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Title: Electrically Conductive Metal–Organic Frameworks

Journal Article · · Chemical Reviews

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); US Army Research Office (ARO); National Science Foundation (NSF)
Grant/Contract Number:
SC0018235
OSTI ID:
1615048
Journal Information:
Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 16 Vol. 120; ISSN 0009-2665
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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Unpaired 3d Electrons on Atomically Dispersed Cobalt Centres in Coordination Polymers Regulate both Oxygen Reduction Reaction (ORR) Activity and Selectivity for Use in Zinc–Air Batteries journal November 2019
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Progressive Structure Designing and Property Tuning of Manganese(II) Coordination Polymers with the Tetra(4-pyridyl)-tetrathiafulvalene Ligand journal March 2019
Direct Self-Assembly of Conductive Nanorods of Metal–Organic Frameworks into Chemiresistive Devices on Shrinkable Polymer Films journal July 2016
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Insight into Understanding Dielectric Behavior of a Zn-MOF Using Variable-Temperature Crystal Structures, Electrical Conductance, and Solid-State 13 C NMR Spectra journal October 2016
Electronic Conductivity in a Porous Vanadyl Prussian Blue Analogue upon Air Exposure journal October 2017
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Set of Multifunctional Azo Functionalized Semiconducting Cd(II)-MOFs Showing Photoswitching Property and Selective CO 2 Adsorption journal December 2017
Redox Activities of Metal–Organic Frameworks Incorporating Rare-Earth Metal Chains and Tetrathiafulvalene Linkers journal February 2019
Concomitant Use of Tetrathiafulvalene and 7,7,8,8-Tetracyanoquinodimethane within the Skeletons of Metal–Organic Frameworks: Structures, Magnetism, and Electrochemistry journal June 2019
Iodine Adsorption in a Redox-Active Metal–Organic Framework: Electrical Conductivity Induced by Host−Guest Charge-Transfer journal September 2019
Bis(dithioline)-Based Metal–Organic Frameworks with Superior Electronic and Magnetic Properties: Spin Frustration to Spintronics and Gas Sensing journal December 2016
Increase in Electrical Conductivity of MOF to Billion-Fold upon Filling the Nanochannels with Conducting Polymer journal July 2016
Unraveling the Semiconducting/Metallic Discrepancy in Ni 3 (HITP) 2 journal January 2018
Highly Conductive 2D Metal–Organic Framework Thin Film Fabricated by Liquid–Liquid Interfacial Reaction Using One-Pot-Synthesized Benzenehexathiol journal December 2018
Electric Transport Properties of Surface-Anchored Metal–Organic Frameworks and the Effect of Ferrocene Loading journal April 2015
Charge Transfer-Induced Molecular Hole Doping into Thin Film of Metal–Organic Frameworks journal August 2015
Semiconductor Behavior of a Three-Dimensional Strontium-Based Metal–Organic Framework journal October 2015
Tunable Electrical Conductivity and Magnetic Property of the Two Dimensional Metal Organic Framework [Cu(TPyP)Cu 2 (O 2 CCH 3 ) 4 ] journal June 2016
Novel Solid-State Solar Cell Based on Hole-Conducting MOF-Sensitizer Demonstrating Power Conversion Efficiency of 2.1% journal April 2017
High-κ Samarium-Based Metal–Organic Framework for Gate Dielectric Applications journal June 2017
Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal–Organic Frameworks journal July 2017
Conductive Copper Benzenehexathiol Coordination Polymer as a Hydrogen Evolution Catalyst journal November 2017
Evaluation of the H 2 Evolving Activity of Benzenehexathiolate Coordination Frameworks and the Effect of Film Thickness on H 2 Production journal January 2018
Inorganic “Conductive Glass” Approach to Rendering Mesoporous Metal–Organic Frameworks Electronically Conductive and Chemically Responsive journal August 2018
Surface Morphology and Electrical Properties of Cu 3 BTC 2 Thin Films Before and After Reaction with TCNQ journal October 2018
Field-Effect Transistor Based on an in Situ Grown Metal–Organic Framework Film as a Liquid-Gated Sensing Device journal September 2019
Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research journal January 2019
Chemiresistive Sensing of Ambient CO 2 by an Autogenously Hydrated Cu 3 (hexaiminobenzene) 2 Framework journal June 2019
Single Crystals of Electrically Conductive Two-Dimensional Metal–Organic Frameworks: Structural and Electrical Transport Properties journal December 2019
Electrically Driven White Light Emission from Intrinsic Metal–Organic Framework journal August 2016
Superexchange Charge Transport in Loaded Metal Organic Frameworks journal July 2016
Oriented Thin Films of Electroactive Triphenylene Catecholate-Based Two-Dimensional Metal–Organic Frameworks journal May 2019
Coordination Polymers of 2,5-Dihydroxybenzoquinone and Chloranilic Acid with the (10,3)- a Topology journal July 2011
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New Porous Crystals of Extended Metal-Catecholates journal August 2012
Hydrocarbon Separations in Metal–Organic Frameworks journal September 2013
