheng, Zhou, Yujuan, Sun, Qi, Li, Bo, Zhao, Run, Jiang, De-en, Guo, Wei, Chen, Hao, Yang, Zhenzhen, Huang, Feihe, & Dai, Sheng. Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage. United States. https://doi.org/10.1038/s41467-020-14892-y
Jie, Kecheng, Zhou, Yujuan, Sun, Qi, Li, Bo, Zhao, Run, Jiang, De-en, Guo, Wei, Chen, Hao, Yang, Zhenzhen, Huang, Feihe, and Dai, Sheng. Thu .
"Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage". United States. https://doi.org/10.1038/s41467-020-14892-y. https://www.osti.gov/servlets/purl/1616810.
@article{osti_1616810,
title = {Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage},
author = {Jie, Kecheng and Zhou, Yujuan and Sun, Qi and Li, Bo and Zhao, Run and Jiang, De-en and Guo, Wei and Chen, Hao and Yang, Zhenzhen and Huang, Feihe and Dai, Sheng},
abstractNote = {The incorporation of supramolecular macrocycles into porous organic polymers may endow the material with enhanced uptake of specific guests through host–guest interactions. Here we report a solvent and catalyst-free mechanochemical synthesis of pillar[5]quinone (P5Q) derived multi-microporous organic polymers with hydrophenazine linkages (MHP-P5Q), which show a unique 3-step N2 adsorption isotherm. In comparison with analogous microporous hydrophenazine-linked organic polymers (MHPs) obtained using simple twofold benzoquinones, MHP-P5Q is demonstrated to have a superior performance in radioactive iodomethane (CH3I) capture and storage. Mechanistic studies show that the rigid pillar[5]arene cavity has additional binding sites though host–guest interactions as well as the halogen bond (-I···N = C-) and chemical adsorption in the multi-microporous MHP-P5Q mainly account for the rapid and high-capacity adsorption and long-term storage of CH3I.},
doi = {10.1038/s41467-020-14892-y},
journal = {Nature Communications},
number = 1,
volume = 11,
place = {United States},
year = {Thu Feb 27 00:00:00 EST 2020},
month = {Thu Feb 27 00:00:00 EST 2020}
}
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Rapid removal of organic micropollutants from water by a porous β-cyclodextrin polymer
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Porous organic molecules
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- Holst, James R.; Trewin, Abbie; Cooper, Andrew I.
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Capture of organic iodides from nuclear waste by metal-organic framework-based molecular traps
journal, September 2017
- Li, Baiyan; Dong, Xinglong; Wang, Hao
- Nature Communications, Vol. 8, Issue 1
Gas storage in porous aromatic frameworks (PAFs)
journal, January 2011
- Ben, Teng; Pei, Cuiying; Zhang, Daliang
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Covalent organic frameworks
journal, January 2012
- Feng, Xiao; Ding, Xuesong; Jiang, Donglin
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Conjugated microporous polymers: design, synthesis and application
journal, January 2013
- Xu, Yanhong; Jin, Shangbin; Xu, Hong
- Chemical Society Reviews, Vol. 42, Issue 20
Bottom-up construction of a superstructure in a porous uranium-organic crystal
journal, April 2017
- Li, Peng; Vermeulen, Nicolaas A.; Malliakas, Christos D.
- Science, Vol. 356, Issue 6338