Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite
Abstract
We present a comprehensive study on the magnetic structure, dynamics, and phase evolution in the single phase double perovskite La2CoMnO6. The mixed valence state due to oxygen deficiency is verified by x-ray photoelectron spectroscopy and confirms a double ferromagnetic transition observed in dc magnetization. Neutron diffraction reveals that the magnetic structure is dominated by long-range ferromagnetic ordering, which is further corroborated by a critical exponents analysis of the paramagnetic to ferromagnetic phase transition. An analysis of the magnetization dynamics by means of linear and nonlinear ac magnetic susceptibilities marks the presence of two distinct cluster-glass-like states that emerge at low temperatures. The isothermal entropy change as a function of temperature and magnetic field (H) is exploited to investigate the mechanism of stabilization of the magnetic phases across the H – T phase diagram. In the regime of the phase diagram where thermal energy is sufficiently low, regions of competing interactions due to local disorder become stabilized and display glasslike dynamics. The freezing mechanism of clusters is illustrated using a unique probe of transverse susceptibility that isolates the effects of the local anisotropy of the spin clusters. Here, the results are summarized in a H – T phase diagram of La2CoMnO6more »
- Authors:
-
- Univ. of South Florida, Tampa, FL (United States)
- Duy Tan Univ., Da Nang (Vietnam)
- Joint Inst. for Nuclear Research, Dubna (Russia)
- Yale Univ., New Haven, CT (United States)
- Publication Date:
- Research Org.:
- Univ. of South Florida, Tampa, FL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; Vietnam National Foundation for Science and Technology Development (NAFOSTED)
- OSTI Identifier:
- 1609900
- Alternate Identifier(s):
- OSTI ID: 1504549
- Grant/Contract Number:
- FG02-07ER46438; 103.02-2017.364
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 99; Journal Issue: 10; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; materials science; physics; magnetic anisotropy; magnetic interactions; magnetic phase transitions; magnetic susceptibility; magnetic nanoparticles; polycrystalline materials; magnetization measurements; susceptibility measurements
Citation Formats
Madhogaria, R. P., Das, R., Clements, E. M., Kalappattil, V., Phan, M. H., Srikanth, H., Dang, N. T., Kozlenko, D. P., and Bingham, N. S. Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite La2CoMnO6. United States: N. p., 2019.
Web. doi:10.1103/physrevb.99.104436.
Madhogaria, R. P., Das, R., Clements, E. M., Kalappattil, V., Phan, M. H., Srikanth, H., Dang, N. T., Kozlenko, D. P., & Bingham, N. S. Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite La2CoMnO6. United States. https://doi.org/10.1103/physrevb.99.104436
Madhogaria, R. P., Das, R., Clements, E. M., Kalappattil, V., Phan, M. H., Srikanth, H., Dang, N. T., Kozlenko, D. P., and Bingham, N. S. Fri .
"Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite La2CoMnO6". United States. https://doi.org/10.1103/physrevb.99.104436. https://www.osti.gov/servlets/purl/1609900.
@article{osti_1609900,
title = {Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite La2CoMnO6},
author = {Madhogaria, R. P. and Das, R. and Clements, E. M. and Kalappattil, V. and Phan, M. H. and Srikanth, H. and Dang, N. T. and Kozlenko, D. P. and Bingham, N. S.},
abstractNote = {We present a comprehensive study on the magnetic structure, dynamics, and phase evolution in the single phase double perovskite La2CoMnO6. The mixed valence state due to oxygen deficiency is verified by x-ray photoelectron spectroscopy and confirms a double ferromagnetic transition observed in dc magnetization. Neutron diffraction reveals that the magnetic structure is dominated by long-range ferromagnetic ordering, which is further corroborated by a critical exponents analysis of the paramagnetic to ferromagnetic phase transition. An analysis of the magnetization dynamics by means of linear and nonlinear ac magnetic susceptibilities marks the presence of two distinct cluster-glass-like states that emerge at low temperatures. The isothermal entropy change as a function of temperature and magnetic field (H) is exploited to investigate the mechanism of stabilization of the magnetic phases across the H – T phase diagram. In the regime of the phase diagram where thermal energy is sufficiently low, regions of competing interactions due to local disorder become stabilized and display glasslike dynamics. The freezing mechanism of clusters is illustrated using a unique probe of transverse susceptibility that isolates the effects of the local anisotropy of the spin clusters. Here, the results are summarized in a H – T phase diagram of La2CoMnO6 from these data.},
doi = {10.1103/physrevb.99.104436},
journal = {Physical Review B},
number = 10,
volume = 99,
place = {United States},
year = {Fri Mar 29 00:00:00 EDT 2019},
month = {Fri Mar 29 00:00:00 EDT 2019}
}
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Cited by: 48 works
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Figures / Tables:
Table 1: Refined structural parameters of LCMO at room temperature.
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Works referencing / citing this record:
The superior NO oxidation activity over La 2 CoMnO 6 double perovskite to that of La 2 GaMnO 6 : effects of magnetic Co 3+ and nonmagnetic Ga 3+
journal, January 2019
- Wang, Qianqian; Ma, Liping; Wang, Lichun
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