Conducting Metal Dithiolene Complexes:  Structural and Electronic Properties journal November 2004
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Metal Azolate Frameworks: From Crystal Engineering to Functional Materials journal September 2011
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Noninnocence in Metal Complexes: A Dithiolene Dawn journal October 2011
Electroconductive Porous Coordination Polymer Cu[Cu(pdt) 2 ] Composed of Donor and Acceptor Building Units journal October 2009
New Insight into the Nature of Cu(TCNQ):  Solution Routes to Two Distinct Polymorphs and Their Relationship to Crystalline Films That Display Bistable Switching Behavior journal January 1999
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A Diamondoid Network of Tetrakis(acetamidato)dirhodium in Mixed Oxidation States Linked by μ 4 -Iodide Having a 10 5 Enhancement of Its Electrical Conductivity by Water Molecules of Hydration journal October 2004
Metal−Organic Thin-Film Transistor (MOTFT) Based on a Bis( o -diiminobenzosemiquinonate) Nickel(II) Complex journal July 2005
Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2−) and the Significantly Stronger Coupling Chloranilate(•3−) Radical Trianion journal February 2007
Semiconducting Lead−Sulfur−Organic Network Solids journal January 2008
Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites journal September 2011
Iodine Release and Recovery, Influence of Polyiodide Anions on Electrical Conductivity and Nonlinear Optical Activity in an Interdigitated and Interpenetrated Bipillared-Bilayer Metal–Organic Framework journal March 2012
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework journal July 2012
π-Conjugated Nickel Bis(dithiolene) Complex Nanosheet journal February 2013
Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) Chains and High Intrinsic Charge Mobility journal May 2013
π-Electron Conjugation in Two Dimensions journal October 2013
Solvothermal Preparation of an Electrocatalytic Metalloporphyrin MOF Thin Film and its Redox Hopping Charge-Transfer Mechanism journal January 2014
Electronic Chemical Potentials of Porous Metal–Organic Frameworks journal February 2014
Nanoporous Cobalt(II) MOF Exhibiting Four Magnetic Ground States and Changes in Gas Sorption upon Post-Synthetic Modification journal March 2014
High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue journal April 2014
Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π-Nanosheet: A Potential Organic Two-Dimensional Topological Insulator journal October 2014
Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water journal December 2014
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks journal January 2015
Enhanced H2 Adsorption in Isostructural Metal−Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions journal November 2008
Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity journal March 2010
Million-Fold Electrical Conductivity Enhancement in Fe 2 (DEBDC) versus Mn 2 (DEBDC) (E = S, O) journal May 2015
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks journal October 2015
Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal–Organic Framework journal December 2015
Selective Formation of Conductive Network by Radical-Induced Oxidation journal February 2016
Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity journal August 2016
High and Reversible Ammonia Uptake in Mesoporous Azolate Metal–Organic Frameworks with Open Mn, Co, and Ni Sites journal July 2016
Porous Field-Effect Transistors Based on a Semiconductive Metal–Organic Framework journal November 2016
Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd 2 (TTFTB) as a Case Study journal October 2016
Hexaaminobenzene as a building block for a Family of 2D Coordination Polymers journal December 2016
The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels journal March 2017
2D Conductive Iron-Quinoid Magnets Ordering up to T c = 105 K via Heterogenous Redox Chemistry journal March 2017
Electronic Properties of Bimetallic Metal–Organic Frameworks (MOFs): Tailoring the Density of Electronic States through MOF Modularity journal March 2017
Reversible Capture and Release of Cl 2 and Br 2 with a Redox-Active Metal–Organic Framework journal April 2017
Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework journal July 2017
Signature of Metallic Behavior in the Metal–Organic Frameworks M 3 (hexaiminobenzene) 2 (M = Ni, Cu) journal September 2017
Porous Scaffolds for Electrochemically Controlled Reversible Capture and Release of Ethylene journal November 2017
Self-Organized Frameworks on Textiles (SOFT): Conductive Fabrics for Simultaneous Sensing, Capture, and Filtration of Gases journal October 2017
Control of Electronic Structure and Conductivity in Two-Dimensional Metal–Semiquinoid Frameworks of Titanium, Vanadium, and Chromium journal February 2018
Increased Electrical Conductivity in a Mesoporous Metal–Organic Framework Featuring Metallacarboranes Guests journal February 2018
Tunable Mixed-Valence Doping toward Record Electrical Conductivity in a Three-Dimensional Metal–Organic Framework journal May 2018
Charge Delocalization and Bulk Electronic Conductivity in the Mixed-Valence Metal–Organic Framework Fe(1,2,3-triazolate) 2 (BF 4 ) x journal June 2018
Stabilization of Hexaaminobenzene in a 2D Conductive Metal–Organic Framework for High Power Sodium Storage journal July 2018
Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal–Organic Framework journal September 2018
Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver–Sulfur Networks journal September 2018
Welding Metallophthalocyanines into Bimetallic Molecular Meshes for Ultrasensitive, Low-Power Chemiresistive Detection of Gases journal December 2018
Connecting Wires: Photoinduced Electronic Structure Modulation in Metal–Organic Frameworks journal March 2019
Chemiresistive Detection of Gaseous Hydrocarbons and Interrogation of Charge Transport in Cu[Ni(2,3-pyrazinedithiolate) 2 ] by Gas Adsorption journal March 2019
Direct Radiation Detection by a Semiconductive Metal–Organic Framework journal May 2019
Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers journal April 2019
Metal–Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy journal June 2019
Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory” journal June 2019
Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal–Organic Frameworks journal May 2019
Room Temperature Metallic Conductivity in a Metal–Organic Framework Induced by Oxidation journal September 2019
Anisotropic Redox Conductivity within a Metal–Organic Framework Material journal October 2019
Partial Oxidation-Induced Electrical Conductivity and Paramagnetism in a Ni(II) Tetraaza[14]annulene-Linked Metal Organic Framework journal September 2019
Three-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction journal October 2019
Influence of the Oxidation State of the Metal Center on the Flexibility and Adsorption Properties of a Porous Metal Organic Framework: MIL-47(V) journal September 2011
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Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene journal March 2013
A spin transition mechanism for cooperative adsorption in metal–organic frameworks journal September 2017
Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2 journal March 2016
Ultrathin metal-organic framework array for efficient electrocatalytic water splitting journal June 2017
A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour journal June 2015
Conductive MOF electrodes for stable supercapacitors with high areal capacitance journal October 2016
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Integration of a (–Cu–S–)n plane in a metal–organic framework affords high electrical conductivity journal April 2019
A semiconducting layered metal-organic framework magnet journal July 2019
Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries journal October 2019
Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry journal September 2018
Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks journal November 2019
Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance journal January 2018
Electron delocalization and charge mobility as a function of reduction in a metal–organic framework journal June 2018
High-mobility band-like charge transport in a semiconducting two-dimensional metal–organic framework journal October 2018
Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture journal September 2019
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A europium( iii ) based metal–organic framework: bifunctional properties related to sensing and electronic conductivity journal January 2014
An electroactive porous network from covalent metal–dithiolene links journal January 2014
Cation exchange at the secondary building units of metal–organic frameworks journal January 2014
Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement journal January 2014
Electrical conductivity and electroluminescence of a new anthracene-based metal–organic framework with π-conjugated zigzag chains journal January 2016
A Cd( ii ) based metal organic framework: a photosensitive current conductor journal January 2015
A cobalt( ii ) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior journal January 2016
Facile interfacial charge transfer across hole doped cobalt-based MOFs/TiO 2 nano-hybrids making MOFs light harvesting active layers in solar cells journal January 2015
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Multifunctional mixed ligand metal organic frameworks: X-ray structure, adsorption, luminescence and electrical conductivity with theoretical correlation journal January 2016
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An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors journal January 2017
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Supramolecular aggregation of a redox-active copper-naphthalenediimide network with intrinsic electron conduction journal January 2019
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Prospects for electroactive and conducting framework materials
  • Murase, Ryuichi; Ding, Bowen; Gu, Qinyi
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2149 https://doi.org/10.1098/rsta.2018.0226
journal May 2019
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